专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明申请

US20210292354A1 Oxo-Nitrogenated Iron Complex, Catalytic System Comprising Said Oxo-Nitrogenated Iron Complex and Process for the (Co)Polymerization of Conjugated Dienes 有权
公开(公告)号：US20210292354A1
公开(公告)日：2021-09-23
申请号：US16345015
申请日：2018-01-18
申请人： Versalis S.P.A.
发明人： Anna Sommazzi , Pampaloni Guido , Giovanni Ricci , Francesco Masi , Filippo Renili
IPC分类号： C07F15/02 , C08F136/08 , C08F136/06 , C07C251/08
摘要： Oxo-nitrogenated iron complex having general formula (I): in which: R1 and R2, identical or different, represent a hydrogen atom; or they are selected from linear or branched, optionally halogenated C1-C20, preferably C1-C15, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R3 represents a hydrogen atom, or it is selected from linear or branched, optionally halogenated C1-C20, preferably C1-C15 alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; X, identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine, preferably chlorine; or they are selected from. linear or branched C1-C20, preferably C1-C15, alkyl groups, —OCOR4 groups or —OR4 groups in which R4 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups; n is 2 or 3. Said oxo-nitrogenated iron complex having general formula (I) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.

2. 发明授权

US10766979B2 Bis-imine pyridine complex of lanthanides catalytic system comprising said bis-imine pyridine complex and process for the (co)polymerization of conjugated dienes 有权
公开(公告)号：US10766979B2
公开(公告)日：2020-09-08
申请号：US15342786
申请日：2016-11-03
申请人： Versalis S.P.A.
发明人： Giovanni Ricci , Anna Sommazzi , Giuseppe Leone , Aldo Boglia , Francesco Masi , Maria Caldararo
IPC分类号： C08F36/04 , C08F36/08 , C08F136/00 , C08F36/00 , C08F36/06
摘要： A bis-imine pyridine complex of lanthanides having general formula (I): Said bis-imine pyridine complex of lanthanides having general formula (I) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.

3. 发明授权

US09617360B2 Process for the preparation of (co) polymers of conjugated dienes in the presence of a catalytic system comprising a bis-imine complex of cobalt 有权
公开(公告)号：US09617360B2
公开(公告)日：2017-04-11
申请号：US14443093
申请日：2013-12-19
申请人： Versalis S.P.A.
发明人： Giovanni Ricci , Anna Sommazzi , Giuseppe Leone , Francesco Masi , Aldo Boglia
IPC分类号： C08F4/80 , C08F36/00 , C08F36/06 , C08F136/06 , C08F4/70
CPC分类号： C08F36/06 , C08F4/7096 , C08F136/06 , C08F4/7006
摘要： Process for the preparation of (co) polymers of conjugated dienes which comprises polymerizing at least one conjugated diene in the presence of a catalytic system comprising at least one bis-imine complex of cobalt having general formula (I) wherein: —n is 0 or 1; —Y represents a group —CR′R″— wherein R′ and R″, equal to or different from each other, represent a hydrogen atom; or a linear or branched C1-C20, preferably C1-C15, alkyl group; or a divalent aromatic group optionally substituted; —R1 and R2, equal to or different from each other, represent a hydrogen atom; or they are selected from a linear or branched Ci-C2o/preferably C1-C15, alkyl group optionally halogenated, cycloalkyl groups optionally substituted; or R1 and R2 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C1-C20, preferably C1-C15, alkyl groups, said cycle optionally containing heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; R3 and R4, equal to or different from each other, represent a hydrogen atom; or they are selected from a linear or branched Ci-C20, preferably C1-C15, alkyl groups optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; or R2 and R4 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched Ci-C2o, preferably C1-C15 alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; or R1 and R3 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C1-C20, preferably C1-C15, alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; X1 and X2, equal to or different from each other, represent a halogen atom such as, for example, chlorine, bromine, iodine; or they are selected from linear or branched C1-C20 preferably C1-C15, alkyl groups, —OCOR5 groups or —OR3 groups wherein R5 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups.

4. 发明申请

US20140213433A1 BIS-IMINE PYRIDINE COMPLEX OF LANTHANIDES CATALYTIC SYSTEM COMPRISING SAID BIS-IMINE PYRIDINE COMPLEX AND PROCESS FOR THE (CO)POLYMERIZATION OF CONJUGATED DIENES 审中-公开
标题翻译： BIS-IMINE PYRIDINE复合物，包含双相异构体吡啶复合物的纳米粒子催化体系和（CO）共聚二烯的聚合方法
公开(公告)号：US20140213433A1
公开(公告)日：2014-07-31
申请号：US14344001
申请日：2012-09-13
申请人： Versalis S.P.A.
发明人： Giovanni Ricci , Anna Sommazzi , Giuseppe Leone , Aldo Boglia , Francesco Masi , Maria Caldararo
IPC分类号： C08F36/04
摘要： A bis-imine pyridine complex of lanthanides having general formula (I): Said bis-imine pyridine complex of lanthanides having general formula (I) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.
摘要翻译：具有通式（I）的镧系元素的双亚胺吡啶络合物：具有通式（I）的镧系元素的所述双亚胺吡啶络合物可有利地用于共轭二烯（共）聚合的催化体系中。

5. 发明授权

US11299505B2 Bis-imine titanium complex, catalytic system comprising said bis-imine titanium complex and process for the (co)polymertzation of conjugated dienes 有权
公开(公告)号：US11299505B2
公开(公告)日：2022-04-12
申请号：US16649131
申请日：2018-09-28
申请人： Versalis S.P.A.
发明人： Guido Pampaloni , Giovanni Ricci , Anna Sommazzi , Massimo Guelfi , Giuseppe Leone , Francesco Masi
IPC分类号： C07F7/28 , C08F4/64 , C08F4/642 , C08F36/06
摘要： Bis-imine titanium complex having general formula (I): wherein: R1 and R2, mutually identical or different, represent a hydrogen atom; or are selected from linear or branched, optionally halogenated, C1-C20 alkyl groups, preferably C1-C15, optionally substituted cycloalkyl groups; R3 and R4, mutually identical or different, represent a hydrogen atom; or are selected from linear or branched, optionally halogenated, C1-C20 alkyl groups, preferably C1-C15, optionally substituted cycloalkyl groups, optionally substituted aryl groups; X1, X2, X3 and X4, mutually identical or different, represent a halogen atom such as chlorine, bromine, iodine; or are selected from linear or branched C1-C20 alkyl groups, preferably C1-C15, —OCOR5 groups or —OR5 groups wherein R5 is selected from linear or branched C1-C20 alkyl groups, preferably C1-C15; or represent an acetylacetonate group (acac); provided that when R1 and R2 represent a methyl group and X1, X2, X3 and X4 represent a chlorine atom, R3 and R4 are different from 2,6-di-isopropylphenyl.

6. 发明授权

US10793653B2 Process for preparing conjugated diene (co)polymers in the presence of a catalytic system comprising a pyridyl iron (III) complex 有权
公开(公告)号：US10793653B2
公开(公告)日：2020-10-06
申请号：US16343716
申请日：2017-10-20
申请人： Versalis S.p.A.
发明人： Giovanni Ricci , Guido Pampaloni , Anna Sommazzi , Massimo Guelfi , Francesco Masi
IPC分类号： C08F36/06 , C07F15/02 , C08F36/08 , C08F136/08 , C08F136/06 , C08F236/06 , C08F4/70 , C08L9/00 , C08F236/08
摘要： A process for preparing conjugated diene (co)polymers comprising polymerizing at least one conjugated diene in the presence of a catalytic system comprising: (a) at least one pyridyl iron (III) complex having general formula (I) or (II): wherein: —R1, R2, R3 and R4, identical or different, represent a hydrogen atom; or are selected from linear or branched, optionally halogenated C1-C20, preferably C1-C15, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; —R5 represents a hydrogen atom, or is selected from linear or branched, optionally halogenated C1-C20, preferably C1-C15, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; —X, identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine; or are selected from linear or branched C1-C20, preferably C1-C15, alkyl groups, —OCOR6 groups or —OR6 groups wherein R6 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups. —n is 3; (b) at least one co-catalyst selected from organo-aluminum derivatives, preferably from: (b1) aluminum compounds having general formula (III): Al(R7)(R8)(R9) (IIl) wherein R7 represents a hydrogen atom, or is selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups, aryl groups, alkylaryl groups, arylalkyl groups, alkoxy groups; R8 and R9, identical or different, are selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups, aryl groups, alkylaryl groups, arylalkyl groups; (b2) aluminoxanes having general formula (IV): (R10)2—Al—O—[-AI(R11)—O-]m-AI-(R12)2 (IV), wherein R10, R11 and R12, identical or different, represent a hydrogen atom, or a halogen atom such as chlorine, bromine, iodine, fluorine; or are selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups, aryl groups, said groups being optionally substituted with one or more silicon or germanium atoms; and m is an integer ranging from 0 to 1000; (b3) partially hydrolyzed organo-aluminum derivatives; (b4) haloaluminum alkyls having general formula (V) or (VI): AI(R13)p(X′)3-p (V) AI2(R13)q(X′)3-q (VI) wherein p is 1 or 2; q is an integer ranging from 1 to 5; R13, identical or different, are selected from linear or branched C1-C20 alkyl groups; X′ represents a chlorine or bromine atom, preferably chlorine; provided that said co-catalyst (b) is not selected from organo-boron derivatives.

7. 发明授权

US10066044B2 Stereoregular diblock polybutadienes having a 1,4-cis/syndiotactic 1,2 structure from stereospecific polymerization 有权
公开(公告)号：US10066044B2
公开(公告)日：2018-09-04
申请号：US15032207
申请日：2014-11-03
申请人： versalis S.p.A.
发明人： Francesco Masi , Anna Sommazzi , Giovanni Ricci , Giuseppe Leone , Salvatore Coppola
IPC分类号： C08F295/00 , C08F4/70
摘要： Stereoregular diblock polybutadiene composed of a polybutadiene block having a 1,4-cis structure and a polybutadiene block having a syndiotactic 1,2 structure. Said stereoregular diblock polybutadiene can be advantageously used in both the footwear industry (for example, in the production of soles for shoes) and in the production of tires for motor vehicles and/or trucks.

8. 发明授权

US11518776B2 Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes 有权
公开(公告)号：US11518776B2
公开(公告)日：2022-12-06
申请号：US16345015
申请日：2018-01-18
申请人： Versalis S.P.A.
发明人： Anna Sommazzi , Guido Pampaloni , Giovanni Ricci , Francesco Masi , Filippo Renili
IPC分类号： C08F36/06 , C08F36/08 , C07F15/02 , C07C251/08 , C08F136/06 , C08F136/08
摘要： Oxo-nitrogenated iron complex having general formula (I): in which: R1 and R2, identical or different, represent a hydrogen atom; or they are selected from linear or branched, optionally halogenated C1-C20, preferably C1-C15, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R3 represents a hydrogen atom, or it is selected from linear or branched, optionally halogenated C1-C20, preferably C1-C15 alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; X, identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine, preferably chlorine; or they are selected from. linear or branched C1-C20, preferably C1-C15, alkyl groups, —OCOR4 groups or —OR4 groups in which R4 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups; n is 2 or 3. Said oxo-nitrogenated iron complex having general formula (I) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.

9. 发明申请

US20200369805A1 PROCESS FOR THE PREPARATION OF POLYISOPRENE WITH A MAINLY ALTERNATING CIS-1,4- ALT-3,4 STRUCTURE IN THE PRESENCE OF A CATALYTIC SYSTEM COMPRISING A PYRIDYL IRON COMPLEX 审中-公开
公开(公告)号：US20200369805A1
公开(公告)日：2020-11-26
申请号：US16962056
申请日：2019-01-16
申请人： VERSALIS S.P.A.
发明人： Giovanni Ricci , Anna Sommazzi , Guido Pampaloni , Giuseppe Leone , Francesco Masi
IPC分类号： C08F136/08 , C07F15/02 , B60C1/00 , A43B1/10
摘要： Process for the preparation of polyisoprene with a mainly alternating cis-1,4-alt-3,4 structure comprising polymerizing isoprene in the presence of a catalytic system comprising: (a) at least one pyridyl iron complex having general formula (I): wherein: R1 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R2 is selected from linear or branched C1-C10, preferably C1-C3, alkyl groups; X, mutually identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine; or they are selected from linear or branched C1-C20, preferably C1-C15, alkyl groups, —OCOR3 groups or —OR3 groups wherein R3 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups. n is 2 or 3; (b) at least one co-catalyst selected from organo-derivative compounds of aluminum, preferably from (b1) aluminoxanes having general formula (II): (R4)2—Al—O—[—Al(R5)—O—]m—Al—(R6)2 (II) wherein R4, R5 and R6, mutually identical or different, represent a hydrogen atom, or a halogen atom such as, for example, chlorine, bromine, iodine, fluorine; or they are selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups, aryl groups, said groups being optionally substituted with one or more silicon or germanium atoms; and m is an integer ranging from 0 to 1000; (b2) aluminum compounds having general formula (III): Al(R7)(R8)(R9) (III) wherein R7 is a hydrogen atom, or is selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups, aryl groups, alkylaryl groups, arylalkyl groups, alkoxy groups; R8 and R9, mutually identical or different, are selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups, aryl groups, alkylaryl groups, arylalkyl groups; wherein the molar ratio between the aluminum present in the co-catalyst and the iron present in the iron pyridyl complex having general formula (I) is ranging from 5 to 60, preferably from 8 to 55.

10. 发明授权

US10654952B2 Nitrogen titanium complex, catalytic system comprising said nitrogen titanium complex and process for the (co)polymerization of conjugated dienes 有权
公开(公告)号：US10654952B2
公开(公告)日：2020-05-19
申请号：US15741896
申请日：2016-07-28
申请人： Versalis S.P.A.
发明人： Anna Sommazzi , Guido Pampaloni , Giovanni Ricci , Francesco Masi , Giuseppe Leone
IPC分类号： C08F36/08 , C08F4/642 , C08F4/643 , C08F36/06 , C07F7/28 , C07F7/00 , C07D221/00 , C08F4/64
摘要： Disclosed are nitrogen titanium complexes having general formula (I) or (II). Catalytic systems that include the nitrogen titanium complexes and that can be used for the (co)polymerization of conjugated dienes are disclosed. Processes for (co)polymerization of conjugated dienes using the catalytic systems are also disclosed.

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式