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    • 5. 发明申请
    • PROCESS FOR EXTRACTION OF RARE EARTH ELEMENTS
    • 提取稀土元素的方法
    • US20130283977A1
    • 2013-10-31
    • US13858166
    • 2013-04-08
    • Vaikuntam I. LakshmananRamamritham SridharM. A. Halim
    • Vaikuntam I. LakshmananRamamritham SridharM. A. Halim
    • C22B59/00
    • C22B59/00C22B3/08C22B3/10Y02P10/234
    • A process for the extraction of rare earth elements, including yttrium, from a rare earth element-bearing ore or concentrate, comprising the steps of leaching the rare earth element-bearing ore or concentrate with a lixiviant of hydrochloric acid and magnesium chloride at atmospheric pressure at a temperature of from 90° C. to the boiling point of the solution and at an Eh of at least 200 mV. After a liquid/solids separation step, the solution obtained is subjected to steps for removal of iron and for recovery of rare earth elements. Alternatively, rare earth element-bearing ore or concentrate may be leached with sulphuric acid and liquid obtained subjected to extraction of iron and other impurities. Raffinate obtained may be treated with oxalic acid, the precipitate dissolved in hydrochloric acid and subjected to solvent extraction for rare earth elements or the raffinate may be subjected to solvent extraction for removal of rare earth elements and then stripped with hydrochloric acid.
    • 一种从含有稀土元素的矿石或浓缩物中提取稀土元素(包括钇)的方法,包括以下步骤:在大气压力下将含稀土元素的矿石或浓缩物与盐酸和氯化镁的浸液浸出 在90℃至该溶液的沸点,至少200mV的Eh下进行。 在液/固分离步骤之后,将所得溶液进行除铁和用于回收稀土元素的步骤。 或者,稀土元素矿石或浓缩物可以用硫酸浸出,所得液体经铁提取和其他杂质。 得到的残液可用草酸处理,沉淀溶解于盐酸中,进行稀土元素的溶剂萃取,或萃取液进行溶剂萃取除去稀土元素,然后用盐酸汽提。
    • 6. 发明授权
    • Process for the recovery of value metals from base metal sulfide ores
    • 从金属硫化物矿石中回收有价金属的工艺
    • US07736606B2
    • 2010-06-15
    • US10950671
    • 2004-09-28
    • G. Bryn HarrisVaikuntam I. LakshmananRamamritham SridharGeorge Puvvada
    • G. Bryn HarrisVaikuntam I. LakshmananRamamritham SridharGeorge Puvvada
    • C22B11/06C22B3/10C22B3/12
    • C22B23/0461C22B3/10C22B15/0069C22B15/0093C22B23/0423Y02P10/234Y02P10/236
    • A process for leaching a value metal from a base metal sulfide ore, comprising the step of leaching the ore with a lixiviant comprising a chloride, an oxidant and hydrochloric acid is disclosed. The leaching is controlled, by use of low concentrations of hydrochloric acid and a redox potential, to effect formation of hydrogen sulfide from the base metal sulfide ore. The hydrogen sulfide is stripped from the leach solution, thereby reducing the amount of sulfate generated in the leach to very low levels. The leaching may also be conducted to limit the co-dissolution of platinum group metals and gold with the base value metals. The leach forms a value metal-rich leachate and a solids residue. The solids residue may be subsequently leached to recover the platinum group metals and gold. The value metal-rich leachate can be is oxidized and neutralized to recover the value base metals. In an embodiment, the chloride is magnesium chloride and lixiviant solution is regenerated.
    • 公开了一种用于从碱金属硫化物矿石中浸出值金属的方法,其包括用包含氯化物,氧化剂和盐酸的浸液浸出矿石的步骤。 通过使用低浓度的盐酸和氧化还原电位来控制浸出,从而从硫化贱金属矿石中形成硫化氢。 从浸出溶液中汽提硫化氢,从而将浸出液中产生的硫酸盐的量减少到非常低的水平。 还可以进行浸出以限制铂族金属和金与基础金属的共溶解。 浸出液形成富含金属的浸出液和固体残渣。 随后浸出固体残渣以回收铂族金属和金。 价值金属富集的浸出液可以被氧化和中和以回收碱金属的价值。 在一个实施方案中,氯化物是氯化镁,并且溶液被再生。
    • 10. 发明授权
    • Process for the recovery of value metals from material containing base metal oxides
    • 从含有贱金属氧化物的材料中回收有价金属的方法
    • US07329396B2
    • 2008-02-12
    • US10844315
    • 2004-05-13
    • G. Bryn HarrisVaikuntam I. LakshmananRamamritham Sridhar
    • G. Bryn HarrisVaikuntam I. LakshmananRamamritham Sridhar
    • C01G51/04C01G49/02C01F5/10
    • C22B3/44C22B23/0423C22B23/0453C22B23/0461Y02P10/234
    • A process for leaching a value metal from oxidic materials, such as a lateritic nickel ore, comprising the step of leaching the ore with a lixiviant comprising a cationic salt (e.g., magnesium chloride) and hydrochloric acid is disclosed. An oxidant or additional metal chloride (such as that which results from the leaching operation) may be added. In one embodiment, the process comprises recovery of a value metal from ore comprising the steps of: leaching the ore with a lixiviant; separating a value metal-rich leachate from the ore in a first solid-liquid separation; oxidizing and neutralizing the value metal-rich leachate so obtained; and separating a solution of magnesium chloride from the leachate so obtained in a second solid-liquid separation. In another embodiment, the lixiviant solution is regenerated from the solution of magnesium chloride. In a further embodiment, regeneration of the lixiviant solution includes a step of producing magnesium oxide from the solution of magnesium chloride.
    • 公开了一种用于从诸如红土镍矿之类的氧化材料中浸取价值金属的方法,其包括用包含阳离子盐(例如氯化镁)和盐酸的浸液浸出矿石的步骤。 可以加入氧化剂或另外的金属氯化物(例如由浸出操作产生的那些)。 在一个实施方案中,该方法包括从矿石中回收价值金属,包括以下步骤:用矿物浸出矿石; 在第一固液分离中从矿石中分离价值富金属的渗滤液; 氧化和中和如此获得的富含金属的浸出液; 并在第二固液分离中从如此获得的浸出液中分离出氯化镁溶液。 在另一个实施方案中,浸出液从氯化镁溶液中再生。 在另一个实施方案中,浸出溶液的再生包括从氯化镁溶液中生产氧化镁的步骤。