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    • 1. 发明授权
    • Substituted 1-arylpyrazoles, pesticidal compositions and use
    • 取代的1-芳基吡唑,农药组合物和用途
    • US4971989A
    • 1990-11-20
    • US497470
    • 1990-03-22
    • Uta Jensen-KorteSchallner, OttoBenedikt BeckerJurgen HartwigWilhelm Stendel
    • Uta Jensen-KorteSchallner, OttoBenedikt BeckerJurgen HartwigWilhelm Stendel
    • A01N43/56C07D231/44C07D401/04
    • C07D401/04C07D231/44
    • Substituted 1-arylpyrazoles useful in combating insects having the arachnida and nematodes of the formula ##STR1## in which R.sup.1 represents hydrogen or alkyl,R.sup.2 represents alkyl or halogenoalkyl,R.sup.3 represents hydrogen or alkanoyl,R.sup.4 represents hydrogen, alkyl, hydroxyalkyl, alkoxyalkyl, alkylthioalkyl, halogenoalkyl, alkenyl, halogenoalkenyl or alkinyl, in each case optionally substituted cycloalkyl, aralkyl or aryl, or, when X represents oxygen or sulphur, R.sup.4 can represent a cation equivalent which is bonded in a salt-like manner,A represents a double-linked alkylene radical,X represents oxygen, sulphur or a radical ##STR2## Ar represents optionally substituted phenyl, pyridyl and n represents a number 0, 1 or 2, where R.sup.5 represents hydrogen, alkyl, hydroxylalkyl, alkoxyalkyl, alylthioalkyl, halogenoalkyl, alkenyl, halogenoalkenyl or alkinyl, or represents optionally substituted cycloalkyl, aralkyl or aryl.
    • 取代的1-芳基吡唑可用于对抗具有式(IMAGE)的蛛网膜和线虫的昆虫,其中R1代表氢或烷基,R2代表烷基或卤代烷基,R3代表氢或烷酰基,R4代表氢,烷基,羟基烷基,烷氧基烷基,烷硫基烷基 ,卤代烷基,烯基,卤代烯基或炔基,在各种情况下均为任选取代的环烷基,芳烷基或芳基,或当X表示氧或硫时,R 4可以表示以盐状结合的阳离子当量,A表示双 连接的亚烷基,X表示氧,硫或基团.Ar代表任意取代的苯基,吡啶基,n代表数字0,1或2,其中R5代表氢,烷基,羟基烷基,烷氧基烷基,烯基硫代烷基,卤代烷基,烯基, 或者代表任意取代的环烷基,芳烷基或芳基。
    • 7. 发明授权
    • Substituted 1-aryl-3-tert.-butyl-pyrazoles
    • 取代的1-芳基-3-叔丁基 - 吡唑
    • US4826867A
    • 1989-05-02
    • US89474
    • 1987-08-25
    • Uta Jensen-KorteReinhold GehringOtto SchallnerJorg StetterBenedikt BeckerWolfgang BehrenzWilhelm Stendel
    • Uta Jensen-KorteReinhold GehringOtto SchallnerJorg StetterBenedikt BeckerWolfgang BehrenzWilhelm Stendel
    • A01N43/56C07D231/12C07D231/16C07D231/22C07D231/38C07D231/40C07D401/04
    • C07D231/38A01N43/56C07D231/16C07D231/40C07D401/04
    • Insecticidally and acaricidally active novel 1-aryl-3-tert.-butyl-pyrazoles of the formula ##STR1## in which R.sup.1 represents nitro or halogen,R.sup.2 represents halogen or the --NR.sup.3 R.sup.4 group, and also may represent hydrogen when R.sup.1 denotes halogen,whereR.sup.3 represents hydrogen, in each case optionally substituted alkyl, alkenyl or alkinyl, and in each case optionally substituted cycloalkyl or cycloalkylalkyl andR.sup.4, independently of R.sup.3, represents the same radicals as R.sup.3l , and, in addition, a ##STR2## radical, where X represents oxygen or sulphur andR.sup.5 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, alkoxyalkyl, alkylthioalkyl, optionally substituted cycloalkyl, optionally substituted aryl, alkoxy, alkylthio, optionally substituted aryloxy, optionally substituted arylthio, alkylamino, dialkylamino or optionally substituted arylamino; andAr represents optionally substituted phenyl, apart from dinitrophenyl, or optionally substituted pyridyl. Intermediates where R.sup.1 is replaced by hydrogen are also new and are also pesticidally active.
    • 杀虫剂和杀螨剂活性的式“IMAGE”的1-芳基-3-叔丁基 - 吡唑,其中R 1表示硝基或卤素,R 2表示卤素或-NR 3 R 4基团,当R1表示卤素时也可以表示氢, 其中R 3表示氢,在各种情况下均为任选取代的烷基,烯基或炔基,并且在每种情况下为任选取代的环烷基或环烷基烷基,R 4独立于R 3,表示与R 3相同的基团,另外, 其中X表示氧或硫,R5表示氢,烷基,烯基,炔基,卤代烷基,烷氧基烷基,烷硫基烷基,任选取代的环烷基,任选取代的芳基,烷氧基,烷硫基,任选取代的芳氧基,任选取代的芳硫基,烷基氨基,二烷基氨基或任选取代的芳基氨基 ; Ar表示除二硝基苯基以外的任意取代的苯基,或任意取代的吡啶基。 R1被氢取代的中间体也是新的,也是杀虫活性的。