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    • 5. 发明授权
    • Bis(thienyl)isopyrazoles and process for preparing and method for using bis(thienyl)isopyrazoles
    • 双(噻吩基)异吡唑及其制备方法和使用双(噻吩基)异吡唑的方法
    • US07456295B1
    • 2008-11-25
    • US11645257
    • 2006-11-25
    • David J. IrvinDavid L. WitkerJohn D. Stenger-SmithJennifer A. Irvin
    • David J. IrvinDavid L. WitkerJohn D. Stenger-SmithJennifer A. Irvin
    • C07D231/10C07D409/06
    • C07D409/04C07D333/22
    • The present invention demonstrates the synthesis of a new pyrazole-containing monomer by means of an easily implemented two-step process. This monomer can be electropolymerized to yield a stable n-doping polymer that may easily be electrochemically characterized. It is demonstrated that the electrochemical behavior of the polymer films produced is dependent upon the conditions applied during electrodeposition. Films deposited by cycling only at relatively positive potentials (0 to 2000 mV) show less intense n-doping responses than those films obtained by scanning the applied potential throughout a wider range (−2000 mV to 2000 mV). It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.
    • 本发明通过易于实施的两步方法证明了新的含吡唑单体的合成。 该单体可以电聚合以产生可以容易地电化学表征的稳定的n掺杂聚合物。 证明所生产的聚合物膜的电化学行为取决于电沉积期间的应用条件。 通过仅在相对正电位(0至2000mV)下循环沉积的膜显示比通过在更宽范围(-2000mV至2000mV)范围内扫描施加电位获得的那些薄膜更强烈的n掺杂响应。 要强调的是,该摘要被提供以符合要求抽象的规则,允许搜索者或其他读者快速确定技术公开的主题。 提交它的理解是,它不会用于解释或限制权利要求的范围。