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1. 发明申请

US20060247377A1 (Meth)acrylic ester of alkenylene glycols and the use thereof 失效
标题翻译：（甲基）亚烷基二醇的丙烯酸酯及其用途
公开(公告)号：US20060247377A1
公开(公告)日：2006-11-02
申请号：US10558996
申请日：2004-06-04
申请人： Ulrich Riegel , Thomas Daniel , Matthias Weismantel , Mark Elliott , Rudiger Funk , Reinhold Schwalm
发明人： Ulrich Riegel , Thomas Daniel , Matthias Weismantel , Mark Elliott , Rudiger Funk , Reinhold Schwalm
IPC分类号： C08L67/02 , C07C67/26
CPC分类号： C07C69/54 , C07C67/08
摘要： The present invention relates to novel (meth)acrylic esters of polyalkoxylated glycols of the formula where AO is independently at each instance is —O—CHR3-CHR4- or —CHR3-CHR4-O— where R3 and R4 are independently H, linear or branched C1-C8-alkyl, p1 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, or 35, p2 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, or 35, n is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 447, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97, 98, 99, 100, R1 and R2 are independently H or CH3, wherein there is at least one AO in (AO)p1 and also at least one AO in (AO)p2 where R3 and R4 are not both H at one and the same time, a simplified process for preparing these esters and use of reaction mixtures thus obtainable.
摘要翻译：本发明涉及下式的聚烷氧基化二醇的（甲基）丙烯酸酯：其中AO各自独立地为-O-CHR 3 -CHR 4 - 或-CHR 3 -CHR 4 -O-，其中R 3和R 4独立地为H，直链或支链C 1 -C 8 - 烷基，p 1为1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21 ，22,23,24,25,26,27,28,29,30,31,32,33,34或35中，p2分别为1,2,3,4,5,6,7,8,9,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34或35， 10，11，12，13，14，15，16，17，18，19，20，21，22，23，24，25，26，27，28，29，30，31，32，33，34，或35，n为1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23 ，24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,447,48 ，49，50，51，52，53，54，55，56，57，58，59，60，61，62，63，64，65，66，67，68，69，70，，71，72，73 ，74，75，76，77，78，79，80，81，82，83，84，85，86，87，88，89，90，91，92，93，94，95，96，97，98 ，99,100，R 1和R 2独立地为H或CH 3，其中存在至少一个AO （AO）p 1和（AO）p2中的至少一个AO，其中R3和R4不同时为一个，制备这些酯的简化方法和使用由此获得的反应混合物。

2. 发明授权

US07405321B2 (Meth)acrylic ester of alkenylene glycols and the use thereof 失效
标题翻译：（甲基）亚烷基二醇的丙烯酸酯及其用途
公开(公告)号：US07405321B2
公开(公告)日：2008-07-29
申请号：US10558996
申请日：2004-06-04
申请人： Ulrich Riegel , Thomas Daniel , Matthias Weismantel , Mark Elliott , Rudiger Funk , Reinhold Schwalm
发明人： Ulrich Riegel , Thomas Daniel , Matthias Weismantel , Mark Elliott , Rudiger Funk , Reinhold Schwalm
IPC分类号： C07C69/52 , C08F20/10 , C08F220/12
CPC分类号： C07C69/54 , C07C67/08
摘要： The present invention relates to novel (meth)acrylic esters of polyalkoxylated glycols of the formula where AO is independently at each instance is —O—CHR3-CHR4- or —CHR3-CHR4-O— where R3 and R4 are independently H, linear or branched C1-C8-alkyl, p1 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, or 35, p2 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, or 35, n is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 447, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97, 98, 99, 100, R1 and R2 are independently H or CH3, wherein there is at least one AO in (AO)p1 and also at least one AO in (AO)p2 where R3 and R4 are not both H at one and the same time, a simplified process for preparing these esters and use of reaction mixtures thus obtainable.
摘要翻译：本发明涉及下式的聚烷氧基化二醇的（甲基）丙烯酸酯：其中AO各自独立地为-O-CHR 3 -CHR 4 - 或-CHR 3 -CHR 4 -O-，其中R 3和R 4独立地为H，直链或支链C 1 -C 8 - 烷基，p 1为1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21 ，22,23,24,25,26,27,28,29,30,31,32,33,34或35中，p2分别为1,2,3,4,5,6,7,8,9,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34或35， 10，11，12，13，14，15，16，17，18，19，20，21，22，23，24，25，26，27，28，29，30，31，32，33，34，或35，n为1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23 ，24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,447,48 ，49，50，51，52，53，54，55，56，57，58，59，60，61，62，63，64，65，66，67，68，69，70，，71，72，73 ，74，75，76，77，78，79，80，81，82，83，84，85，86，87，88，89，90，91，92，93，94，95，96，97，98 ，99,100，R 1和R 2独立地为H或CH 3，其中存在至少一个AO （AO）p1和（AO）p2中的至少一个AO，其中R3和R4不同时为一个，一个简单的制备这些酯的方法和使用如此获得的反应混合物。

3. 发明申请

US20050165208A1 (Meth)acrylic esters of polyalkoxylated glycerine 审中-公开
标题翻译：（甲基）丙烯酸酯的聚烷氧基化甘油
公开(公告)号：US20050165208A1
公开(公告)日：2005-07-28
申请号：US10516702
申请日：2003-06-10
申请人： Andreas Popp , Thomas Daniel , Jurgen Schroder , Thomas Kaworek , Rudiger Funk , Reinhold Schwalm , Matthias Weismantel , Ulrich Riegel
发明人： Andreas Popp , Thomas Daniel , Jurgen Schroder , Thomas Kaworek , Rudiger Funk , Reinhold Schwalm , Matthias Weismantel , Ulrich Riegel
IPC分类号： A61L15/60 , C07B61/00 , C07C67/08 , C07C67/62 , C07C69/54 , C08F20/20 , C08G65/26 , C08G65/332 , C08G63/66
CPC分类号： C08G65/3322 , A61L15/60 , C07C67/08 , C08G65/2609 , C08G2650/58 , C07C69/54
摘要： The present invention relates to novel (meth)acrylic esters of polyalkoxylated glycerol, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.
摘要翻译：本发明涉及聚烷氧基化甘油的新型（甲基）丙烯酸酯，制备这些酯的简化方法以及由此得到的反应混合物的用途。

4. 发明申请

US20050215752A1 (Meth)acrylic esters of polyalkoxylated trimethylolpropane 失效
标题翻译：（甲基）丙烯酸酯，聚烷氧基化三羟甲基丙烷
公开(公告)号：US20050215752A1
公开(公告)日：2005-09-29
申请号：US10517042
申请日：2003-06-06
申请人： Andreas Popp , Thomas Daniel , Jurgen Schroder , Thomas Jaworek , Rudiger Funk , Reinhold Schwalm , Matthias Weismantel , Ulrich Riegel
发明人： Andreas Popp , Thomas Daniel , Jurgen Schroder , Thomas Jaworek , Rudiger Funk , Reinhold Schwalm , Matthias Weismantel , Ulrich Riegel
IPC分类号： C08G65/332 , A61L15/60 , C07B61/00 , C07C67/08 , C07C69/54 , C08F290/06 , C08G65/26 , C08G65/28 , C08G63/02
CPC分类号： C08G65/3322 , A61L15/60 , C07C67/08 , C08G65/2609 , Y10T428/249921 , C07C69/54
摘要： The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where AO is for each AO independently at each instance EO, PO or BO where EO is O—CH2-CH2- PO is independently at each instance O—CH2-CH(CH3)- or O—CH(CH3)-CH2- BO is independently at each instance O—CH2-CH(CH2-CH3)- or O—CH(CH2-CH3)-CH2- p1+p2+p3 is 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74 or 75, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.
摘要翻译：本发明涉及下式的聚烷氧基化三羟甲基丙烷的新的（甲基）丙烯酸酯：其中AO各自独立地为每个AO，PO或BO，其中EO为O-CH 2 -CH 2 - ，PO各自独立地为O-CH 2 -CH（CH 3） - 或O-CH（CH 3）-CH 2 - BO在每种情况下独立地为O-CH 2 -CH（CH 2 -CH 3） - 或O-CH（CH 2 -CH 3）-CH 2 - ，p 1 + p 2 + p 3 是28，29，30，31，32，33，34，35，36，37，38，39，40，41，42，43，44，45，46，47，48，49，50，51，52 ，53,54,55,66,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74或75，R1，R2 和R3独立地为H或CH3，制备这些酯的简化方法以及由此得到的反应混合物的使用。

5. 发明申请

US20060212011A1 Mixtures of polyalkoxylated trimethylolpropane (meth) acrylate 审中-公开
标题翻译：聚烷氧基化三羟甲基丙烷（甲基）丙烯酸酯的混合物
公开(公告)号：US20060212011A1
公开(公告)日：2006-09-21
申请号：US10551630
申请日：2004-04-02
申请人： Andreas Popp , Thomas Daniel , Jurgen Schroder , Thomas Jaworek , Rudiger Funk , Reinhold Schwalm , Matthias Weismantel
发明人： Andreas Popp , Thomas Daniel , Jurgen Schroder , Thomas Jaworek , Rudiger Funk , Reinhold Schwalm , Matthias Weismantel
IPC分类号： A61F13/15 , C07C69/52 , C08F265/02
CPC分类号： C08F220/06 , A61L15/60 , C07C67/08 , C08F222/1006 , C08G65/2609 , C08G65/3322 , C07C69/54
摘要： The present invention relates to novel mixtures of (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where AO is for each AO independently at each instance EO, PO or BO where EO is O—CH2-CH2- PO is independently at each instance O—CH2-CH(CH3)- or O—CH(CH3)-CH2- BO is independently at each instance O—CH2-CH(CH2-CH3)- or O—CH(CH2-CH3)-CH2- p1+p2+p3 is 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74 or 75, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these ester mixtures and the use of reaction mixtures thus obtainable.
摘要翻译：本发明涉及下式的聚烷氧基化三羟甲基丙烷的（甲基）丙烯酸酯的新混合物，其中AO在每种情况下各自独立地为每个AO，PO或BO，其中EO为O-CH 2 -CH 2 - ，PO各自独立地为O -CH 2 -CH（CH 3） - 或O-CH（CH 3）-CH 2 - BO在每种情况下独立地为O-CH 2 -CH（CH 2 -CH 3） - 或O-CH（CH 2 -CH 3）-CH 2 - + p3为28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51 ，52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74或75，R1 ，R2和R3独立地为H或CH3，制备这些酯混合物的简化方法以及由此获得的反应混合物的使用。

6. 发明申请

US20060020078A1 (Meth) acrylic esters of polyalkoxylated trimethylolpropane 失效
标题翻译：（甲基）丙烯酸酯，聚烷氧基化三羟甲基丙烷
公开(公告)号：US20060020078A1
公开(公告)日：2006-01-26
申请号：US10516698
申请日：2003-06-10
申请人： Andreas Popp , Thomas Daniel , Jurgen Schroder , Thomas Jaworek , Rudiger Funk , Reinhold Schwalm , Matthias Wesimantel , Ulrich Riegel
发明人： Andreas Popp , Thomas Daniel , Jurgen Schroder , Thomas Jaworek , Rudiger Funk , Reinhold Schwalm , Matthias Wesimantel , Ulrich Riegel
IPC分类号： C08L33/00 , C07C69/52
CPC分类号： C08G65/3322 , A61L15/60 , C07C67/08 , C08G65/2609 , C07C69/54
摘要： The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where EO is O—CH2-CH2- PO is independently at each instance O—CH2-CH(CH3)- or O—CH(CH3)-CH2- n1, n2 and n3 are independently 4, 5 or 6, n1+n2+n3 is 14, 15 or 16, m1, m2 and m3 are independently 1, 2 or 3, m1+m2+m3 is 4, 5 or 6, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.
摘要翻译：本发明涉及下式的聚烷氧基化三羟甲基丙烷的新型（甲基）丙烯酸酯：其中EO为O-CH 2 -CH 2 - ，PO各自独立地为O-CH 2 -CH（CH 3） - 或O-CH（CH 3）-CH 2 - n1，n2和n3分别为4,5或6，n1 + n2 + n3为14,15或16，m1，m2和m3分别为1,2或3，m1 + m2 + m3为4,5或6 ，R 1，R 2和R 3独立地为H或CH 3，制备这些酯的简化方法以及由此得到的反应混合物的用途。

7. 发明申请

US20080306209A1 Production of a Water-Absorbing Resin to Which a Particulate Additive is Admixed 有权
标题翻译：混合颗粒添加剂的吸水树脂的生产
公开(公告)号：US20080306209A1
公开(公告)日：2008-12-11
申请号：US12158502
申请日：2006-12-28
申请人： Uwe Stueven , Rudiger Funk , Matthias Weismantel , Thomas Daniel , Annemarie Hillebrecht , Dominicus van Esbroeck , Karl J. Possemiers
发明人： Uwe Stueven , Rudiger Funk , Matthias Weismantel , Thomas Daniel , Annemarie Hillebrecht , Dominicus van Esbroeck , Karl J. Possemiers
IPC分类号： C08F2/44 , C08K3/32 , C08K5/04 , C08K3/34
CPC分类号： C08F2/44 , C08F220/06 , C08F222/1006
摘要： The invention relates to a process for producing a water-absorbing resin by polymerization of a reaction mixture comprising at least one hydrophilic monomer and, if appropriate, at least one crosslinker in a reactor, which comprises admixing the reaction mixture with at least one first portion of a particulate additive before the reaction mixture has reached a residence time of 40% of the overall residence time in the reactor and with at least one second portion of a particulate additive when the reaction mixture has reached a residence time of 45% or more of the overall residence time in the reactor, the additive being selected from water-absorbing resin powders, fillers and mixtures thereof, the total solids content of monomer and additive being in the range from 30% to 60% by weight, the amount of additive being in the range from 5% to 50% by weight, based on the monomers, and the weight ratio of the first portion to the second portion of the additive being in the range from 10:1 to 1:5. The resin powder is recycled fine-sized material for example. Not only the residual monomer content, specifically the residual crosslinker content, but also the level of extractables in the water-absorbing resin are reduced by the method of addition described. A high fraction of additives can be incorporated without the properties of the water-absorbing resin obtained being adversely affected. The additives enter a sufficiently firm bond with the resin, so that no excessive dusting occurs on exposure to mechanical stress.
摘要翻译：本发明涉及通过聚合包含至少一种亲水单体和如果合适的反应器中至少一种交联剂的反应混合物来生产吸水树脂的方法，其包括将反应混合物与至少一个第一部分的反应混合物在反应混合物的停留时间达到总反应器停留时间的40％的停留时间和至少一个第二部分的颗粒状添加剂之前，当反应混合物达到45％或更多的停留时间时，在反应器中的总停留时间，添加剂选自吸水树脂粉末，填料及其混合物，单体和添加剂的总固体含量在30重量％至60重量％的范围内，添加剂的量为基于单体的5重量％至50重量％的范围，并且添加剂的第一部分与第二部分的重量比在10:1至 1：5。树脂粉末是例如再循环的精细尺寸的材料。通过所述的添加方法，不仅残留单体含量，特别是残留交联剂含量，而且吸水性树脂中的可萃取物的含量都降低。可以并入高分数的添加剂，而不会对获得的吸水性树脂的性能产生不良影响。添加剂与树脂进行足够牢固的粘合，使得在暴露于机械应力时不会发生过度的除尘。

8. 发明申请

US20080202987A1 Method for Grading a Particulate Water-Absorbing Resin 有权
标题翻译：颗粒状吸水树脂分级方法
公开(公告)号：US20080202987A1
公开(公告)日：2008-08-28
申请号：US11813306
申请日：2005-12-31
申请人： Matthias Weismantel , Rudiger Funk , Thomas Daniel , Uwe Stueven
发明人： Matthias Weismantel , Rudiger Funk , Thomas Daniel , Uwe Stueven
IPC分类号： B07B9/02 , B07B1/46 , B07B1/40
CPC分类号： B07B1/56 , B07B1/40 , B07B1/46
摘要： Process for classifying a particulate water-absorbing resin using a sieving apparatus at a reduced pressure compared with the ambient pressure and a sieving apparatus for classifying a particulate water-absorbing resin at a reduced pressure compared with the ambient pressure.
摘要翻译：使用与环境压力相比减压的筛分装置对颗粒状吸水性树脂进行分级的方法以及与环境压力相比在减压下分级粒状吸水性树脂的筛分装置。

9. 发明申请

US20080004408A1 Method for the Continuous Production of Crosslinked Particulate Gel-Type Polymers 审中-公开
标题翻译：连续生产交联颗粒凝胶型聚合物的方法
公开(公告)号：US20080004408A1
公开(公告)日：2008-01-03
申请号：US11662824
申请日：2005-09-21
申请人： Uwe Stueven , Matthias Weismantel , Rudiger Funk , Annemarie Hillebrecht , Dominicus Esbroeck , Karl Possemiers , Ronny Kaey
发明人： Uwe Stueven , Matthias Weismantel , Rudiger Funk , Annemarie Hillebrecht , Dominicus Esbroeck , Karl Possemiers , Ronny Kaey
IPC分类号： C08F2/01
CPC分类号： B01J19/0066 , B01J8/10 , B01J2208/0061 , C08F2/01 , C08F6/008 , C08F6/10 , C08F220/06 , C08F220/56
摘要： Disclosed is a method for the continuous production of crosslinked, particulate, gel-type polymers by copolymerizing a) water-soluble, monoethylenically unsaturated monomers, b) 0.001 to 5 molar percent of monomers containing at least two polymerizable groups, the percentage being relative to the monomers (a), in a mixer. The substances that are added at the beginning of the kneader are conveyed in an axial direction towards the end of the mixer. The inventive method is characterized in that at least one of the following conditions is met: i) the filling level in the kneader mixer is at least 71 percent; ii) the water-soluble, monoethylenically unsaturated monomers contain up to 150 ppm of a semicyclic ether of a hydroquinone; iii) the temperature in the polymerization zone exceeds 65° C.; iv) the kneader has a remixing rate of less than 0.33.
摘要翻译：公开了通过共聚a）水溶性单烯属不饱和单体，b）0.001至5摩尔％的含有至少两个可聚合基团的单体，其相对于单体（a），在混合器中。在捏合机开始时添加的物质沿轴向方向输送到混合器的末端。本发明的方法的特征在于满足以下条件中的至少一个：i）捏合机混合器中的填充水平为至少71％; ii）水溶性单烯属不饱和单体含有高达150ppm的氢醌的半环醚; iii）聚合区域的温度超过65℃。 iv）捏合机的再混合率小于0.33。

10. 发明授权

US6107432A Water-swellable, hydrophilic polymer compositions 失效
标题翻译：水溶胀性亲水性聚合物组合物
公开(公告)号：US6107432A
公开(公告)日：2000-08-22
申请号：US84941
申请日：1998-05-26
申请人： Fritz Engelhardt , Rudiger Funk , Norbert Herfert , Matthias Weismantel
发明人： Fritz Engelhardt , Rudiger Funk , Norbert Herfert , Matthias Weismantel
IPC分类号： A61F13/53 , A61L15/60 , C08F2/44 , C08F4/04 , C08F4/34 , C08F4/36 , C08F20/00 , C08F20/04 , C08F251/00 , C08G63/00
CPC分类号： C08F251/00 , A61L15/60 , C08F20/04 , C08F4/36
摘要： The present invention relates to water-swellable, hydrophilic polymer compositions which can be prepared by free-radical (co)polymerization of one or more hydrophilic monomers in the presence of starch and/or chemically modified starch, wherein a free-radical initiator which forms three or more free radical sites per molecule is used.
摘要翻译：本发明涉及水溶胀性亲水性聚合物组合物，其可通过在淀粉和/或化学改性淀粉的存在下自由基（共）聚合一种或多种亲水单体而制备，其中形成自由基引发剂使用每个分子三个或更多个自由基位点。

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