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    • 2. 发明授权
    • Cyclic shrinkage of a templated 3D network material
    • 模板3D网络材料的循环收缩
    • US07329377B2
    • 2008-02-12
    • US10799160
    • 2004-03-12
    • Yung-Hoon HaEdwin L. Thomas
    • Yung-Hoon HaEdwin L. Thomas
    • B29C33/76
    • B29C33/424B29C33/448B33Y70/00B33Y80/00
    • Methods are provided for producing a shrunken replica or a shrunken inverse replica of a multicontinuous structure. In one embodiment, the method comprises (1) infiltrating a first multicontinuous structure with a first fluid material which can be immobilized and shrunken, wherein the first multicontinuous structure comprises at least a first phase and a second phase which is immiscible with the first phase, and the infiltration displaces the second phase in the first multicontinuous structure to form a second multicontinuous structure which comprises at least the first phase and a third phase which consists of the first fluid material; (2) immobilizing the infiltrated first fluid material in the second multicontinuous structure; (3) removing the first phase from the second multicontinuous structure; and (4) shrinking (e.g., by a pyrolysis process) the third phase of the second multicontinuous structure, to produce an isotropically shrunken inverse replica of the first multicontinuous structure.
    • 提供了用于产生多连续结构的收缩复制品或缩小反向复制品的方法。 在一个实施方案中,该方法包括(1)用可固定和收缩的第一流体材料渗透第一多连续结构,其中第一多连续结构包括与第一相不混溶的至少第一相和第二相, 并且所述渗透置换所述第一多连续结构中的所述第二相以形成第二多连续结构,所述第二相连结构至少包括所述第一相和由所述第一流体材料组成的第三相; (2)将渗透的第一流体材料固定在第二多连续结构中; (3)从第二多连续结构中去除第一相; 和(4)第二多连续结构的第三相收缩(例如,通过热解过程),以产生第一多连续结构的各向同性收缩的反向复制品。
    • 3. 发明授权
    • Method for preparing oriented polymer structures and said structures
    • 制备取向聚合物结构和所述结构的方法
    • US6143831A
    • 2000-11-07
    • US608801
    • 1996-02-29
    • Edwin L. ThomasRamon J. Albalak
    • Edwin L. ThomasRamon J. Albalak
    • B29C43/24B29C55/00B29D7/01C08F2/00C08F293/00
    • B29D7/01B29C43/24B29C55/00B29K2096/04
    • A system for preparing oriented block copolymer structures includes a copolymer solution, a device capable of providing a flow field and an evaporation device. The device can be at least two cylinders that are parallel and adjacent to one another to form a nip and a driving mechanism to rotate each cylinder. Means for controlling a solvent environment and evaporation are provided. A method for preparing oriented block copolymer structures includes providing at least two cylinders which are parallel and adjacent to one another so as to form at least one nip, rotating each of the cylinders such that at the nip the cylinder surfaces are moving in the same direction with substantially the same or different tangential velocity, introducing a block copolymer solution into one of the nips of the rotating cylinders, thereby subjecting the polymer solution to a flow field and whereby orientation of the solution begins and evaporating the solvent from the block copolymer solution, whereby ordered microphase separation occurs and the oriented block copolymer structure is formed on the surface of at least one cylinder.
    • 用于制备取向嵌段共聚物结构的体系包括共聚物溶液,能提供流场的装置和蒸发装置。 该装置可以是至少两个彼此平行并相邻的气缸,以形成压区和驱动机构来旋转每个气缸。 提供了控制溶剂环境和蒸发的方法。 制备取向嵌段共聚物结构的方法包括提供至少两个彼此平行和相邻的圆柱体,以便形成至少一个压区,使每个气缸旋转,使得在压区处,气缸表面沿相同方向移动 以大致相同或不同的切向速度,将嵌段共聚物溶液引入旋转圆筒的一个夹头中,从而使聚合物溶液进行流场,并且由此开始溶液的取向并从溶胶中蒸发溶剂, 由此发生有序的微相分离,并且在至少一个气缸的表面上形成取向的嵌段共聚物结构。
    • 6. 发明授权
    • Polymeric photonic band gap materials
    • 聚合光子带隙材料
    • US06433931B1
    • 2002-08-13
    • US09367332
    • 2000-01-10
    • Yoel FinkEdwin L. Thomas
    • Yoel FinkEdwin L. Thomas
    • G02B110
    • B82Y20/00G02B6/1225
    • A polymeric photonic band gap structure can be defined by a block copolymeric species, a mixture of homopolymers, or a combination optionally with appropriate dielectric contrast enhancing additives. The structure includes periodic, phase-separated microdomains alternating in refractive index, the domains sized to provide a photonic band gap in the UV-visible spectrum. A method of the invention involves creating a defect in a polymeric article including a periodic structure of a plurality occuring separate domains. The defect can be created by inserting into the material a plane of a material different from materials defining the polymeric article. According to another method of the invention, a defect is created in a polymeric article, including a periodic structure of a plurality of periodically occuring separate domains, by altering polymeric material in the article. The polymeric material can be altered by removing polymeric material via radiation, by exposing the material to intersecting beams of radiation, by removing the material via etching or the like. A defect can be created in one embodiment by magnetically guiding a defined by a block copolymeric species, a mixture of homopolymers, or a combination optionally with appropriate dielectric contrast enhancing additives.
    • 聚合物光子带隙结构可以通过嵌段共聚物种,均聚物混合物或任选地与合适的介电对比增强添加剂的组合来定义。 该结构包括折射率交替的周期性,相分离的微区域,其尺寸设计成在UV-可见光谱中提供光子带隙。 本发明的方法涉及在聚合物制品中产生缺陷,所述聚合物制品包括多个发生的分离区域的周期性结构。 可以通过将不同于限定聚合物制品的材料的材料的平面插入到材料中来产生缺陷。 根据本发明的另一种方法,通过改变制品中的聚合物材料,在聚合物制品中产生缺陷,包括多个周期性发生的分开的区域的周期结构。 聚合材料可以通过通过辐射去除聚合材料,通过将材料暴露于相交的辐射束,通过蚀刻等去除材料来改变。 在一个实施方案中可以通过磁性引导由嵌段共聚物种类,均聚物混合物或任选地与合适的介电对比增强添加剂组合来限定的缺陷。