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    • 4. 发明授权
    • Synthesis of phenyl-substituted polyfluoroanthenes and the use thereof
    • 苯基取代的多氟代苯的合成及其用途
    • US08137822B2
    • 2012-03-20
    • US11912998
    • 2006-04-03
    • Florian DoetzSimon NordHorst WeissJoachim Roesch
    • Florian DoetzSimon NordHorst WeissJoachim Roesch
    • H01L51/54C09K11/06
    • H05B33/14C08G61/10C09K11/06C09K2211/1416H01L51/0035H01L51/0043H01L51/0052H01L51/5012Y10S428/917
    • The invention relates to a method for producing polyfluoroanthenes containing repeat units of general formula (I), said method consisting of the following steps: a) a monomer fluoroanthene derivative of formula IIa is produced; b) optionally the monomer fluoroanthene derivative of formula IIa is converted into another monomer fluoroanthene derivative of formula IIb; and c) the monomer fluoroanthene derivative of formula IIa or IIb is polymerised, optionally together with at least one other comonomer. The invention also relates to polyfluoroanthenes that can be produced according to the inventive method, films, a light-emitting layer containing or consisting of at least one inventive polyfluoroanthene, OLEDs containing at least one inventive polyfluoroanthene, OLEDs containing an inventive light-emitting layer, a device containing an inventive OLED, and the use of the inventive polyfluoroanthene emitter substances in OLEDs.
    • 本发明涉及一种含有通式(I)重复单元的多氟代a的制备方法,所述方法包括以下步骤:a)制备式Ⅱa的单体氟代蒽衍生物; b)任选地,式IIa的单体氟代蒽衍生物转化成式IIb的另一单体氟代蒽衍生物; 和c)式IIa或IIb的单体氟代蒽衍生物聚合,任选与至少一种其它共聚单体一起聚合。 本发明还涉及可根据本发明方法制备的多氟代苯,膜,含有或由至少一种本发明的多氟代烯烃组成的发光层,含有至少一种本发明的多氟蒽的OLED,含有本发明的发光层的OLED, 含有本发明OLED的器件,以及本发明的多氟蒽发光物质在OLED中的用途。