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1. 发明授权

US07071261B2 Aqueous composition containing polymeric nanoparticles 失效
公开(公告)号：US07071261B2
公开(公告)日：2006-07-04
申请号：US10461952
申请日：2003-06-13
申请人： Wayne Devonport , Ralph Craig Even , Ann Robertson Hermes , Dennis Paul Lorah , Joseph David Tanzer , Antony Keith VanDyk
发明人： Wayne Devonport , Ralph Craig Even , Ann Robertson Hermes , Dennis Paul Lorah , Joseph David Tanzer , Antony Keith VanDyk
IPC分类号： C08L39/00 , C08L33/14
CPC分类号： B82Y30/00 , A01N25/10 , A01N25/24 , A61K8/8152 , A61K2800/413 , A61Q3/02 , B08B17/06 , B08B17/065 , B32B27/00 , B32B27/08 , B82Y5/00 , C04B24/2641 , C04B40/0039 , C04B41/483 , C04B41/63 , C08F8/44 , C08F257/02 , C08F265/04 , C08F265/06 , C08F285/00 , C08F291/00 , C08J3/07 , C08J9/0004 , C08J2300/14 , C08L27/06 , C08L33/06 , C08L33/12 , C08L51/003 , C08L67/02 , C08L69/00 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2666/02 , C09B63/00 , C09B67/0005 , C09D5/033 , C09D5/14 , C09D7/43 , C09D7/65 , C09D7/67 , C09D11/101 , C09D17/00 , C09D17/001 , C09D133/06 , C09D151/003 , C09J5/00 , C09J5/06 , C09J7/35 , C09J7/38 , C09J7/385 , C09J11/08 , C09J133/06 , C09J151/003 , C09J2433/00 , C09J2469/00 , C09J2477/00 , C08F2/22 , C08L2666/04 , C08L2666/24
摘要： An aqueous composition including an aqueous dispersion of polymeric nanoparticles having a mean diameter of from 1 to 50 nanometers, the particles including, as polymerized units, at least one multi-ethylenically-unsaturated monomer and at least one ethylenically unsaturated water soluble monomer is discloseded. Certain embodiments of the composition include pigment particles and other polymer particles. The aqueous compositions include aqueous coating compositions.

2. 发明授权

US07273842B1 Colorants, dispersants and dispersions containing polymeric nanoparticles 有权
标题翻译：含有聚合物纳米粒子的着色剂，分散剂和分散体
公开(公告)号：US07273842B1
公开(公告)日：2007-09-25
申请号：US10461953
申请日：2003-06-13
申请人： Antony Keith VanDyk , Dennis Paul Lorah
发明人： Antony Keith VanDyk , Dennis Paul Lorah
IPC分类号： C11D3/37
CPC分类号： B01J13/0004 , A01N25/10 , A01N25/24 , A61K8/8152 , A61K2800/413 , A61Q3/02 , B01F17/0028 , B01F17/005 , B01F17/0057 , B01F17/0064 , B08B17/06 , B08B17/065 , B32B27/08 , B82Y5/00 , B82Y30/00 , C04B24/2641 , C04B40/0039 , C04B41/483 , C04B41/63 , C08F8/44 , C08F257/02 , C08F265/04 , C08F265/06 , C08F285/00 , C08F291/00 , C08J3/07 , C08L27/06 , C08L33/06 , C08L33/12 , C08L51/003 , C08L67/02 , C08L69/00 , C08L2666/02 , C09B63/00 , C09B67/0005 , C09D5/033 , C09D5/14 , C09D7/45 , C09D7/65 , C09D7/67 , C09D11/101 , C09D17/00 , C09D17/001 , C09D133/06 , C09D151/003 , C09J133/06 , C09J151/003 , C08L2666/04 , C08L2666/24
摘要： Colorants, dispersants, and dispersions are provided which include PNPs having a mean diameter in the range of from 1 to 50 nanometers, an acid value in the range of from 0 to 700 mg KOH/g PNP solids, an amine value in the range of from 0 to 250, a hydroxyl number in the range of from 0 to 250 mg KOH/g PNP solids, and containing at least 2 wt % of a polarizable group. Also provided are methods for preparing colorants, dispersants, and dispersions, which include PNPs.
摘要翻译：提供着色剂，分散剂和分散体，其包括平均直径在1至50纳米范围内的PNP，在0至700mg KOH / g PNP固体的范围内的酸值，在 0至250，羟基数在0至250mg KOH / g PNP固体的范围内，并且含有至少2重量％的可极化基团。还提供了制备着色剂，分散剂和分散体的方法，其包括PNP。

3. 发明授权

US06797328B2 Coating composition 有权
标题翻译：涂料组成
公开(公告)号：US06797328B2
公开(公告)日：2004-09-28
申请号：US10349906
申请日：2003-01-23
申请人： Albert Benner Brown , Ralph Craig Even , Dennis Paul Lorah , Alvin Michael Maurice , Robert Victor Slone , Xun Tang
发明人： Albert Benner Brown , Ralph Craig Even , Dennis Paul Lorah , Alvin Michael Maurice , Robert Victor Slone , Xun Tang
IPC分类号： B05D300
CPC分类号： C08F4/34 , C08F20/12
摘要： An aqueous composition suitable for use, when dry, as an improved coating is provided including an aqueous emulsion polymer, the polymer having a glass transition temperature (Tg) from greater than 20° C. to 80° C., formed by the free radical polymerization of at least one ethylenically unsaturated nonionic acrylic monomer and 0-7.5%, by weight based on the total weight of the polymer, ethylenically unsaturated acid monomer in the presence of 0.01-1.0%, by weight based on the total weight of the polymer, t-alkyl hydroperoxide, t-alkyl peroxide, or t-alkyl perester wherein the t-alkyl group includes at least 5 Carbon atoms and, optionally, at least one other oxidant. A method of preparing the emulsion polymer, a method for providing a coated substrate wherein the coating contains the emulsion polymer having a Tg from −20° C. to 80° C., and a method for improving the scrub resistance of a coating by including the emulsion polymer having a Tg from −20° C. to 80° C. are also provided.
摘要翻译：提供适用于干燥时作为改进涂层的水性组合物，包括水性乳液聚合物，所述聚合物的玻璃化转变温度（Tg）大于20℃至80℃，由自由基形成至少一种烯键式不饱和非离子丙烯酸单体的聚合，基于聚合物的总重量，基于聚合物总重量的0.01-1.0％的烯键式不饱和酸单体的总重量为0-7.5％叔烷基过氧化氢，叔烷基过氧化物或叔烷基过酸酯，其中叔烷基包括至少5个碳原子和任选的至少一种其它氧化剂。一种制备乳液聚合物的方法，一种提供涂覆基质的方法，其中该涂层含有-20℃至80℃的Tg的乳液聚合物，以及一种通过包括以下步骤改善涂层的耐擦洗性的方法：还提供了具有-20℃至80℃的Tg的乳液聚合物。

4. 发明授权

US06689824B2 Prepaints and method of preparing road-marking paints from prepaints 失效
标题翻译：制备涂料前处理剂和制备路标油漆的方法
公开(公告)号：US06689824B2
公开(公告)日：2004-02-10
申请号：US09785637
申请日：2001-02-16
申请人： John Michael Friel , John William Hook, III , Bernhard Helmut Lieser , Jerry William Washel , Dennis Paul Lorah , Donald Craig Schall , Ann Robertson Hermes
发明人： John Michael Friel , John William Hook, III , Bernhard Helmut Lieser , Jerry William Washel , Dennis Paul Lorah , Donald Craig Schall , Ann Robertson Hermes
IPC分类号： F21V722
CPC分类号： B01F13/1055 , B01F13/1063 , B01F15/00123 , B01F15/00305 , B44D2/002 , B44D3/003 , B44D3/08 , C09D5/004 , C09D7/40 , C09D7/80 , C09D17/008
摘要： Sets of prepaints useful for forming a road-marking paint line are provided. Also provided are methods which permit the person applying the road-marking paint to vary the properties of the road-marking paint at the application point to suit the ambient conditions, including temperature, humidity, traffic flow and the like.
摘要翻译：提供了一些用于形成道路标线漆线的预涂料。还提供了允许使用道路标线漆的人改变应用点处的道路标线漆的特性以适应包括温度，湿度，交通流量等在内的环境条件的方法。

5. 发明授权

US06545084B2 Coating composition 有权
标题翻译：涂料组成
公开(公告)号：US06545084B2
公开(公告)日：2003-04-08
申请号：US09981349
申请日：2001-10-17
申请人： Albert Benner Brown , Ralph Craig Even , Dennis Paul Lorah , Alvin Michael Maurice , Robert Victor Slone , Xun Tang
发明人： Albert Benner Brown , Ralph Craig Even , Dennis Paul Lorah , Alvin Michael Maurice , Robert Victor Slone , Xun Tang
IPC分类号： C08L3102
CPC分类号： C08F4/34 , C08F20/12
摘要： An aqueous composition suitable for use, when dry, as an improved coating is provided including an aqueous emulsion polymer, the polymer having a glass transition temperature (Tg) from greater than 20° C. to 80° C., formed by the free radical polymerization of at least one ethylenically unsaturated nonionic acrylic monomer and 0-7.5%, by weight based on the total weight of the polymer, ethylenically unsaturated acid monomer in the presence of 0.01-1.0%, by weight based on the total weight of the polymer, t-alkyl hydroperoxide, t-alkyl peroxide, or t-alkyl perester wherein the t-alkyl group includes at least 5 Carbon atoms and, optionally, at least one other oxidant. A method of preparing the emulsion polymer is also provided.
摘要翻译：提供适用于干燥时作为改进涂层的水性组合物，包括水性乳液聚合物，所述聚合物的玻璃化转变温度（Tg）大于20℃至80℃，由自由基形成至少一种烯键式不饱和非离子丙烯酸单体的聚合，基于聚合物的总重量，基于聚合物总重量的0.01-1.0％的烯键式不饱和酸单体的总重量为0-7.5％叔烷基过氧化氢，叔烷基过氧化物或叔烷基过酸酯，其中叔烷基包括至少5个碳原子和任选的至少一种其它氧化剂。还提供了制备乳液聚合物的方法。

6. 发明授权

US06887928B2 Method of improving viscosity stability upon addition of a colorant component 失效
标题翻译：添加着色剂组分时提高粘度稳定性的方法
公开(公告)号：US06887928B2
公开(公告)日：2005-05-03
申请号：US10025706
申请日：2001-12-26
申请人： Joseph David Tanzer , Jerome Michael Harris , Henry Jude Eichman , Homayoun Jamasbi , Dennis Paul Lorah
发明人： Joseph David Tanzer , Jerome Michael Harris , Henry Jude Eichman , Homayoun Jamasbi , Dennis Paul Lorah
IPC分类号： C09B67/20 , C09D7/02 , C09D7/12 , C09D7/14 , C09D17/00 , C08J3/00 , C08K5/05 , C08L75/00
CPC分类号： C09B67/0066 , C08L1/02 , C08L33/26 , C09B67/0063 , C09D7/43 , C09D7/45 , C09D7/80 , C09D17/001
摘要： A tinting composition containing a colorant component is disclosed. In addition, a method of improving the viscosity stability of a composition upon the addition of a colorant component employing an associative thickener, a macromolecular compound having a hydrophobic cavity, a dispersing resin and combinations thereof is disclosed.
摘要翻译：公开了含有着色剂组分的着色组合物。此外，公开了一种在使用缔合增稠剂，具有疏水性空腔的高分子化合物，分散树脂及其组合的添加着色剂组分时提高组合物的粘度稳定性的方法。

7. 发明授权

US07091275B1 Aqueous polymeric composition containing polymeric nanoparticles and treatments prepared therefrom 有权
标题翻译：含有聚合物纳米颗粒的水性聚合物组合物和由其制备的处理
公开(公告)号：US07091275B1
公开(公告)日：2006-08-15
申请号：US10461954
申请日：2003-06-13
申请人： David Richard Amick , Wayne Devonport , Antony Keith Van Dyk , Catherine Ann Finegan , Joseph Michael Hoefler , Dennis Paul Lorah , Alvin Michael Maurice
发明人： David Richard Amick , Wayne Devonport , Antony Keith Van Dyk , Catherine Ann Finegan , Joseph Michael Hoefler , Dennis Paul Lorah , Alvin Michael Maurice
IPC分类号： C08L33/00 , C08L33/02
CPC分类号： C09D133/02 , C08K3/22
摘要： An aqueous polymeric composition containing select polymeric nanoparticles is provided. The select polymeric nanoparticles contain as polymerized units at least one multiethylenically unsaturated monomer and at least one water soluble monomer; and have a mean diameter in the range of from 1 to 50 nanometers. Also provided are aqueous polymeric compositions that further contain second particles such as pigment particles or second polymer particles. The aqueous polymeric composition is useful for preparing coatings having at least one improved property compared to a coating absent the select polymeric nanoparticles. Further, the aqueous polymeric composition is useful for treating wood. A coating prepared from the aqueous polymeric composition is also provided.
摘要翻译：提供含有选择聚合物纳米颗粒的含水聚合物组合物。选择的聚合物纳米颗粒含有至少一种多烯属不饱和单体和至少一种水溶性单体作为聚合单元; 并且具有在1至50纳米范围内的平均直径。还提供了还含有第二颗粒如颜料颗粒或第二聚合物颗粒的水性聚合物组合物。与不含选择聚合物纳米颗粒的涂层相比，含水聚合物组合物可用于制备具有至少一种改进性能的涂层。此外，水性聚合物组合物可用于处理木材。还提供了由含水聚合物组合物制备的涂层。

8. 发明授权

US07109257B2 Modified clays and methods for making and using same 失效
公开(公告)号：US07109257B2
公开(公告)日：2006-09-19
申请号：US10254167
申请日：2002-09-25
申请人： Dennis Paul Lorah , Robert Victor Slone , George Max Lein
发明人： Dennis Paul Lorah , Robert Victor Slone , George Max Lein
IPC分类号： C08K9/04 , C08K3/34
CPC分类号： C01B33/44 , C04B30/00 , C08K9/02 , C08K9/04
摘要： Processes for modifying the surface chemistry of a clay are disclosed. In one embodiment, there is provided a process for modifying the surface chemistry of a clay, wherein the process comprises: providing a clay dispersion comprising at least one unmodified clay wherein said clay has a first exchangeable cation; adding a second cation to the clay dispersion, wherein at least a portion of the second cation exchanges with at least a portion of the first cation to form a modified clay dispersion; and combining at least one polar containing agent with the modified clay dispersion to provide a modified clay.

9. 发明授权

US06914095B2 Nanocomposite compositions and methods for making and using same 失效
标题翻译：纳米复合组合物及其制备和使用方法
公开(公告)号：US06914095B2
公开(公告)日：2005-07-05
申请号：US09954135
申请日：2001-09-17
申请人： Dennis Paul Lorah , Robert Victor Slone
发明人： Dennis Paul Lorah , Robert Victor Slone
IPC分类号： C09K3/10 , C08F2/00 , C08F2/44 , C08F265/06 , C08F292/00 , C08K9/04 , C08K9/08 , C08K3/34
CPC分类号： B82Y30/00 , C08F2/00 , C08F2/44 , C08F265/06 , C08F292/00 , C08K9/04 , C08K9/08 , C08K2201/011
摘要： The present invention is directed, in part, to improved nanocomposite compositions and processes for preparing same. In one embodiment, there is provided a process for preparing an aqueous nanocomposite dispersion, wherein the process comprises: providing at least one first ethylenically unsaturated monomer; providing an aqueous clay dispersion comprising an at least partially exfoliated aqueous clay having a first exchangeable cation and, optionally, at least one second ethylenically unsaturated monomer; adding a second cation to said aqueous clay dispersion, wherein at least a portion of the second cation exchanges with at least a portion of the first cation to form a modified aqueous clay dispersion; combining the first ethylenically unsaturated monomer and the modified aqueous clay dispersion; and polymerizing at least a portion of the first or second monomer to form the aqueous nanocomposite dispersion wherein at least one of the first or the second monomers comprises a polar monomer.
摘要翻译：本发明部分地涉及改进的纳米复合材料组合物及其制备方法。在一个实施方案中，提供了一种制备水性纳米复合物分散体的方法，其中所述方法包括：提供至少一种第一烯属不饱和单体; 提供一种含水粘土分散体，其包含至少部分剥离的水性粘土，其具有第一可交换阳离子和任选的至少一种第二烯属不饱和单体; 向所述含水粘土分散体中加入第二阳离子，其中至少一部分第二阳离子与第一阳离子的至少一部分交换以形成改性的含水粘土分散体; 将第一烯属不饱和单体和改性含水粘土分散体结合; 并聚合第一或第二单体的至少一部分以形成水性纳米复合物分散体，其中第一或第二单体中的至少一种包含极性单体。

10. 发明授权

US07189767B2 Colorants, dispersants, dispersions, and inks 失效
标题翻译：着色剂，分散剂，分散体和油墨
公开(公告)号：US07189767B2
公开(公告)日：2007-03-13
申请号：US10097257
申请日：2002-03-15
申请人： Robert Howard Gore , Eric Jon Langenmayr , Warren Harvey Machleder , Dennis Paul Lorah , Antony Keith Van Dyk , Newman Mayer Bortnick
发明人： Robert Howard Gore , Eric Jon Langenmayr , Warren Harvey Machleder , Dennis Paul Lorah , Antony Keith Van Dyk , Newman Mayer Bortnick
IPC分类号： C09D11/10 , C09D11/16
CPC分类号： C09D11/32 , B01F17/0014 , B01F17/0028 , B01F17/0035 , B01F17/005 , B01F17/0057 , B01F17/0064 , B01F17/0071 , C09B67/0061 , C09B69/10
摘要： Colorant, dispersants, dispersions, and inks are provided which include crosslinked polymeric nanoparticles (hereafter “PNPs”) having a mean diameter in the range of from 1 to 50 nanometers, the PNPs including as polymerized units at least one multi-ethylenically-unsaturated monomer. Also provided are methods for preparing colorants, dispersants, dispersions, and inks which include PNPs.
摘要翻译：提供着色剂，分散剂，分散体和油墨，其包括平均直径在1至50纳米范围内的交联聚合物纳米颗粒（以下称为“PNP”），PNP包括作为聚合单元的至少一种多烯属不饱和单体。还提供了制备包括PNP的着色剂，分散剂，分散体和油墨的方法。

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