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    • 5. 发明授权
    • Carbonyl-substituted cyan azo dye-providing materials
    • 羰基取代的青色偶氮染料提供材料
    • US4273708A
    • 1981-06-16
    • US46137
    • 1979-06-06
    • Kenneth N. KilminsterColin Holstead
    • Kenneth N. KilminsterColin Holstead
    • C09B29/28G03C7/00G03C8/10C07C107/04C09B29/20C09B29/22C09B29/36
    • C09B29/28G03C8/10Y10S534/02
    • Cyan azo dye-providing compounds have the formula: ##STR1## wherein: R.sup.1 is selected from the group consisting of aryl, alkyl or NR.sup.11 R.sup.12 wherein R.sup.11 is alkyl or aryl and R.sup.12 is alkyl, or R.sup.11 and R.sup.12, taken together with the nitrogen atom to which they are attached, is a heterocyclic group;X is --CO-- or --SO.sub.2 --;R.sup.3 is --COOH or --CAR and is attached in the meta or para position to X in the benzene ring;R is alkyl; ##STR2## can be taken together with R and the nitrogen atom to which it is attached to form a heterocyclic ring unsubstituted or substituted with a carboxy group; andCAR is a carrier moiety which, as a function of oxidation under alkaline conditions, releases a diffusible dye, with the proviso that the compound contains at least one CAR group and, excepting when R and R.sup.2 form a heterocyclic group and X is --SO.sub.2 --, must contain at least one carboxy group. The compounds are particularly useful in photographic elements and more particularly useful in image transfer film units.
    • 氰基偶氮染料提供化合物具有下式:其中:R 1选自芳基,烷基或NR 11 R 12,其中R 11是烷基或芳基,R 12是烷基,或R 11和R 12与氮原子一起 它们所连接的是杂环基团; X是-CO-或-SO 2 - ; R3是-COOH或-CAR,并且在苯环中与X位置连接在间位或对位; R是烷基; < IMAGE>可以与R及其所连接的氮原子一起形成未被取代或被羧基取代的杂环; 并且CAR是载体部分,其在碱性条件下作为氧化的函数释放可扩散染料,条件是该化合物含有至少一个CAR基团,并且除了当R和R 2形成杂环基并且X是-SO 2 - 必须含有至少一个羧基。 这些化合物在照相元件中特别有用,更特别适用于图像转印膜单元。
    • 6. 发明授权
    • Compounds which release cyan dyes or dye forming materials
    • 释放青色染料或染料形成材料的化合物
    • US4195993A
    • 1980-04-01
    • US934454
    • 1978-08-17
    • Kenneth N. KilminsterColin Holstead
    • Kenneth N. KilminsterColin Holstead
    • C09B29/28G03C7/00G03C8/10G03C5/54G03C1/10G03C1/40G03C1/76
    • C09B29/28G03C8/10Y10S534/02
    • Cyan azo dye-providing compounds have the formula: ##STR1## wherein: R.sup.1 is selected from the group consisting of aryl, alkyl or NR.sup.11 R.sup.12 wherein R.sup.11 is alkyl or aryl and R.sup.12 is alkyl, or R.sup.11 and R.sup.12, taken together with the nitrogen atom to which they are attached, is a heterocyclic group;X is --CO-- or --SO.sub.2 --;R.sup.3 is --COOH or --CAR and is attached in the meta or para position to X in the benzene ring;R is alkyl; ##STR2## or can be taken together with R and the nitrogen atom to which it is attached to form a heterocyclic ring unsubstituted or substituted with a carboxy group; andCAR is a carrier moiety which, as a function of oxidation under alkaline conditions, releases a diffusible dye, with the proviso that the compound contains at least one CAR group and, excepting when R and R.sup.2 form a heterocyclic group and X is --SO.sub.2 --, must contain at least one carboxy group. The compounds are particularly useful in photographic elements and more particularly useful in image transfer film units.
    • 氰基偶氮染料提供化合物具有下式:其中:R 1选自芳基,烷基或NR 11 R 12,其中R 11是烷基或芳基,R 12是烷基,或R 11和R 12与氮原子一起 它们所连接的是杂环基团; X是-CO-或-SO 2 - ; R3是-COOH或-CAR,并且在苯环中与X位置连接在间位或对位; R是烷基; 或者可以与R及其所连接的氮原子一起形成未被取代或被羧基取代的杂环; 并且CAR是载体部分,其在碱性条件下作为氧化的函数释放可扩散染料,条件是该化合物含有至少一个CAR基团,并且除了当R和R 2形成杂环基并且X是-SO 2 - 必须含有至少一个羧基。 这些化合物在照相元件中特别有用,更特别适用于图像转印膜单元。
    • 7. 发明授权
    • Photographic silver halide element and process
    • 摄影卤化银元素和工艺
    • US4853319A
    • 1989-08-01
    • US132531
    • 1987-12-14
    • Sundaram KrishnamurthyBrian H. JohnstonKenneth N. KilminsterDavid C. VogelPaul R. Buckland
    • Sundaram KrishnamurthyBrian H. JohnstonKenneth N. KilminsterDavid C. VogelPaul R. Buckland
    • C07D231/52G03C7/305G03C7/384
    • G03C7/384C07D231/52G03C7/30529
    • Novel pyrazolone photographic couplers contain in the coupling position a coupling-off group represented by the formula: ##STR1## wherein: L.sub.1 and L.sub.2 individually are unsubstituted or substituted methylene or ethylene;m and n individually are 0 or 1;Y is R.sub.1 or ZR.sub.2 ;R.sub.1 is an unsubstituted or substituted aryl or heterocyclic group, or is a secondary or tertiary carbon group represented by ##STR2## wherein R.sub.3 and R.sub.4 are selected from the group consisting of halogen, R.sub.2 and Z.sub.1 R.sub.b ; wherein Z is O, S, or NR.sub.a ; Z.sub.1 is O, S, or NR.sub.c ; and R.sub.2 is an unsubstituted or substituted alkyl, aryl, or heterocyclic group. R.sub.5, R.sub.6, R.sub.a, R.sub.b and R.sub.c are as defined in the specification. R.sub.3 optionally joins together with at least one of R.sub.4 and R.sub.5 to form one or two alicyclic or heterocyclic rings, which are optionally further substituted; andX represents the atoms selected from a group consisting of carbon, oxygen, nitrogen, and sulfur atoms necessary to complete a 5-, 6-, or 7-member unsaturated ring. This ring optionally contains further substituents than those indicated above, including other rings fused to the ring containing X.These couplers are useful in photographic elements and processes.
    • 新型吡唑啉酮照相成色剂在偶联位置含有由下式表示的偶联离去基团:其中:L1和L2各自为未取代或取代的亚甲基或亚乙基; m和n分别为0或1; Y为R1或ZR2; R1是未取代或取代的芳基或杂环基,或是由下式表示的仲或叔碳基,其中R3和R4选自卤素,R2和Z1Rb; 其中Z为O,S或NR a; Z1是O,S或NRc; 并且R 2是未取代或取代的烷基,芳基或杂环基。 R5,R6,Ra,Rb和Rc如说明书中所定义。 R3任选地与R4和R5中的至少一个连接以形成一个或两个脂环族或杂环,其任选进一步被取代; X表示选自由完成5-,6-或7-元不饱和环所必需的碳,氧,氮和硫原子的原子。 该环任选地含有除上述指示基之外的其它取代基,包括与含有X的环稠合的其它环。这些偶联剂可用于照相元件和方法。