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1. 发明授权

US08444812B2 Creping adhesives with improved film properties 有权
标题翻译：起皱粘合剂具有改善的膜性能
公开(公告)号：US08444812B2
公开(公告)日：2013-05-21
申请号：US12273217
申请日：2008-11-18
申请人： Vladimir A. Grigoriev , Gary S. Furman, Jr. , Mingli Wei , Winston Su , Christopher D. Kaley , Bryan M. Schertzer
发明人： Vladimir A. Grigoriev , Gary S. Furman, Jr. , Mingli Wei , Winston Su , Christopher D. Kaley , Bryan M. Schertzer
IPC分类号： B31F1/12
CPC分类号： D21H21/146 , C08G73/028 , C08G73/0286 , C08L79/02 , C09J179/02
摘要： The invention provides a composition of matter used to produce very soft high grades of tissue paper. The composition of matter comprises a PAE resin acidified with a multifunctional acid. The multifunctional acid includes but is not limited to carboxyl and sulfonyl. The acid has a functional group selected from carboxyl and sulfonyl and a functional group selected from carboxyl, sulfonyl, hydroxyl, lactone, phenol, amine and heterocycle. The PAE resin facilitates the use of an adhesive in a Yankee Dryer apparatus that is durable when the adhesive is wet but remains soft when the adhesive becomes dry. These properties allow the adhesive to be strong and remain engaged to the dryer apparatus when wet but be easily removed by the creping blade when dry.
摘要翻译：本发明提供用于生产非常柔软的高等级的薄纸的物质组合物。物质组成包括用多官能酸酸化的PAE树脂。多官能酸包括但不限于羧基和磺酰基。酸具有选自羧基和磺酰基的官能团和选自羧基，磺酰基，羟基，内酯，苯酚，胺和杂环的官能团。 PAE树脂有助于在扬克烘干机设备中使用粘合剂，该粘合剂在粘合剂湿润时是耐用的，而当粘合剂变干时保持柔软。这些特性使得粘合剂坚固并且在湿润时保持与干燥设备接合，但是当干燥时易于被起皱刀片除去。

2. 发明申请

US20100122785A1 CREPING ADHESIVES WITH IMPROVED FILM PROPERTIES 有权
标题翻译：用改进的胶片特性来制造粘合剂
公开(公告)号：US20100122785A1
公开(公告)日：2010-05-20
申请号：US12273217
申请日：2008-11-18
申请人： Vladimir A. Grigoriev , Gary S. Furman, JR. , Mingli Wei , Winston Su , Christopher D. Kaley , Bryan M. Schertzer
发明人： Vladimir A. Grigoriev , Gary S. Furman, JR. , Mingli Wei , Winston Su , Christopher D. Kaley , Bryan M. Schertzer
IPC分类号： B31F1/12 , C08L77/06
CPC分类号： D21H21/146 , C08G73/028 , C08G73/0286 , C08L79/02 , C09J179/02
摘要： The invention provides a composition of matter used to produce very soft high grades of tissue paper. The composition of matter comprises a PAE resin acidified with a multifunctional acid. The multifunctional acid includes but is not limited to carboxyl and sulfonyl. The acid has a functional group selected from carboxyl and sulfonyl and a functional group selected from carboxyl, sulfonyl, hydroxyl, lactone, phenol, amine and heterocycle. The PAE resin facilitates the use of an adhesive in a Yankee Dryer apparatus that is durable when the adhesive is wet but remains soft when the adhesive becomes dry. These properties allow the adhesive to be strong and remain engaged to the dryer apparatus when wet but be easily removed by the creping blade when dry.
摘要翻译：本发明提供用于生产非常柔软的高等级的薄纸的物质组合物。物质组成包括用多官能酸酸化的PAE树脂。多官能酸包括但不限于羧基和磺酰基。酸具有选自羧基和磺酰基的官能团和选自羧基，磺酰基，羟基，内酯，苯酚，胺和杂环的官能团。 PAE树脂有助于在扬克烘干机设备中使用粘合剂，该粘合剂在粘合剂湿润时是耐用的，而当粘合剂变干时保持柔软。这些特性使得粘合剂坚固并且在湿润时保持与干燥设备接合，但是当干燥时易于被起皱刀片除去。

3. 发明申请

US20130079575A1 METHOD OF PRODUCING OLEFINS VIA METATHESIS 有权
标题翻译：通过METATHESIS生产油脂的方法
公开(公告)号：US20130079575A1
公开(公告)日：2013-03-28
申请号：US13246994
申请日：2011-09-28
申请人： Bryan M. Schertzer , Karol L. Grela , Justyna Czaban
发明人： Bryan M. Schertzer , Karol L. Grela , Justyna Czaban
IPC分类号： C07C2/08
CPC分类号： C07C6/04 , C07C2531/22 , C07C2531/24 , C07C11/02
摘要： Disclosed is a method of producing an organic compound. The method uses a metathesis catalyst in a coupling reaction of an olefin. The method comprises the steps of introducing the olefin into a container; either placing the container under vacuum or bubbling a gas through the olefin; adding an additive with the olefin; mixing the olefin and the additive, the mixing creating a mixture; adding an amount of the metathesis catalyst to the mixture, the amount being less than about 100 ppm by weight of the mixture; and optionally heating the mixture to a temperature, the temperature being greater than room temperature.
摘要翻译：公开了一种生产有机化合物的方法。该方法在烯烃的偶联反应中使用复分解催化剂。该方法包括将烯烃引入容器中的步骤; 将容器放置在真空下或鼓泡气体通过烯烃; 加入添加剂与烯烃; 混合烯烃和添加剂，混合产生混合物; 向混合物中加入一定量的复分解催化剂，其量小于混合物的约100ppm重量; 并且可选地将混合物加热到一个温度，该温度大于室温。

4. 发明授权

US08242287B2 Process for reacting an α, β-unsaturated dicarboxylic acid compound with an ethylenically unsaturated hydrocarbon 有权
标题翻译：使α，bgr-不饱和二羧酸化合物与烯属不饱和烃反应的方法
公开(公告)号：US08242287B2
公开(公告)日：2012-08-14
申请号：US12403072
申请日：2009-03-12
申请人： Bryan M. Schertzer , Timothy P. McGinnis
发明人： Bryan M. Schertzer , Timothy P. McGinnis
IPC分类号： C07D307/34 , C07D307/36
CPC分类号： C07C51/353 , C07C55/02
摘要： The invention provides an improved method of synthesizing chemicals according to the ene reaction. The method addresses two problems that previously could not be addressed simultaneously, preventing charring of the reaction, and preventing gaseous degradation of the reagents. The method involves adding a boron bearing compound and an aromatic/antioxidant compound to the ene reaction. Combining these two compounds together inhibits charring and also causes an effect that neither compound can accomplish alone. The addition of these two compounds together also more effectively prevents either of the reagents from degrading than when either reagent is added alone. As a result the method reduces costs by reducing the amount of reagents needed for a synthesis and further reduces costs by eliminating the need to filter out char from the end products of the ene reaction. The method is particularly useful in the ene reaction synthesis of ASA from olefins and maleic anhydride.
摘要翻译：本发明提供了根据烯类反应合成化学品的改进方法。该方法解决了以前不能同时解决的两个问题，防止反应发生炭化，并防止试剂的气体降解。该方法包括将硼载体化合物和芳族/抗氧化剂化合物加入到烯类反应中。将这两种化合物结合在一起抑制炭化，并且还引起两种化合物都可以单独实现的效果。当两种化合物一起添加时，与单独添加任一种试剂相比，更有效地防止任一试剂降解。因此，该方法通过减少合成所需的试剂的量来降低成本，并且通过不需要从烯酯反应的最终产物中过滤掉炭而进一步降低成本。该方法特别可用于烯烃和马来酸酐的烯醇反应合成ASA。

5. 发明申请

US20100234621A1 PROCESS FOR REACTING AN ALPHA, BETA-UNSATURATED DICARBOXYLIC ACID COMPOUND WITH AN ETHYLENICALLY UNSATURATED HYDROCARBON 有权
标题翻译：反应ALPHA，不饱和二羧酸的化合物与乙烯不饱和烃反应的方法
公开(公告)号：US20100234621A1
公开(公告)日：2010-09-16
申请号：US12403072
申请日：2009-03-12
申请人： Bryan M. Schertzer , Timothy P. McGinnis
发明人： Bryan M. Schertzer , Timothy P. McGinnis
IPC分类号： C07D307/60
CPC分类号： C07C51/353 , C07C55/02
摘要： The invention provides an improved method of synthesizing chemicals according to the ene reaction. The method addresses two problems that previously could not be addressed simultaneously, preventing charring of the reaction, and preventing gaseous degradation of the reagents. The method involves adding a boron bearing compound and an aromatic/antioxidant compound to the ene reaction. Combining these two compounds together inhibits charring and also causes an effect that neither compound can accomplish alone. The addition of these two compounds together also more effectively prevents either of the reagents from degrading than when either reagent is added alone. As a result the method reduces costs by reducing the amount of reagents needed for a synthesis and further reduces costs by eliminating the need to filter out char from the end products of the ene reaction. The method is particularly useful in the ene reaction synthesis of ASA from olefins and maleic anhydride.
摘要翻译：本发明提供了根据烯类反应合成化学品的改进方法。该方法解决了以前无法同时解决的两个问题，防止反应发生炭化，并防止试剂的气体降解。该方法包括将硼载体化合物和芳族/抗氧化剂化合物加入到烯类反应中。将这两种化合物结合在一起抑制炭化，并且还引起两种化合物都可以单独实现的效果。当两种化合物一起添加时，与单独添加任一种试剂相比，更有效地防止任一试剂降解。因此，该方法通过减少合成所需的试剂的量来降低成本，并且通过消除从烯酯反应的最终产物中过滤出炭的需要而进一步降低成本。该方法特别可用于烯烃和马来酸酐的烯醇反应合成ASA。

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