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1. 发明授权

US4314911A Polymerization catalyst 失效
标题翻译：聚合催化剂
公开(公告)号：US4314911A
公开(公告)日：1982-02-09
申请号：US69363
申请日：1979-08-23
申请人： Umberto Giannini , Paolo Longi , Domenico Deluca , Angelo Pricca
发明人： Umberto Giannini , Paolo Longi , Domenico Deluca , Angelo Pricca
IPC分类号： C08F4/00 , C08F4/02 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00 , C08F4/022
摘要： New, highly active catalysts for the polymerization of ethylene and mixtures of ethylene with higher alpha-olefins and/or diolefins, are disclosed. The catalysts are prepared by mixing (a) hydrides or organometallic compounds of metals belonging to Groups I, II or III of the Mendelyeev Periodic Table with (b) the products obtained by contacting titanium compounds with activated anhydrous halides of magnesium or manganese, diluted with anhydrous compounds of metals belonging to Groups III or IV of said Periodic Table, and which are different from either (a) or the titanium compound of (b).
摘要翻译：公开了用于乙烯聚合和乙烯与高级α-烯烃和/或二烯烃的混合物的新型高活性催化剂。通过将（a）属于门多利夫周期表第I，II或III族的金属的氢化物或有机金属化合物与（b）通过使钛化合物与镁或锰的活性无水卤化物接触而获得的产物来制备催化剂，属于所述周期表第III族或第IV族的金属的无水化合物，它们不同于（a）或钛化合物（b）。

2. 发明授权

US4265785A Polymerization catalyst 失效
标题翻译：聚合催化剂
公开(公告)号：US4265785A
公开(公告)日：1981-05-05
申请号：US65430
申请日：1979-08-10
申请人： Umberto Giannini , Paolo Longi , Domenico Deluca , Angelo Pricca
发明人： Umberto Giannini , Paolo Longi , Domenico Deluca , Angelo Pricca
IPC分类号： C08F4/00 , C08F4/02 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00 , C08F4/022
摘要： New, highly active catalysts for the polymerization of ethylene and mixtures of ethylene with higher alpha-olefins and/or diolefins, are disclosed. The catalysts are prepared by mixing (a) hydrides or organometallic compounds of metals belonging to Groups I, II or III of the Mendelycev Periodic Table with (b) the products obtained by contacting titanium compounds with activated anhydrous halides of magnesium or manganese, diluted with anhydrous compounds of metals belonging to Group III or IV of said Periodic Table, and which are different from either (a) or the titanium compound of (b).
摘要翻译：公开了用于乙烯聚合和乙烯与高级α-烯烃和/或二烯烃的混合物的新型高活性催化剂。催化剂通过将（a）属于门多塞夫周期表第I，II或III族的金属的氢化物或有机金属化合物与（b）通过使钛化合物与镁或锰的活性无水卤化物接触而获得的产物来制备，属于所述周期表III或IV族的金属的无水化合物，它们不同于（a）或（b）的钛化合物。

3. 发明授权

US4542197A Polymerization catalyst 失效
标题翻译：聚合催化剂
公开(公告)号：US4542197A
公开(公告)日：1985-09-17
申请号：US553060
申请日：1983-11-18
申请人： Umberto Giannini , Paolo Longi , Domenico Deluca , Bruno Pivotto
发明人： Umberto Giannini , Paolo Longi , Domenico Deluca , Bruno Pivotto
IPC分类号： C08F4/654 , C08F4/02 , C08F4/64 , C08F4/646 , C08F10/00 , C08F110/02 , C08F10/02
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： Polymerization catalysts, particularly catalysts for the polymerization of olefins, are disclosed. The catalysts are prepared by mixing hydrides of organometallic compounds of metals belonging to Groups I to III of the Mendelyeev Periodic Table with products obtained by contacting (1) titanium compounds of the formulaMpTi.sub.m X.sub.(n. m) +pin which M is an alkaline metal or the group NR.sub.4 in which the valences of the quaternary nitrogen atom are satisfied by hydrogen and/or by hydrocarbon groups or is part of a heterocyclic ring; X.sub.n. m substituents are NR.sub.2 group in which the Rs represent hydrogen, and/or hydrocarbon groups or, in part, halogen atoms; n is the titanium valence; m is a whole number from 1 to 3 inclusive; and p is zero or a whole number from 1 to 3, inclusive; with (2) carriers consisting of anhydrous Mg halides which are in active form or converted to active form by the conditions under which the carriers are contacted with the titanium compounds. The catalysts are particularly effective in the polymerization of ethylene and the copolymerization thereof with higher alpha-olefins and/or diolefins.
摘要翻译：公开了聚合催化剂，特别是用于烯烃聚合的催化剂。催化剂是通过将属于门多利夫周期表第I至III族的金属的有机金属化合物的氢化物与通式（1）式MpTimX（n，m）+ p的钛化合物（其中M为碱金属或其中通过氢和/或烃基或杂环的一部分满足季氮原子的化合价的基团NR4; Xn。取代基是NR 2基团，其中R 5表示氢，和/或烃基或部分卤素原子; n是钛价; m是从1到3的整数; p为0或1〜3的整数; 与（2）由无机Mg卤化物组成的载体，其由活性形式或通过载体与钛化合物接触的条件转化为活性形式。该催化剂在乙烯的聚合和其与高级α-烯烃和/或二烯烃的共聚合中是特别有效的。

4. 发明授权

US4613655A Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US4613655A
公开(公告)日：1986-09-23
申请号：US225366
申请日：1981-01-15
申请人： Paolo Longi , Umberto Giannini , Romano Mazzocchi , Domenico Deluca
发明人： Paolo Longi , Umberto Giannini , Romano Mazzocchi , Domenico Deluca
IPC分类号： C08F4/02 , C08F4/50 , C08F4/64 , C08F10/00 , C08F10/02
CPC分类号： C08F4/022 , C08F10/00 , Y10S526/906
摘要： New catalysts for the polymerization of olefins and more particularly of ethylene and mixtures thereof with higher alpha-olefins and/or diolefins, are disclosed. The catalysts are prepared by mixing (a) a hydride or an organo-metallic compound of a metal belonging to Groups I, II or III of the Mendelyeev Periodic Table with (b) the product obtained by contacting a titanium compound (1) with a mixture of an anhydrous magnesium halide (2) in a particular active form and an anhydrous compound of a metal belonging to Group I or II of said Periodic Table, (3). In the particular active form to which it is converted, during or prior to the contacting the anhydrous magnesium halide is characterized in that, in its X-ray spectrum, the diffraction line which is most intense in the X-ray spectrum of the normal, inactive magnesium halide shows a decreased intensity, and/or the active magnesium halide has a surface area greater than 3 m.sup.2 /g.
摘要翻译：公开了用于烯烃聚合，更特别是乙烯及其与高级α-烯烃和/或二烯烃的混合物的新型催化剂。催化剂通过将（a）属于门多利夫周期表第I，II或III族的金属的氢化物或有机金属化合物与（b）通过使钛化合物（1）与具有活性的无水卤化镁（2）和属于所述周期表第I或II族金属的无水化合物的混合物，（3）。在其转化的特定活性形式中，在接触期间或之前，无水卤化镁的特征在于，在其X射线光谱中，法线的X射线光谱中最强的衍射线，无活性卤化镁显示出降低的强度，和/或活性卤化镁的表面积大于3m 2 / g。

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