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1. 发明授权

US4956421A Preparation of oxyalkylated, carboxyl-containing polymers 失效
标题翻译：烷氧基化的含羧基聚合物的制备
公开(公告)号：US4956421A
公开(公告)日：1990-09-11
申请号：US367680
申请日：1989-06-19
申请人： Walter Denzinger , Heinrich Hartmann , Richard Baur , Johannes Perner , Wolfgang Trieselt , Horst Trapp , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Richard Baur , Johannes Perner , Wolfgang Trieselt , Horst Trapp , Hans-Juergen Raubenheimer
IPC分类号： C08F8/14 , C08F20/00 , C08F20/04 , C08F22/00 , C08F22/02
CPC分类号： C08F8/14
摘要： Oxyalkylated, carboxyl-containing polymers are prepared by reacting(A) a polymer which contains one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids as copolymerized units with(B) an alkylene oxidein an aqueous medium at not more than 120.degree. C. by a process in which the reaction is started at a pH of from 5.0 to 5.9 and is ended after a pH of from 5.5 to 8.5 has been reached. As a result of monitoring of the pH, the selectivity of the addition reaction of alkylene oxides with the polymers (A) is substantially improved compared with known processes.
摘要翻译：通过使（A）含有一种或多种单烯键式不饱和C 3 -C 6 - 羧酸作为共聚单元的聚合物与水性介质中的（B）环氧烷烃在不大于120℃下反应来制备烷氧基化的含羧基聚合物。通过反应开始于5.0至5.9的pH并在达到5.5至8.5的pH后结束的方法。作为监测pH的结果，与已知方法相比，烯化氧与聚合物（A）的加成反应的选择性显着提高。

2. 发明授权

US5008032A Use of partially esterified copolymers in liquid detergents 失效
标题翻译：在液体洗涤剂中使用部分酯化的共聚物
公开(公告)号：US5008032A
公开(公告)日：1991-04-16
申请号：US417474
申请日：1989-10-05
申请人： Paul Diessel , Johannes Perner , Walter Denzinger , Heinrich Hartmann , Hans-Juergen Raubenheimer
发明人： Paul Diessel , Johannes Perner , Walter Denzinger , Heinrich Hartmann , Hans-Juergen Raubenheimer
IPC分类号： C08L67/00 , C11D3/37
CPC分类号： C11D3/3765
摘要： Liquid, alkaline detergent formulations which contain as essential constituents a surfactant, water and 0.1-20% by weight of partially esterified copolymers are obtainable by the copolymerization of(a) one or more C.sub.4 -C.sub.28 -olefins and(b) ethylenically unsaturated dicarboxylic anhydrides of from 4 to 8 carbon atomsin a molar ratio of 1:1 and subsequent partial esterification of the copolymers of the reaction products(A) C.sub.1 -C.sub.30 -alcohols, C.sub.8 -C.sub.22 fatty acids, C.sub.1 -C.sub.12 -alkylphenols or secondary C.sub.2 -C.sub.30 -amines with(B) one or more C.sub.2 -C.sub.4 -alkylene oxides or tetrahydrofuranin a molar ratio of (A):(B) of from 1:2 to 1:50 and hydrolysis of the anhydride groups of the copolymer to carboxyl groups, the partial esterification of the copolymers being carried on until more than 5 to 50% of the carboxyl groups of the copolymers have been esterified.
摘要翻译：通过（a）一种或多种C 4 -C 28 - 烯烃和（b）烯属不饱和二羧酸酐共聚获得含有作为表面活性剂，水和0.1-20重量％部分酯化共聚物的基本组分的液体，碱性洗涤剂制剂 4至8个碳原子，摩尔比为1:1，随后反应产物（A）C 1 -C 30醇，C 8 -C 22脂肪酸，C 1 -C 12烷基酚或仲C2-C30的共聚物的部分酯化 - 胺与（B）一种或多种C 2 -C 4 - 烯化氧或四氢呋喃的摩尔比为（A）：（B）为1:2至1:50，并将共聚物的酸酐基水解成羧基，承载共聚物的部分酯化直到共聚物的羧基的5至50％已被酯化。

3. 发明授权

US4621127A Preparation of carboxyl-containing polymers 失效
标题翻译：含羧基聚合物的制备
公开(公告)号：US4621127A
公开(公告)日：1986-11-04
申请号：US777328
申请日：1985-09-18
申请人： Walter Denzinger , Heinrich Hartmann , Johannes Perner , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Johannes Perner , Hans-Juergen Raubenheimer
IPC分类号： C08F2/00 , C08F2/10 , C08F2/38 , C08F2/44 , C08F20/00 , C08F20/04 , C08F20/06 , C08F22/00 , C08F22/02 , C08F120/04 , C08F22/04
CPC分类号： C08F20/04 , C08F2/10
摘要： Carboxyl-containing polymers which are water-soluble at least in the neutralized form are prepared by a method in which a monoethylenically unsaturated C.sub.3 -C.sub.5 -carboxylic acid is polymerized in the presence or absence of a carboxyl-free copolymerizable ethylenically unsaturated monomer in aqueous solution in the presence of polymerization initiator and of from 0.01 to 5% by weight, based on the monomers, of an inorganic acid of phosphorus in which the phosphorus has an oxidation state of from 1 to 4, its water-soluble salts, a water-soluble --PO(OH).sub.2 -containing compound and/or its water-soluble salts and, if required, a polymerization regulator. Virtually colorless or only slightly colored polymer solutions are obtained.
摘要翻译：至少以中和形式具有水溶性的含羧基聚合物是通过在存在或不存在无羧基的可共聚烯键式不饱和单体的水溶液中聚合单烯属不饱和C3-C5-羧酸的方法制备的在聚合引发剂存在下，基于单体为0.01〜5重量％的磷的氧化态为1〜4的磷的无机酸，其水溶性盐，水溶性盐，可溶性的含PO（OH）2的化合物和/或其水溶性盐，如果需要，可以使用聚合调节剂。获得几乎无色或仅有微量的聚合物溶液。

4. 发明授权

US4444561A Copolymers which contain basic groups and are used as antiredeposition agents in washing and after-treating textile goods containing synthetic fibers 失效
标题翻译：含有碱性基团并用作洗涤和后处理含有合成纤维的纺织品的抗再沉积剂的共聚物
公开(公告)号：US4444561A
公开(公告)日：1984-04-24
申请号：US467443
申请日：1983-02-17
申请人： Walter Denzinger , Wolfgang Trieselt , Johannes Perner , Heinrich Hartmann
发明人： Walter Denzinger , Wolfgang Trieselt , Johannes Perner , Heinrich Hartmann
IPC分类号： D06M15/333 , C11D3/00 , C11D3/37 , D06L1/12 , D06M15/327 , D06M15/39 , D06M101/00 , D06M101/16 , B08B3/04
CPC分类号： C11D3/3776 , C11D3/0036
摘要： Textile goods containing synthetic fibers are washed and after-treated by a process wherein, as an antiredeposition agent, a copolymer is employed which contains, as copolymerized monomers,(a) from 50 to 90% by weight of one or more vinyl esters of C.sub.1 -C.sub.4 aliphatic carboxylic acids,(b) from 5 to 35% by weight of one or more N-vinyllactams,(c) from 1 to 20% by weight of one or more monomers containing basic groups, or of salts or quaternization products of these monomers, and(d) from 0 to 20% by weight of one or more further monomers which are copolymerizable with monomers (a), (b) and (c) and are free from carboxyl and basic groups,the percentages in each case being based on the sum of the monomers, with the proviso that the percentages sum to 100.
摘要翻译：含有合成纤维的纺织品通过以下方法洗涤和后处理：其中，作为抗再沉积剂，使用含共聚单体的共聚物，（a）50至90重量％的一种或多种C1的乙烯基酯 -C4脂族羧酸，（b）5-35重量％的一种或多种N-乙烯基内酰胺，（c）1-20％重量的一种或多种含有碱性基团的单体，或其盐或季铵化产物这些单体，和（d）0至20重量％的一种或多种可与单体（a），（b）和（c）共聚的其它单体，并且不含羧基和碱基，每种情况下的百分数基于单体的总和，条件是百分比等于100。

5. 发明授权

US4280919A Detergents and cleansers containing oxyalkylated alcohols as biodegradable, low-foam surfactants 失效
标题翻译：含有烷氧基化醇的洗涤剂和清洁剂可生物降解，低泡沫表面活性剂
公开(公告)号：US4280919A
公开(公告)日：1981-07-28
申请号：US144948
申请日：1980-04-29
申请人： Dieter Stoeckigt , Dieter Kiessling , Johannes Perner , Wolfgang Trieselt , Horst Trapp
发明人： Dieter Stoeckigt , Dieter Kiessling , Johannes Perner , Wolfgang Trieselt , Horst Trapp
IPC分类号： B01D19/04 , C11D1/722 , C11D3/00 , C11D17/00 , C11D3/075 , C11D3/10 , C11D3/37
CPC分类号： B01D19/04 , B01D19/0404 , C11D1/722 , C11D3/0026
摘要： A detergent and cleanser which contains an oxyalkylated alcohol of the formula ##STR1## where R is C.sub.8 -C.sub.18 -alkyl, x is from 2 to 4.5 and y is from 2 to 5, as a low-foam, biodegradable surfactant additive.
摘要翻译：一种洗涤剂和清洁剂，其含有式为“IMAGE”的烷氧基化醇，其中R为C 8 -C 18烷基，x为2至4.5，y为2至5，作为低泡沫可生物降解的表面活性剂添加剂。

6. 发明授权

US5009805A Liquid detergent with copolymer additive 失效
标题翻译：液体洗涤剂与共聚添加剂
公开(公告)号：US5009805A
公开(公告)日：1991-04-23
申请号：US424084
申请日：1989-10-19
申请人： Johannes Perner , Paul Diessel , Heinrich Hartmann , Walter Denzinger , Alfred Oftring , Willibald Schoenleben
发明人： Johannes Perner , Paul Diessel , Heinrich Hartmann , Walter Denzinger , Alfred Oftring , Willibald Schoenleben
IPC分类号： C11D3/32 , C11D3/37
CPC分类号： C11D3/3773
摘要： Liquid detergent formulations contain as essential constituents a surfactant and 0.1-20% by weight of a copolymer which contains(a) 50-99 mol % of units of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, a half ester of a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, an ester of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a C.sub.2 -C.sub.30 -olefin, styrene, a C.sub.1 -C.sub.3 -alkylstyrene, a C.sub.1 -C.sub.28 -alkyl vinyl ether, a vinyl ester of a saturated C.sub.1 -C.sub.8 -monocarboxylic acid or a mixture thereof and(b) 50-1 mol % of units of an amide of a monoethylenically unsaturated C.sub.3 -C.sub.8 -carboxylic acid where the amide groups have the structure ##STR1## where R.sup.1 is C.sub.8 -C.sub.28 -alkyl or preferably ##STR2## R.sup.3 and R.sup.4 are each H, CH.sub.3 or C.sub.2 H.sub.5, R is C.sub.1 -C.sub.28 -alkyl,n is from 2 to 100 andR.sup.2 is H or R.sup.1,and has a K value of from 8 to 200, or a salt thereof.
摘要翻译：液体洗涤剂配方含有表面活性剂和0.1-20重量％的共聚物，其含有（a）50-99摩尔％的单烯属不饱和C3-C8-单羧酸单元，单烯属不饱和C4-C8-二羧酸酸，单烯键式不饱和C4-C8-二羧酸的半酯，单烯属不饱和C3-C8-一元羧酸的酯，C2-C30-烯烃，苯乙烯，C1-C3-烷基苯乙烯，C1-C28- 烷基乙烯基醚，饱和C1-C8-一元羧酸的乙烯基酯或其混合物，和（b）50-1摩尔％的单烯属不饱和C 3 -C 8 - 羧酸的酰胺单元，其中酰胺基具有其中R 1为C 8 -C 28 - 烷基或优选R 3和R 4各自为H，CH 3或C 2 H 5，R为C 1 -C 28 - 烷基，n为2至100，R 2为H或R 1，并且的K值为8〜200，或其盐。

7. 发明授权

US4647396A Copolymers for detergents and cleaning agents 失效
标题翻译：用于洗涤剂和清洁剂的共聚物
公开(公告)号：US4647396A
公开(公告)日：1987-03-03
申请号：US703614
申请日：1985-02-21
申请人： Walter Denzinger , Heinrich Hartmann , Albert Hettche , Ulrich Kaluza , Johannes Perner , Christos Vamvakaris
发明人： Walter Denzinger , Heinrich Hartmann , Albert Hettche , Ulrich Kaluza , Johannes Perner , Christos Vamvakaris
IPC分类号： C08F20/00 , C08F20/26 , C08F220/00 , C08F220/04 , C08F220/06 , C08F220/28 , C08F222/02 , C11D3/37 , C08F22/04 , C08F22/20
CPC分类号： C11D3/3757 , C08F220/28
摘要： The invention relates to copolymers as ingredients for detergents and cleaning agents, which contain monoethylenically unsaturated mono- and dicarboxylic acids, their hydroxyalkyl esters and, if appropriate, other ethylenically unsaturated compounds as monomer units, and are distinguished by a particular calicum-binding and magnesium-binding capacity, detergents and cleaning agents containing these copolymers, and their use in detergents and cleaning agents, in particular as sequestering agents and anti-redeposition agents.
摘要翻译：本发明涉及作为洗涤剂和清洁剂的成分的共聚物，其含有单烯键式不饱和单羧酸和二羧酸，它们的羟烷基酯和（如果合适的话）其它烯键式不饱和化合物作为单体单元，并且由特定的孔隙结合和镁包含这些共聚物的结合能力，洗涤剂和清洁剂，以及它们在洗涤剂和清洁剂中的用途，特别是作为螯合剂和抗再沉积剂。

8. 发明授权

US4816553A Polyacetals, preparation thereof from dialdehydes and polyolcarboxylic acids, and use of same 失效
标题翻译：聚缩醛，其由二醛和多元羧酸制备，及其用途
公开(公告)号：US4816553A
公开(公告)日：1989-03-28
申请号：US156686
申请日：1988-02-17
申请人： Richard Baur , Rolf Fikentscher , Alfred Oftring , Felix Richter , Wolfgang Trieselt , Paul Diessel , Ekhard Winkler , Johannes Perner
发明人： Richard Baur , Rolf Fikentscher , Alfred Oftring , Felix Richter , Wolfgang Trieselt , Paul Diessel , Ekhard Winkler , Johannes Perner
IPC分类号： C11D3/20 , C07C41/00 , C07C41/50 , C07C43/30 , C07C67/00 , C08G4/00 , C09K3/00 , C11D3/37 , C08G16/02
CPC分类号： C11D3/3711 , C08G4/00
摘要： Polyacetals obtainable by reaction of(a) a dialdehyde of the formulaOHC--A.sub.n --CHO whereA=C.sub.1 -C.sub.4 -alkylene or ##STR1## and n is 0 or 1, is reacted with(b) a polycarboxylic acid of 5 to 7 carbon atoms which contains not less than 3 OH groups,in a molar ratio (a):(b) of 1:0.25 to 4 in an aqueous medium in the presence of an acid catalyst, are used as additives in washing agents and as complexing agents for heavy metal ions.
摘要翻译：其中A = C1-C4-亚烷基或和n为0或1的通式为OHC-An-CHO的二醛与（b）5至7的多元羧酸反应得到的聚缩醛在酸性催化剂存在下，在含水介质中，摩尔比（a）：（b）为1:0.25〜4的含有不少于3个OH基团的碳原子被用作洗涤剂中的添加剂和络合剂重金属离子剂。

9. 发明授权

US5656646A Mixtures of polymers of monoethylenically unsaturated dicarboxylic acids and polymers of ethylenically unsaturated monocarboxylic acids and/or polyaminocarboxylic acids and their use 失效
标题翻译：单烯属不饱和二羧酸的聚合物和烯属不饱和一元羧酸和/或聚氨基羧酸的聚合物的混合物及其用途
公开(公告)号：US5656646A
公开(公告)日：1997-08-12
申请号：US424486
申请日：1995-05-22
申请人： Johannes Perner , Paul Diessel , Helmut Guembel , Walter Denzinger , Heinrich Hartmann , Matthias Kroner
发明人： Johannes Perner , Paul Diessel , Helmut Guembel , Walter Denzinger , Heinrich Hartmann , Matthias Kroner
IPC分类号： H04L27/20 , C02F5/10 , C08L33/02 , C08L35/00 , C08L51/02 , C08L77/04 , C11D3/37 , H04B7/00 , H04J3/16 , H04J3/22 , H04J3/24 , H04J11/00 , H04J13/00 , H04J13/18 , H04L20060101 , H04L1/00 , H04L1/08 , H04L12/00 , H04L27/30 , H04L29/06 , H04Q7/38
CPC分类号： C11D3/3788 , C02F5/10 , C08L33/02 , C08L35/00 , C11D3/3757 , C11D3/3769 , H04J13/0048 , H04J13/18 , H04J3/1688 , H04J3/22 , H04J3/24 , H04L1/0057 , H04L1/0059 , H04L1/0065 , H04L1/0071 , H04L1/08 , C08L51/02 , C08L77/04
摘要： Mixtures of(I)polymers of monoethylenically unsaturated dicarboxylic acids having a molecular weight of from 200 to 5,000 and(II)(1) copolymers having a molecular weight of from 10,000 to 150,000 and comprising(a) from 10 to 70% by weight of monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acids or the salts thereof and(b) from 30 to 90% by weight of monoethylenically unsaturated C.sub.3 -C.sub.10 -monocarboxylic acids and/or the salts thereof,(2) graft polymers having a molecular weight of from 5,000 to 150,000, which are obtainable by free radical graft polymerization of(A) monoethylenically unsaturated C.sub.3 -C.sub.10 -carboxylic acids or the anhydrides and/or the salts thereof in the presence of(B) mono-, oligo- or polysaccharides and the derivatives thereof in a weight ratio (A) : (B) of (95 to 20) : (5 to 80), and/or(3) polyaminocarboxylic acids and/or polymers containing aminocarboxylic acid groupscontain the components (I) and (II) in a weight ratio of from 10 : 0.5 to 0.5 : 10 and are used as additives for phosphate-free or low-phosphate textile detergents or as dispersants or coating inhibitors in cleaners for hard surfaces.
摘要翻译： PCT No.PCT / EP93 / 03159 Sec。 371日期：1995年5月22日 102（e）日期1995年5月22日PCT提交1993年11月11日PCT公布。出版物WO94 / 12571 日期1994年6月9日分子量为200〜5,000的单烯属不饱和二羧酸（I）的聚合物和（II）（1）分子量为10,000〜150,000的共聚物的混合物，（a）10〜 70重量％的单烯属不饱和C4-C8-二羧酸或其盐，和（b）30-90重量％的单烯属不饱和C 3 -C 10 - 一元羧酸和/或其盐，（2）接枝聚合物，其具有（A）单烯键式不饱和C3-C10-羧酸或其酸酐和/或其盐在（B）单 - ，低聚 - （甲基）丙烯酸酯存在下，通过自由基接枝聚合获得的分子量为5,000至150,000，或多糖及其衍生物的重量比（A）：（B）（95〜20）：（5-80）和/或（3）含氨基羧酸的聚氨基羧酸和/或聚合物含有组分（ I）和（II）的重量比为10:0.5至0。 5：10，用作无磷酸盐或低磷酸盐纺织洗涤剂的添加剂，或用作硬表面清洁剂中的分散剂或涂层抑制剂。

10. 发明授权

US5536884A Mixture of at least two alkoxylated alcohols and use thereof as a foam-suppressing surfactant additament in cleaning compositions for mechanized cleaning processes 失效
标题翻译：至少两种烷氧基化醇的混合物及其作为用于机械化清洗方法的清洁组合物中的泡沫抑制表面活性剂添加剂的用途
公开(公告)号：US5536884A
公开(公告)日：1996-07-16
申请号：US104164
申请日：1993-08-23
申请人： Dieter Stoeckigt , Richard Baur , Horst Trapp , Johannes Perner
发明人： Dieter Stoeckigt , Richard Baur , Horst Trapp , Johannes Perner
IPC分类号： C11D1/722 , C11D1/825 , C11D3/00 , C11D17/00
CPC分类号： C11D3/0026 , C11D1/722 , C11D1/8255
摘要： A mixture suitable for use as a foam-suppressing surfactant additament in cleaning compositions for mechanized cleaning processes comprises at least two mixtures of alkoxylated alcohols IR--O--(C.sub.2 H.sub.4 O).sub.x --(C.sub.3 H.sub.6 O).sub.y --H (I)where x is an average degree of ethoxylation between 1 and 12, y is an average degree of propoxylation between 1 and 15, one alkoxylated alcohol mixture carries straight-chain or branched C.sub.8 -C.sub.18 -alkyl groups as the radical R and one other alkoxylated alcohol mixture carries straight-chain or branched C.sub.10 -C.sub.20 -alkyl groups as the radical R, subject to the proviso that the two radicals R differ by at least 0.5 in the average number of carbon atoms, and the two alkoxylated alcohol mixtures present in a ratio of from 10:90 to 90:10.
摘要翻译： PCT No.PCT / EP92 / 00289 Sec。 371日期：1993年8月23日 102（e）日期1993年8月23日PCT提交1992年2月11日PCT公布。出版物WO92 / 14808 日本9月3日，1992.适合用作机械化清洗方法的清洁组合物中的泡沫抑制表面活性剂添加剂的混合物包含至少两种烷氧基化醇I RO-（C 2 H 4 O）x - （C 3 H 6 O）y H（I） x是1至12之间的平均乙氧基化度，y是1至15之间的平均丙氧基化度，一个烷氧基化醇混合物携带直链或支链C 8 -C 18烷基作为基团R和一个其它烷氧基化醇混合物带有直链或支链的C 10 -C 20烷基作为基团R，条件是两个基团R在平均碳原子数上差异至少为0.5，两个烷氧基化醇混合物的比例为从10:90到90:10。

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