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1. 发明授权

US06955728B1 Acyloxy silane treatments for metals 有权
标题翻译：金属氧化硅烷处理
公开(公告)号：US06955728B1
公开(公告)日：2005-10-18
申请号：US10031731
申请日：2000-07-19
申请人： Wim J. van Ooij , Danqing Zhu
发明人： Wim J. van Ooij , Danqing Zhu
IPC分类号： B05D7/24 , B05D7/14 , C09D183/07 , C09D183/08 , C23C22/48 , C23C22/53 , C23C22/56 , C23C22/60 , C23C22/68 , C23C26/00 , C23C28/00 , B05D3/00
CPC分类号： C23C28/00 , C23C22/48 , C23C22/53 , C23C22/56 , C23C22/60 , C23C22/68 , C23C2222/20 , Y10T428/12569 , Y10T428/12799 , Y10T428/31663
摘要： A method of treating a metal surface by application of a solution containing at least one acyloxy silane and at least one basic compound. A composition having at least one acyloxy silane and at least one basic compound is also provided, along with a silane coated metal surface.
摘要翻译：一种通过使用含有至少一种酰氧基硅烷和至少一种碱性化合物的溶液处理金属表面的方法。还提供了具有至少一个酰氧基硅烷和至少一种碱性化合物的组合物以及硅烷涂覆的金属表面。

2. 发明申请

US20080081120A1 Superprimer 审中-公开
标题翻译：超级。
公开(公告)号：US20080081120A1
公开(公告)日：2008-04-03
申请号：US11821089
申请日：2007-06-21
申请人： Wim Van Ooij , Trilok Mugada , Karthik Suryanarayanan , Anuj Seth , Danqing Zhu , Lin Yang
发明人： Wim Van Ooij , Trilok Mugada , Karthik Suryanarayanan , Anuj Seth , Danqing Zhu , Lin Yang
IPC分类号： C08K3/08 , B05D3/02
CPC分类号： C09D5/106 , C09D5/002 , C09D5/08 , C23C2222/20
摘要： A composition capable of coating a substrate and curing to provide a hydrophobic film inhibiting corrosion, the composition comprising: (a) a bis-silane comprising between about 0.5 weight percent to about 50 weight percent of the composition; and (b) a water soluble or dispersible polymer comprising between 10 weight percent to about 80 weight percent of the composition. A further exemplary superprimer in accordance with the instant invention includes a composition capable of coating a substrate and curing to provide a hydrophobic film inhibiting corrosion, the composition comprising: (a) a mixture of silanes; (b) a dispersible or soluble resin; and (c) an aqueous or non-aqueous solvent. Moreover, the invention includes the aforementioned superprimer composition, wherein the mixture of silanes includes at least one of a bis-sulfur silane, a bis-benzene silane, a bis-alkane silane, a bis-alkene silane, and a bis-amino silane.
摘要翻译：一种能够涂覆底物并固化以提供疏水膜抑制腐蚀的组合物，所述组合物包含：（a）包含组合物的约0.5重量％至约50重量％的双硅烷; 和（b）包含组合物的10重量％至约80重量％的水溶性或可分散的聚合物。根据本发明的另一示例性超级引物包括能够涂覆底物并固化以提供疏水膜抑制腐蚀的组合物，所述组合物包含：（a）硅烷的混合物; （b）可分散或可溶的树脂; 和（c）水性或非水性溶剂。此外，本发明包括上述超级引导剂组合物，其中硅烷混合物包括双 - 硫硅烷，双 - 苯硅烷，双 - 烷烃硅烷，双 - 烯烃硅烷和双 - 氨基硅烷中的至少一种。

3. 发明授权

US08597482B2 Process for depositing rinsable silsesquioxane films on metals 有权
标题翻译：在金属上沉积可冲洗的倍半硅氧烷膜的方法
公开(公告)号：US08597482B2
公开(公告)日：2013-12-03
申请号：US13230160
申请日：2011-09-12
申请人： Danqing Zhu , William J Vanooij , Wenchao Zhang
发明人： Danqing Zhu , William J Vanooij , Wenchao Zhang
IPC分类号： C25D13/20 , B05D3/00 , C23C22/34
CPC分类号： C25D5/48 , B05D7/14 , B05D7/51 , C09D5/082 , C25D13/20
摘要： Cleaned metal surfaces are coated with an aqueous anti-corrosion treatment. The anti-corrosion treatment includes an organofunctional silsesquioxane and a fluoro metallic acid such as H2TiF6, H2ZrF6, as well as others and blends. The metal surface can be rinsed immediately after coating, making this anti-corrosion treatment suitable for preparing a metal surface for electrocoating.
摘要翻译：清洁的金属表面涂有水性防腐处理。防腐处理包括有机官能倍半硅氧烷和氟金属酸如H 2 TiF 6，H 2 ZrF 6，以及其它和共混物。金属表面可以在涂覆后立即进行冲洗，使得该防腐处理适合于制备用于电泳的金属表面。

4. 发明申请

US20120061248A1 PROCESS FOR DEPOSITING RINSABLE SILSESQUIOXANE FILMS ON METALS 有权
标题翻译：在金属上沉积可熔化的硅烷氧化物膜的方法
公开(公告)号：US20120061248A1
公开(公告)日：2012-03-15
申请号：US13230160
申请日：2011-09-12
申请人： Danqing Zhu , William J. Vanooij , Wenchao Zhang
发明人： Danqing Zhu , William J. Vanooij , Wenchao Zhang
IPC分类号： C25D5/34 , C09D7/12 , B05D1/36
CPC分类号： C25D5/48 , B05D7/14 , B05D7/51 , C09D5/082 , C25D13/20
摘要： Cleaned metal surfaces are coated with an aqueous anti-corrosion treatment. The anti-corrosion treatment includes an organofunctional silsesquioxane and a fluoro metallic acid such as H2TiF6, H2ZrF6, as well as others and blends. The metal surface can be rinsed immediately after coating, making this anti-corrosion treatment suitable for preparing a metal surface for electrocoating.
摘要翻译：清洁的金属表面涂有水性防腐处理。防腐处理包括有机官能倍半硅氧烷和氟金属酸如H 2 TiF 6，H 2 ZrF 6，以及其它和共混物。金属表面可以在涂覆后立即进行冲洗，使得该防腐处理适合于制备用于电泳的金属表面。

5. 发明申请

US20080118646A1 SILOXANE OLIGOMER TREATMENT FOR METALS 失效
标题翻译：硅氧烷低温处理金属
公开(公告)号：US20080118646A1
公开(公告)日：2008-05-22
申请号：US11938897
申请日：2007-11-13
申请人： Danqing Zhu , William J. Van Ooij
发明人： Danqing Zhu , William J. Van Ooij
IPC分类号： B05D3/12 , B05D1/02 , B05D1/28 , B05D1/18
CPC分类号： C09D5/002 , C09D5/08 , C09D183/08 , C23C22/62 , C23C22/68 , C23C22/83 , C23C2222/20 , Y10T428/31663
摘要： A method of applying to a clean metal surface an aqueous solution comprised of a small percentage of organofunctional siloxane oligomers. The organofunctional siloxane oligomers used in this method include silsesquioxanes. The organofunctional siloxane oligomers are applied to a metal surface prior to the application of a topcoat and function to inhibit corrosion of the metal surface.
摘要翻译：将清洁金属表面施用由少量有机官能硅氧烷低聚物组成的水溶液的方法。该方法中使用的有机官能硅氧烷低聚物包括倍半硅氧烷。有机官能硅氧烷低聚物在施加面漆之前施加到金属表面，并且具有抑制金属表面腐蚀的作用。

6. 发明申请

US20080026151A1 ADDITION OF SILANES TO COATING COMPOSITIONS 审中-公开
标题翻译：添加硅烷涂料组合物
公开(公告)号：US20080026151A1
公开(公告)日：2008-01-31
申请号：US11829509
申请日：2007-07-27
申请人： Danqing Zhu , William Van Ooij
发明人： Danqing Zhu , William Van Ooij
IPC分类号： B05D3/00 , C04B41/50
CPC分类号： C09D5/086 , C08G18/718
摘要： A coating composition for use on a cleaned but untreated metal surfaces includes a liquid polymerizable coating composition such as a urethane paint, or the like, blended with an organofunctional silane. The organofunctional silane can be a bis-functional monomeric or an oligomeric silane such as a silsesquioxane. The composition can be applied directly to an untreated metal surface. The silane in the coating composition improves adhesion of the coating composition and deters corrosion.
摘要翻译：用于清洁但未处理的金属表面的涂料组合物包括与有机官能硅烷共混的液体可聚合涂料组合物，例如聚氨酯涂料等。有机官能硅烷可以是双官能单体或低聚硅烷，如倍半硅氧烷。组合物可以直接施加到未处理的金属表面。涂料组合物中的硅烷改善涂料组合物的粘附性并阻止腐蚀。

7. 发明申请

US20070056469A1 Silane coating compositions and methods of use thereof 有权
标题翻译：硅烷涂料组合物及其使用方法
公开(公告)号：US20070056469A1
公开(公告)日：2007-03-15
申请号：US11366284
申请日：2006-03-02
申请人： William van Ooij , Karthik Suryanarayanan , Jaspreet Gandhi , Naveen Simhadri , Chetan Shivane , Matthew Stacy , Danqing Zhu
发明人： William van Ooij , Karthik Suryanarayanan , Jaspreet Gandhi , Naveen Simhadri , Chetan Shivane , Matthew Stacy , Danqing Zhu
IPC分类号： B60C1/00 , C07D295/18
CPC分类号： C09D4/00 , C09D5/086 , C09D183/04 , C09D183/08 , C23C2222/20 , C08G77/04 , C08G77/28 , C08G77/26 , C08L2666/02
摘要： A method of treating a substrate, such as a metal surface, by application of a silane coating composition containing at least one water-soluble or dispersible silane and a polymeric resin, which may be provided as a water-based dispersion of polymeric resin, the polymeric resin being present in an amount less than 10% by weight of the composition to slow the rate of corrosion of the metal surface and/or to promote adhesion of rubber thereto. The at least one silane can include a bis-amino silane, a vinyl silane, a bis-sulfur silane, or mixtures thereof and the polymeric resin may include an epoxy resin, acrylate resin, polyurethane resin, novolac resin, or mixtures thereof. The silane coating compositions may be either water or solvent based.
摘要翻译：通过应用含有至少一种水溶性或可分散的硅烷和聚合物树脂的硅烷涂料组合物来处理基材例如金属表面的方法，其可以作为聚合物树脂的水基分散体提供，聚合物树脂的存在量小于组合物的10重量％，以减缓金属表面的腐蚀速率和/或促进橡胶与其粘合。所述至少一种硅烷可包括双氨基硅烷，乙烯基硅烷，双硫硅烷或其混合物，聚合物树脂可包括环氧树脂，丙烯酸酯树脂，聚氨酯树脂，酚醛清漆树脂或其混合物。硅烷涂料组合物可以是水或溶剂型。

8. 发明授权

US08383204B2 Siloxane oligomer treatment for metals 失效
标题翻译：硅氧烷低聚物处理金属
公开(公告)号：US08383204B2
公开(公告)日：2013-02-26
申请号：US11938897
申请日：2007-11-13
申请人： Danqing Zhu , William J. Van Ooij
发明人： Danqing Zhu , William J. Van Ooij
IPC分类号： B05D3/02
CPC分类号： C09D5/002 , C09D5/08 , C09D183/08 , C23C22/62 , C23C22/68 , C23C22/83 , C23C2222/20 , Y10T428/31663
摘要： A method of applying to a clean metal surface an aqueous solution comprised of a small percentage of organofunctional siloxane oligomers. The organofunctional siloxane oligomers used in this method include silsesquioxanes. The organofunctional siloxane oligomers are applied to a metal surface prior to the application of a topcoat and function to inhibit corrosion of the metal surface.
摘要翻译：将清洁金属表面施用由少量有机官能硅氧烷低聚物组成的水溶液的方法。该方法中使用的有机官能硅氧烷低聚物包括倍半硅氧烷。有机官能硅氧烷低聚物在施加面漆之前施加到金属表面，并且具有抑制金属表面腐蚀的作用。

9. 发明授权

US07994249B2 Silane coating compositions and methods of use thereof 有权
标题翻译：硅烷涂料组合物及其使用方法
公开(公告)号：US07994249B2
公开(公告)日：2011-08-09
申请号：US11366284
申请日：2006-03-02
申请人： William J. van Ooij , Karthik Suryanarayanan , Jaspreet Singh Gandhi , Naveen B V Simhadri , Chetan Shivane , Matthew B. Stacy , Danqing Zhu
发明人： William J. van Ooij , Karthik Suryanarayanan , Jaspreet Singh Gandhi , Naveen B V Simhadri , Chetan Shivane , Matthew B. Stacy , Danqing Zhu
IPC分类号： C08K5/544 , C08K5/548
CPC分类号： C09D4/00 , C09D5/086 , C09D183/04 , C09D183/08 , C23C2222/20 , C08G77/04 , C08G77/28 , C08G77/26 , C08L2666/02
摘要： A method of treating a substrate, such as a metal surface, by application of a silane coating composition containing at least one water-soluble or dispersible silane and a polymeric resin, which may be provided as a water-based dispersion of polymeric resin, the polymeric resin being present in an amount less than 10% by weight of the composition to slow the rate of corrosion of the metal surface and/or to promote adhesion of rubber thereto. The at least one silane can include a bis-amino silane, a vinyl silane, a bis-sulfur silane, or mixtures thereof and the polymeric resin may include an epoxy resin, acrylate resin, polyurethane resin, novolac resin, or mixtures thereof. The silane coating compositions may be either water or solvent based.
摘要翻译：通过应用含有至少一种水溶性或可分散的硅烷和聚合物树脂的硅烷涂料组合物来处理基材例如金属表面的方法，其可以作为聚合物树脂的水基分散体提供，聚合物树脂的存在量小于组合物的10重量％，以减缓金属表面的腐蚀速率和/或促进橡胶与其粘合。所述至少一种硅烷可包括双氨基硅烷，乙烯基硅烷，双硫硅烷或其混合物，聚合物树脂可包括环氧树脂，丙烯酸酯树脂，聚氨酯树脂，酚醛清漆树脂或其混合物。硅烷涂料组合物可以是水或溶剂型。

10. 发明申请

US20090264574A1 Superprimer 审中-公开
标题翻译：超级。
公开(公告)号：US20090264574A1
公开(公告)日：2009-10-22
申请号：US12367571
申请日：2009-02-09
申请人： Wim Johan Van Ooij , Trilok Mugada , Karthik Suryanarayanan , Anuj Seth , Danqing Zhu , Lin Yang
发明人： Wim Johan Van Ooij , Trilok Mugada , Karthik Suryanarayanan , Anuj Seth , Danqing Zhu , Lin Yang
IPC分类号： C08K3/08
CPC分类号： C09D5/106 , C09D5/002 , C09D5/08 , C23C2222/20
摘要： A composition capable of coating a substrate and curing to provide a hydrophobic film inhibiting corrosion, the composition comprising: (a) a bis-silane comprising between about 0.5 weight percent to about 50 weight percent of the composition; and (b) a water soluble or dispersible polymer comprising between 10 weight percent to about 80 weight percent of the composition. A further exemplary superprimer in accordance with the instant invention includes a composition capable of coating a substrate and curing to provide a hydrophobic film inhibiting corrosion, the composition comprising: (a) a mixture of silanes; (b) a dispersible or soluble resin; and (c) an aqueous or non-aqueous solvent. Moreover, the invention includes the aforementioned superprimer composition, wherein the mixture of silanes includes at least one of a bis-sulfur silane, a bis-benzene silane, a bis-alkane silane, a bis-alkene silane, and a bis-amino silane.
摘要翻译：一种能够涂覆底物并固化以提供疏水膜抑制腐蚀的组合物，所述组合物包含：（a）包含组合物的约0.5重量％至约50重量％的双硅烷; 和（b）包含组合物的10重量％至约80重量％的水溶性或可分散的聚合物。根据本发明的另一示例性超级引物包括能够涂覆底物并固化以提供疏水膜抑制腐蚀的组合物，所述组合物包含：（a）硅烷的混合物; （b）可分散或可溶的树脂; 和（c）水性或非水性溶剂。此外，本发明包括上述超级引导剂组合物，其中硅烷的混合物包括双 - 硫硅烷，双 - 苯硅烷，双 - 烷烃硅烷，双 - 烯烃硅烷和双 - 氨基硅烷中的至少一种。

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