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1. 发明授权

US5350781A Process for the production of polyurethane foams 失效
标题翻译：生产聚氨酯泡沫的方法
公开(公告)号：US5350781A
公开(公告)日：1994-09-27
申请号：US123951
申请日：1993-09-20
申请人： Ulrich Liman , Hartwig Grammes , Dirk Wegener , Manuel Kaiser
发明人： Ulrich Liman , Hartwig Grammes , Dirk Wegener , Manuel Kaiser
IPC分类号： C08G18/06 , C08G18/00 , C08G18/08 , C08G18/22 , C08G18/67 , C08G101/00 , C08J9/02
CPC分类号： C08G18/225 , C08G18/6795 , C08G2101/0008 , C08G2101/0016 , C08G2101/0041 , C08G2101/0083 , C08G2170/60
摘要： A process for the production of polyurethane foams by reacting a reaction mixture consisting essentially ofa) a polyisocyanate component, withb) a polyol component free from salt groups, in the presence ofc) at least one blowing agent,d) salts of ester-functional .alpha.,.beta.-unsaturated carboxylic acids and, optionally,e) other auxiliaries and additives typically used in polyurethane chemistry.Component d) the salts of ester-functional .alpha.,.beta.-unsaturated carboxylic acids are the reaction products of (i) monohydric or polyhydric alcohols, with (ii) unsaturated dicarboxylic acids or unsaturated dicarboxylic anhydrides, which contain on a statistical average at least one alkali metal carboxylate group and at most 0.5 alcoholic hydroxyl groups per molecule. The present invention also relates to the composites produced by back-foaming of a plastic film as a surface layer wherein the foam is produced by the process described above.
摘要翻译：一种制备聚氨酯泡沫体的方法，该方法通过使基本上由a）多异氰酸酯组分组成的反应混合物与b）不含盐的多元醇组分在c）至少一种发泡剂，d）酯的盐功能性α，β-不饱和羧酸和任选的e）通常用于聚氨酯化学的其它助剂和添加剂。组分d）酯官能α，β-不饱和羧酸的盐是（i）一元醇或多元醇与（ii）不饱和二羧酸或不饱和二羧酸酐的反应产物，其含有至少一个统计平均值碱金属羧酸盐基团，每分子含有至多0.5个醇羟基。本发明还涉及通过作为表面层的塑料膜的反发泡制备的复合材料，其中通过上述方法制造泡沫体。

2. 发明授权

US5445879A Process for the preparation of composite bodies 失效
标题翻译：复合体的制备工艺
公开(公告)号：US5445879A
公开(公告)日：1995-08-29
申请号：US347442
申请日：1994-12-01
申请人： Ulrich Liman , Dirk Wegener , Hartwig Grammes
发明人： Ulrich Liman , Dirk Wegener , Hartwig Grammes
IPC分类号： C08J9/02 , C08G18/00 , C08G18/08 , C08G18/22 , C08G18/48 , C08J9/14 , B32B3/26
CPC分类号： C08G18/225 , C08G18/4887 , C08G2101/0008 , C08G2101/0016 , C08G2101/0083 , Y10T428/249953 , Y10T428/249991
摘要： The present invention is directed to an improved process for the preparation of composite bodies by back-foaming plastics sheets with a polyurethane reaction mixture. The improvement is in using certain hydroxycarboxylic acids present in the alkali salt form as the catalyst.
摘要翻译： PCT No.PCT / EP93 / 01325 Sec。 371 1994年12月1日第 102（e）日期1994年12月1日PCT提交1993年5月26日PCT公布。公开号WO93 / 25597 日本1993年12月23日。本发明涉及通过用聚氨酯反应混合物回填塑料片材来制备复合体的改进方法。改进在于使用以碱金属盐形式存在的某些羟基羧酸作为催化剂。

3. 发明授权

US5210127A Free-flowing, thermoplastically processible and post-crosslinkable polyurethane powders 失效
标题翻译：自由流动，热塑性可交联聚氨酯粉末
公开(公告)号：US5210127A
公开(公告)日：1993-05-11
申请号：US964592
申请日：1992-10-21
申请人： Joachim Werner , Walter Meckel , Ulrich Liman , Dirk Wegener , Werner Rasshofer , James W. Rosthauser
发明人： Joachim Werner , Walter Meckel , Ulrich Liman , Dirk Wegener , Werner Rasshofer , James W. Rosthauser
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/79 , C08G18/80 , C08J3/12 , C08J3/24 , C08J5/18 , C08J9/10 , C08J9/16 , C08L75/00 , C08L75/04
CPC分类号： C08J3/24 , C08G18/0871 , C08G18/10 , C08G18/8064 , C08G2101/00 , C08G2140/00 , C08G2350/00 , C08G2410/00 , C08J2375/04
摘要： Novel powders useful in the slush molding process are produced by reacting an emulsion of either an isocyanate or an isocyanate reactive material with either an isocyanate reactive material or an isocyanate, depending upon the nature of the component used to make the emulsion in the presence of an at least partially blocked isocyanate and an organic carrier. The final reaction product is subsequently removed from the carrier.
摘要翻译：通过将异氰酸酯或异氰酸酯反应性材料的乳液与异氰酸酯反应性材料或异氰酸酯反应来制备可用于搪塑成型方法的新型粉末，这取决于在存在下制备乳液的组分的性质至少部分封端的异氰酸酯和有机载体。随后从载体中除去最终的反应产物。

4. 发明授权

US5416125A Process for the production of semirigid foams containing urethane groups with improved flow properties 失效
标题翻译：用于生产含有具有改善的流动性质的氨基甲酸酯基团的半刚性泡沫的方法
公开(公告)号：US5416125A
公开(公告)日：1995-05-16
申请号：US325715
申请日：1994-10-19
申请人： Ulrich Liman , Peter Gansen
发明人： Ulrich Liman , Peter Gansen
IPC分类号： C08J9/02 , B32B5/20 , C08G18/40 , C08G18/65 , C08G18/76 , C08G101/00 , C08J9/00 , C08J9/14 , C08L75/04 , C08G18/06 , C08J9/08
CPC分类号： C08G18/7664 , C08G2101/0016 , C08G2101/0083
摘要： The present invention relates to a process for the production of semi-rigid foams containing urethane groups which exhibit very good flow properties during the production process. These semi-rigid foams are produced by reacting a reaction mixture of:1) polyisocyanates,2) organic compounds containing at least two isocyanate-reactive hydrogen atoms and having a molecular weight in the range from 400 to 10,000, and3) water and/or organic blowing agents.In particular, the polyisocyanates comprise a mixture of:a) 55 to 87% by weight, based on 100% by weight of the mixture, of 4,4'-diphenylmethane diisocyanate,b) 8 to 40% by weight, based on 100% by weight of the mixture, of 2,4'-diphenylmethane diisocyanate,c) 0.1 to 4% by weight, based on 100% by weight of the mixture, of 2,2'-diphenylmethane diisocyanate, andd) 5 to 35% by weight, based on 100% by weight of the mixture, of polyphenyl polymethylene polyisocyanates.
摘要翻译：本发明涉及一种生产含有氨基甲酸酯基团的半刚性泡沫的方法，在生产过程中表现出非常好的流动性。这些半刚性泡沫体通过以下反应混合物制备：1）多异氰酸酯，2）含有至少两个异氰酸酯反应性氢原子并且分子量在400至10,000的有机化合物，和3）水和/ 或有机发泡剂。特别地，多异氰酸酯包括以下混合物：a）基于100重量％的混合物的55-87重量％的4,4'-二苯基甲烷二异氰酸酯，b）8至40重量％，基于100 混合物的重量％，2,4'-二苯基甲烷二异氰酸酯，c）0.1至4重量％，基于100重量％的混合物，2,2'-二苯基甲烷二异氰酸酯，和d）5至35 基于100重量％的混合物的重量％的聚苯基多亚甲基多异氰酸酯。

5. 发明授权

US5482979A Compounds containing tertiary amino groups, a process for their production and their use as catalysts 失效
标题翻译：含有叔氨基的化合物，其制备方法及其用作催化剂
公开(公告)号：US5482979A
公开(公告)日：1996-01-09
申请号：US255524
申请日：1994-06-08
申请人： Josef Sanders , Ulrich Liman , Klaus Konig
发明人： Josef Sanders , Ulrich Liman , Klaus Konig
IPC分类号： C07C229/30 , C08G18/18 , C08G18/67 , C07C229/02
CPC分类号： C07C229/30 , C08G18/1825 , C08G18/1866 , C08G18/6795 , C08G2101/00
摘要： Compounds containing ester groups and tertiary amino groups and optionally hydroxyl groups are made by reacting optionally hydroxyfunctional acetoacetic acid esters of monofunctional or polyfunctional alcohols (particularly polyfunctional polyether polyols) with primary/tertiary polyamines (particularly diamines). These compounds are useful as optionally incorporable catalysts for the isocyanate addition reaction in the production of polyurethane foams by the isocyanate polyaddition process.
摘要翻译：含有酯基和叔氨基和任选的羟基的化合物是通过使任意的单功能或多官能醇（特别是多官能聚醚多元醇）的羟基官能的乙酰乙酸酯与伯/叔多胺（特别是二胺）反应制得的。这些化合物可用作用于通过异氰酸酯加聚方法生产聚氨酯泡沫体中的异氰酸酯加成反应的任选的可加入的催化剂。

6. 发明授权

US5356945A Reactive polyurethanes 失效
标题翻译：活性聚氨酯
公开(公告)号：US5356945A
公开(公告)日：1994-10-18
申请号：US77003
申请日：1993-06-15
申请人： Joachim Werner , Ulrich Liman , Walter Meckel , Armin Zenner , Wolfgang Patzold
发明人： Joachim Werner , Ulrich Liman , Walter Meckel , Armin Zenner , Wolfgang Patzold
IPC分类号： C08G18/10 , C08G18/65 , C08G18/78 , C08G18/79 , C08G18/80 , C08G18/00
CPC分类号： C08G18/8064 , C08G18/10 , C08G18/7887 , C08G18/798 , C08G18/8061 , C08G2150/20 , C08G2170/20
摘要： The present invention relates to polyurethanes with softening temperatures above 80.degree. C. which are NCO-free, which are reactive via masked isocyanates, which are essentially linear and extensively pre-lengthened, and their preparation. The polyurethanes can be used as powders which can be processed like thermoplastics and post-cured.
摘要翻译：本发明涉及软化温度高于80℃的不含NCO的聚氨酯，其通过掩蔽的异氰酸酯是反应性的，其基本上是线性的并且被广泛地预延长，以及它们的制备。聚氨酯可以作为粉末使用，其可以像热塑性塑料一样加工并且后固化。

7. 发明授权

US6020386A Process for the production of hydroxyfunctional compounds from (polyurethane) polyurea waste 失效
标题翻译：从（聚氨酯）聚脲废料生产羟基官能化合物的方法
公开(公告)号：US6020386A
公开(公告)日：2000-02-01
申请号：US189861
申请日：1994-02-01
申请人： Thomas Munzmay , Walter Meckel , Ulrich Liman , Hartmut Nefzger , Werner Rasshofer , Karl-Heinz Dorner , Andreas Ruckes
发明人： Thomas Munzmay , Walter Meckel , Ulrich Liman , Hartmut Nefzger , Werner Rasshofer , Karl-Heinz Dorner , Andreas Ruckes
IPC分类号： C08G18/83 , C08G18/32 , C08J11/22 , C08L75/00 , C08J11/04
CPC分类号： C08J11/22 , C08J2375/00 , Y02P20/582 , Y02W30/706
摘要： Hydroxyfunctional compounds suitable for use in the polyisocyanate polyaddition process are obtained from polyurethane and/or polyurethane polyurea waste by decomposition with an alcohol and subsequent reaction of the alcoholysis products to reduce their content of low molecular weight, sterically unhindered aromatic amines. In this process, polyurethane and/or polyurethane polyurea waste is first treated with a low molecular weight diol or polyol at a temperature of from about 160 to 260.degree. C. The resultant alcoholysis product may then either be further heated at a temperature lower than that used in the first step within the ranger of from about 50 to 180.degree. C. or reacted with a dialkyl carbonate and/or 1,3-dicarbonyl compound.
摘要翻译：适用于多异氰酸酯加聚方法的羟基官能化合物通过用醇分解从聚氨酯和/或聚氨酯聚脲废物中获得，随后醇解产物的反应降低其低分子量空间不受阻碍的芳族胺的含量。在该方法中，聚氨酯和/或聚氨酯聚脲废物首先在约160至260℃的温度下用低分子量二醇或多元醇进行处理。然后可以在低于该温度的温度下进一步加热得到的醇解产物。在第一步中用于约50至180℃的游C.，或与碳酸二烷基酯和/或1,3-二羰基化合物反应。

8. 发明授权

US5416130A Process for the production of polyurethane foams 失效
标题翻译：生产聚氨酯泡沫的方法
公开(公告)号：US5416130A
公开(公告)日：1995-05-16
申请号：US206784
申请日：1994-03-04
申请人： Ulrich Liman , Heinz Eickhaus , Gerd Steinert
发明人： Ulrich Liman , Heinz Eickhaus , Gerd Steinert
IPC分类号： B32B5/20 , C08G18/16 , C08G18/22 , C08G18/38 , C08G18/48 , C08G101/00 , C08J9/02 , C08J9/14 , C08G8/04
CPC分类号： C08G18/161 , B32B5/20 , C08G18/225 , C08G18/3829 , C08G2101/00 , C08G2170/60
摘要： A process for the production of polyurethane foams, in particular for the production of composite articles by back-foaming a plastics film as covering layer by the reaction ofa) one or more polyisocyanates withb) a polyol component which is free from salt groups in the presence ofc) at least one blowing agent,d) alkali metal carboxylates ande) from 0.01 to 30% by weight, based upon the weight of component b), of one or more organic compounds which are different from components a) through d), which are free from tertiary amino groups, metal and phosphorus and which have a dipole moment above 2.0 Debye.
摘要翻译：一种生产聚氨酯泡沫体的方法，特别是通过使a）一种或多种多异氰酸酯与b）不含盐的多元醇组分的反应，将塑料薄膜作为覆盖层进行反发泡来生产复合制品存在c）至少一种发泡剂，d）碱金属羧酸盐，和e）以组分b）的重量为基准的0.01至30重量％的一种或多种不同于组分a）至 d），其不含叔氨基，金属和磷，偶极矩高于2.0德拜。

9. 发明授权

US07205430B2 Production of di- and polyisocyanates of the diphenylmethane series with defined acidity 有权
标题翻译：生产具有确定酸度的二苯基甲烷系列的二异氰酸酯和多异氰酸酯
公开(公告)号：US07205430B2
公开(公告)日：2007-04-17
申请号：US11048667
申请日：2005-02-01
申请人： Ulrich Liman , Heinz-Herbert Müller , Robert Vieler , Ralf Echterhoff
发明人： Ulrich Liman , Heinz-Herbert Müller , Robert Vieler , Ralf Echterhoff
IPC分类号： C07C263/00 , C07C249/00
CPC分类号： C07C263/10 , C07C263/20 , C08G18/7664 , C07C265/14
摘要： The invention relates to a process for the production of di- and polyisocyanates of the diphenylmethane series and mixtures thereof, in which aniline and formaldehyde are reacted in the presence of an acid catalyst to form di- and polyamines of the diphenylmethane series; the di- and polyamines of the diphenylmethane series are phosgenated, optionally in the presence of a solvent, to obtain a crude di- and polyisocyanate; from the crude di- and polyisocyanate, at least one fraction containing at least 5 wt. % 3-ring and multi-ring MDI and at least one fraction containing at least 95 wt. % 2-ring MDI are separated by distillation, and the acidities of the fraction containing at least 5 wt. % 3-ring MDI and multi-ring MDI, and/or the fraction containing at least 95 wt. % 2-ring MDI are determined analytically; and an acidic compound is added to the fraction containing at least 5 wt. % 3-ring MDI and multi-ring MDI, and/or the fraction containing at least 95 wt. % 2-ring MDI, so that the desired acidity is achieved.
摘要翻译：本发明涉及二苯基甲烷系列的二异氰酸酯和多异氰酸酯的制造方法及其混合物，其中苯胺和甲醛在酸催化剂的存在下反应形成二苯基甲烷系列的二胺和多胺; 任选在溶剂存在下，将二苯基甲烷系列的二胺和多胺光气化，得到粗二异氰酸酯和多异氰酸酯; 从粗二异氰酸酯和多异氰酸酯，至少含有至少5wt。％3环和多环MDI和至少一个含有至少95wt。％2环MDI通过蒸馏分离，并且含有至少5wt。％3环MDI和多环MDI，和/或含有至少95重量％％2环MDI是分析确定的; 并将酸性化合物加入到含有至少5wt。％3环MDI和多环MDI，和/或含有至少95重量％％2环MDI，从而达到所需的酸度。

10. 发明授权

US07038002B2 Production of mixtures of diisocyanates and polyisocyanates from the diphenylmethane series with high contents of 4,4′-methylenediphenyl diisocyanate and 2,4′-methylenediphenyl diisocyanate 有权
标题翻译：从二苯基甲烷系列与高含量的4,4'-亚甲基二苯基二异氰酸酯和2,4'-亚甲基二苯基二异氰酸酯制备二异氰酸酯和多异氰酸酯的混合物
公开(公告)号：US07038002B2
公开(公告)日：2006-05-02
申请号：US10896129
申请日：2004-07-21
申请人： Hans-Georg Pirkl , Ulrich Liman , Robert Vieler , Ralf Echterhoff
发明人： Hans-Georg Pirkl , Ulrich Liman , Robert Vieler , Ralf Echterhoff
IPC分类号： C08G18/00 , C08G18/32
CPC分类号： C07C263/10 , C07C263/20 , C07C265/14
摘要： A fraction of diisocyanates of the diphenylmethane series containing at least 95 wt. % binuclear methylenediphenyl diisocyanate is obtained by a) reacting aniline and formaldehyde in the presence of an acid catalyst to produce diamines and polyamines of the diphenylmethane series containing binuclear methylenediphenyl diamine, b) phosgenating the diamines and polyamines produced in a), optionally in the presence of a solvent, to produce a crude diisocyanate and polyisocyanate, and c) separating a fraction containing at least 95 wt. % binuclear methylenediphenyl diisocyanate with a 4,4′-MDI content of over 60 wt. %, a 2,4′-MDI content of 4 to 35 wt. % and a 2,2′-MDI content of 0.01 to 10 wt. %, relative to the mass of the fraction, and a maximum of 20 ppm phenyl isocyanate and optionally a maximum of 50 ppm solvent from the crude diisocyanate and polyisocyanate produced in b) in a single distillation step with optional upstream and/or downstream separation of low-boiling components.
摘要翻译：二苯基甲烷系列的二异氰酸酯的一部分含有至少95wt。通过以下方法获得％双核亚甲基二苯基二异氰酸酯：a）在酸催化剂存在下使苯胺和甲醛反应，生成含有双核亚甲基二苯基二胺的二苯基甲烷系列的二胺和多胺，b）使a）中产生的二胺和多胺光气化，的溶剂，以产生粗二异氰酸酯和多异氰酸酯，和c）分离含有至少95重量％具有超过60重量％的4,4'-MDI含量的双核亚甲基二苯基二异氰酸酯。％，2,4'-MDI含量为4〜35wt。％和2,2'-MDI含量为0.01〜10wt。相对于馏分的质量，最大值为20ppm的苯基异氰酸酯和任选的最大值为50ppm的溶剂，来自粗制二异氰酸酯和b）中产生的多异氰酸酯，在单一蒸馏步骤中具有任选的上游和/或下游分离低沸点组分。

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