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1. 发明授权

US4283272A Manufacture of hydrocracked low pour lubricating oils 失效
标题翻译：加氢裂化低润滑油的制造
公开(公告)号：US4283272A
公开(公告)日：1981-08-11
申请号：US159011
申请日：1980-06-12
申请人： William E. Garwood , Murray R. Silk
发明人： William E. Garwood , Murray R. Silk
IPC分类号： C10G47/16 , C10G49/22 , C10G65/12 , C10G67/00 , C10G67/06
CPC分类号： C10G65/12 , C10G2400/10
摘要： Hydrocracked, low pour lubricating oils of good stability are manufactured by passing a suitable hydrocarbon feed and hydrogen sequentially through a hydrocracking zone, a catalytic dewaxing zone, and a hydrotreating zone, all at high pressure and in that order, with purification of the hydrogen gas prior to passage to the dewaxing zone. By maintaining all zones at high pressure, the efficiency of the process is augmented.
摘要翻译：通过使合适的烃进料和氢气依次通过加氢裂化区，催化脱蜡区和加氢处理区，全部以高压和顺序通过氢气净化来制备加氢裂化的低倾点润滑油在通过脱蜡区之前。通过将所有区域保持在高压状态，增加了处理效率。

2. 发明授权

US4283271A Manufacture of hydrocracked low pour lubricating oils 失效
标题翻译：加氢裂化低润滑油的制造
公开(公告)号：US4283271A
公开(公告)日：1981-08-11
申请号：US158980
申请日：1980-06-12
申请人： William E. Garwood , Murray R. Silk
发明人： William E. Garwood , Murray R. Silk
IPC分类号： C10G47/16 , C10G65/12 , C10G49/22
CPC分类号： C10G65/12 , C10G2400/10
摘要： Hydrocracked, low pour lubricating oils of good stability are manufactured by passing a suitable hydrocarbon feed sequentially through a hydrocracking zone, a catalytic dewaxing zone, and a hydrotreating zone, all at high pressure and in that order, and with separation of hydrocrackate from recycle hydrogen prior to dewaxing. Only clean makeup hydrogen is fed to the dewaxer, passed through the hydrotreater, and then on to the hydrocracker, thereby providing an exceptionally efficient process.
摘要翻译：通过使合适的烃进料依次通过加氢裂化区，催化脱蜡区和加氢处理区，全部以高压和依次顺序，并将氢化裂解物从再循环氢气中分离出来制备具有良好稳定性的加氢裂化低倾点润滑油脱蜡之前。只有干净的补充氢气才能进入脱蜡机，通过加氢处理器，然后再加到加氢裂化器上，从而提供了非常有效的工艺。

3. 发明授权

US5243112A Lubricant range hydrocarbons from light olefins 失效
标题翻译：来自轻质烯烃的润滑剂范围烃
公开(公告)号：US5243112A
公开(公告)日：1993-09-07
申请号：US776247
申请日：1985-09-16
申请人： Arthur W. Chester , Francis G. Dwyer , William E. Garwood , James C. Vartuli
发明人： Arthur W. Chester , Francis G. Dwyer , William E. Garwood , James C. Vartuli
IPC分类号： C07C2/12
CPC分类号： C07C2/12 , C07C2529/70
摘要： Lower olefins are upgraded to high viscosity index lubricants by converting olefinic feed over a medium pore zeolite catalyst consisting essentially of aluminosilicate HzSM-22 under oligomerization conditions.
摘要翻译：通过在低聚条件下通过基本上由铝硅酸盐HzSM-22组成的中孔沸石催化剂转化烯烃进料，将低级烯烃升级为高粘度指数润滑剂。

4. 发明授权

US5140949A Zeolite-clay composition and uses thereof 失效
公开(公告)号：US5140949A
公开(公告)日：1992-08-25
申请号：US758668
申请日：1991-09-12
申请人： Pochen Chu , William E. Garwood
发明人： Pochen Chu , William E. Garwood
IPC分类号： A23K1/175 , B01J20/16 , B01J20/18
CPC分类号： B01J20/18 , A23K20/28 , B01J20/16
摘要： A hydrous aluminosilicate adsorbent composition in which the active adsorbent is a mixture of non-fibrous clay with non-fibrous zeolite. The composition is useful as a feed supplement in animal husbandry, and as a topical adsorbent for veterinary use. The mixture has a high capacity for adsorption of ammonium cations, and a synergistically high selectivity for their adsorption. Beneficial effects as feed supplement may arise from lowering the amount of ammonia passed to the liver from the alimentary canal.

5. 发明授权

US4942021A Multistage system for conversion of lower olefins with reactor quenching means 失效
标题翻译：用反应器淬火方法转化低级烯烃的多级体系
公开(公告)号：US4942021A
公开(公告)日：1990-07-17
申请号：US137224
申请日：1987-12-23
申请人： William E. Garwood , Frederick J. Krambeck , John D. Kushnerick , Samuel A. Tabak
发明人： William E. Garwood , Frederick J. Krambeck , John D. Kushnerick , Samuel A. Tabak
IPC分类号： C07C2/12 , C07C11/02 , C10G50/00
CPC分类号： C07C11/02 , C07C2/12 , C10G50/00
摘要： A continuous multistage catalytic conversion system for upgrading lower olefins comprisingfirst adaibatic catalytic bed reactor means containing an acidic zeolite solid catalyst;means for feeding light olefinic gas directly to the first reactor without addition of separate diluent or recycle streams;means for operating the first reactor under olefin partial conversion conditions at elevated temperature to control adiabatic temperature increase;interstage quench means for injecting a liquid coolant directly into first stage effluent for reducing the temperature thereof and protecting downstream catalyst;second catalytic bed reactor means for receiving cooled first stage effluent with injected liquid coolant and further converting the olefins over a metallic zeolite catalyst having a metal ethene oligomerization component;means for cooling and recovering heavier liquid hydrocarbon product from the second reactor effluent; andmeans for recovering liquid coolant from the second effluent for recycle to the interstage quench means.
摘要翻译：一种用于升级低级烯烃的连续多级催化转化系统，包括含有酸性沸石固体催化剂的第一辅助催化床反应器装置; 用于将轻质烯属气体直接供给到第一反应器而不加入单独的稀释剂或再循环流的装置; 用于在高温下在烯烃部分转化条件下操作第一反应器的装置，以控制绝热温度升高; 级间骤冷装置，用于将液体冷却剂直接注入第一级流出物中以降低其温度并保护下游催化剂; 第二催化床反应器装置，用于接收具有注入的液体冷却剂的冷却的第一级流出物，并进一步转化具有金属乙烯低聚组分的金属沸石催化剂的烯烃; 用于从第二反应器流出物冷却和回收较重液体烃产物的装置; 以及用于从第二流出物回收液体冷却剂以再循环到级间骤冷装置的装置。

6. 发明授权

US4414097A Catalytic process for manufacture of low pour lubricating oils 失效
标题翻译：用于制造低润滑油的催化方法
公开(公告)号：US4414097A
公开(公告)日：1983-11-08
申请号：US369852
申请日：1982-04-19
申请人： Arthur W. Chester , William E. Garwood
发明人： Arthur W. Chester , William E. Garwood
IPC分类号： B01J29/00 , B01J29/65 , B01J29/70 , B01J29/74 , C10G45/64 , C10G65/12 , C10G67/04 , C10G49/08 , C10G47/16
CPC分类号： B01J29/74 , B01J29/70 , B01J2229/26 , B01J2229/42 , C10G2400/10
摘要： This invention relates to an energy-efficient process for dewaxing hydrocrackate and manufacturing a stabilized and dewaxed hydrocracked lubricating oil stock from hydrocarbon feedstock boiling above about 343.degree. C.
摘要翻译：本发明涉及一种用于脱氢加氢裂化剂的能量有效的方法，并从沸点高于约343℃的烃原料制备稳定和脱蜡的加氢裂化润滑油原料。

7. 发明授权

US4361503A Catalyst for converting synthesis gas to high octane predominantly olefinic naphtha 失效
标题翻译：将合成气转化为高辛烷值主要是烯烃石脑油的催化剂
公开(公告)号：US4361503A
公开(公告)日：1982-11-30
申请号：US220923
申请日：1980-12-29
申请人： Francis G. Dwyer , William E. Garwood
发明人： Francis G. Dwyer , William E. Garwood
IPC分类号： B01J29/40 , B01J29/46 , C07C1/04 , B01J29/28 , B01J29/30
CPC分类号： C07C1/044 , B01J29/40 , B01J29/46 , B01J2229/26 , B01J2229/42 , C07C2529/072
摘要： An improved catalyst composition is disclosed for converting synthesis gas to hydrocarbon mixtures. The catalyst comprises an iron-containing, Fischer-Tropsch catalyst and a crystalline zeolite having a silica-to-alumina ratio of greater than 200 (including zeolites containing essentially no alumina) and an (R.sub.2 O+M.sub.2 /.sub.n O):SiO.sub.2 rate of less than 1.1:1 where M is a metal other than a metal of Group IIIA, n is the valence of said metal, and R is an alkyl ammonium radical, said organosilicate being characterized by a specified x-ray diffraction pattern.
摘要翻译：公开了一种改进的催化剂组合物，用于将合成气转化为烃混合物。催化剂包含含铁的费 - 托催化剂和二氧化硅与氧化铝之比大于200的结晶沸石（包括基本上不含氧化铝的沸石）和（R2O + M2 / nO）：SiO 2的比例较小超过1.1:1，其中M是不同于IIIA族金属的金属，n是所述金属的化合价，R是烷基铵基团，所述有机硅酸盐的特征在于规定的x射线衍射图。

8. 发明授权

US4313821A Processing of coal liquefaction products 失效
标题翻译：煤液化产品加工
公开(公告)号：US4313821A
公开(公告)日：1982-02-02
申请号：US128658
申请日：1980-03-10
申请人： William E. Garwood , Sterling E. Voltz , Ellen L. Wu
发明人： William E. Garwood , Sterling E. Voltz , Ellen L. Wu
IPC分类号： C10G1/00 , C10G53/08 , C10G61/06 , C10G25/05
CPC分类号： C10G1/002 , C10G2400/02
摘要： A process for removing undesirable elements, e.g. nitrogen, sulfur, oxygen, from the light organic liquid product derived from a solvent refined coal liquefaction process, while preserving octane number, which comprises the steps of (1) subjecting the light liquids to an ion-exchange resin treatment and (2) contacting the resulting ion-exchanged liquids with a zeolite acting as an adsorbent under specified conditions of space velocity, temperature and pressure.
摘要翻译：用于去除不需要的元素的方法，例如氮，硫，氧，来自溶剂精炼煤液化工艺的轻质有机液体产物，同时保持辛烷值，其包括以下步骤：（1）使轻液体进行离子交换树脂处理和（2）接触所得到的离子交换液体在空速，温度和压力的特定条件下具有作为吸附剂的沸石。

9. 发明授权

US4211640A Process for the treatment of olefinic gasoline 失效
标题翻译：烯烃汽油的处理方法
公开(公告)号：US4211640A
公开(公告)日：1980-07-08
申请号：US41844
申请日：1979-05-24
申请人： William E. Garwood , Wooyoung Lee
发明人： William E. Garwood , Wooyoung Lee
IPC分类号： C10G57/02 , B01J21/12 , B01J29/40 , C10G29/16 , C10G35/095 , C10G50/00 , C10G25/04
CPC分类号： B01J29/40 , C10G29/16
摘要： A process is disclosed for the treatment of highly olefinic gasoline containing at least about 50% by weight of olefins by contacting said olefinic gasoline with a special group of acidic crystalline aluminosilicate zeolites, such as those of the ZSM-5 type in order to enhance the gum stability of said gasoline and produce products comprising both gasoline and fuel oil.
摘要翻译：公开了一种用于处理含有至少约50重量％的烯烃的高度烯烃汽油的方法，其中所述烯烃汽油与特殊的一组酸性结晶硅铝酸盐沸石（例如ZSM-5型沸石）相接触，以增强所述汽油的胶稳定性并且产生包含汽油和燃料油的产品。

10. 发明授权

US4049734A Conversion of coal to high octane gasoline 失效
标题翻译：煤转化为高辛烷值汽油
公开(公告)号：US4049734A
公开(公告)日：1977-09-20
申请号：US566149
申请日：1975-04-08
申请人： William E. Garwood , Solomon M. Jacob , James C. Kuo , John J. Wise
发明人： William E. Garwood , Solomon M. Jacob , James C. Kuo , John J. Wise
IPC分类号： C07C2/62 , C10L1/06 , C07G15/00
CPC分类号： C10L1/06 , C07C2/62 , Y02P20/125 , Y10S585/934 , Y10S585/943
摘要： An integrated process for converting coal to high octane gasoline by gasifying the coal in such manner as to form a gas comprising carbon oxides, hydrogen and methane; contacting this gas in one or a series of steps with one or a series of catalysts, respectively comprising a special high silica to alumina ratio zeolite; converting the carbon oxides and hydrogen by such contact to a product comprising water, high octane aromatic gasoline and light hydrocarbon gases; alkylating the C.sub.3 and C.sub.4 olefins with the isobutane in the light gases to produce alkylate gasoline; admixing the aromatic and alkylate gasolines; and subjecting the C.sub.2.sup.- portion of the product to catalytic methanation via a nickel catalyst to produce synthetic natural gas.
摘要翻译：通过气化煤以形成包含碳氧化物，氢气和甲烷的气体的方式将煤转化为高辛烷值汽油的综合方法; 将该气体与一种或一系列催化剂在一个或一系列步骤中接触，分别包含特殊的高二氧化硅与氧化铝比的沸石; 通过这样的接触将碳氧化物和氢气转化为包含水，高辛烷值芳烃汽油和轻烃气体的产品; 在轻质气体中用异丁烷烷基化C3和C4烯烃以产生烷基化汽油; 混合芳族和烷基化汽油; 并使产物的C2部分经由镍催化剂进行催化甲烷化以产生合成天然气。

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