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    • 9. 发明授权
    • Process for preparing environmentally stable products by the remediation
of contaminated sediments and soils
    • 污染沉积物和土壤的修复产生的环境稳定的产品
    • US5855666A
    • 1999-01-05
    • US773677
    • 1996-12-24
    • Richard L. KaoSarabjit S. RandhavaSurjit S. RandhavaMichael C. MensingerAmirali G. RehmatAnthony L. Lee
    • Richard L. KaoSarabjit S. RandhavaSurjit S. RandhavaMichael C. MensingerAmirali G. RehmatAnthony L. Lee
    • C04B28/02C04B18/02C04B18/04C04B18/10C04B18/30
    • C04B18/108C04B18/026Y02W30/91Y02W30/92Y10S106/90
    • This invention relates to thermo-chemical remediation and decontamination of sediments and soils contaminated with organic contaminants as well as inorganic materials with subsequent beneficial reuse. Novel environmentally stable products of commercial value are produced when certain additives such as calcium and metal oxides are mixed with the contaminated materials. In the process, the mixture is heated to 1150.degree. C..about.1500.degree. C. to produce a molten reaction product with at least part of an excess amount of oxygen mixture or air is continuously bubbled through the melt in order to provide mixing and achieve high thermal destruction and removal efficiencies of the organic contaminants. The melt is then quickly quenched in moist air, steam, or water to avoid the transformation of the amorphous material into crystals. The inorganic contaminants such as chromium, nickel, zinc, etc. are incorporated and completely immobilized within the amorphous silicate network. Atmospheric emissions resulting from this process are nontoxic and capable of meeting currently specified health and environmental requirements.The amorphous material can be pulverized to yield a powder which evinces cementitious properties either by reaction with alkali solution or by blending it with other materials to produce blended cements. The compressive strengths of the concretes made from the powder of the subject invention and blends thereof are comparable to, or greater than the ASTM requirements for general purpose concrete applications. The powder of the subject invention, blended cements, and concrete/mortar derived therefrom also easily pass the EPA TCLP leach test to achieve environmental acceptability.
    • 本发明涉及用有机污染物污染的沉积物和土壤以及随后有益再利用的无机材料的热化学修复和去污。 当某些添加剂如钙和金属氧化物与受污染的材料混合时,产生具有商业价值的新型环境稳定的产品。 在该过程中,将混合物加热至1150℃。将差异1500℃以产生具有至少部分过量氧混合物或空气的熔融反应产物连续鼓泡通过熔体,以提供混合并实现 高热破坏和有机污染物的去除效率。 然后将熔体在潮湿的空气,蒸汽或水中快速淬火,以避免将无定形材料转变成晶体。 将无机污染物如铬,镍,锌等掺入并完全固定在无定形硅酸盐网络内。 这个过程产生的大气排放是无毒的,能够达到目前规定的健康和环境要求。 可以将无定形材料粉碎以产生通过与碱溶液反应或通过与其它材料混合以产生混合水泥而产生水泥性质的粉末。 由本发明的粉末及其共混物制成的混凝土的抗压强度与通用混凝土应用的ASTM要求相当或更大。 本发明的粉末,混合水泥和由其衍生的混凝土/砂浆也容易通过EPA TCLP浸出试验以达到环境可接受性。