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1. 发明授权

US5185308A Catalysts and processes for the manufacture of vinyl acetate 失效
标题翻译：用于制造乙酸乙烯酯的催化剂和方法
公开(公告)号：US5185308A
公开(公告)日：1993-02-09
申请号：US696215
申请日：1991-05-06
申请人： William J. Bartley , Simon Jobson , Gordon G. Harkreader , Melanie Kitson , Michael F. Lemanski
发明人： William J. Bartley , Simon Jobson , Gordon G. Harkreader , Melanie Kitson , Michael F. Lemanski
IPC分类号： B01J31/04 , B01J23/44 , B01J23/52 , B01J23/54 , B01J23/58 , B01J31/28 , B01J37/02 , B01J37/03 , B01J37/06 , B01J37/16 , C07B61/00 , C07C67/05 , C07C67/055 , C07C69/15
CPC分类号： B01J23/44 , B01J23/52 , B01J23/58 , C07C67/055 , B01J35/008 , B01J37/0201 , B01J37/0205 , B01J37/03 , B01J37/06 , B01J37/16
摘要： A shell impregnated catalyst for use in the production of vinyl acetate from ethylene, acetic acid and an oxygen containing gas is provided. The catalyst has a productivity of greater than 661 grams of vinyl acetate per hour per liter of catalyst at 150.degree. C. and consists essentially of:(1) a catalyst support having a particle diameter from about 3 to about 7 mm and a pore volume of 0.2 to 1.5 ml per gram(2) palladium and gold distributed in the outermost 1.0 mm thick layer of the catalyst support particles, and(3) from about 3.5 to 9.5% by weight of potassium acetate.The catalyst is characterized by having a gold to palladium weight ratio in the range 0.60 to 1.25.
摘要翻译：提供了用于从乙烯，乙酸和含氧气体生产乙酸乙烯酯的壳体浸渍催化剂。催化剂在150℃下每小时催化剂具有大于661克乙酸乙烯酯的生产率，并且基本上由以下组成：（1）具有约3至约7mm的粒径的催化剂载体和孔体积分布在最外层1.0mm厚的催化剂载体颗粒中的每克（2）钯和金为0.2至1.5ml，和（3）约3.5至9.5重量％的乙酸钾。催化剂的特征在于金与钯的重量比在0.60至1.25的范围内。

2. 发明授权

US5274181A Catalysts and processes for the manufacture of vinyl acetate 失效
标题翻译：用于制造乙酸乙烯酯的催化剂和方法
公开(公告)号：US5274181A
公开(公告)日：1993-12-28
申请号：US957143
申请日：1992-10-07
申请人： William J. Bartley , Simon Jobson , Gordon G. Harkreader , Melanie Kitson , Mike Lemanski
发明人： William J. Bartley , Simon Jobson , Gordon G. Harkreader , Melanie Kitson , Mike Lemanski
IPC分类号： B01J23/44 , B01J23/52 , B01J23/58 , B01J37/06 , C07C67/055 , C07C67/05
CPC分类号： B01J23/58 , B01J23/44 , B01J23/52 , C07C67/055 , B01J35/0073 , B01J37/06
摘要： A shell impregnated catalyst for use in the production of vinyl acetate from ethylene, acetic acid and an oxygen containing gas is provided. The catalyst has a productivity of greater than 661 grams of vinyl acetate per hour per liter of catalyst at 150.degree. C. and consists essentially of:(1) a catalyst support having a particle diameter from about 3 to about 7 mm and a pore volume of 0.2 to 1.5 ml per gram(2) palladium and gold distributed in the outermost 1.0 mm thick layer of the catalyst support particles, and(3) from about 3.5 to 9.5% by weight of potassium acetate.The catalyst is characterised by having a gold to palladium weight ratio in the range 0.60 to 1.25.
摘要翻译：提供了用于从乙烯，乙酸和含氧气体生产乙酸乙烯酯的壳体浸渍催化剂。催化剂在150℃下每小时催化剂具有大于661克乙酸乙烯酯的生产率，并且基本上由以下组成：（1）具有约3至约7mm的粒径的催化剂载体和孔体积分布在最外层1.0mm厚的催化剂载体颗粒中的每克（2）钯和金为0.2至1.5ml，和（3）约3.5至9.5重量％的乙酸钾。催化剂的特征在于金与钯的重量比在0.60至1.25的范围内。

3. 发明授权

US07491843B2 Integrated process for the production of vinyl acetate and/or acetic acid 失效
公开(公告)号：US07491843B2
公开(公告)日：2009-02-17
申请号：US09985274
申请日：2001-11-02
申请人： Simon Jobson , Derrick John Watson
发明人： Simon Jobson , Derrick John Watson
IPC分类号： C07C69/02 , C07C67/00 , C07C67/02 , C07C67/04 , C07C67/05
CPC分类号： C07C51/25 , B01J2219/00006 , B01J2219/00038 , B01J2219/0004 , C07C51/44 , C07C67/05 , C07C67/055 , C07C67/54 , Y02P20/125 , C07C53/08 , C07C69/01 , C07C69/15
摘要： Acetic acid and/or vinyl acetate are produced by an integrated process which comprises the steps: (a) contacting in a first reaction zone a gaseous feedstock comprising ethylene and/or ethane and optionally steam with a molecular oxygen-containing gas in the presence of a catalyst active for the oxidation of ethylene to acetic acid and/or ethane to acetic acid and ethylene to produce a first product stream comprising acetic acid, water and ethylene (either as unreacted ethylene and/or as co-produced ethylene) and optionally also ethane, carbon monoxide, carbon dioxide and/or nitrogen; (b) contacting in a second reaction zone in the presence or absence of additional ethylene and/or acetic acid at least a portion of the first gaseous product stream comprising at least acetic acid and ethylene and optionally also one or more of water, ethane, carbon monoxide, carbon dioxide and/or nitrogen with a molecular oxygen-containing gas in the presence of a catalyst active for the production of vinyl acetate to produce a second product stream comprising vinyl acetate, water, acetic acid and optionally ethylene, (c) separating the product stream from step (b) by distillation into an overhead azeotrope fraction comprising vinyl acetate and water and a base fraction comprising acetic acid; (d) either (i) recovering acetic acid from the base fraction separated in step (c) and optionally recycling the azeotrope fraction separated in step (c) after partial or complete separation of the water therefrom to step (c), or (ii) recovering vinyl acetate from the azeotrope fraction separated in step (c) and optionally recycling the base fraction separated in step (c) to step (b), or (iii) recovering acetic acid from the base fraction separated in step (c) and recovering vinyl acetate from the overhead azeotrope fraction recovered in step (c).

4. 发明授权

US07189377B1 Apparatus for performing integrated process for reproduction of vinyl acetate and/or acetic acid using a fluidized bed 有权
公开(公告)号：US07189377B1
公开(公告)日：2007-03-13
申请号：US09626157
申请日：2000-07-26
申请人： Simon Jobson , Derrick John Watson
发明人： Simon Jobson , Derrick John Watson
IPC分类号： B01J10/00
CPC分类号： C07C51/25 , B01J2219/00006 , B01J2219/00038 , B01J2219/0004 , C07C51/44 , C07C67/05 , C07C67/055 , C07C67/54 , Y02P20/125 , C07C53/08 , C07C69/01 , C07C69/15
摘要： 1. Acetic acid and/or vinyl acetate are produced by an integrated process which comprises the steps:— (a) contacting in a first reaction zone a gaseous feedstock comprising ethylene and/or ethane and optionally steam with a molecular oxygen-containing gas in the presence of a catalyst active for the oxidation of ethylene to acetic acid and/or ethane to acetic acid and ethylene to produce a first product stream comprising acetic acid, water and ethylene (either as unreacted ethylene and/or as co-produced ethylene) and optionally also ethane, carbon monoxide, carbon dioxide and/or nitrogen; (b) contacting in a second reaction zone in the presence or absence of additional ethylene and/or acetic acid at least a portion of the first gaseous product stream comprising at least acetic acid and ethylene and optionally also one or more of water, ethane, carbon monoxide, carbon dioxide and/or nitrogen with a molecular oxygen-containing gas in the presence of a catalyst active for the production of vinyl acetate to produce a second product stream comprising vinyl acetate, water, acetic acid and optionally ethylene; (c) separating the product stream from step (b) by distillation into an overhead azeotrope fraction comprising vinyl acetate and water and a base fraction comprising acetic acid; (d) either (i) recovering acetic acid from the base fraction separated in step (c) and optionally recycling the azeotrope fraction separated in step (c) after partial or complete separation of the water therefrom to step (c), or (ii) recovering vinyl acetate from the azeotrope fraction separated in step (c) and optionally recycling the base fraction separated in step (c) to step (b), or (iii) recovering acetic acid from the base fraction separated in step (c) and recovering vinyl acetate from the overhead azeotrope fraction recovered in step (c).

5. 发明授权

US06180821B2 Integrated process for the production of vinyl acetate and/or acetic acid using a fluidized bed 有权
公开(公告)号：US06180821B2
公开(公告)日：2001-01-30
申请号：US09461097
申请日：1999-12-14
申请人： Simon Jobson , Derrick John Watson
发明人： Simon Jobson , Derrick John Watson
IPC分类号： C07C6900
CPC分类号： C07C51/25 , C07C67/055 , Y02P20/125 , C07C53/08 , C07C69/01 , C07C69/15
摘要： Acetic acid and/or vinyl acetate are produced by an integrated process in which a gaseous feedstock comprising ethylene and/or ethane and optionally steam is contacted in a first reaction zone (step (a)) with a molecular oxygen-containing gas in the presence of a catalyst active for the oxidation of ethylene to acetic acid and/or ethane to acetic acid and ethylene to produce a first product stream comprising acetic acid, water and ethylene (either as unreacted ethylene and/or as co-produced ethylene) and optionally also ethane, carbon monoxide, carbon dioxide and/or nitrogen. At least a portion of the first gaseous product stream comprising at least acetic acid and ethylene and optionally also one or more of water, ethane, carbon monoxide, carbon dioxide and/or nitrogen is contacted in a second reaction zone (step (b)) in the presence or absence of additional ethylene and/or acetic acid with a molecular oxygen-containing gas in the presence of a catalyst active for the production of vinyl acetate to produce a second product stream comprising vinyl acetate, water, acetic acid and optionally ethylene. The second product stream is separated by distillation (step (c)) into an overhead azeotrope fraction comprising vinyl acetate and water and a base fraction comprising acetic acid. The process then comprises either (i) recovering acetic acid from the base fraction separated in step (c) and optionally recycling the azeotrope fraction separated in step (c) after partial or complete separation of the water therefrom to step (c), or (ii) recovering vinyl acetate from the azeotrope fraction separated in step (c) and optionally recycling the base fraction separated in step (c) to step (b), or (iii) recovering acetic acid from the base fraction separated in step (c) and recovering vinyl acetate from the overhead azeotrope fraction recovered in step (c).

6. 发明授权

US6040474A Integrated process for the production of vinyl acetate and/or acetic acid 失效
公开(公告)号：US6040474A
公开(公告)日：2000-03-21
申请号：US55398
申请日：1998-04-06
申请人： Simon Jobson , Derrick John Watson
发明人： Simon Jobson , Derrick John Watson
IPC分类号： C07C51/25 , C07C53/08 , C07C67/055 , C07C69/15 , C07C69/00
CPC分类号： C07C51/25 , C07C67/055 , Y02P20/125
摘要： 1. Acetic acid and/or vinyl acetate are produced by an integrated process which comprises the steps:(a) contacting in a first reaction zone a gaseous feedstock comprising ethylene and/or ethane and optionally steam with a molecular oxygen-containing gas in the presence of a catalyst active for the oxidation of ethylene to acetic acid and/or ethane to acetic acid and ethylene to produce a first product stream comprising acetic acid, water and ethylene (either as unreacted ethylene and/or as co-produced ethylene) and optionally also ethane, carbon monoxide, carbon dioxide and/or nitrogen;(b) contacting in a second reaction zone in the presence or absence of additional ethylene and/or acetic acid at least a portion of the first gaseous product stream comprising at least acetic acid and ethylene and optionally also one or more of water, ethane, carbon monoxide, carbon dioxide and/or nitrogen with a molecular oxygen-containing gas in the presence of a catalyst active for the production of vinyl acetate to produce a second product stream comprising vinyl acetate, water, acetic acid and optionally ethylene;(c) separating the product stream from step (b) by distillation into an overhead azeotrope fraction comprising vinyl acetate and water and a base fraction comprising acetic acid;(d) either (i) recovering acetic acid from the base fraction separated in step (c) and optionally recycling the azeotrope fraction separated in step (c) after partial or complete separation of the water therefrom to step (c),or (ii) recovering vinyl acetate from the azeotrope fraction separated in step (c) and optionally recycling the base fraction separated in step (c) to step (b),or (iii) recovering acetic acid from the base fraction separated in step (c) and recovering vinyl acetate from the overhead azeotrope fraction recovered in step (c).

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