专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US5500198A Composite catalyst for carbon monoxide and hydrocarbon oxidation 失效
标题翻译：用于一氧化碳和烃氧化的复合催化剂
公开(公告)号：US5500198A
公开(公告)日：1996-03-19
申请号：US142519
申请日：1993-10-26
申请人： Wei Liu , Maria Flytzani-Stephanopoulos
发明人： Wei Liu , Maria Flytzani-Stephanopoulos
IPC分类号： B01D53/86 , B01J23/00 , B01J23/83 , C01B32/50 , C01B31/18 , C01B31/20 , B01D53/62 , B01D53/72
CPC分类号： C01B31/20 , B01D53/864 , B01D53/8668 , B01J23/002 , B01J23/83 , B01J2523/00
摘要： A method and composition for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdnum, copper, cobalt, maganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.
摘要翻译：一氧化碳和/或烃化合物完全氧化的方法和组合物。该方法包括在金属氧化物复合催化剂存在下使一氧化碳和/或烃与氧化剂反应。通过将萤石型氧离子导体与活性过渡金属组合来制备催化剂。选自氧化铈，氧化锆，氧化钍，氧化铪和氧化铀的萤石氧化物，可以被碱土金属和稀土氧化物掺杂。使用选自钼，铜，钴，锰，镍和银的过渡金属作为添加剂。过渡金属与萤石氧化物的原子比小于1。

2. 发明授权

US5384301A Catalyst for elemental sulfur recovery process 失效
标题翻译：元素硫回收工艺催化剂
公开(公告)号：US5384301A
公开(公告)日：1995-01-24
申请号：US097367
申请日：1993-07-23
申请人： Maria Flytzani-Stephanopoulos , Wei Liu
发明人： Maria Flytzani-Stephanopoulos , Wei Liu
IPC分类号： B01D53/86 , B01J23/10 , C01B17/04
CPC分类号： B01D53/8609 , B01J23/10 , C01B17/0473 , C01B17/0486
摘要： A catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas:[(OF.sub.2).sub.1-n (RO.sub.1)n].sub.1-k M.sub.k,[(FO.sub.2).sub.1-n (RO.sub.1.5).sub.n ].sub.1-k M.sub.k, or[Ln.sub.x Zr.sub.1-x O.sub.2-0.5x ].sub.1-k M.sub.kwherein FO.sub.2 is a fluorite-type oxide; RO represents an alkaline earth oxide; RO.sub.1.5 is a Group IIIB or rare earth oxide; Ln is a rare earth element having an atomic number from 57 to 65 or mixtures thereof; M is a transition metal or a mixture of transition metals; n is a number having a value from 0.0 to 0.35; k is a number having a value from 0.0 to about 0.5; and x is a number having a value from about 0.45 to about 0.55.
摘要翻译：用于从各种含SO2的工业气体流直接回收元素硫的催化还原方法。催化方法提供高活性和选择性，以及在反应气氛中的稳定性，用一氧化碳或其它还原气体还原SO2至元素硫产物。二氧化硫和还原气体的反应发生在具有以下经验式之一的金属氧化物复合催化剂上：[（OF2）1-n（RO1）n] 1-kMk，[（FO2）1-n（RO1。 5）n] 1-kMk或[LnxZr1-xO2-0.5x] 1-kMk其中FO2是萤石型氧化物; RO代表碱土金属氧化物; RO1.5是IIIB族或稀土氧化物; Ln是原子序数为57〜65的稀土元素或其混合物; M是过渡金属或过渡金属的混合物; n是0.0至0.35的数值; k是0.0至约0.5的数值; x为约0.45至约0.55的数值。

3. 发明申请

US20120035403A1 CONVERTING BIOMASS TO GASEOUS FUEL HYDROCARBONS 有权
标题翻译：将生物质转化为气体燃料油
公开(公告)号：US20120035403A1
公开(公告)日：2012-02-09
申请号：US13202239
申请日：2010-02-23
申请人： Maria Flytzani-Stephanopoulos , Branko Zugic , Brian Ricks , Gregory Stephanopoulos
发明人： Maria Flytzani-Stephanopoulos , Branko Zugic , Brian Ricks , Gregory Stephanopoulos
IPC分类号： C10G1/00
CPC分类号： C10G3/45 , C07C1/2078 , C07C2521/00 , C07C2521/16 , C07C2521/18 , C07C2523/02 , C07C2523/14 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/50 , C07C2523/52 , C07C2523/70 , C07C2523/72 , C07C2527/04 , C07C2529/00 , C07C2529/04 , C10G3/42 , C10G3/47 , C10G3/49 , C10G3/50 , C10G2300/1014 , Y02P30/20
摘要： A method includes providing a solution containing a C2-6 carboxylic acid or a C2-6 carboxylate that is derived from biomass; and contacting the solution with a solid catalyst to form a C1-5 hydrocarbon.
摘要翻译：一种方法包括提供含有衍生自生物质的C2-6羧酸或C2-6羧酸盐的溶液; 并将该溶液与固体催化剂接触以形成C 1-5烃。

4. 发明申请

US20060128565A1 Catalyst having metal in reduced quantity and reduced cluster size 有权
标题翻译：催化剂具有减少量的金属和降低的簇尺寸
公开(公告)号：US20060128565A1
公开(公告)日：2006-06-15
申请号：US10534110
申请日：2003-11-07
申请人： Maria Flytzani-Stephanopoulos , Howard Saltburg , Qi Fu
发明人： Maria Flytzani-Stephanopoulos , Howard Saltburg , Qi Fu
IPC分类号： B01J23/10
CPC分类号： C01B3/40 , B01J23/10 , B01J23/42 , B01J23/52 , B01J23/63 , B01J23/66 , B01J35/006 , B01J37/03 , B01J37/06 , C01B3/16 , C01B3/326 , C01B2203/0233 , C01B2203/0283 , C01B2203/1011 , C01B2203/1041 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223 , Y02P20/52
摘要： The invention contemplates a method of making a catalytic material, and uses of the material. The catalytic material is made by depositing catalytic metals, such as gold or platinum, on substrate materials, such as lanthanum-doped ceria or other oxides. The catalytic metal, which comprises both crystalline and non-crystalline structures, is treated, for example with aqueous basic NaCN solution, to leach away at least some of the crystalline metallic component. The remaining noncystalline metallic component associated with the substrate exhibits catalytic activity that is substantially similar to the catalyst as prepared. The use of the catalyst in an apparatus such as a reactor or analytic instrument is contemplated, as is the use of the catalyst in efficient, cost-effective reactions, such as removal of carbon monoxide from fuel gases, for example by performing the water gas shift reaction.
摘要翻译：本发明考虑了制备催化材料的方法和材料的用途。催化材料通过在诸如金或铂的催化金属上沉积在诸如掺镧掺杂的二氧化铈或其它氧化物的衬底材料上而制成。包括结晶和非结晶结构的催化金属例如用碱性NaCN水溶液处理以去除至少一些结晶金属组分。与底物相关的剩余的非结晶金属组分显示出与所制备的催化剂基本相似的催化活性。预期在诸如反应器或分析仪器的装置中使用催化剂，以及催化剂在有效且成本有效的反应中的使用，例如从燃料气体中除去一氧化碳，例如通过执行水气转变反应。

5. 发明授权

US08377841B2 Catalyst having metal in reduced quantity and reduced cluster size 失效
标题翻译：催化剂具有减少量的金属和降低的簇尺寸
公开(公告)号：US08377841B2
公开(公告)日：2013-02-19
申请号：US13243173
申请日：2011-09-23
申请人： Maria Flytzani-Stephanopoulos , Howard M. Saltsburg , Qi Fu
发明人： Maria Flytzani-Stephanopoulos , Howard M. Saltsburg , Qi Fu
IPC分类号： B01J23/00 , B01J23/10 , B01J21/04
CPC分类号： C01B3/40 , B01J23/10 , B01J23/42 , B01J23/52 , B01J23/63 , B01J23/66 , B01J35/006 , B01J37/03 , B01J37/06 , C01B3/16 , C01B3/326 , C01B2203/0233 , C01B2203/0283 , C01B2203/1011 , C01B2203/1041 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223 , Y02P20/52
摘要： The invention contemplates a method of making a catalytic material, and uses of the material. The catalytic material is made by depositing catalytic metals, such as gold or platinum, on substrate materials, such as lanthanum-doped ceria or other oxides. The catalytic metal, which comprises both crystalline and non-crystalline structures, is treated, for example with aqueous basic NaCN solution, to leach away at least some of the crystalline metallic component. The remaining noncrystalline metallic component associated with the substrate exhibits catalytic activity that is substantially similar to the catalyst as prepared. The use of the catalyst in an apparatus such as a reactor or analytic instrument is contemplated, as is the use of the catalyst in efficient, cost-effective reactions, such as removal of carbon monoxide from fuel gases, for example by performing the water gas shift reaction.
摘要翻译：本发明考虑了制备催化材料的方法和材料的用途。催化材料通过在诸如金或铂的催化金属上沉积在诸如掺镧掺杂的二氧化铈或其它氧化物的衬底材料上而制成。包括结晶和非结晶结构的催化金属例如用碱性NaCN水溶液处理以去除至少一些结晶金属组分。与基材相关的剩余的非结晶金属组分显示出与所制备的催化剂基本相似的催化活性。预期在诸如反应器或分析仪器的装置中使用催化剂，以及催化剂在有效且成本有效的反应中的使用，例如从燃料气体中除去一氧化碳，例如通过执行水气转变反应。

6. 发明申请

US20080260607A1 Treatment of Gold-Ceria Catalysts with Oxygen to Improve Stability Thereof in the Water-Gas Shift and Selective Co Oxidation Reactions 审中-公开
标题翻译：用氧气处理金 - 二氧化铈催化剂，提高水煤气转换和选择性Co氧化反应的稳定性
公开(公告)号：US20080260607A1
公开(公告)日：2008-10-23
申请号：US11718563
申请日：2005-11-04
申请人： Maria Flytzani-Stephanopoulos , Weiling Deng
发明人： Maria Flytzani-Stephanopoulos , Weiling Deng
IPC分类号： B01J23/10 , B01J38/12 , B01J23/00 , B01J16/00 , B01J38/04
CPC分类号： B01J23/63 , B01J23/10 , B01J23/66 , C01B3/16 , C01B3/583 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C10K3/04 , H01M4/90 , H01M8/0612 , H01M8/0668 , Y02P20/52
摘要： A method for improving the performance of catalysts by the addition of small amounts of oxygen to feed stock streams. Examples are shown for the improved operation of gold-ceria catalysts in the water-gas shift (WGS) and PROX reactions. The catalytic material is made by depositing catalytic metals, such as gold or platinum, on substrate materials, such as doped or undoped ceria. The deposited metal, which comprises both crystalline and non-crystalline structures, is treated, for example with aqueous basic NaCN solution, to remove at least some of the crystalline metallic component. The remaining noncystalline metallic component associated with the substrate exhibits catalytic activity that is substantially similar to the catalyst as prepared. The use of the catalyst is contemplated in efficient, cost-effective reactions, such as removal of carbon monoxide from fuel gases, for example by performing the water gas shift reaction and/or the PROX reaction.
摘要翻译：一种通过加入少量氧来提炼原料流来提高催化剂性能的方法。示出了在水煤气变换（WGS）和PROX反应中金 - 二氧化铈催化剂的改进操作的实例。催化材料通过在诸如掺杂或未掺杂的二氧化铈的基底材料上沉积诸如金或铂的催化金属来制备。包含结晶和非结晶结构的沉积金属例如用碱性NaCN水溶液处理以除去至少一些结晶金属组分。与底物相关的剩余的非结晶金属组分显示出与所制备的催化剂基本相似的催化活性。考虑到有效的，具有成本效益的反应（例如通过进行水煤气变换反应和/或PROX反应从燃料气体中除去一氧化碳）来使用催化剂。

7. 发明授权

US5538703A Hot gas desulfurization by injection of regenerable sorbents in gasifier-exit ducts 失效
标题翻译：通过在气化器出口管道注入可再生吸附剂进行热气脱硫
公开(公告)号：US5538703A
公开(公告)日：1996-07-23
申请号：US506125
申请日：1995-07-24
申请人： Maria Flytzani-Stephanopoulos
发明人： Maria Flytzani-Stephanopoulos
IPC分类号： B01D53/52 , C01B17/04 , C01B17/50 , B01D53/48
CPC分类号： B01D53/52 , C01B17/0408 , C01B17/508
摘要： A method and system for capturing H.sub.2 S from hot gas streams such as from a coal or other fuel gasifier are disclosed. Zinc or zinc oxide precursors in gas, liquid, or fine powder form are injected into the hot duct work of coal gasifier exit after fly ash has been removed to react with H.sub.2 S gas. In addition to ZnO sulfidation, a portion of the Zn-based reagents converted to the vapor state in the reducing fuel gas environment, reacts with H.sub.2 S and forms fine ZnS particles that are then collected on a high efficiency, high temperature filter. Periodically, the filter is backflushed, and spent sorbent is collected in a hopper, removed for regeneration, and returned to the injection system.
摘要翻译：公开了一种用于从诸如煤或其它燃料气化器的热气流捕获H 2 S的方法和系统。气体，液体或细粉末形式的锌或氧化锌前体在除去粉煤灰后与H 2 S气体反应注入到煤气化炉出口的热管道中。除了ZnO硫化之外，还原燃料气体环境中一部分转变为蒸汽状态的Zn基试剂也与H 2 S反应形成精细的ZnS颗粒，然后将其收集在高效率的高温过滤器上。周期性地将过滤器反吹，并将废弃的吸附剂收集在料斗中，去除再生，并返回到注射系统。

8. 发明授权

US5242673A Elemental sulfur recovery process 失效
标题翻译：元素硫回收过程
公开(公告)号：US5242673A
公开(公告)日：1993-09-07
申请号：US791491
申请日：1991-11-12
申请人： Maria Flytzani-Stephanopoulos , Zhicheng Hu
发明人： Maria Flytzani-Stephanopoulos , Zhicheng Hu
IPC分类号： B01D53/86 , B01J23/10 , C01B17/04
CPC分类号： C01B17/0486 , B01D53/8609 , B01J23/10 , C01B17/0473
摘要： An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO.sub.2 in the regenerator off gas stream to elemental sulfur in the presence of a catalyst.
摘要翻译：用于从各种含SO 2的工业气体流直接回收元素硫的改进的催化还原方法。催化方法提供了组合的高活性和选择性，用于一氧化碳或其他还原气体将SO2还原成元素硫产物。二氧化硫和还原气体的反应发生在基于氧化铈的某些催化剂制剂上。该方法是与再生器结合的单级催化硫回收方法，例如在干式，再生式烟道气脱硫或其它方法中使用的那些，其包括在存在下将再生器中的SO 2直接还原成元素硫的催化剂。

9. 发明授权

US08628744B2 Sulfur-tolerant water-gas shift catalysts 有权
标题翻译：耐硫水煤气变换催化剂
公开(公告)号：US08628744B2
公开(公告)日：2014-01-14
申请号：US13504702
申请日：2010-11-09
申请人： Maria Flytzani-Stephanopoulos , Ioannis Valsamakis
发明人： Maria Flytzani-Stephanopoulos , Ioannis Valsamakis
IPC分类号： B01D53/00 , B01J27/02 , B01J27/053 , B01J27/055 , C01B3/16 , C01B3/18 , C01B31/18 , C01B31/20
CPC分类号： C01B3/16 , B01J37/035 , C01B32/40 , Y02P20/52
摘要： A method for oxidizing carbon monoxide by a water-gas shift (WGS) reaction and a method for reducing carbon dioxide by a reverse water-gas shift (RWGS) reaction, both using a catalyst of the formula xMZLn2O2SOy, in which M, Ln, x, and y are as defined herein. Also disclosed are novel compositions for use as catalysts for both the WGS and RWGS reactions.
摘要翻译：通过水煤气变换（WGS）反应氧化一氧化碳的方法和通过反向水煤气变换（RWGS）反应来还原二氧化碳的方法，均使用式xMZLn2O2SOy的催化剂，其中M，Ln， x和y如本文所定义。还公开了用作WGS和RWGS反应的催化剂的新型组合物。

10. 发明申请

US20120178616A1 CATALYST HAVING METAL IN REDUCED QUANTITY AND REDUCED CLUSTER SIZE 失效
标题翻译：催化剂具有减少数量和减少的集料尺寸的金属
公开(公告)号：US20120178616A1
公开(公告)日：2012-07-12
申请号：US13243173
申请日：2011-09-23
申请人： Maria Flytzani-Stephanopoulos , Howard M. Saltsburg , Qi Fu
发明人： Maria Flytzani-Stephanopoulos , Howard M. Saltsburg , Qi Fu
IPC分类号： B01J23/66 , B01J37/02 , B01J23/52 , B01J23/42 , B01J29/04 , B01J27/24 , B01J27/053 , B01J27/04 , B01J37/03 , B01J37/08 , B01J35/02 , B01J27/22 , B82Y40/00 , B82Y30/00
CPC分类号： C01B3/40 , B01J23/10 , B01J23/42 , B01J23/52 , B01J23/63 , B01J23/66 , B01J35/006 , B01J37/03 , B01J37/06 , C01B3/16 , C01B3/326 , C01B2203/0233 , C01B2203/0283 , C01B2203/1011 , C01B2203/1041 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223 , Y02P20/52
摘要： The invention contemplates a method of making a catalytic material, and uses of the material. The catalytic material is made by depositing catalytic metals, such as gold or platinum, on substrate materials, such as lanthanum-doped ceria or other oxides. The catalytic metal, which comprises both crystalline and non-crystalline structures, is treated, for example with aqueous basic NaCN solution, to leach away at least some of the crystalline metallic component. The remaining noncrystalline metallic component associated with the substrate exhibits catalytic activity that is substantially similar to the catalyst as prepared. The use of the catalyst in an apparatus such as a reactor or analytic instrument is contemplated, as is the use of the catalyst in efficient, cost-effective reactions, such as removal of carbon monoxide from fuel gases, for example by performing the water gas shift reaction.
摘要翻译：本发明考虑了制备催化材料的方法和材料的用途。催化材料通过在诸如金或铂的催化金属上沉积在诸如掺镧掺杂的二氧化铈或其它氧化物的衬底材料上而制成。包括结晶和非结晶结构的催化金属例如用碱性NaCN水溶液处理以去除至少一些结晶金属组分。与基材相关的剩余的非结晶金属组分显示出与所制备的催化剂基本相似的催化活性。预期在诸如反应器或分析仪器的装置中使用催化剂，以及催化剂在有效且成本有效的反应中的使用，例如从燃料气体中除去一氧化碳，例如通过执行水气转变反应。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式