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    • 5. 发明授权
    • Process for the production of photographic images and photographic
materials used in this process
    • 用于生产此过程中使用的摄影图像和照相材料的方法
    • US4353974A
    • 1982-10-12
    • US237012
    • 1981-02-23
    • Terence C. WebbPatrick D. P. ThomasWilliam E. Long
    • Terence C. WebbPatrick D. P. ThomasWilliam E. Long
    • G03C7/02G03C1/00G03C5/16G03C5/29G03C5/30G03C7/28G03C8/08G03C5/54
    • G03C8/08G03C5/16G03C5/3028G03C7/28Y10S430/162
    • A process for the production of a photographic image which comprises(a) imagewise exposing a photographic assembly which comprises at least during a silver halide developing step, in order optionally a supercoat layer, at least one silver halide emulsion layer, a layer containing a layer substantive hydroxypyridone azamethine compound of the general formula ##STR1## wherein R.sub.1 is hydrogen or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl, amino or heterocyclic radical, Y represents hydrogen or hydroxy, --CN, --COOR.sup.1, --CONR.sup.1 R.sup.2 or --COR.sup.1 or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical and Z is hydrogen or is --CN, --COOR.sup.3, --CONR.sup.3 R.sup.4, --SO.sub.3 H, --SO.sub.3.sup.- or --COR.sup.3, where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each independently represent hydrogen or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical, and E represents the atoms necessary to complete an optionally substituted heterocyclic or aromatic ring, and a support, there being optionally one or more interlayers between each of said components,(b) treating the exposed photographic assembly with an aqueous alkaline processing bath, containing a silver halide developer and(c) in the non-latent image areas, allowing the silver halide developer to diffuse in a counter-imagewise manner from the silver halide emulsion layer(s) to the layer containing the compound of formula (1) and there to bleach the compound to form a photographic dye image.The developers used in this process exhibit an increased stability against oxidizing agents.
    • 一种用于生产照相图像的方法,其包括(a)成像曝光照相组合件,其至少包括在卤化银显影步骤期间,任选地为超涂层,至少一个卤化银乳剂层,含有层 (1)其中R 1是氢或任选取代的烷基,芳烷基,环烷基,芳基,氨基或杂环基团的实质羟基吡啶酮氮杂酮化合物,Y代表氢或羟基,-CN,-COOR1,-CONR1R2或 -COR1或任选取代的烷基,芳烷基,环烷基,芳基或杂环基,Z是氢或是-CN,-COOR 3,-CONR 3 R 4,-SO 3 H,-SO 3 - 或-COR 3,其中R 1,R 2,R 3和R 4各自 独立地表示氢或任选取代的烷基,芳烷基,环烷基,芳基或杂环基,E表示完成任选取代的杂环或芳环所必需的原子,以及支持物, 每个所述组分之间的一个或多个中间层,(b)用含有卤化银显影剂的水性碱性处理浴处理曝光的照相组合物,和(c)在非潜像区域中,使卤化银显影剂扩散 以相对成像的方式从卤化银乳剂层到含有式(1)化合物的层,并漂白化合物以形成照相染料图像。 在该方法中使用的显影剂表现出对氧化剂的增加的稳定性。
    • 7. 发明授权
    • Development inhibitor releasing compounds and their use in photographic
materials
    • 发展抑制剂释放化合物及其在照相材料中的应用
    • US4259437A
    • 1981-03-31
    • US72735
    • 1979-09-05
    • Terence C. Webb
    • Terence C. Webb
    • G03C7/26C07C45/63C07C45/71C07D249/12C07D403/06G03C7/305G03C7/00G03C1/06
    • G03C7/305C07C45/63C07C45/71C07D249/12Y10S430/158
    • Development inhibitor releasing compounds of the formula ##STR1## are provided wherein R.sub.1 is hydrogen or a substituent which may contain a long chain ballasting group and n is 1 or 2, or R.sub.1 may form an annelated ring, R.sub.2 is hydrogen or alkyl having 1 to 4 carbon atoms, R.sub.3 is alkyl, aryl or aralkyl, Y is hydrogen, halogen, optionally substituted phenyl, --COOR.sub.4, --COR.sub.4, ##STR2## or --OR.sub.4 where R.sub.4 is alkyl or aryl or a group ##STR3## where Z represents the atoms necessary to complete an optionally substituted 5- or 6-membered heterocyclic ring which optionally may be benzannelated.The new DIR-compounds form colorless compounds when reacted with the oxidation products of the color developing agent. They have an extremely high reactivity with the oxidation products of the color developing agent so that only small quantities of the DIR-compounds are required to produce excellent intra-image and inter-image effects of excellent speed.
    • 提供了发展抑制剂释放式“IMAGE”的化合物,其中R 1是氢或可以含有长链压载基团且n为1或2的取代基,或R 1可以形成环状的环,R 2是氢或具有1〜 4个碳原子,R 3是烷基,芳基或芳烷基,Y是氢,卤素,任选取代的苯基,-COOR 4,-COR 4,-OR 4或-OR 4,其中R 4是烷基或芳基或一个基团,其中Z代表 必要的原子完成任选地被取代的5-或6-元杂环。 当与彩色显影剂的氧化产物反应时,新的DIR化合物形成无色的化合物。 它们与彩色显影剂的氧化产物具有非常高的反应性,因此仅需要少量的DIR化合物来产生出色的速度优异的图像内和图像间效果。
    • 8. 发明授权
    • Photographic elements containing amino-substituted hydroxy-pyridones
    • 含有氨基取代羟基 - 吡啶酮的摄影元素
    • US4233399A
    • 1980-11-11
    • US37071
    • 1979-05-08
    • Rainer KitzingJohn G. V. ScottTerence C. WebbGraham Evans
    • Rainer KitzingJohn G. V. ScottTerence C. WebbGraham Evans
    • C09B53/00C09B53/02G03C1/83G03C1/84
    • C09B53/02G03C1/83
    • Pyridone dyestuffs of the formula ##STR1## are provided wherein R.sub.1 is hydrogen or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical or an optionally substituted amino group,R.sub.2, R.sub.3, R.sub.4 each independently represent hydrogen, halogen, alkoxy, or optionally substituted alkyl or cycloalkyl,R.sub.5 and R.sub.6 each independently represent hydrogen or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical or R.sub.5 and R.sub.6, R.sub.3 and R.sub.5 and R.sub.4 and R.sub.6 form heterocyclic rings,Y is hydrogen or hydroxy, --CN, --COOR.sub.7, --CONR.sub.7 R.sub.8 or --COR.sub.7 or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical, andZ represents --CN, --COOR.sub.9, --CONR.sub.9 R.sub.10, --SO.sub.3 H, --SO.sub.3 .crclbar. or --COR.sub.9, where R.sub.7, R.sub.8, R.sub.9 and R.sub.10 each independently represent hydrogen or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical.The dyestuffs can be used e.g. as cyan image dyestuffs in photographic material, as diffusible dyes which may become mordanted in a receptor layer or as filter, antihalation or acutance dyes in photographic material.
    • 提供式“IMAGE”的吡啶酮染料,其中R 1为氢或任选取代的烷基,芳烷基,环烷基,芳基或杂环基或任选取代的氨基,R 2,R 3,R 4各自独立地表示氢,卤素,烷氧基或 任选取代的烷基或环烷基,R 5和R 6各自独立地表示氢或任选取代的烷基,芳烷基,环烷基,芳基或杂环基或R 5和R 6,R 3和R 5以及R 4和R 6形成杂环,Y是氢或羟基, CN,-COOR 7,-CONR 7 R 8或-COR 7或任选取代的烷基,芳烷基,环烷基,芳基或杂环基,Z表示-CN,-COOR 9,-CONR 9 R 10,-SO 3 H,-SO 3( - )或-COR 9, R 7,R 8,R 9和R 10各自独立地表示氢或任选取代的烷基,芳烷基,环烷基,芳基或杂环基。 染料可以例如使用。 作为照相材料中的青色图像染料,可以作为可能在受体层中变色的漫射染料或作为照相材料中的过滤器,防晕或吸收染料。
    • 9. 发明授权
    • Substituted 1,2,4-triazoles as DIR compounds and their use in
photographic materials
    • 取代的1,2,4-三唑作为DIR化合物及其在照相材料中的用途
    • US4362878A
    • 1982-12-07
    • US158979
    • 1980-06-12
    • Terence C. Webb
    • Terence C. Webb
    • G03C7/26C07C45/63C07C45/71C07D249/12C07D403/06G03C7/305
    • G03C7/305C07C45/63C07C45/71C07D249/12Y10S430/158
    • Development inhibitor releasing compounds of the formula: ##STR1## are provided wherein R.sub.1 is hydrogen or a substituent which may contain a long chain ballasting group and n is 1 or 2, or R.sub.1 may form an annelated ring, R.sub.2 is hydrogen or alkyl having 1 to 4 carbon atoms, R.sub.3 is alkyl, aryl or aralkyl, Y is hydrogen, halogen, optionally substituted phenyl, --COOR.sub.4, --COR.sub.4, ##STR2## or --OR.sub.4 where R.sub.4 is alkyl or aryl or a group ##STR3## where Z represents the atoms necessary to complete an optionally substituted 5- or 6-membered heterocyclic ring which optionally may be benzannelated.The new DIR-compounds form colorless compounds when reacted with the oxidation products of the color developing agent. They have an extremely high reactivity with the oxidation products of the color developing agent so that only small quantities of the DIR-compounds are required to produce excellent intra-image and inter-image effects of excellent speed.
    • 提供了具有下式的发展抑制剂释放化合物:其中R1是氢或可以含有长链压载基团且n为1或2的取代基,或R 1可以形成环状环,R 2是氢或具有1个 至4个碳原子,R 3为烷基,芳基或芳烷基,Y为氢,卤素,任选取代的苯基,-COOR 4,-COR 4,-OR 4或-OR 4,其中R 4为烷基或芳基或基团, 完成任选地被取代的5或6元杂环所必需的原子,其任选地可以被苄基化。 当与彩色显影剂的氧化产物反应时,新的DIR化合物形成无色的化合物。 它们与彩色显影剂的氧化产物具有非常高的反应性,因此仅需要少量的DIR化合物来产生出色的速度优异的图像内和图像间效果。