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    • 7. 发明授权
    • Production of reinforced polytetramethyleneadipamide
    • 生产增强聚四亚甲基己二胺
    • US5332778A
    • 1994-07-26
    • US97909
    • 1993-07-28
    • Gunter PipperWalter Goetz
    • Gunter PipperWalter Goetz
    • C08G69/28C08L77/06C08G69/30C08K3/40
    • C08G69/28C08L77/06
    • A process for producing nylon-4,6 which is filled with a reinforcing agent by mixing a reinforcing agent with nylon-4,6 in the melt comprises the steps ofa) polycondensing a salt of 1,4-diaminobutane and adipic acid in the presence of excess 1,4-diaminobutane and water at polyamide-forming temperatures under superatmospheric pressure to give a precondensate having a relative viscosity .ltoreq.1.60,b) polycondensing the precondensate of a) in solid phase in the presence of steam at 220.degree.-270.degree. C. to obtain a nylon-4,6 having a relative viscosity of from 2.0 to 2.6,c) incorporating a reinforcing agent in the melt into nylon-4,6 from stage b) to obtain a nylon-4,6 filled with a reinforcing agent,d) polycondensing said filled nylon-4,6 in solid phase in the presence of steam at 220.degree.-270.degree. C. to a relative viscosity of at least 3.2.
    • 通过将增强剂与尼龙-4.6混合在熔体中而填充有增强剂的尼龙4,6的方法包括以下步骤:a)将1,4-二氨基丁烷和己二酸的盐缩聚在 在超大气压下在聚酰胺形成温度下存在过量的1,4-二氨基丁烷和水,得到相对粘度<1.60的预缩合物,b)在220℃的蒸气存在下使固相中的a)的预缩合物缩聚 -270℃,得到相对粘度为2.0〜2.6的尼龙-4,6,c)将熔融物中的增强剂加入到步骤b)中的尼龙4,6中,得到尼龙4,6 填充有增强剂,d)在220-270℃的蒸气存在下将固体状的所述填充尼龙4,6的聚缩聚物至少为3.2的相对粘度。
    • 8. 发明授权
    • Thermoplastic molding materials based on polyamide blends
    • 基于聚酰胺混合物的热塑性模塑材料
    • US5071924A
    • 1991-12-10
    • US376502
    • 1989-07-07
    • Eckhard M. KochGerhard HeinzWalter GoetzGunter Pipper
    • Eckhard M. KochGerhard HeinzWalter GoetzGunter Pipper
    • C08L21/00C08L77/00
    • C08L77/00
    • Thermoplastic molding materials contain, as essential components,A) 20-98% by weight of a partly aromatic amide copolymer essentially consisting ofa.sub.1) 40-90% by weight of units derived from terephthalic acid and hexamethylenediamine,a.sub.2) 0-50% by weight of units derived from .epsilon.-caprolactam anda.sub.3) 0-60% by weight of units derived from adipic acid and hexamethylenediamine,components a.sub.2) and/or a.sub.3) accounting altogether for not less than 10% by weight of the total number of units,B) 2-80% by weight of a partly crystalline thermoplastic polyamide which differs from A)and furthermoreC) 0-50% by weight of an elastomeric impact modifier andD) 0-60% by weight of fibrous or particulate fillers or a mixture of these.
    • 热塑性成型材料含有A)20-98重量%的部分芳族酰胺共聚物,其基本上由a1)40-90重量%的衍生自对苯二甲酸和六亚甲基二胺的单元组成,a2)0-50% 衍生自ε-己内酰胺的单元的重量和a3)0-60重量%衍生自己二酸和六亚甲基二胺的单元,组分a2)和/或a3)总计占总单元重量的10重量% B)2-80重量%的不同于A)的部分结晶的热塑性聚酰胺,此外C)0-50重量%的弹性体抗冲改性剂和D)0-60重量%的纤维或颗粒填料或 这些的混合物。
    • 10. 发明授权
    • Thermoplastic polyamide molding materials
    • 热塑性聚酰胺成型材料
    • US5650466A
    • 1997-07-22
    • US583189
    • 1996-01-04
    • Axel GottschalkHerbert FischGunter PipperMartin Weber
    • Axel GottschalkHerbert FischGunter PipperMartin Weber
    • C08G69/26C08L35/06C08L77/00C08L77/06C08L77/10C08L39/04
    • C08L35/06C08G69/265C08L77/00C08L77/06
    • Thermoplastic molding materials containA) from 5 to 95% by weight of a semicrystalline, partly aromatic copolyamide composed ofa.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,a.sub.2) from 6 to 20 mol % of units which are derived from isophthalic acid,a.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine anda.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms, the molar percentages of the components a.sub.1) to a.sub.4) summing to 100%,B) from 5 to 95% by weight of a copolymer of vinylaromatic compounds with .alpha.,.beta.-unsaturated dicarboxylic anhydrides and .alpha.,.beta.-unsaturated dicarboximides,C) from 0 to 90% by weight of an SAN, ABS or ASA polymer or of a polymer of a C.sub.1 -C.sub.18 -alkyl ester of (meth)acrylic acid or of a mixture thereof,D) from 0 to 20% by weight of an elastomeric polymer,E) from 0 to 50% by weight of a fibrous or particulate filler andF) from 0 to 30% by weight of conventional additives and processing assistants,the percentages by weight of the components A) to F) summing to 100 %.
    • 热塑性成型材料含有A)5〜95重量%的半结晶部分芳族共聚酰胺,其由a1- 30〜44摩尔%的衍生自对苯二甲酸的单元组成,a2)6〜20摩尔%的单元, 衍生自间苯二甲酸,a3)43至49.5摩尔%的衍生自六亚甲基二胺的单元和a4)0.5至7摩尔%的衍生自6至30个碳原子的脂族环状二胺的单元,摩尔百分数 组分a1)至a4)相加至100%,B)5至95重量%的乙烯基芳族化合物与α,β-不饱和二羧酸酐和α,β-不饱和二羧酸酯的共聚物,C)0至90% 重量的SAN,ABS或ASA聚合物或(甲基)丙烯酸或其混合物的C 1 -C 18烷基酯的聚合物,D)0至20重量%的弹性体聚合物,E) 0至50重量%的纤维或颗粒填料和F)0至30重量%的c 常规添加剂和加工助剂,组分A)至F)的重量百分数相加至100%。