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1. 发明授权

US08524845B2 Catalyst composition and a process for the oligomerization of ethylene 有权
标题翻译：催化剂组合物和乙烯低聚方法
公开(公告)号：US08524845B2
公开(公告)日：2013-09-03
申请号：US12223218
申请日：2007-02-06
申请人： Vugar O. Aliyev , Atieh Abu-Raqabah , Fahad Al-Khodairi , Akif H. Azizov , Akber A. Khanmetov , Bilal V. Guliyev , Reyhan V. Aliyeva , Chingiz K. Rasulov , Minavar J. Ibrahimova
发明人： Vugar O. Aliyev , Atieh Abu-Raqabah , Fahad Al-Khodairi , Akif H. Azizov , Akber A. Khanmetov , Bilal V. Guliyev , Reyhan V. Aliyeva , Chingiz K. Rasulov , Minavar J. Ibrahimova
IPC分类号： C08F4/64 , C08F4/76 , C08F4/52
CPC分类号： B01J31/223 , B01J31/0214 , B01J31/0215 , B01J31/0235 , B01J31/143 , B01J2231/20 , B01J2531/48 , C07C2/32 , C07C2531/22 , C08F10/00 , C07C11/02 , C08F4/64058
摘要： The present invention relates to a catalyst composition for the oligomerization of ethylene comprising at least one transition metal bisphenolate compound and at least one cocatalyst. The transition metal bisphenolate is a zirconium bisphenolate.The invention also relates to a process for the oligomerization of ethylene in the presence of the catalyst composition according to the invention. The process results in a high yield of C4-C18 linear alpha-olefin and C6-C10 linear alpha-olefin.
摘要翻译：本发明涉及用于乙烯低聚的催化剂组合物，其包含至少一种过渡金属双酚盐化合物和至少一种助催化剂。过渡金属双酚盐是双酚钛。本发明还涉及在本发明催化剂组合物存在下乙烯低聚的方法。该方法产生高产率的C 4 -C 18直链α-烯烃和C 6 -C 10直链α-烯烃。

2. 发明申请

US20100152398A1 Catalyst Composition And A Process For The Oligomerization Of Ethylene 有权
标题翻译：催化剂组合物和乙烯低聚的方法
公开(公告)号：US20100152398A1
公开(公告)日：2010-06-17
申请号：US12223218
申请日：2007-02-06
申请人： Vugar O. Aliyev , Atieh Abu-Raqabah , Fahad Al-Khodairi , Akif H. Azizov , Akber A. Khanmetov , Bilal V. Guliyev , Reyhan V. Aliyeva , Chingiz K. Rasulov , Minavar J. Ibrahimova
发明人： Vugar O. Aliyev , Atieh Abu-Raqabah , Fahad Al-Khodairi , Akif H. Azizov , Akber A. Khanmetov , Bilal V. Guliyev , Reyhan V. Aliyeva , Chingiz K. Rasulov , Minavar J. Ibrahimova
IPC分类号： C08F110/02 , C08F2/00
CPC分类号： B01J31/223 , B01J31/0214 , B01J31/0215 , B01J31/0235 , B01J31/143 , B01J2231/20 , B01J2531/48 , C07C2/32 , C07C2531/22 , C08F10/00 , C07C11/02 , C08F4/64058
摘要： The present invention relates to a catalyst composition for the oligomerization of ethylene comprising at least one transition metal bisphenolate compound and at least one cocatalyst. The transition metal bisphenolate is a zirconium bisphenolate.The invention also relates to a process for the oligomerization of ethylene in the presence of the catalyst composition according to the invention. The process results in a high yield of C4-C18 linear alpha-olefin and C6-C10 linear alpha-olefin.
摘要翻译：本发明涉及用于乙烯低聚的催化剂组合物，其包含至少一种过渡金属双酚盐化合物和至少一种助催化剂。过渡金属双酚盐是双酚钛。本发明还涉及在本发明催化剂组合物存在下乙烯低聚的方法。该方法产生高产率的C 4 -C 18直链α-烯烃和C 6 -C 10直链α-烯烃。

3. 发明授权

US08653316B2 Process for the preparation of linear alpha-olefins and catalyst used therein 有权
标题翻译：用于制备线性α-烯烃和其中使用的催化剂的方法
公开(公告)号：US08653316B2
公开(公告)日：2014-02-18
申请号：US11990173
申请日：2006-08-10
申请人： Vugar O. Aliyev , Atieh Abu-Raqabah , Mohammad Zahoor
发明人： Vugar O. Aliyev , Atieh Abu-Raqabah , Mohammad Zahoor
IPC分类号： C07C2/22 , B01J31/04
CPC分类号： B01J31/2226 , B01J31/04 , B01J31/143 , B01J2231/20 , B01J2531/48 , C07C2/30 , C07C11/02
摘要： The present invention relates to a process for the preparation of linear low molecular weight alpha-olefins having 4 to 24 carbon atoms, comprising oligomerizing ethylene in an inert solvent in the presence of a catalyst system comprising: (i) zirconium carboxylate of the formula (R1COO)mZrCl4-m, wherein R1 is saturated or unsaturated aliphatic C1-C10 hydrocarbon or aromatic C6-C14 hydrocarbon and m fulfills 1≦m≦4, (ii) at least one aluminum compound selected from organoaluminum compounds of the formula R2nAlX3-n, wherein R2 is C1-C20 alkyl, X is chlorine, bromine or iodine, and n fulfills 1≦n≦2, and/or aluminoxanes, and (iii) at least two different additives selected from the group consisting of hydrogen, esters, ketones, ethers, amines, anhydrides, phosphines and sulfur compounds; as well as to a catalyst used therein.
摘要翻译：本发明涉及制备具有4至24个碳原子的线型低分子量α-烯烃的方法，包括在惰性溶剂中在催化剂体系存在下使乙烯低聚，包括：（i）式 R1COO）mZrCl4-m，其中R1是饱和或不饱和脂族C 1 -C 10烃或芳族C 6 -C 14烃，m满足1〜4，（ii）至少一种选自式R 2 n AlX 3-n的有机铝化合物的铝化合物其中R2是C1-C20烷基，X是氯，溴或碘，n满足1≤n≤2和/或铝氧烷，和（iii）至少两种选自氢，酯，酮，醚，胺，酸酐，膦和硫化合物; 以及其中使用的催化剂。

4. 发明授权

US07919569B2 Process for the polymerizaion of olefins 有权
标题翻译：烯烃聚合方法
公开(公告)号：US07919569B2
公开(公告)日：2011-04-05
申请号：US11921616
申请日：2006-05-12
申请人： Wei Xu , Vugar O. Aliyev , Sirajudeen Mohamed , Atieh Abu-Raqabah
发明人： Wei Xu , Vugar O. Aliyev , Sirajudeen Mohamed , Atieh Abu-Raqabah
IPC分类号： C08F4/602 , C08F4/609 , C08F4/642 , C08F4/649 , C08F4/6592
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F2/002 , C08F210/14
摘要： The present invention relates to a process for the polymerization of olefins, comprising the steps of introducing at least one olefin, at least one polymerization catalyst, at least one cocatalyst and at least one cocatalyst aid, and optionally a scavenger, into a polymerization reactor, and polymerizing the olefin, wherein the cocatalyst aid is a reaction product prepared separately prior to the introduction into the reactor by reacting at least one metal alkyl compound of group IIA or IIIA of the periodic system of elements and at least one compound (A) of the formula RmXR′n, wherein R is a branched, straight, or cyclic, substituted or unsubstituted, hydrocarbon group having 1 to 30 carbon atoms, R′ is hydrogen or any functional group with at least one active hydrogen, X is at least one heteroatom selected from the group of O, N, P or S or a combination thereof, and wherein n and m are each at least 1 and are such that the formula has no net charge.
摘要翻译：本发明涉及一种烯烃聚合方法，包括以下步骤：将至少一种烯烃，至少一种聚合催化剂，至少一种助催化剂和至少一种助催化剂助剂以及任选的清除剂引入聚合反应器中，并且使所述烯烃聚合，其中所述助催化剂是通过使至少一种元素周期系统的IIA族或IIIA族的至少一种金属烷基化合物与至少一种元素周期系统的至少一种化合物（A）反应，在引入反应器之前分别制备的反应产物式RmXR'n，其中R是具有1至30个碳原子的支链，直链或环状的取代或未取代的烃基，R'是氢或具有至少一个活性氢的任何官能团，X是至少一个选自O，N，P或S或其组合的杂原子，并且其中n和m各自为至少1并且使得该式不具有净电荷。

5. 发明申请

US20090306449A1 Process for the Preparation of Linear Alpha-Olefins and Catalyst Used Therein 有权
标题翻译：线性α-烯烃及其所用催化剂的制备方法
公开(公告)号：US20090306449A1
公开(公告)日：2009-12-10
申请号：US11990173
申请日：2006-08-10
申请人： Vugar O. Aliyev , Atieh Abu-Raqabah , Mohammad Zahoor
发明人： Vugar O. Aliyev , Atieh Abu-Raqabah , Mohammad Zahoor
IPC分类号： C07C2/26 , B01J31/14
CPC分类号： B01J31/2226 , B01J31/04 , B01J31/143 , B01J2231/20 , B01J2531/48 , C07C2/30 , C07C11/02
摘要： The present invention relates to a process for the preparation of linear low molecular weight alpha-olefins having 4 to 24 carbon atoms, comprising oligomerizing ethylene in an inert solvent in the presence of a catalyst system comprising: (i) zirconium carboxylate of the formula (R1COO)mZrCl4-m, wherein R1 is saturated or unsaturated aliphatic C1-C10 hydrocarbon or aromatic C6-C14 hydrocarbon and m fulfills 1≦m≦4, (ii) at least one aluminum compound selected from organoaluminum compounds of the formula R2nAlX3-n, wherein R2 is C1-C20 alkyl, X is chlorine, bromine or iodine, and n fulfills 1≦n≦2, and/or aluminoxanes, and (iii) at least two different additives selected from the group consisting of hydrogen, esters, ketones, ethers, amines, anhydrides, phosphines and sulfur compounds; as well as to a catalyst used therein.
摘要翻译：本发明涉及制备具有4至24个碳原子的线型低分子量α-烯烃的方法，包括在惰性溶剂中在催化剂体系存在下使乙烯低聚，包括：（i）式 R1COO）mZrCl4-m，其中R1是饱和或不饱和脂族C 1 -C 10烃或芳族C 6 -C 14烃，m满足1≤n≤4，（ii）至少一种铝化合物，其选自式R2nAlX3的有机铝化合物 -n，其中R2是C1-C20烷基，X是氯，溴或碘，n满足1≤n≤2，和/或铝氧烷，和（iii）至少两种不同的添加剂，其选自氢，酯，酮，醚，胺，酸酐，膦和硫化合物; 以及其中使用的催化剂。

6. 发明申请

US20090203859A1 Process for the polymerizaion of olefins 有权
标题翻译：烯烃聚合方法
公开(公告)号：US20090203859A1
公开(公告)日：2009-08-13
申请号：US11921616
申请日：2006-05-12
申请人： Wei Xu , Vugar O. Aliyev , Sirajudeen Mohamed , Atieh Abu-Raqabah
发明人： Wei Xu , Vugar O. Aliyev , Sirajudeen Mohamed , Atieh Abu-Raqabah
IPC分类号： C08F4/52
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F2/002 , C08F210/14
摘要： The present invention relates to a process for the polymerization of olefins, comprising the steps of introducing at least one olefin, at least one polymerization catalyst, at least one cocatalyst and at least one cocatalyst aid, and optionally a scavenger, into a polymerization reactor, and polymerizing the olefin, wherein the cocatalyst aid is a reaction product prepared separately prior to the introduction into the reactor by reacting at least one metal alkyl compound of group IIA or IIIA of the periodic system of elements and at least one compound (A) of the formula RmXR′n, wherein R is a branched, straight, or cyclic, substituted or unsubstituted, hydrocarbon group having 1 to 30 carbon atoms, R′ is hydrogen or any functional group with at least one active hydrogen, X is at least one heteroatom selected from the group of O, N, P or S or a combination thereof, and wherein n and m are each at least 1 and are such that the formula has no net charge.
摘要翻译：本发明涉及一种烯烃聚合方法，包括以下步骤：将至少一种烯烃，至少一种聚合催化剂，至少一种助催化剂和至少一种助催化剂助剂以及任选的清除剂引入聚合反应器中，并且使所述烯烃聚合，其中所述助催化剂是通过使至少一种元素周期系统的IIA族或IIIA族的至少一种金属烷基化合物与至少一种元素周期系统的至少一种化合物（A）反应，在引入反应器之前分别制备的反应产物式RmXR'n，其中R是具有1至30个碳原子的支链，直链或环状的取代或未取代的烃基，R'是氢或具有至少一个活性氢的任何官能团，X是至少一个选自O，N，P或S或其组合的杂原子，并且其中n和m各自为至少1并且使得该式不具有净电荷。

7. 发明授权

US07662894B2 Polymer supported metallocene catalyst composition for polymerizing olefins 失效
标题翻译：用于聚合烯烃的聚合物负载金属茂催化剂组合物
公开(公告)号：US07662894B2
公开(公告)日：2010-02-16
申请号：US11641160
申请日：2006-12-19
申请人： Orass Hamed , Akhlaq Moman , Atieh Abu-Raqabah
发明人： Orass Hamed , Akhlaq Moman , Atieh Abu-Raqabah
IPC分类号： C08F4/76 , C08F4/64 , C08F4/50 , C08F4/52 , B01J31/38
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F110/06 , Y10S526/904 , C08F4/65904 , C08F4/68 , C08F4/027 , C08F2500/04 , C08F2500/18
摘要： A catalyst composition for polymerizing olefins to polymers having bimodal molecular weight distribution comprises two transition metal-containing metallocene compounds, a magnesium compound, an alcohol, an aluminum containing co-catalyst and a polymeric support. The transition metal in one of the metallocene compounds is zirconium and the transition metal in the second metallocene compound is selected from the group consisting of titanium, vanadium and hafnium. Polyolefin polymers made using the catalyst composition have broad molecular weight distributions and are useful in film and blow molding applications.
摘要翻译：用于将烯烃聚合成具有双峰分子量分布的聚合物的催化剂组合物包含两种含过渡金属的茂金属化合物，镁化合物，醇，含铝助催化剂和聚合物载体。茂金属化合物之一中的过渡金属是锆，第二茂金属化合物中的过渡金属选自钛，钒和铪。使用该催化剂组合物制备的聚烯烃聚合物具有宽分子量分布，并且可用于膜和吹塑应用。

8. 发明授权

US07094726B2 Catalyst composition and process for olefin polymerization and copolymerization using supported metallocene catalyst systems 失效
公开(公告)号：US07094726B2
公开(公告)日：2006-08-22
申请号：US10445474
申请日：2003-05-27
申请人： Akhlaq Moman , Orass Hamed , Atieh Abu-Raqabah
发明人： Akhlaq Moman , Orass Hamed , Atieh Abu-Raqabah
IPC分类号： B01J31/16
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F110/02 , Y10S526/943 , C08F4/65916
摘要： A catalyst composition includes: A) a solid catalyst precursor containing a metallocene compound, a magnesium compound and a particulate polymeric material; and B) a cocatalyst containing aluminum compound. The catalyst is prepared by combining metallocene compound, magnesium compound and particles of polymeric material to form a catalyst precursor; and activating the catalyst precursor with alkylaluminums and/or aluminoxanes. Homopolymeric or copolymeric polyolefins are produced by contacting olefins or olefins and alpha-olefins with the catalyst composition.

9. 发明授权

US06861487B2 Catalyst precursor for the polymerization of olefins and polymerization process using the same 失效
标题翻译：用于烯烃聚合的催化剂前体和使用其的聚合方法
公开(公告)号：US06861487B2
公开(公告)日：2005-03-01
申请号：US10414118
申请日：2003-04-15
申请人： Orass Hamed , Akhlaq A. Moman , Atieh Abu-Raqabah , Abdulaziz Al-Nezari
发明人： Orass Hamed , Akhlaq A. Moman , Atieh Abu-Raqabah , Abdulaziz Al-Nezari
IPC分类号： B01J31/00 , C08F4/42 , C08F4/44 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/16
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/63916 , C08F4/68 , C08F4/027 , C08F2500/12 , C08F2500/18 , C08F2500/04 , C08F210/14
摘要： The present invention relates to a catalyst precursor for homo- or copolymerization of olefins comprising a metallocene compound, a magnesium containing compound and a thermoplastic polymer support, and optionally further comprising a metal alkoxy compound, an aluminum containing compound, a silicon containing compound and/or an alcohol. The invention further relates to the process of polymerizing olefins using the inventive catalyst precursor.
摘要翻译：本发明涉及包含茂金属化合物，含镁化合物和热塑性聚合物载体的烯烃均聚或共聚的催化剂前体，任选地还包含金属烷氧基化合物，含铝化合物，含硅化合物和/ 或酒精。本发明还涉及使用本发明的催化剂前体聚合烯烃的方法。

10. 发明授权

US08304504B2 Catalyst precursor for the production of olefins with an odd number of carbons atoms, process for its preparation and production method for such olefins 有权
标题翻译：用于生产具有奇数个碳原子的烯烃的催化剂前体，其制备方法和这种烯烃的制备方法
公开(公告)号：US08304504B2
公开(公告)日：2012-11-06
申请号：US11919147
申请日：2006-04-04
申请人： Marcus Seitz , Helmut G. Alt , Syriac J. Palackal , Atieh Abu-Raqabah
发明人： Marcus Seitz , Helmut G. Alt , Syriac J. Palackal , Atieh Abu-Raqabah
IPC分类号： C08F4/80 , C08F4/70 , C08F110/02 , C07F15/02
CPC分类号： B01J31/1815 , B01J31/143 , B01J2231/20 , B01J2531/842 , C07C2/32 , C07C2531/22 , C07D213/53 , C07F15/025 , C08F10/00 , C08F4/7042
摘要： The present invention relates to a catalyst precursor for the production of odd olefins having the formula: wherein X and Y are halogen and n is 2 or 3; and to a process for its preparation and a method for oligomerization of ethylene.
摘要翻译：本发明涉及用于制备具有下式的奇异烯烃的催化剂前体：其中X和Y是卤素，n是2或3; 以及其制备方法和乙烯低聚方法。

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