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1. 发明授权

US5912110A Photographic coupler capable of releasing a photographically useful group 失效
标题翻译：能够释放摄影有用组的摄影耦合器
公开(公告)号：US5912110A
公开(公告)日：1999-06-15
申请号：US872496
申请日：1997-06-10
申请人： William James Begley , Teh Hsuan Chen , Frank Dino Coms , Donald Singleton, Jr.
发明人： William James Begley , Teh Hsuan Chen , Frank Dino Coms , Donald Singleton, Jr.
IPC分类号： G03C7/00 , C07D403/12 , G03C7/30 , G03C7/305 , G03C1/08 , G03C7/26 , G03C7/32
CPC分类号： C07D403/12 , G03C7/30576 , Y10S430/156 , Y10S430/157 , Y10S430/158 , Y10S430/159 , Y10S430/16 , Y10S430/161
摘要： A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the layer containing a photographic coupler represented by the formula ##STR1## wherein COUP is a coupler moiety having a coupling site to which T.sup.1 is attached;T.sup.1 is a timing or linking group which releases from COUP during processing and which functions by electron transfer down a conjugated chain, or by nucleophilic displacement reaction, to release from HETERO;HETERO is a heterocyclic group containing at least two heteroatoms independently selected from oxygen, nitrogen, or sulfur, wherein one of the heteroatoms is directly attached to T.sup.1 ;R.sup.1 and R.sup.2 are independently selected from hydrogen, or an aliphatic, carbocyclic, or heterocyclic group, or may be bonded together to form a 5, 6, or 7 membered ring; andPUG is a photographically useful group.
摘要翻译：一种照相元件，包括其上设置有至少一个卤化银乳剂层的支撑体，该层包含由下式表示的照相成色剂：其中COUP是具有与T1连接的偶合位点的成色剂部分; T1是在加工期间从COUP释放的定时或连接基团，并且通过电子转移共轭链或通过亲核取代反应从HETERO释放的功能; HETERO是含有至少两个独立地选自氧，氮或硫的杂原子的杂环基，其中一个杂原子直接连接到T1上; R 1和R 2独立地选自氢或脂族，碳环或杂环基，或可以键合在一起形成5,6或7元环; PUG是一个摄影有用的小组。

2. 发明授权

US5686234A Photographic element containing a coupler capable of releasing a photographically useful group 失效
标题翻译：含有能够释放摄影有用组的耦合器的照相元件
公开(公告)号：US5686234A
公开(公告)日：1997-11-11
申请号：US590661
申请日：1996-01-24
申请人： William James Begley , Teh Hsuan Chen , Donald Singleton, Jr. , Frank Dino Coms
发明人： William James Begley , Teh Hsuan Chen , Donald Singleton, Jr. , Frank Dino Coms
IPC分类号： C07D403/12 , G03C7/305 , G03C7/40
CPC分类号： C07D403/12 , G03C7/30576 , G03C2200/33 , Y10S430/156 , Y10S430/157 , Y10S430/158 , Y10S430/159 , Y10S430/16
摘要： A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the layer containing a photographic coupler represented by the formula COUP--T.sup.1 --T.sup.2 --(T.sup.3).sub.b --PUG wherein COUP is a coupler moiety having a coupling site to which T.sup.1 is attached; T.sup.1 is a timing or linking group which releases from COUP during processing and which functions by electron transfer down a conjugated or unconjugated chain, or by nucleophilic displacement reaction, to release T.sup.2, T.sup.2 being an indazole timing or linking group which, after release from T.sup.1, functions by electron transfer down a conjugated chain to release T.sup.3 or PUG, and which is represented by the formula: ##STR1## wherein ** denotes the point of attachment to T.sup.1 and *** denotes the point of attachment to T.sup.3 or PUG; R.sup.1 and R.sup.2 are independently selected from hydrogen, or an aliphatic, carbocyclic, or heterocyclic group, or may be bonded together to form a 5, 6, or 7 membered ring; V is independently selected from the group consisting of an alkyl, carbocyclic, heterocyclic, halo, carbamoyl, sulfamoyl, carbonamido, sulfonamido, keto, sulfo, nitro, hydroxyl, carboxyl, amino, alkoxy, alkoxycarbonyl, aryloxy, or arylthio group; q is 0, 1, 2, 3 or 4; T.sup.3 is a timing or linking group attached to T.sup.2 which is released therefrom after T.sup.2 releases from T.sup.1, and which functions by electron transfer down a conjugated or unconjugated chain, or by nucleophilic displacement reaction, to release PUG; b is 0 or 1; and PUG is a photographically useful group.
摘要翻译：一种照相元件，包括一个载体，其上至少有一个卤化银乳剂层，该层含有由COUP-T1-T2-（T3）代表的COUP-T1-T2-（T3）b-PUG的照相成色剂，其中COUP是具有偶合位点的成色剂部分， T1连接; T1是在加工期间从COUP释放的定时或连接基团，并且通过电子转移通过共轭或非共轭链或通过亲核取代反应进行功能释放T2，T2是吲唑定时或连接基团，其在从T1释放后通过电子转移共轭链释放T3或PUG起作用，其由下式表示：其中**表示与T1的连接点，***表示与T3或PUG的连接点; R 1和R 2独立地选自氢或脂族，碳环或杂环基，或可以键合在一起形成5,6或7元环; 卤素，氨基甲酰基，氨基磺酰基，碳酰氨基，亚磺酰氨基，酮基，磺基，硝基，羟基，羧基，氨基，烷氧基，烷氧基羰基，芳氧基或芳硫基。 q是0，1，2，3或4; T3是连接T2的定时或连接基团，其在T2从T2释放后从其释放，并且通过电子转移通过共轭或非共轭链或通过亲核置换反应起作用以释放PUG; b为0或1; PUG是一个摄影有用的小组。

3. 发明授权

US5962656A Indazole containing coupler 失效
标题翻译：含吲唑的成色剂
公开(公告)号：US5962656A
公开(公告)日：1999-10-05
申请号：US872118
申请日：1997-06-10
申请人： William James Begley , Teh Hsuan Chen , Donald Singleton, Jr. , Frank Dino Coms
发明人： William James Begley , Teh Hsuan Chen , Donald Singleton, Jr. , Frank Dino Coms
IPC分类号： C07D403/12 , G03C7/305 , C07D231/56 , C07D403/14
CPC分类号： C07D403/12 , G03C7/30576 , G03C2200/33 , Y10S430/156 , Y10S430/157 , Y10S430/158 , Y10S430/159 , Y10S430/16
摘要： A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the layer containing a photographic coupler represented by the formulaCOUP--T.sup.1 --T.sup.2 --(T.sup.3).sub.b --PUGwhereinCOUP is a coupler moiety having a coupling site to which T.sup.1 is attached;T.sup.1 and T3 are timing or linking groups;T.sup.2 is an indazole timing or linking group which, after release from T.sup.1, functions by electron transfer down a conjugated chain to release T.sup.3 or PUG, and which is represented by the formula: ##STR1## wherein ** denotes the point of attachment to T.sup.1 and *** denotes the point of attachment to T.sup.3 or PUG;R.sup.1 and R.sup.2 are independently selected from hydrogen, or an aliphatic, carbocyclic, or heterocyclic group, or may be bonded together to form a 5, 6, or 7 membered ring;V is independently a substituent group as further defined;q is 0, 1, 2, 3 or 4;b is 0 or 1; andPUG is a photographically useful group.
摘要翻译：一种照相元件，包括其上设置有至少一个卤化银乳剂层的载体，该层含有由式COUP-T1-T2-（T3）b-PUG表示的照相偶联物，其中COUP是具有偶合位点的成色剂部分，其中T1 被附上; T1和T3是定时或链接组; T2是吲唑定时或连接基团，其在从T1释放后通过电子转移到共轭链下达释放T3或PUG而起作用，其由下式表示：其中**表示与T1和**的连接点 *表示与T3或PUG的连接点; R 1和R 2独立地选自氢或脂族，碳环或杂环基，或可以键合在一起形成5,6或7元环; V独立地是进一步定义的取代基; q是0，1，2，3或4; b为0或1; PUG是一个摄影有用的小组。

4. 发明授权

US5670301A Photographic element containing a coupler capable of releasing a photographically useful group 失效
标题翻译：含有能够释放摄影有用组的耦合器的照相元件
公开(公告)号：US5670301A
公开(公告)日：1997-09-23
申请号：US590644
申请日：1996-01-24
申请人： William James Begley , Teh Hsuan Chen , Frank Dino Coms , Donald Singleton, Jr.
发明人： William James Begley , Teh Hsuan Chen , Frank Dino Coms , Donald Singleton, Jr.
IPC分类号： G03C7/00 , C07D403/12 , G03C7/30 , G03C7/305
CPC分类号： C07D403/12 , G03C7/30576 , Y10S430/156 , Y10S430/157 , Y10S430/158 , Y10S430/159 , Y10S430/16 , Y10S430/161
摘要： A photographic element comprising a support having situated thereon at least one silver halide emulsion layer, the layer containing a photographic coupler represented by the formula ##STR1## wherein COUP is a coupler moiety having a coupling site to which T.sup.1 is attached; T.sup.1 is a timing or linking group which releases from COUP during processing and which functions by electron transfer down a conjugated chain, or by nucleophilic displacement reaction, to release from HETERO; HETERO is a heterocyclic group containing at least two heteroatoms independently selected from oxygen, nitrogen, or sulfur, wherein one of the heteroatoms is directly attached to T.sup.1 ; R.sup.1 and R.sup.2 are independently selected from hydrogen, or an aliphatic, carbocyclic, or heterocyclic group, or may be bonded together to form a 5, 6, or 7 membered ring; and PUG is a photographically useful group.
摘要翻译：一种照相元件，包括一个载体，其上设置有至少一个卤化银乳剂层，该层包含由式“IMAGE”表示的照相成色剂，其中COUP是具有与T1连接的偶合位点的成色剂部分; T1是在加工期间从COUP释放的定时或连接基团，并且通过电子转移共轭链或通过亲核取代反应从HETERO释放的功能; HETERO是含有至少两个独立地选自氧，氮或硫的杂原子的杂环基，其中一个杂原子直接连接到T1上; R 1和R 2独立地选自氢或脂族，碳环或杂环基，或可以键合在一起形成5,6或7元环; PUG是一个摄影有用的小组。

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