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1. 发明授权

US07473724B2 Preparation of silica reinforced polyisoprene-rich rubber composition and tire with component thereof 失效
标题翻译：二氧化硅增强的富含聚异戊二烯的橡胶组合物和其组分的轮胎的制备
公开(公告)号：US07473724B2
公开(公告)日：2009-01-06
申请号：US11058531
申请日：2005-02-15
申请人： Wen-Liang Hsu , Shingo Futamura , Kenneth Allen Bates , Adel Farhan Halasa , Kuo-Chih Hua , Bruce Raymond Hahn
发明人： Wen-Liang Hsu , Shingo Futamura , Kenneth Allen Bates , Adel Farhan Halasa , Kuo-Chih Hua , Bruce Raymond Hahn
IPC分类号： C08K5/15
CPC分类号： B60C1/0016
摘要： This invention relates to the preparation of a cis 1,4-polyisoprene rubber-rich rubber composition containing precipitated silica which has been pre-treated with a fatty alcohol and/or epoxidized soybean oil together with an organosilane containing polysulfide coupling agent and to tires having at least one component comprised of such rubber composition. The invention particularly relates to a process of (a) preparing a natural rubber-rich rubber composition comprised of pre-treating precipitated silica aggregates prior to blending with, or in the presence of, dry natural rubber with a fatty alcohol and/or epoxidized soybean oil to the exclusion of sulfur curative for the natural rubber, mixing an organalkoxysiloxane based polysulfide coupling agent with said dry natural rubber coincidentally with or subsequent to said precipitated silica aggregate fatty alcohol and/or epoxidized soybean oil pre-treatment to form a composite thereof, to the exclusion of sulfur curative, followed by (b) mixing the resulting rubber mixture with sulfur curative and (c) curing the resulting rubber composition.
摘要翻译：本发明涉及含有沉淀二氧化硅的顺式1,4-聚异戊二烯橡胶丰富橡胶组合物的制备，该组合物已经用脂肪醇和/或环氧化大豆油与含有机硅烷的多硫化物偶联剂预处理，并且具有至少一种由这种橡胶组合物组成的组分。本发明特别涉及（a）制备富含天然橡胶的橡胶组合物的方法，所述橡胶组合物在与天然橡胶与脂肪醇和/或环氧化大豆混合之前或在干燥天然橡胶存在下预处理沉淀二氧化硅骨料油，以排除天然橡胶的硫固化剂，将所述有机烷氧基硅氧烷基多硫化物偶联剂与所述干燥天然橡胶在所述沉淀二氧化硅骨料脂肪醇和/或环氧化大豆油预处理中或之后巧合地混合以形成其复合物，排除硫固化剂，然后（b）将所得橡胶混合物与硫固化剂混合，和（c）固化所得橡胶组合物。

2. 发明授权

US07906593B2 Rubber composition containing an alkoxysilane coupled in-chain functionalized elastomer and tire with component thereof 有权
标题翻译：含有烷氧基硅烷的链烷基官能化弹性体和轮胎与其组分的橡胶组合物
公开(公告)号：US07906593B2
公开(公告)日：2011-03-15
申请号：US11110025
申请日：2005-04-20
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Kenneth Allen Bates , David Andrew Benko , Shingo Futamura , Kuo-Chih Hua
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Kenneth Allen Bates , David Andrew Benko , Shingo Futamura , Kuo-Chih Hua
IPC分类号： C08C19/12 , C08F4/46 , C08F236/00 , C08F30/08 , B60K15/04 , B60C1/00 , C08K5/24 , A61K8/81 , C08G73/10
CPC分类号： B60C1/0016 , C08C19/25 , C08C19/44 , C08L15/00 , C08L19/006 , C08L21/00 , C08L2666/08
摘要： This invention relates to a precipitated silica reinforced conjugated diene-based elastomer composition containing an alkoxysilane coupled, in-chain functionalized, conjugated diene-based elastomer and to a tire having at least one component thereof. Said in-chain functionalized conjugated diene-based elastomer is a conjugated diene-based elastomer which contains a plurality of at least one of in-chain p- and m-(2-pyrrolidinoethyl) styrene (PES) and m-(2-pyrrolidino-1-methylethyl) alpha-methylstyrene (PAMS) groups.
摘要翻译：本发明涉及一种沉淀二氧化硅增强共轭二烯系弹性体组合物，其含有烷氧基硅烷偶联，链内官能化共轭二烯类弹性体和具有至少一种组分的轮胎。所述的链内官能化共轭二烯系弹性体是共轭二烯系弹性体，其含有多个至少一种链内对称和间 - （2-吡咯烷基乙基）苯乙烯（PES）和间 - （2-吡咯烷子基） -1-甲基乙基）α-甲基苯乙烯（PAMS）基团。

3. 发明授权

US07285584B2 Tire with component comprised of rubber composition containing hydrophobated, pre-silanized silica 失效
公开(公告)号：US07285584B2
公开(公告)日：2007-10-23
申请号：US11303279
申请日：2005-12-16
申请人： Wen-Liang Hsu , Shingo Futamura , Kuo-Chih Hua , Kenneth Allen Bates , Ping Zhang
发明人： Wen-Liang Hsu , Shingo Futamura , Kuo-Chih Hua , Kenneth Allen Bates , Ping Zhang
IPC分类号： C08K9/06 , C08K3/36
CPC分类号： B60C1/0025 , B60C1/00 , B60C1/0016 , B60C2001/0033 , C08K5/103 , C08K9/06 , Y10S152/905 , Y10T152/10495 , C08L21/00
摘要： The invention relates to a tire having at least one component comprised of a rubber composition which contains a hydrophobated, pre-silanized silica, namely a pre-silanized silica hydrophobated with an epoxidized soybean oil and/or epoxidized rubber tree seed oil in situ within said rubber composition. Such tire component may be, for example although not limited to, a tire tread, sidewall and/or sidewall insert.

4. 发明申请

US20080066838A1 Carbon black-rich rubber composition containing particulate hydrophylic water absorbing polymer and tire with tread thereof 审中-公开
标题翻译：含有炭黑的橡胶组合物含有颗粒状亲水吸收聚合物和具有胎面的轮胎
公开(公告)号：US20080066838A1
公开(公告)日：2008-03-20
申请号：US11517631
申请日：2006-09-08
申请人： Ping Zhang , Paul Harry Sandstrom , Joseph John Kulig , Shingo Futamura , Kenneth Allen Bates , Wen-Liang Hsu , Kuo-Chih Hua
发明人： Ping Zhang , Paul Harry Sandstrom , Joseph John Kulig , Shingo Futamura , Kenneth Allen Bates , Wen-Liang Hsu , Kuo-Chih Hua
IPC分类号： B60C11/00
CPC分类号： B60C1/0016 , C08K3/013 , C08K7/02 , C08L21/00 , C08L29/04 , C08L33/02 , C08L33/26 , C08L2666/04
摘要： This invention relates to a rubber composition which contains a dispersion of a particulate hydrophilic water absorbing polymer and tire with a tread thereof.
摘要翻译：本发明涉及一种橡胶组合物，其含有颗粒状亲水性吸水聚合物和轮胎与其胎面的分散体。

5. 发明申请

US20090151830A1 TIRE WITH TREAD RUBBER COMPOSITION WHICH CONTAINS DUAL SILICA MOIETIES 有权
标题翻译：轮胎与含有双硅胶的橡胶组合物
公开(公告)号：US20090151830A1
公开(公告)日：2009-06-18
申请号：US11957549
申请日：2007-12-17
申请人： Paul Harry Sandstrom , Kuo-Chih Hua , Shingo Futamura , Kenneth Allen Bates
发明人： Paul Harry Sandstrom , Kuo-Chih Hua , Shingo Futamura , Kenneth Allen Bates
IPC分类号： C08K5/5415 , B60C11/00
CPC分类号： C08K9/04 , C08K3/36 , C08K5/548 , C08K9/06 , C08L21/00
摘要： The invention relates to a tire having a tread of a cured rubber composition which contains dual silica moieties in a sense of containing both hydrophilic precipitated silica and in situ hydrophobated precipitated silica.
摘要翻译：本发明涉及一种具有固化橡胶组合物的胎面的轮胎，该橡胶组合物含有双重二氧化硅部分，其含有亲水性沉淀二氧化硅和原位疏水沉淀二氧化硅。

6. 发明申请

US20090151831A1 TIRE WITH TREAD RUBBER COMPOSITION WHICH CONTAINS DUAL SILICA MOIETIES 审中-公开
公开(公告)号：US20090151831A1
公开(公告)日：2009-06-18
申请号：US11957751
申请日：2007-12-17
申请人： Paul Harry Sandstrom , Kuo-Chih Hua , Shingo Futamura , Kenneth Allen Bates
发明人： Paul Harry Sandstrom , Kuo-Chih Hua , Shingo Futamura , Kenneth Allen Bates
IPC分类号： C08K5/5415 , B60C1/00
CPC分类号： C08K9/04 , C08K3/36 , C08K5/548 , C08K9/06 , C08L21/00
摘要： The invention relates to a tire having a tread of a cured rubber composition which contains dual silica moieties in a sense of containing both hydrophilic precipitated silica and in situ hydrophobated precipitated silica.

7. 发明授权

US08522847B2 Tire with tread rubber composition which contains dual silica moieties 有权
标题翻译：胎面橡胶组合物，含有双重硅胶部分
公开(公告)号：US08522847B2
公开(公告)日：2013-09-03
申请号：US11957549
申请日：2007-12-17
申请人： Paul Harry Sandstrom , Kuo-Chih Hua , Shingo Futamura , Kenneth Allen Bates
发明人： Paul Harry Sandstrom , Kuo-Chih Hua , Shingo Futamura , Kenneth Allen Bates
IPC分类号： B60C1/00 , C08K3/36
CPC分类号： C08K9/04 , C08K3/36 , C08K5/548 , C08K9/06 , C08L21/00
摘要： The invention relates to a tire having a tread of a cured rubber composition which contains dual silica moieties in a sense of containing both hydrophilic precipitated silica and in situ hydrophobated precipitated silica.
摘要翻译：本发明涉及一种具有固化橡胶组合物的胎面的轮胎，该橡胶组合物含有双重二氧化硅部分，其含有亲水性沉淀二氧化硅和原位疏水沉淀二氧化硅。

8. 发明申请

US20080027162A1 Silica reinforced rubber composition and use in tires 审中-公开
标题翻译：二氧化硅增强橡胶组合物和用于轮胎
公开(公告)号：US20080027162A1
公开(公告)日：2008-01-31
申请号：US11492622
申请日：2006-07-25
申请人： Kuo-Chih Hua , Shingo Futamura , Wen-Liang Hsu , Paul Harry Sandstrom
发明人： Kuo-Chih Hua , Shingo Futamura , Wen-Liang Hsu , Paul Harry Sandstrom
IPC分类号： B60C1/00 , C08K3/22
CPC分类号： B60C1/0016 , B60C1/0025 , C08K3/22 , C08K5/09 , C08L21/00
摘要： This invention relates to the preparation of silica-rich rubber compositions which contain silica reinforcement and silica coupler together with a specified combination of zinc oxide and long chain (fatty) carboxylic acid such as stearic acid. The silica, silica coupling agent, zinc oxide and stearic acid are combined in a manner to form a complex network. The silica is a precipitated silica in a form of silica aggregates which contain hydroxyl groups on its surface. A preferred silica coupling agent is a bis (3-trialkoxysilylalkyl) polysulfide which contains an average of from 2 to about 4, preferably from 2 to about 2.6, connecting sulfur atoms in its polysulfidic bridge. The invention further relates to tires having a component thereof such as, for example, a tread.
摘要翻译：本发明涉及含有二氧化硅增强物和二氧化硅偶联剂以及氧化锌和长链（脂肪）羧酸如硬脂酸的指定组合的二氧化硅富集橡胶组合物的制备。二氧化硅，二氧化硅偶联剂，氧化锌和硬脂酸以形成复合网络的方式组合。二氧化硅是二氧化硅聚集体形式的沉淀二氧化硅，其表面含有羟基。优选的二氧化硅偶联剂是在其多硫桥中连接硫原子的平均为2至约4，优选2至约2.6的双（3-三烷氧基甲硅烷基烷基）多硫化物。本发明还涉及具有其部件例如胎面的轮胎。

9. 发明申请

US20060247360A1 Rubber composition containing an alkoxysilane coupled in-chain functionalized elastomer and tire with component thereof 有权
标题翻译：含有烷氧基硅烷的链烷基官能化弹性体和轮胎与其组分的橡胶组合物
公开(公告)号：US20060247360A1
公开(公告)日：2006-11-02
申请号：US11110025
申请日：2005-04-20
申请人： Adel Halasa , Wen-Liang Hsu , Kenneth Bates , David Benko , Shingo Futamura , Kuo-Chih Hua
发明人： Adel Halasa , Wen-Liang Hsu , Kenneth Bates , David Benko , Shingo Futamura , Kuo-Chih Hua
IPC分类号： B60C1/00
CPC分类号： B60C1/0016 , C08C19/25 , C08C19/44 , C08L15/00 , C08L19/006 , C08L21/00 , C08L2666/08
摘要： This invention relates to a precipitated silica reinforced conjugated diene-based elastomer composition containing an alkoxysilane coupled, in-chain functionalized, conjugated diene-based elastomer and to a tire having at least one component thereof. Said in-chain functionalized conjugated diene-based elastomer is a conjugated diene-based elastomer which contains a plurality of at least one of in-chain p- and m-(2-pyrrolidinoethyl) styrene (PES) and m-(2-pyrrolidino-1-methylethyl) alpha-methylstyrene (PAMS) groups.
摘要翻译：本发明涉及一种沉淀二氧化硅增强共轭二烯系弹性体组合物，其含有烷氧基硅烷偶联，链内官能化共轭二烯类弹性体和具有至少一种组分的轮胎。所述的链内官能化共轭二烯系弹性体是共轭二烯系弹性体，其含有多个至少一种链内对称和间 - （2-吡咯烷基乙基）苯乙烯（PES）和间 - （2-吡咯烷子基） -1-甲基乙基）α-甲基苯乙烯（PAMS）基团。

10. 发明申请

US20070142518A1 Tire with component comprised of rubber composition containing hydrophobated, pre-silanized silica 失效
标题翻译：轮胎与含有疏水化预硅烷化二氧化硅的橡胶组合物组成
公开(公告)号：US20070142518A1
公开(公告)日：2007-06-21
申请号：US11303279
申请日：2005-12-16
申请人： Wen-Liang Hsu , Shingo Futamura , Kuo-Chih Hua , Kenneth Bates , Ping Zhang
发明人： Wen-Liang Hsu , Shingo Futamura , Kuo-Chih Hua , Kenneth Bates , Ping Zhang
IPC分类号： B60C1/00
CPC分类号： B60C1/0025 , B60C1/00 , B60C1/0016 , B60C2001/0033 , C08K5/103 , C08K9/06 , Y10S152/905 , Y10T152/10495 , C08L21/00
摘要： The invention relates to a tire having at least one component comprised of a rubber composition which contains a hydrophobated, pre-silanized silica, namely a pre-silanized silica hydrophobated with an epoxidized soybean oil and/or epoxidized rubber tree seed oil in situ within said rubber composition. Such tire component may be, for example although not limited to, a tire tread, sidewall and/or sidewall insert.
摘要翻译：本发明涉及一种具有至少一种组分的轮胎，该组合物由橡胶组合物组成，所述橡胶组合物含有疏水化的预硅烷化二氧化硅，即与所述环氧化大豆油和/或环氧化橡胶树种子油原位疏水化的预硅烷化二氧化硅橡胶组成。这种轮胎部件可以是例如但不限于轮胎胎面，侧壁和/或侧壁插入件。

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