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1. 发明授权

US5138046A Process for preparing alkylglucoside compounds from oligo- and/or polysaccharides 失效
标题翻译：从寡糖和/或多糖制备烷基葡糖苷化合物的方法
公开(公告)号：US5138046A
公开(公告)日：1992-08-11
申请号：US656041
申请日：1991-05-13
申请人： Willi Wuest , Rainer Eskuchen , Josef Wollman , Karlheinz Hill , Manfred Biermann
发明人： Willi Wuest , Rainer Eskuchen , Josef Wollman , Karlheinz Hill , Manfred Biermann
IPC分类号： B01F17/56 , C07H15/04 , C08B31/10 , C11D1/68
CPC分类号： C07H15/04 , Y02P20/582
摘要： Surface active alkylglucosides are prepared in a 2-step process from starch or starch degradation products such as polyglucose or glucose syrup, the first step consisting of reaction with a short chained alcohol, particularly butanol, while the second step comprises transacetalization with the longer chained C.sub.8-22, more particularly C.sub.12-18, alcohol, with fatty alcohols of natural origin preferably being used.
摘要翻译： PCT No.PCT / EP89 / 00923。 371日期1991年5月13日 102（e）日期1991年5月13日PCT PCT 1989年8月4日PCT公布。出版物WO90 / 01489 1990年2月22日。表面活性烷基葡糖苷以淀粉或淀粉降解产物如葡萄糖或葡萄糖浆为原料，以两步法制备，第一步是与短链醇（特别是丁醇）反应，其中第二步包括使用较长链C8-22，更特别是C12-18醇，与优选使用天然来源的脂肪醇进行缩醛化。

2. 发明授权

US5576425A Process for the direct production of alkyl glycosides 失效
标题翻译：直接生产烷基糖苷的方法
公开(公告)号：US5576425A
公开(公告)日：1996-11-19
申请号：US279673
申请日：1994-07-25
申请人： Karlheinz Hill , Manfred Biermann , Henry Rossmaier , Rainer Eskuchen , Willi Wuest , Josef Wollmann , Andreas Bruns , Guenter Hellmann , Karl-Heinz Ott , Walter Winkle , Klaus Wollmann
发明人： Karlheinz Hill , Manfred Biermann , Henry Rossmaier , Rainer Eskuchen , Willi Wuest , Josef Wollmann , Andreas Bruns , Guenter Hellmann , Karl-Heinz Ott , Walter Winkle , Klaus Wollmann
IPC分类号： C07H15/04 , C07G3/00 , C07H1/00
CPC分类号： C07H15/04
摘要： The aliphatic primary alcohols are reacted with a glycose, more especially glucose, in the presence of an acidic catalyst in certain process steps so that particularly light-colored and alkali-stable alkyl glucosides are obtained after a subsequent, compulsory bleaching step, which represents an improvement over known direct synthesis processes. The process may be carried out both on a laboratory scale and also on an industrial production scale.
摘要翻译：脂肪族伯醇在一定的工艺步骤中，在酸性催化剂的存在下，与糖，更特别是葡萄糖反应，从而在随后的强制漂白步骤之后获得特别是浅色和碱稳定的烷基葡糖苷，改进已知的直接合成方法。该过程可以在实验室规模上进行，也可以在工业生产规模上进行。

3. 发明授权

US5374716A Process for the production of surface active alkyl glycosides 失效
标题翻译：生产表面活性烷基糖苷的方法
公开(公告)号：US5374716A
公开(公告)日：1994-12-20
申请号：US517955
申请日：1990-04-27
申请人： Manfred Biermann , Karlheinz Hill , Willi Wuest , Rainer Eskuchen , Josef Wollmann , Andreas Bruns , Guenter Hellmann , Karl-Heinz Ott , Walter Winkle , Klaus Wollmann
发明人： Manfred Biermann , Karlheinz Hill , Willi Wuest , Rainer Eskuchen , Josef Wollmann , Andreas Bruns , Guenter Hellmann , Karl-Heinz Ott , Walter Winkle , Klaus Wollmann
IPC分类号： B01F17/56 , C07H15/04 , C11D1/68 , C07H1/00 , C07H15/10 , C08B31/10
CPC分类号： C07H15/04
摘要： A process for the production of surface-active alkyl glycosides which is carried out by the transacetalization method with butanol, leads to a new alkyl glycoside as end product which is characterized by high color-stability in alkaline medium; besides a high proportion of alkyl monoglycoside, the product also contains polyglycoside on polyglycose and butyl glucoside.
摘要翻译：通过用丁醇进行转化方法制备表面活性烷基糖苷的方法，得到新的烷基糖苷作为终产物，其特征在于在碱性介质中具有高的颜色稳定性; 除了高比例的烷基单糖苷外，该产品还含有聚糖苷和丁基葡糖苷上的多糖苷。

4. 发明授权

US5312974A Process for the production of light-colored lower alkane-sulfonic acids, more particularly methanesulfonic acid 失效
标题翻译：制备浅色低级烷烃磺酸，更特别是甲磺酸的方法
公开(公告)号：US5312974A
公开(公告)日：1994-05-17
申请号：US778825
申请日：1991-12-19
申请人： Willi Wuest , Rainer Eskuchen , Christoph Lohr
发明人： Willi Wuest , Rainer Eskuchen , Christoph Lohr
IPC分类号： C07C303/02 , C07C309/04 , C07C61/00
CPC分类号： C07C303/02
摘要： The description is of a process for the production of light-colored lower alkane sulfonic acids, especially methane sulphonic acid, by reacting the corresponding alkyl halide with alkaline halides and obtaining the free alkane sulphonic acid. In the process of the invention, the reaction is performed as a liquid/liquid reaction at temperature not exceeding 120 degrees C., and at such high pressures that even the lower alkyl halide is in the liquid phase at the reaction temperature, the aqueous reaction mixture is reduced by water content of some 50% wt. at the most, the alkaline sulphonic acid is liberated from its alkaline salt by the addition of HCl, the solid salt phase still remaining in the reaction mixture is separated out and the free alkaline sulphonic acid is obtained from the liquid phase. To obtain an alkane sulphonic acid which is virtually free of chloride ions, the primary reaction product concentrated into the aqueous salt sludge by the partial removal of water is preferably converted with a multi-molar excess of HCl is extracted from the isolated liquid phase and virtually chloride-free alkane sulphonic acid is obtained together with the residual water as the basic phase of distillation.
摘要翻译： PCT No.PCT / EP90 / 00962 Sec。 371 1991年12月19日第 102（e）1991年12月19日PCT PCT 1990年6月19日PCT公布。公开号WO91 / 00268 日本1991年1月10日。该描述是通过使相应的烷基卤化物与碱性卤化物反应并获得游离烷烃磺酸来生产浅色低级烷烃磺酸，特别是甲磺酸的方法。在本发明的方法中，反应在不超过120℃的温度下作为液/液反应进行，并且在如此高的压力下，即使低级烷基卤化物在反应温度下处于液相，混合物的含水量减少了约50％wt。最多的是通过加入HCl将碱性磺酸从其碱性盐中释放出来，分离残留在反应混合物中的固体盐相，从液相中获得游离碱性磺酸。为了获得基本上不含氯离子的烷烃磺酸，通过部分除去水而浓缩到含水盐污泥中的初级反应产物优选用多摩尔过量的HCl从分离的液相中提取，实际上与残余水一起作为蒸馏的基本相，获得不含氯化物的烷烃磺酸。

5. 发明授权

US5041691A Aldol condensation of nitroparaffins 失效
标题翻译：硝基烷烃的醛醇缩合
公开(公告)号：US5041691A
公开(公告)日：1991-08-20
申请号：US345517
申请日：1989-05-01
申请人： Willi Wuest , Rainer Eskuchen , Herbert Esser
发明人： Willi Wuest , Rainer Eskuchen , Herbert Esser
IPC分类号： C07C67/00 , C07C201/00 , C07C201/12 , C07C205/12 , C07C205/15
CPC分类号： C07C201/12
摘要： A process for reacting nitroparaffins with formaldehyde in the presence of potassium hydroxide by aldol condensation which can be carried out continuously or discontinuously and on a large scale. This is achieved by mixing the nitroparaffin, aqueous aldehyde solution and potassium hydroxide in the absence of organic solvents and carrying out the reaction while maintaining the temperature between -5.degree. and +20.degree. C.
摘要翻译：在氢氧化钾存在下，通过醛醇缩合使硝基烷烃与甲醛反应的方法，其可以连续地或不连续地并且大规模地进行。这是通过在不存在有机溶剂的情况下将硝基石蜡，醛水溶液和氢氧化钾混合并在保持温度在-5℃和+ 20℃之间进行反应来实现的。

6. 发明授权

US5318709A Process for the production of surfactant mixtures based on ether sulfonates and their use 失效
标题翻译：用于生产基于醚磺酸盐的表面活性剂混合物及其用途的方法
公开(公告)号：US5318709A
公开(公告)日：1994-06-07
申请号：US778116
申请日：1991-12-05
申请人： Willi Wuest , Rainer Eskuchen , Bernd Richter
发明人： Willi Wuest , Rainer Eskuchen , Bernd Richter
IPC分类号： B01F17/02 , C07C303/02 , C07C303/32 , C09K8/584 , E21B43/22 , C07C309/09
CPC分类号： C07C303/02 , C07C303/32 , C09K8/584 , Y10S507/936
摘要： A process for the production of a surfactant mixture for use in enhanced oil recovery wherein the surfactant mixture comprises an alkyl ether sulfonic acid or salt thereof as a principal constituent and at most a substantially equal quantity of alkoxylated alcohol. The surfactant mixture is prepared by reacting an alkyl ether sulfate with a stoichiometric excess of an alkali metal sulfite solution at about 160.degree. C. to 220.degree. C. under mildly alkaline pH conditions, and then extracting sulfate salt therefrom using a substantially water-insoluble alcohol at a lowered temperature.
摘要翻译： PCT No.PCT / EP90 / 00855 Sec。 371 1991年12月5日第 102（e）1991年12月5日日期PCT提交1990年5月28日PCT公布。 WO90 / 15050 PCT公开号日本1990年12月13日。一种用于生产用于增强油采收率的表面活性剂混合物的方法，其中表面活性剂混合物包含烷基醚磺酸或其盐作为主要成分和至多基本相等量的烷氧基化醇。表面活性剂混合物通过烷基醚硫酸盐与化学计量过量的碱金属亚硫酸盐溶液在约160℃至220℃下在温和碱性pH条件下反应制备，然后使用基本上不溶于水的硫酸盐酒精在降低的温度。

7. 发明授权

US4927946A Process for the preparation of 5-bromo-5-nitro-1,3-dioxane 失效
标题翻译：制备5-溴-5-硝基-1,3-二恶烷的方法
公开(公告)号：US4927946A
公开(公告)日：1990-05-22
申请号：US345918
申请日：1989-05-01
申请人： Willi Wuest , Rainer Eskuchen , Herbert Esser , Hasso Leischner
发明人： Willi Wuest , Rainer Eskuchen , Herbert Esser , Hasso Leischner
IPC分类号： C07D319/06
CPC分类号： C07D319/06
摘要： Unpurified 2-bromo-2-nitro-1,3-propanediol is used as the starting material for a process for the preparation of 5-bromo-5-nitro-1,3-dioxane from 2-nitro-1,3-propanediol without the use of an organic solvent on an industrial scale. This is carried out in such a way that in a first stage a mixture of bromine and aqueous hydrogen bromide solution is cooled and an aqueous solution of an alkali metal or an alkaline-earth metal salt of 2-nitro-1,3-propanediol is added at such a rate that, with cooling, the maximum reaction temperature does not exceed 30.degree. C., and then in a second reaction stage paraformaldehyde and sulfuric acid are added, left to react above room temperature, and the organic phase separated.
摘要翻译：未纯化的2-溴-2-硝基-1,3-丙二醇用作从2-硝基-1,3-丙二醇制备5-溴-5-硝基-1,3-二恶烷的方法的起始原料而不使用工业规模的有机溶剂。以这样的方式进行：在第一阶段中，将溴和溴化氢水溶液的混合物冷却，并将2-硝基-1,3-丙二醇的碱金属或碱土金属盐的水溶液为以这样的速度加入，冷却后最大反应温度不超过30℃，然后在第二反应阶段加入多聚甲醛和硫酸，使其在室温以上反应，分离有机相。

8. 发明授权

US5559219A Modified process for the direct production of alkyl glycosides 失效
标题翻译：直接生产烷基糖苷的改良方法
公开(公告)号：US5559219A
公开(公告)日：1996-09-24
申请号：US952535
申请日：1992-02-09
申请人： Willi Wuest , Joseph Wollmann , Rainer Eskuchen
发明人： Willi Wuest , Joseph Wollmann , Rainer Eskuchen
IPC分类号： C07H15/04 , C07H1/00 , C07H3/02
CPC分类号： C07H15/04
摘要： Alkyl glycosides are produced by direct synthesis from higher monofunctional alcohols and powder-form glycoses, particularly anhydrous glucose and/or glucose monohydrate, in the presence of acidic catalysts at elevated temperatures, the interior of the reactor being kept under reduced pressure and the glycose being introduced with delay into the alcohol reactants present in excess therein, the alcohol reactants containing the acidic catalyst and being heated to the reaction temperature, while water released in the reaction mixture is removed from the reaction zone via the gas phase. A partial stream is run off from the liquid reaction mixture and delivered to a premixing zone into which the powder-form reactant is simultaneously introduced and is converted with the liquid partial stream into a paste which is delivered to the interior of the reactor via a following intensive mixer. The premixing zone is in direct pressure equalization with the reduced pressure of the reactor interior via the intensive mixer on the one hand and, at the same time, with the ambient pressure via the feed unit used for the powder-form glycose on the other hand, the consistency of the paste formed in the premixing zone being selected so that the paste serves as a pressure-equalizing sealing compound and, hence, as a so-called "living seal".
摘要翻译： PCT No.PCT / EP91 / 01010 Sec。 371日期1992年2月9日 102（e）1992年2月9日PCT PCT 1991年5月31日PCT公布。出版物WO91 / 19722 日期1991年12月26日烷基糖苷通过在高温下在酸性催化剂存在下由高级单官能醇和粉末形糖糖，特别是无水葡萄糖和/或葡萄糖一水合物进行直接合成来制备，反应器内部保持减少压力，并且将糖类延迟引入其中存在的醇反应物中，醇反应物含有酸性催化剂并被加热至反应温度，同时通过气相将反应混合物中释放的水从反应区除去。部分物流从液体反应混合物中流出并且被输送到预混合区，粉末形式的反应物同时被引入到该预混合区中，并且用液体部分流转化成糊状物，该浆料经由下列物质被输送到反应器的内部密集搅拌机一方面，预混合区域通过强化混合器在反应器内部的压力下进行直接均压，另一方面，通过用于粉末形式的糖的进料单元的环境压力选择在预混合区中形成的糊状物的稠度，使得糊状物用作均压密封剂，因此作为所谓的“活性密封”。

9. 发明授权

US5510482A Process for bleaching discolored surface-active alkyl glycosides and for working up the bleached material 失效
标题翻译：用于漂白变色的表面活性烷基糖苷并用于处理漂白材料的方法
公开(公告)号：US5510482A
公开(公告)日：1996-04-23
申请号：US324318
申请日：1994-10-17
申请人： Willi Wuest , Rainer Eskuchen , Paul Schulz , Volker Bauer , Franz-Josef Carduck , Herbert Esser , Christiane Zeise , Manfred Weuthen , Josef Penninger
发明人： Willi Wuest , Rainer Eskuchen , Paul Schulz , Volker Bauer , Franz-Josef Carduck , Herbert Esser , Christiane Zeise , Manfred Weuthen , Josef Penninger
IPC分类号： C07H15/04 , C07H1/06
CPC分类号： C07H15/04
摘要： The crude reaction products from the synthesis of alkyl glycosides are bleached by kneading the material substantially freed from the excess fatty alcohol and containing at most limited quantities of water with an oxidizing agent at such elevated temperatures that the reaction mixture lends itself to plastic processing. Temperatures of from about 50.degree. to 150.degree. C. are particularly suitable, although it is best to apply temperatures in the range from about 80.degree. to 100.degree. C. using aqueous hydrogen peroxide as the oxidizing agent. Bleaching is carried out under basic conditions, optionally by addition of an alkaline compound, such as for example 50% sodium hydroxide solution. The bleached product accumulates in the form of a solid. It is preferably mixed with typical compatible solids, more particularly typical constituents of detergents and cleaning preparations, to form a solid and preferably free-flowing alkyl glycoside compound.
摘要翻译：来自合成烷基糖苷的粗反应产物通过在基本上不含过量脂肪醇的物质中混合并在氧化剂中含有至多有限量的水的温度下漂白，使得反应混合物适合塑性加工。约50℃至150℃的温度是特别合适的，尽管最好使用过氧化氢水溶液作为氧化剂，在约80℃至100℃的范围内施加温度。漂白在碱性条件下进行，任选地加入碱性化合物，例如50％氢氧化钠溶液。漂白产品以固体的形式积聚。其优选与典型的相容性固体，更特别是洗涤剂和清洁制剂的典型组分混合以形成固体和优选自由流动的烷基糖苷化合物。

10. 发明授权

US5001285A Process for the bromination of nitro-alcohols 失效
标题翻译：溴化硝基醇的方法
公开(公告)号：US5001285A
公开(公告)日：1991-03-19
申请号：US345516
申请日：1989-05-01
申请人： Willi Wuest , Rainer Eskuchen , Herbert Esser
发明人： Willi Wuest , Rainer Eskuchen , Herbert Esser
IPC分类号： C07C67/00 , C07C201/00 , C07C201/12 , C07C205/08 , C07C205/15 , C07C205/26
CPC分类号： C07C201/12
摘要： A process for the preparation of geminate bromo-nitro-alcohols by the bromination of alkali metal or alkaline-earth metal salts of nitroalcohols in aqueous solution, while cooling the reaction mixture so that the maximum reaction temperature does not exceed 30.degree. C. In carrying out the reaction, the aqueous solution of nitroalcohol salt is added to a mixture of bromine and aqueous hydrobromic acid.
摘要翻译：通过在水溶液中溴化碱金属或硝基醇的碱土金属盐，同时冷却反应混合物使得最大反应温度不超过30℃，从而制备配位溴 - 硝基醇。反应后，将硝基醇盐的水溶液加入到溴和氢溴酸水溶液的混合物中。

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