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1. 发明授权

US08815997B2 Aqueous compositions comprising ion exchange resins that deliver paint and primer properties in a coating 有权
标题翻译：包含在涂层中提供涂料和底漆性能的离子交换树脂的水性组合物
公开(公告)号：US08815997B2
公开(公告)日：2014-08-26
申请号：US13453057
申请日：2012-04-23
申请人： Wei Zhang , Ozzie M. Pressley , Monica A. Luckenbach , James C. Bohling
发明人： Wei Zhang , Ozzie M. Pressley , Monica A. Luckenbach , James C. Bohling
IPC分类号： C08L31/00 , C08J5/20
CPC分类号： C09D5/002 , C09D5/022 , C09D5/1637 , C09D7/65 , C09D143/02
摘要： The present invention provides one component aqueous compositions comprising (i) from 0.01 to 7 wt. %, based on the total weight of solids in the composition, of anion exchange resin beads having a weight average particle size of from 0.1 to 20 μm a low crosslinker content, the anion exchange resin copolymer beads being chosen from gelular beads, beads having a dual morphology, and mixtures thereof, (ii) an emulsion copolymer having a copolymerization residue of one or more phosphorus acid monomer, and having an anionic surfactant or its polymerization residue and a reductant or its polymerization residue and, (iii) at least one phosphorous containing surfactant in the amount of from 0.1 to 5 wt. %, based on the weight of emulsion copolymer solids. The compositions find use as coating binders and either pigmented or unpigmented paints and enable the provision of a single coat primer plus topcoat with excellent stain blocking.
摘要翻译：本发明提供单组分水性组合物，其包含（i）0.01至7重量％％，基于组合物中固体的总重量，具有低交联剂含量的重均粒径为0.1至20μm的阴离子交换树脂珠，阴离子交换树脂共聚物珠选自凝胶珠，具有双重形态及其混合物，（ii）具有一个或多个磷酸单体的共聚残基并具有阴离子表面活性剂或其聚合残基和还原剂或其聚合残基的乳液共聚物，和（iii）至少一种磷含量为0.1-5重量％的表面活性剂。％，基于乳液共聚物固体的重量。该组合物用作涂料粘合剂和着色或未着色的涂料，并且能够提供具有优异污渍阻挡性能的单一涂料底漆和外涂层。

2. 发明申请

US20120277333A1 STABILIZED AQUEOUS COMPOSITIONS COMPRISING CATIONIC POLYMERS THAT DELIVER PAINT AND PRIMER PROPERTIES IN A COATING 有权
标题翻译：稳定的水性组合物包含在涂料中提供涂料和涂料性能的阳离子聚合物
公开(公告)号：US20120277333A1
公开(公告)日：2012-11-01
申请号：US13452995
申请日：2012-04-23
申请人： Ozzie M. Pressley , Monica A. Luckenbach , Wei Zhang , Ronald C. Faulk
发明人： Ozzie M. Pressley , Monica A. Luckenbach , Wei Zhang , Ronald C. Faulk
IPC分类号： C08K3/32
CPC分类号： C08L43/02 , C09D143/02
摘要： The present invention provides one component aqueous compositions comprising (i) a cationic stain blocking polymer chosen from (a) 0.01 to 7 wt. % of anion exchange resin copolymer gelular or dual morphology beads that have a weight average particle size of from 0.1 to 20 μm and a low copolymerized crosslinker content of from 0.5 to 2.0 wt. %, (b) from 1 to 30 wt. % a crosslinked cationic addition polymer and (c) mixtures thereof, (ii) one or more emulsion copolymer having a copolymerized residue of at least one phosphorus acid monomer, and (iii) a stabilizer of from 0.1 to 2 wt. % of an inorganic phosphorus containing dispersant, and from 0.2 to 5.0 wt. % of a mixture of a nonionic surfactant and an anionic surfactant, both wt. % s based on the total weight of emulsion compolymer solids. The compositions provide stabilized binders for in a single coat primer plus topcoat coatings and paints.
摘要翻译：本发明提供一种单组分水性组合物，其包含（i）阳离子染色阻挡聚合物，其选自（a）0.01至7重量％％的阴离子交换树脂共聚物凝胶或双重形态的珠，其重均粒径为0.1-20μm，低共聚交联剂含量为0.5-2.0wt。％，（b）1〜30wt。％的交联阳离子加成聚合物和（c）它们的混合物，（ii）一种或多种具有至少一种含磷酸单体的共聚残基的乳液共聚物，和（iii）0.1至2wt。％的无机磷分散剂，和0.2〜5.0重量％％的非离子表面活性剂和阴离子表面活性剂的混合物，％s基于乳液共聚物固体的总重量。组合物提供稳定的粘合剂，用于单一涂层底漆和顶涂层涂料和涂料。

3. 发明授权

US08791190B2 Stabilized aqueous compositions comprising cationic polymers that deliver paint and primer properties in a coating 有权
标题翻译：稳定的含水组合物包含在涂层中提供涂料和底漆性能的阳离子聚合物
公开(公告)号：US08791190B2
公开(公告)日：2014-07-29
申请号：US13452995
申请日：2012-04-23
申请人： Ozzie M. Pressley , Monica A. Luckenbach , Wei Zhang , Ronald C. Faulk
发明人： Ozzie M. Pressley , Monica A. Luckenbach , Wei Zhang , Ronald C. Faulk
IPC分类号： C08K3/32 , C08J5/20
CPC分类号： C08L43/02 , C09D143/02
摘要： The present invention provides one component aqueous compositions comprising (i) a cationic stain blocking polymer chosen from (a) 0.01 to 7 wt. % of anion exchange resin copolymer gelular or dual morphology beads that have a weight average particle size of from 0.1 to 20 μm and a low copolymerized crosslinker content of from 0.5 to 2.0 wt. %, (b) from 1 to 30 wt. % a crosslinked cationic addition polymer and (c) mixtures thereof, (ii) one or more emulsion copolymer having a copolymerized residue of at least one phosphorus acid monomer, and (iii) a stabilizer of from 0.1 to 2 wt. % of an inorganic phosphorus containing dispersant, and from 0.2 to 5.0 wt. % of a mixture of a nonionic surfactant and an anionic surfactant, both wt. % s based on the total weight of emulsion copolymer solids. The compositions provide stabilized binders for in a single coat primer plus topcoat coatings and paints.
摘要翻译：本发明提供一种单组分水性组合物，其包含（i）阳离子染色阻挡聚合物，其选自（a）0.01至7重量％％的阴离子交换树脂共聚物凝胶或双重形态的珠，其重均粒径为0.1-20μm，低共聚交联剂含量为0.5-2.0wt。％，（b）1〜30wt。％的交联阳离子加成聚合物和（c）它们的混合物，（ii）一种或多种具有至少一种含磷酸单体的共聚残基的乳液共聚物，和（iii）0.1至2wt。％的无机磷分散剂，和0.2〜5.0重量％％的非离子表面活性剂和阴离子表面活性剂的混合物，％基于乳液共聚物固体的总重量。组合物提供稳定的粘合剂，用于单一涂层底漆和顶涂层涂料和涂料。

4. 发明授权

US09221992B2 Aqueous coating compositions 有权
标题翻译：水性涂料组合物
公开(公告)号：US09221992B2
公开(公告)日：2015-12-29
申请号：US14119905
申请日：2012-05-31
申请人： James C. Bohling , Arnold S. Brownell , Catherine A. Finegan , Ozzie M. Pressley , Wei Zhang
发明人： James C. Bohling , Arnold S. Brownell , Catherine A. Finegan , Ozzie M. Pressley , Wei Zhang
IPC分类号： C09D133/12 , C09D5/02 , C09D7/12 , C08F2/38 , C08F265/06 , C09D151/00
CPC分类号： C09D133/12 , C08F2/38 , C08F265/06 , C09D5/028 , C09D7/62 , C09D151/003 , C08F2220/1825 , C08F220/14 , C08F220/06 , C08F230/02 , C08F2220/346 , C08L51/003 , C08L33/12 , C08F2220/1808 , C08F2220/283
摘要： An aqueous coating composition including a) a composite particle including an opacifying pigment particle such as, for example, TiO2 and, disposed thereon, a plurality of particles of a first polymer, the first polymer being a select P-acid containing emulsion polymer and b) from 7% to 25% by weight, based on the total weight of polymer in the aqueous coating composition, of a select second polymer is provided. A method for forming the aqueous coating composition, a method for forming a dried coating therefrom, and the coating so formed are also provided.
摘要翻译：一种水性涂料组合物，其包含a）包含不透明颜料颗粒例如TiO 2的复合颗粒，并且在其上设置多个第一聚合物颗粒，所述第一聚合物是选择含P酸的乳液聚合物和b ）为7〜25重量％，基于水性涂料组合物中的聚合物的总重量，选择的第二聚合物。还提供了一种形成水性涂料组合物的方法，由其形成干燥涂层的方法和如此形成的涂层。

5. 发明申请

US20140187706A1 AQUEOUS COATING COMPOSITIONS 有权
标题翻译：水性涂料组合物
公开(公告)号：US20140187706A1
公开(公告)日：2014-07-03
申请号：US14119905
申请日：2012-05-31
申请人： James C. Bohling , Arnold S. Brownell , Catherine A. Finegan , Ozzie M. Pressley , Wei Zhang
发明人： James C. Bohling , Arnold S. Brownell , Catherine A. Finegan , Ozzie M. Pressley , Wei Zhang
IPC分类号： C09D133/12
CPC分类号： C09D133/12 , C08F2/38 , C08F265/06 , C09D5/028 , C09D7/62 , C09D151/003 , C08F2220/1825 , C08F220/14 , C08F220/06 , C08F230/02 , C08F2220/346 , C08L51/003 , C08L33/12 , C08F2220/1808 , C08F2220/283
摘要： An aqueous coating composition including a) a composite particle including an opacifying pigment particle such as, for example, TiO2 and, disposed thereon, a plurality of particles of a first polymer, the first polymer being a select P-acid containing emulsion polymer and b) from 7% to 25% by weight, based on the total weight of polymer in the aqueous coating composition, of a select second polymer is provided. A method for forming the aqueous coating composition, a method for forming a dried coating therefrom, and the coating so formed are also provided.
摘要翻译：一种水性涂料组合物，其包含a）包含不透明颜料颗粒例如TiO 2的复合颗粒，并且在其上设置多个第一聚合物颗粒，所述第一聚合物是选择含P酸的乳液聚合物和b ）为7〜25重量％，基于水性涂料组合物中的聚合物的总重量，选择的第二聚合物。还提供了一种形成水性涂料组合物的方法，由其形成干燥涂层的方法和如此形成的涂层。

6. 发明授权

US08318848B2 Scrub and stain-resistant coating 有权
标题翻译：擦拭和防污涂层
公开(公告)号：US08318848B2
公开(公告)日：2012-11-27
申请号：US11711351
申请日：2007-02-27
申请人： Catherine Ann Finegan , Ozzie M. Pressley , William D. Rohrbach , Wei Zhang
发明人： Catherine Ann Finegan , Ozzie M. Pressley , William D. Rohrbach , Wei Zhang
IPC分类号： C08K3/22
CPC分类号： C08F230/02 , C08F220/06 , C08F220/18 , C08K3/22 , C08K2003/2241 , C09D143/02
摘要： A coating composition comprising aqueous dispersion of particles made from a copolymer comprising, based on the weight of the copolymer one or more monoethylenically unsaturated monomers; acid functional or anionic monomer and phosphorous-containing monomer.
摘要翻译：一种涂料组合物，其包含由共聚物制成的颗粒的水性分散体，所述共聚物包含基于所述共聚物的重量的一种或多种单烯属不饱和单体; 酸官能或阴离子单体和含磷单体。

7. 发明申请

US20090171005A1 Scrub and stain-resistant coating 有权
标题翻译：擦拭和防污涂层
公开(公告)号：US20090171005A1
公开(公告)日：2009-07-02
申请号：US12317879
申请日：2008-12-30
申请人： Catherine Ann Finegan , Ozzie M. Pressley , William D. Rohrbach , Wei Zhang
发明人： Catherine Ann Finegan , Ozzie M. Pressley , William D. Rohrbach , Wei Zhang
IPC分类号： C08L43/02 , C08L33/08
CPC分类号： C09D5/02 , C08F220/18 , C08F230/02 , C08K3/22 , C08K3/346 , C09D143/02
摘要： A waterborne coating composition is provided, comprising a vinyl copolymer with an optimized level of phosphorus-containing functional groups in conjunction with at least 20% by weight of the copolymer, of ethyl acrylate, methyl acrylate or combinations thereof and one or more opacifying colorants, preferably titanium dioxide.
摘要翻译：提供了一种水性涂料组合物，其包含具有优化的含磷官能团水平的乙烯基共聚物与至少20重量％的共聚物，丙烯酸乙酯，丙烯酸甲酯或其组合和一种或多种不透明的着色剂，优选二氧化钛。

8. 发明申请

US20070208129A1 Scrub and stain-resistant coating 有权
标题翻译：擦拭和防污涂层
公开(公告)号：US20070208129A1
公开(公告)日：2007-09-06
申请号：US11711351
申请日：2007-02-27
申请人： Catherine Ann Finegan , Ozzie M. Pressley , William D. Rohrbach , Wei Zhang
发明人： Catherine Ann Finegan , Ozzie M. Pressley , William D. Rohrbach , Wei Zhang
IPC分类号： C08K3/22
CPC分类号： C08F230/02 , C08F220/06 , C08F220/18 , C08K3/22 , C08K2003/2241 , C09D143/02
摘要： A coating composition comprising aqueous dispersion of particles made from a copolymer comprising, based on the weight of the copolymer one or more monoethylenically unsaturated monomers; acid functional or anionic monomer and phosphorous-containing monomer.
摘要翻译：一种涂料组合物，其包含由共聚物制成的颗粒的水性分散体，所述共聚物包含基于所述共聚物的重量的一种或多种单烯属不饱和单体; 酸官能或阴离子单体和含磷单体。

9. 发明授权

US08883880B2 Soluble shell polymer composition and method for its preparation 有权
标题翻译：可溶性壳聚合物组合物及其制备方法
公开(公告)号：US08883880B2
公开(公告)日：2014-11-11
申请号：US13597335
申请日：2012-08-29
申请人： Monica Luckenbach , Ozzie M. Pressley , Wei Zhang
发明人： Monica Luckenbach , Ozzie M. Pressley , Wei Zhang
IPC分类号： C08F265/06 , C08K5/42 , C08F230/02 , C09D151/06 , C09D151/00 , C08L51/00
CPC分类号： C08F265/06 , C08F230/02 , C09D151/06 , C08F2/22
摘要： The present invention relates to a soluble shell polymer composition comprising an alkali soluble emulsion polymer shell and an alkali insoluble emulsion polymer core, which composition is stabilized by a surfactant of the formula R—(OCH2CH2)2-6OSO3−M+, where R is a linear, branched, or cyclic C8-C24 alkyl or C12-C18 aralkyl group and M+ is a counterion. The invention further relates to a method of preparing the composition and its use as a binder in coatings formulations. Formulations prepared with the soluble shell polymer composition have excellent freeze-thaw profiles and hiding.
摘要翻译：本发明涉及一种可溶性壳聚合物组合物，其包含碱溶性乳液聚合物壳和碱不溶性乳液聚合物核心，该组合物由式R-（OCH 2 CH 2）2 -POSO 3 -M +的表面活性剂稳定，其中R为直链，支链或环状C 8 -C 24烷基或C 12 -C 18芳烷基，M +为抗衡离子。本发明还涉及一种制备组合物的方法及其在涂料制剂中作为粘合剂的用途。用可溶性壳聚合物组合物制备的制剂具有优异的冻融特性和隐藏性。

10. 发明申请

US20130066005A1 SOLUBLE SHELL POLYMER COMPOSITION AND METHOD FOR ITS PREPARATION 有权
标题翻译：可溶性壳聚合物组合物及其制备方法
公开(公告)号：US20130066005A1
公开(公告)日：2013-03-14
申请号：US13597335
申请日：2012-08-29
申请人： Monica Luckenbach , Ozzie M. Pressley , Wei Zhang
发明人： Monica Luckenbach , Ozzie M. Pressley , Wei Zhang
IPC分类号： C09D185/02 , C08L85/02
CPC分类号： C08F265/06 , C08F230/02 , C09D151/06 , C08F2/22
摘要： The present invention relates to a soluble shell polymer composition comprising an alkali soluble emulsion polymer shell and an alkali insoluble emulsion polymer core, which composition is stabilized by a surfactant of the formula R—(OCH2CH2)2-6OSO3−M+, where R is a linear, branched, or cyclic C8-C24 alkyl or C12-C18 aralkyl group and M+ is a counterion. The invention further relates to a method of preparing the composition and its use as a binder in coatings formulations. Formulations prepared with the soluble shell polymer composition have excellent freeze-thaw profiles and hiding.
摘要翻译：本发明涉及一种可溶性壳聚合物组合物，其包含碱溶性乳液聚合物壳和碱不溶性乳液聚合物核心，该组合物由式R-（OCH 2 CH 2）2 -POSO 3 -M +的表面活性剂稳定，其中R为直链，支链或环状的C 8 -C 24烷基或C 12 -C 18芳烷基，M +为抗衡离子。本发明还涉及一种制备组合物的方法及其在涂料制剂中作为粘合剂的用途。用可溶性壳聚合物组合物制备的制剂具有优异的冻融特性和隐藏性。

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