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    • 3. 发明申请
    • Thermoplastic vulcanizate with high temperature processing aid
    • 热塑性硫化胶具有高温加工助剂
    • US20060142491A1
    • 2006-06-29
    • US11022716
    • 2004-12-27
    • Edward Park
    • Edward Park
    • C08F8/00
    • C08J3/20B29B7/7495C08K5/05C08K5/54C08L27/12C08L71/02C08L2205/02C08L2205/03C08L2666/02C08L2666/04
    • Processable rubber compositions contain a vulcanized fluorocarbon elastomer dispersed in a matrix of a thermoplastic polymeric material. In one embodiment the matrix forms a continuous phase and the vulcanized elastomeric material is in the form of particles forming a non-continuous phase. The compositions are made by combining a curative, an uncured fluorocarbon elastomer, a high temperature processing aid and a thermoplastic material, and heating the mixture at a temperature and for a time sufficient to effect vulcanization of the elastomeric material, while mechanical energy is applied to mix the mixture during the heating step. Shaped articles such as seals, gaskets, O-rings, and hoses may be readily formed from the rubber compositions according to conventional thermoplastic processes such as blow molding, injection molding, and extrusion.
    • 可加工橡胶组合物含有分散在热塑性聚合材料基体中的硫化氟碳弹性体弹性体。 在一个实施方案中,基质形成连续相,并且硫化的弹性体材料为形成非连续相的颗粒形式。 组合物通过将固化剂,未固化的氟碳弹性体,高温加工助剂和热塑性材料组合并在足以实现弹性体材料硫化的温度和时间内加热混合物而制备,同时机械能被施加到 在加热步骤期间混合混合物。 根据常规热塑性方法如吹塑,注射成型和挤出,可以从橡胶组合物容易地形成诸如密封件,垫圈,O形环和软管的成型制品。
    • 5. 发明申请
    • Thermoplastic vulcanizate with functional fillers
    • 具有功能性填料的热塑性硫化胶
    • US20060004126A1
    • 2006-01-05
    • US10880682
    • 2004-06-30
    • Edward ParkFrancis Walker
    • Edward ParkFrancis Walker
    • C08K9/06C08K3/40C08K3/04
    • C08J3/24C08J2315/02
    • Processable rubber compositions contain a vulcanized fluorocarbon elastomer and functional filler dispersed in a matrix of a thermoplastic polymeric material. In one embodiment the matrix forms a continuous phase and the vulcanized elastomeric material is in the form of particles forming a non-continuous phase. The compositions are made by combining a curative, an uncured fluorocarbon elastomer, a functional filler and a thermoplastic material, and heating the mixture at a temperature and for a time sufficient to effect vulcanization of the elastomeric material, while mechanical energy is applied to mix the mixture during the heating step. Shaped articles such as seals, gaskets, O-rings, and hoses may be readily formed from the rubber compositions according to conventional thermoplastic processes such as blow molding, injection molding, and extrusion.
    • 可加工橡胶组合物含有分散在热塑性聚合材料基体中的硫化氟碳弹性体和功能填料。 在一个实施方案中,基质形成连续相,并且硫化的弹性体材料为形成非连续相的颗粒形式。 组合物通过组合固化剂,未固化的氟碳弹性体,功能填料和热塑性材料制成,并在足以实现弹性体材料硫化的温度和时间下加热混合物,同时施加机械能以混合 加热步骤中的混合物。 根据常规热塑性方法如吹塑,注射成型和挤出,可以从橡胶组合物容易地形成诸如密封件,垫圈,O形环和软管的成型制品。
    • 9. 发明申请
    • Melt-processable adhesives for bonding pervious fluoropolymeric layers in multilayer composites
    • 用于粘合多层复合材料中透明含氟聚合物层的可熔融加工的粘合剂
    • US20070190284A1
    • 2007-08-16
    • US11352062
    • 2006-02-10
    • Edward Park
    • Edward Park
    • B32B3/02B32B27/08
    • B32B7/12B32B15/08B32B15/085B32B15/18B32B25/04B32B25/08B32B27/06B32B27/08B32B27/16B32B27/322B32B2270/00B32B2274/00B32B2581/00Y10T428/215Y10T428/31511Y10T428/3154Y10T428/31544Y10T428/31678
    • A homogenous fluoropolymeric melt-bonded layer in a multilayer composite coheres to a pervious fluoropolymer layer of fluoroelastomeric thermoplastic and/or etched polytetrafluoroethylene. Before curing, the homogenous fluoropolymer has a stoichiometrically identical monomer unit with the pervious fluoropolymer, the homogenous fluoropolymer liquefaction range supra-point temperature is not greater than that of the pervious fluoropolymer, the homogenous fluoropolymer liquefaction range supra-point temperature is not less than the pervious fluoropolymer liquefaction range sub-point temperature, and the homogenous fluoropolymer liquefaction range supra-point viscosity is less than that of the pervious fluoropolymer. In some multilayer composites, the homogenous fluoropolymeric melt-bonded layer coheres to a third layer of plastic, metal, ceramic, rubber, wood, and/or leather. In such 3+ layer composites, the homogenous fluoropolymeric contains an epoxy compound, a phenoxy compound, silane, and/or a heat-polymerizable thermoplastic oligomer. Various composites according to the technology are adapted for use as gaskets, dynamic seals, compression seals, or o-rings.
    • 多层复合材料中均匀的含氟聚合物熔融粘合层与含氟弹性体热塑性和/或蚀刻聚四氟乙烯的渗透含氟聚合物层结合。 固化前,均相含氟聚合物与透明含氟聚合物具有化学计量相同的单体单元,均匀含氟聚合物液化范围超出上限温度不高于渗透性含氟聚合物,均匀含氟聚合物液化范围上限温度不低于 渗透性氟聚合物液化范围亚点温度,均匀含氟聚合物液化范围超粘度小于渗透性含氟聚合物。 在一些多层复合材料中,均匀的含氟聚合物熔融粘合层粘合到第三层塑料,金属,陶瓷,橡胶,木材和/或皮革上。 在这种3+层复合材料中,均匀含氟聚合物含有环氧化合物,苯氧基化合物,硅烷和/或热可聚合热塑性低聚物。 根据该技术的各种复合材料适用于垫片,动态密封件,压缩密封件或O形圈。
    • 10. 发明申请
    • Fluorocarbon rubber with enhanced low temperature properties
    • 氟碳橡胶具有增强的低温性能
    • US20070167574A1
    • 2007-07-19
    • US11332872
    • 2006-01-13
    • Edward Park
    • Edward Park
    • C08L27/12
    • C08L27/12C08L27/16C08L77/00C08L2205/02C08L2205/22C08L2666/02C08L2666/04
    • Processable rubber compositions containing a vulcanized elastomeric material dispersed in a matrix of a thermoplastic polymeric material. The vulcanized elastomeric material is a peroxide cure polymeric material containing repeating units derived from fluorine-containing monomers and at least one peroxide cure site monomer. In one embodiment the matrix forms a continuous phase and the vulcanized elastomeric material is in the form of particles forming a non-continuous phase. The compositions are made by combining a radical curing system, a fluorocarbon elastomer material, and a fluoroplastic material, and heating the mixture at a temperature and for a time sufficient to effect vulcanization of the elastomeric material, while mechanical energy is applied to mix the mixture during the heating step. Shaped articles may be readily formed from the rubber compositions according to conventional thermoplastic processes such as blow molding, injection molding, and extrusion. Examples of useful articles include seals, gaskets, O-rings, and hoses.
    • 含有分散在热塑性聚合物材料基质中的硫化弹性体材料的可加工的橡胶组合物。 硫化弹性体材料是含有衍生自含氟单体和至少一种过氧化物固化位点单体的重复单元的过氧化物固化聚合材料。 在一个实施方案中,基质形成连续相,并且硫化的弹性体材料为形成非连续相的颗粒形式。 组合物通过组合自由基固化体系,氟碳弹性体材料和氟塑料材料制成,并在足以实现弹性体材料硫化的温度和时间下加热混合物,同时施加机械能以混合混合物 在加热步骤期间。 成型制品可以根据常规的热塑性方法如吹塑,注模和挤出由橡胶组合物容易地形成。 有用的物品的实例包括密封件,垫圈,O型圈和软管。