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    • 6. 发明授权
    • Sulfo containing monoazo dyestuffs containing a benzthiazole diazo
moiety and an N-benzylamino anilino coupling component
    • 含有苯并噻唑重氮部分的含磺酸单偶氮染料和N-苄基氨基苯胺基偶联组分
    • US4041024A
    • 1977-08-09
    • US294526
    • 1972-10-03
    • Gerhard WolfrumHans-Gunter Otten
    • Gerhard WolfrumHans-Gunter Otten
    • C09B29/00C09B29/08C09B35/06C09B35/22D06P1/06D06P3/24
    • C09B29/0088C09B29/08C09B29/0803
    • Azo dyestuffs of formula ##STR1## wherein R.sub.1 denotes hydrogen, C.sub.1 --C.sub.4 alkyl, Cl, Br, --OCH.sub.3, --OC.sub.2 H.sub.5, --NO.sub.2, --CN, --SCN, --SO.sub.2 CH.sub.3, --SO.sub.2 C.sub.2 H.sub.5, --SO.sub.3 H, --SO.sub.2 NX.sub.2 (X=H or C.sub.m H.sub.2m.sub.+1 with m = 1-4) or --COOC.sub.n H.sub.2n.sub.+1 (n = 0-4);R.sub.2 represents hydrogen, CH.sub.3, C.sub.2 H.sub.5, --OCH.sub.3, --OC.sub.2 H.sub.5, Cl, Br, or the grouping --NHCOC.sub.n H.sub.2n.sub.+1 (n = 0-4);R.sub.3 denotes hydrogen, OCH.sub.3, OC.sub.2 H.sub.5, CH.sub.3 or C.sub.2 H.sub.5 ;R.sub.4 represents C.sub.n H.sub.2n.sub.+1 (n = o-4), or CH.sub.2 CH.sub.2 SO.sub.3 H;R.sub.5 represents hydrogen or a sulphonic acid group, and p is 1 or 2,With only one of the residues R.sub.1, R.sub.4 and R.sub.5 representing or containing a sulphonic acid group. The dyestuffs are suitable for dyeing nitrogen-containing materials especially for dyeing synthetic polyamide and polyurethane fibers. The dyestuffs are very well absorbed on the polyamide fibers both from an acid dyebath and from a neutral dyebath. In one example synthetic polyamide fibers are dyed in clear shades having good to very good fastness properties.
    • 其中R1表示氢,C1-C4烷基,C1,Br,-OCH3,-OC2H5,-NO2,-CN,-SCN,-SO2CH3,-SO2C2H5,-SO3H,-SO2NX2(X = H或CmH2m + 1,m = 1-4)或-COOCnH2n + 1(n = 0-4); R 2表示氢,CH 3,C 2 H 5,-OCH 3,-OC 2 H 5,Cl,Br或分组-NHCOC n H 2n + 1(n = 0-4); R3表示氢,OCH3,OC2H5,CH3或C2H5; R4表示C n H 2n + 1(n = o-4)或CH 2 CH 2 SO 3 H; R5代表氢或磺酸基团,p是1或2,只有一个表示或含有磺酸基团的残基R1,R4和R5。 该染料适用于染色含氮材料,特别是染色合成聚酰胺和聚氨酯纤维。 染料在酸性染浴和中性染浴上均聚酰胺纤维非常好地被吸收。 在一个实例中,合成聚酰胺纤维以清晰的色调染色,具有良好至非常好的牢度性能。
    • 8. 发明授权
    • Water-soluble phenylazoaminonaphthol sulphonic acid dyestuffs
    • 水溶性苯偶氮基萘酚磺酸染料
    • US4218373A
    • 1980-08-19
    • US917572
    • 1978-06-21
    • Gerhard WolfrumErich KlaukeHans-Gunter Otten
    • Gerhard WolfrumErich KlaukeHans-Gunter Otten
    • C09B29/01C09B29/30C09B43/24D06P1/06D06P1/39D06P3/24
    • C09B29/0003C09B29/30C09B43/24
    • A water-soluble monoazo dyestuff which, in the form of the free acid, corresponds to the formula ##STR1## wherein R.sub.1 denotes alkyl which can be mono-substituted by chlorine, hydroxyl, C.sub.1 to C.sub.4 alkoxy, cyano, phenyl or tolyl, cyclohexyl which can be optionally substituted by C.sub.1 -C.sub.4 alkyl, phenyl, C.sub.1 -C.sub.4 -alkyl phenyl, chlorophenyl, bromophenyl, trifluoromethylphenyl or naphthyl, alkenyl or benzenesulphonyl which can be substituted by fluorine, chlorine, bromine, trifluoromethyl, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sub.2 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl which can be substituted by hydroxyl, cyano, formylamino, C.sub.1 -C.sub.4 alkylcarbonylamino or benzoylamino which in turn can be substituted by methyl, chlorine, bromine or trifluoromethyl; cyclohexyl or phenyl which can be substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 -alkoxy, chlorine, bromine or trifluoromethyl andR.sub.3 denotes hydrogen or C.sub.1 -C.sub.4 -alkyl and a process for the preparation of such water-soluble mono-azo dyestuff. The dyestuffs according to the invention are suitable for dyeing natural and synthetic fibre materials, for example for dyeing wool or polyamide fibres, in level, deep red to violet shades with very good fastness to light, wet processing and perspiration.
    • 游离酸形式的水溶性单偶氮染料对应于下式:其中R 1表示可以被氯,羟基,C 1至C 4烷氧基,氰基,苯基或甲苯基, 苯基,C 1 -C 4烷基苯基,氯苯基,溴苯基,三氟甲基苯基或萘基,可被氟,氯,溴,三氟甲基,C 1 -C 4 - 烷基取代的烯基或苯磺酰基, C 1 -C 4烷氧基,R 2表示氢,可被羟基,氰基,甲酰氨基,C 1 -C 4烷基羰基氨基或苯甲酰基氨基取代的C 1 -C 4 - 烷基,其又可被甲基,氯,溴或三氟甲基取代; 可被C 1 -C 4烷基,C 1 -C 4 - 烷氧基,氯,溴或三氟甲基取代的环己基或苯基,R 3表示氢或C 1 -C 4 - 烷基,以及制备这种水溶性单偶氮染料的方法。 根据本发明的染料适用于染色天然和合成纤维材料,例如染色羊毛或聚酰胺纤维,水平,深红色至紫色色调具有非常好的耐光牢度,湿润加工和出汗。