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1. 发明授权

US06958408B2 Ligands with at least a fluorosilcone substituent useful for preparing metal-locenes 失效
标题翻译：具有至少一个可用于制备金属 - 烯烃的氟硅酮取代基的配体
公开(公告)号：US06958408B2
公开(公告)日：2005-10-25
申请号：US10344528
申请日：2001-08-02
申请人： Virginie Cheron , Jean-Luc Couturier , Hendrik Hagen , Gerard Van Koten , Berth Jan Deelman
发明人： Virginie Cheron , Jean-Luc Couturier , Hendrik Hagen , Gerard Van Koten , Berth Jan Deelman
IPC分类号： C07F7/12 , C07F7/08 , C07F17/00 , C08F2/06 , C08F4/42 , C08F4/622 , C08F4/6392 , C08F4/642 , B01J31/00 , C08F4/44
CPC分类号： C07F17/00 , C07F7/081 , Y10S526/943
摘要： The invention concerns ligands with at least a fluorosilicone substituent of general formulae (I) and (II); a method for preparing them and their use for producing catalysts useful for olefin polymerisation
摘要翻译：本发明涉及至少具有通式（I）和（II）的氟硅酮取代基的配体; 制备它们的方法及其用于生产用于烯烃聚合的催化剂的用途

2. 发明申请

US20090131704A1 Process for the Preparation of Monoalkyltin Trihalides and Dialkyltin Dihalides 有权
标题翻译：单烷基锡三卤化物和二烷基锡二卤化物的制备方法
公开(公告)号：US20090131704A1
公开(公告)日：2009-05-21
申请号：US11995259
申请日：2006-07-11
申请人： Maarten Boele , Berth-Jan Deelman , Gerard Van Koten , Erika Monika Wagner
发明人： Maarten Boele , Berth-Jan Deelman , Gerard Van Koten , Erika Monika Wagner
IPC分类号： C07F7/22
CPC分类号： C07F7/2208
摘要： The present invention relates to a process for the production of monoalkyltin trihalides of the formula RSnHal3, in which R=alkyl or cycloalkyl and Hal=Cl. Br or I. Said process comprises contacting the corresponding alkene or cycioalkene, stannous halide SnHal2, hydrogen halide HHal and optionally Sn metal, in the presence of at least one transition metal-based catalyst, thereafter isolating the monoalkyltin trihalides from the medium. The present invention also relates to a process for the production of dialkyltin dihalides of the formula R2SnHal2 from monoalkyltin trihalides of the formula RsnHal3′. in which R=alkyl or cycloakyl and Hal=Cl, Br or I. Said process comprises contacting monoalkyltin trihalides RsnHal3 and Sn metal, optionally thereafter isolating the dialkyltin dihalides R2SnHal2 from the medium.
摘要翻译：本发明涉及制备式RSnHal3的单烷基锡三卤化物的方法，其中R =烷基或环烷基，Hal = Cl。所述方法包括在至少一种基于过渡金属的催化剂的存在下，使相应的烯烃或环烯烃，卤化锡SnHal2，卤化氢氦气和任选的Sn金属接触，然后从介质中分离三烷基卤化锡。本发明还涉及由式R n SnHal 3'的单烷基锡三卤化物制备式R 2 SnHal 2的二烷基锡二卤化物的方法。其中R =烷基或环烷基，Hal = Cl，Br或I.所述方法包括使单卤代三卤化物RsnHal 3和Sn金属接触，然后任选地从介质中分离二烷基锡二卤化物R 2 SnHal 2。

3. 发明授权

US07592472B2 Process for the preparation of monoalkyltin trihalides and dialkyltin dihalides 有权
标题翻译：制备单烷基锡三卤化物和二烷基锡二卤化物的方法
公开(公告)号：US07592472B2
公开(公告)日：2009-09-22
申请号：US11995259
申请日：2006-07-11
申请人： Maarten Boele , Berth-Jan Deelman , Gerard Van Koten , Erika Monika Wagner
发明人： Maarten Boele , Berth-Jan Deelman , Gerard Van Koten , Erika Monika Wagner
IPC分类号： C07F7/22
CPC分类号： C07F7/2208
摘要： The present invention relates to a process for the production of monoalkyltin trihalides of the formula RSnHal3, in which R=alkyl or cycloalkyl and Hal=Cl. Br or I. Said process comprises contacting the corresponding alkene or cycloalkene, stannous halide SnHal2, hydrogen halide HHal and optionally Sn metal, in the presence of at least one transition metal-based catalyst, thereafter isolating the monoalkyltin trihalides from the medium. The present invention also relates to a process for the production of dialkyltin dihalides of the formula R2SnHal2 from monoalkyltin trihalides of the formula RsnHal3′. in which R=alkyl or cycloakyl and Hal=Cl, Br or I. Said process comprises contacting monoalkyltin trihalides RsnHal3 and Sn metal, optionally thereafter isolating the dialkyltin dihalides R2SnHal2 from the medium.
摘要翻译：本发明涉及制备式RSnHal3的单烷基锡三卤化物的方法，其中R =烷基或环烷基，Hal = Cl。所述方法包括在至少一种基于过渡金属的催化剂的存在下，使相应的烯烃或环烯烃，卤化锡SnHal 2，卤化氢合成物和任选的Sn金属接触，然后从介质中分离出单烷基锡三卤化物。本发明还涉及由式R n SnHal 3'的单烷基锡三卤化物制备式R 2 SnHal 2的二烷基锡二卤化物的方法。其中R =烷基或环烷基，Hal = Cl，Br或I.所述方法包括使单卤代三卤化物RsnHal 3和Sn金属接触，然后任选地从介质中分离二烷基锡二卤化物R 2 SnHal 2。

4. 发明授权

US5834393A Adduct of an organometal compound and a compatible anion, supported catalyst component supported catalyst processes for the preparation thereof 失效
标题翻译：有机金属化合物和相容阴离子的加合物，负载型催化剂组分，负载型催化剂及其制备方法
公开(公告)号：US5834393A
公开(公告)日：1998-11-10
申请号：US610647
申请日：1996-03-04
申请人： Grant Berent Jacobsen , Peter Wijkens , Johann T. B. H. Jastrzebski , Gerard Van Koten
发明人： Grant Berent Jacobsen , Peter Wijkens , Johann T. B. H. Jastrzebski , Gerard Van Koten
IPC分类号： B01J31/12 , C07F5/02 , C07F7/00 , C07F7/28 , C07F17/00 , C08F4/02 , C08F4/60 , C08F4/603 , C08F4/606 , C08F4/619 , C08F4/6192 , C08F10/00 , B01J31/00 , B01J21/02
CPC分类号： C07F17/00 , C08F10/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192
摘要： A supported catalyst component comprising (a) a support material, an organometal compound, and (b) an activator compound comprising b.1) a cation which is capable of reacting with a transition metal metallocene compound to form a catalytically active transition metal complex, and b.2) a compatible anion having up to 100 nonhydrogen atoms and containing at least one substituent comprising an active hydrogen moiety; a supported catalyst comprising the supported catalyst component and a transition metal compound; process for making the same; an addition polymerization process using the supported catalyst; complex compounds, and a method for preparing the same. In the mixture of the support material, the organometal compound, and the ionic activator compound, the organometal compound reacts with residual hydroxyl groups on the support, forming a hydrocarbon byproduct and an organometal compound bound to the support, and the active hydrogen on the anion of the activator reacts further with the bound organometal compound to form a further hydrocarbon byproduct. The order of addition is immaterial as long as these are the three essential ingredients added in the formation of the support-bound activator complex.
摘要翻译：一种载体催化剂组分，其包含（a）载体材料，有机金属化合物和（b）活化剂化合物，其包含b.1）能够与过渡金属茂金属化合物反应形成催化活性过渡金属络合物的阳离子，和b.2）具有至多100个非氢原子并含有至少一个包含活性氢部分的取代基的相容阴离子; 负载催化剂，其包含负载型催化剂组分和过渡金属化合物; 制作相同的过程; 使用负载型催化剂的加成聚合法; 络合物，及其制备方法。在载体材料，有机金属化合物和离子活化剂化合物的混合物中，有机金属化合物与载体上的残余羟基反应，形成烃副产物和与载体结合的有机金属化合物，阴离子上的活性氢的活化剂进一步与结合的有机金属化合物反应以形成另外的烃副产物。加入的顺序是无关紧要的，只要这些是在形成支持结合的活化剂复合物中添加的三种必需成分即可。

5. 发明授权

US4898955A Meta-containing enolate compounds 失效
标题翻译：含元醇的烯醇化合物
公开(公告)号：US4898955A
公开(公告)日：1990-02-06
申请号：US283194
申请日：1988-12-12
申请人： Gerard Van Koten , Frederick H. Van Der Steen , Johann T. B. H. Jastrzebski
发明人： Gerard Van Koten , Frederick H. Van Der Steen , Johann T. B. H. Jastrzebski
IPC分类号： C07D205/095 , C07D205/08 , C07D205/085 , C07F3/06 , C07F5/02 , C07F5/06 , C07F7/00 , C07F7/10 , C07F7/22 , C07F7/28
CPC分类号： C07F3/06 , C07D205/085
摘要： Trans-.beta.-lactams are prepared in a nearly quantitative yield by a condensation reaction of a new intermediate metal enolate and an appropriate imine. Certain new metal enolates are provided as intermediates.

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