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    • 9. 发明授权
    • Oxime esters of substituted quinoline-8-carboxylic acids and use thereof
as herbicides
    • 取代喹啉-8-羧酸的肟酯及其作为除草剂的用途
    • US4808212A
    • 1989-02-28
    • US944519
    • 1986-12-22
    • Peter PlathKarl EickenBernd ZeehUlrich EichenauerHelmut HagenRolf-Dieter KohlerNorbert MeyerBruno Wuerzer
    • Peter PlathKarl EickenBernd ZeehUlrich EichenauerHelmut HagenRolf-Dieter KohlerNorbert MeyerBruno Wuerzer
    • C07D333/00A01N43/42A01N43/48A01N43/653C07D215/32C07D215/48C07D335/00C07D401/12C07D405/12C07D409/12C07D521/00
    • C07D231/12A01N43/42A01N43/653C07D215/32C07D233/56C07D249/08C07D405/12C07D409/12
    • Oxime esters of substituted quinoline-8-carboxylic acids of the formula ##STR1## where X is hydrogen, C.sub.1 -C.sub.4 -alkyl or halogen, Z is hydrogen or methyl, R.sup.1 is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxymethyl, C.sub.1 -C.sub.4 -alkoxyethyl, C.sub.1 -C.sub.4 -alkylthiomethyl, C.sub.1 -C.sub.4 -alkylthioethyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.5 -C.sub.8 -cycloalkyl, each of which is unsubstituted or bears up to 3 methyl substituents, hydrogen, cyano, acetyl, benzoyl, unsubstituted benzyl or phenyl, or benzyl or phenyl bearing up to 3 substitutents selected from the group consisting of halogen, cyano, trifluoromethyl, C.sub.1 -C.sub.4 -haloalkyloxy, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkyl, hydroxy, dimethylamino or acetamino, R.sup.2 is hydrogen if R.sup.1 is not hydrogen, R.sup.2 further denotes C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxymethyl, chloromethyl, azolylmethyl, 1,1-dimethoxymethyl, cyano, C.sub.1 -C.sub.4 -alkoxycarbony, C.sub.1 -C.sub.4 -alkoxy, phenyl if R.sup.1 is H, CH.sub.3 or acetyl, or R.sup.2 denotes, when R.sup.1 is H or methyl, furyl, tetrahydrofuryl, thienyl, tetrahydropyranyl, tetrahydrothiopyranyl, dihydro-.DELTA..sup.3 -pyranyl or dihydro-.DELTA..sup.3 -thiopyranyl; further, R.sup.1 and R.sup.2, together with the carbon atom to which they are linked, denote C.sub.1 -C.sub.12 -cycloalkylidene, C.sub.5 -C.sub.6 -cycloalkenylidene or 4-oxacyclohexadienylidene, each of which is unsubstituted or bears up to 3 methyl substituents, it being possible, where the ring is 5-membered or 6-membered, or doubly unsaturated 6-membered, for it to contain an oxygen or sulfur atom, their preparation, and their use as herbicides.
    • 其中X是氢,C 1 -C 4烷基或卤素,Z是氢或甲基的取代喹啉-8-羧酸的肟酯,R 1是C 1 -C 6烷基,C 1 -C 4烷氧基甲基, C 1 -C 4 - 烷氧基乙基,C 1 -C 4 - 烷硫基甲基,C 1 -C 4 - 烷硫基乙基,C 1 -C 4 - 烷氧基羰基,C 3 -C 6 - 烯基或C 5 -C 8 - 环烷基,其各自为未取代的或至多含有3个甲基取代基 ,氰基,乙酰基,苯甲酰基,未取代的苄基或苯基,或带有至多3个选自卤素,氰基,三氟甲基,C 1 -C 4卤代烷氧基,C 1 -C 6 - 烷硫基,C 1 -C 4 - 烷氧基的取代基的苄基或苯基 C1-C4烷基,羟基,二甲基氨基或乙酰氨基,如果R1不是氢,R2是氢,R2还表示C1-C6-烷基,C1-C4-烷氧基甲基,氯甲基,唑基甲基,1,1-二甲氧基甲基,氰基,C1 -C 1-4烷氧基羰基,C 1 -C 4 - 烷氧基,如果R 1为H,CH 3或乙酰基,则为苯基,或R 2表示当R 1为H或甲基时,呋喃基,四氢呋喃基,噻吩基,四氢吡喃基,四氢噻喃基,二 水合-3β-吡喃基或二氢-D-3,3-噻喃基; 此外,R 1和R 2与它们所连接的碳原子一起表示C 1 -C 12 - 亚环烷基,C 5 -C 6 - 环亚烯基或4-氧杂环己二亚苯基,其各自是未取代的或最多含有3个甲基取代基,可能是 ,其中环为5元或6元,或双不饱和6元,含有氧或硫原子,其制备及其作为除草剂的用途。
    • 10. 发明授权
    • N-arylsulfonyl-N'-pyrimidyl ureas
    • N-芳基磺酰基-N'-嘧啶基脲
    • US4808211A
    • 1989-02-28
    • US116902
    • 1987-11-05
    • Karl EickenPeter PlathBruno WuerzerNorbert Meyer
    • Karl EickenPeter PlathBruno WuerzerNorbert Meyer
    • A01N47/36C07D403/04C07D521/00C07D239/69A01N43/54C07D401/04C07D409/14
    • C07D521/00A01N47/36C07D403/04
    • Novel N-arylsulfonyl-N'-pyrimidyl-ureas of the formula ##STR1## where A is a radical of the formula ##STR2## where R.sup.1 is hydrogen, halogen, cyano, nitro, haloalkyl, alkyl, alkoxy, CO-R.sup.4, S(O).sub.m -alkyl or SO.sub.2 R.sup.5,R.sup.2 is hydrogen, halogen, methyl, ethyl, methoxy or ethoxy,R.sup.3 is hydrogen, halogen, nitro or methoxy,R.sup.4 is hydrogen, alkyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, phenoxy, benzyloxy or alkoxy which is unsubstituted or substituted by halogen atoms or alkoxy,R.sup.5 is alkoxy, phenoxy or benzyloxy which is unsubstituted or substituted by 1 to 3 halogen atoms,m is one of the integers 0, 1 and 2,R.sup.6 is oxygen or sulfur,R.sup.7 is hydrogen or alkyl,X is alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or halogen,Y is the methyne group -CH= andZ is azolyl linked via nitrogen, salts of these compounds, and their use for combating the growth of unwanted plants.
    • 其中A是下式的基团:其中R 1是氢,卤素,氰基,硝基,卤代烷基,烷基,烷氧基,CO-R 4,S(C 1 -C 6)烷基的新的N-芳基磺酰基-N'-嘧啶基 - 脲 (O)m-烷基或SO 2 R 5,R 2是氢,卤素,甲基,乙基,甲氧基或乙氧基,R 3是氢,卤素,硝基或甲氧基,R 4是氢,烷基,烷氧基,烯氧基,炔氧基,烷硫基,苯氧基,苄氧基 或未被取代或被卤素原子或烷氧基取代的烷氧基,R5是未取代或被1至3个卤素原子取代的烷氧基,苯氧基或苄氧基,m是整数0,1和2之一,R6是氧或硫, R 7是氢或烷基,X是烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基或卤素,Y是甲炔基-CH =,Z是通过氮连接的唑基,这些化合物的盐,以及它们用于防止不想要的 植物。