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    • 2. 发明授权
    • Immobilized Lewis Acid catalysts
    • 固定化路易斯酸催化剂
    • US5563313A
    • 1996-10-08
    • US398463
    • 1995-03-03
    • Tze-Chiang ChungFrank J. ChenJon E. StanatAlok Kumar
    • Tze-Chiang ChungFrank J. ChenJon E. StanatAlok Kumar
    • C08F4/02C08F4/00C08F4/06C08F4/14C08F8/00C08F10/00C07C2/02
    • C08F10/00
    • Immobilized Lewis Acid catalyst comprising polymer having at least one Lewis Acid immobilized within the structure therein, said polymer having monomer units represented by the structural formula:--[A].sub.a --[B].sub.b --[C].sub.c --wherein a represents about 1 to about 99 mole %b represents about 0 to about 50 mole %c represents about 1 to about 99 mole %a+b+c is preferably about 100%; ##STR1## C is selected from the group consisting of: ##STR2## (III) combinations thereof, wherein D is OH, halide, OR.sup.4, NH.sub.2, NHR.sup.3, OM', or OM";E is the residue of the reaction of at least one Lewis Acid with the D substituent of monomer unit B;R.sup.1 represents proton, C.sub.1 -C.sub.24 alkyl group, or C.sub.3 -C.sub.24 cycloalkyl;R.sup.2 represents C.sub.1 -C.sub.24 alkylene group, C.sub.3 -C.sub.24 cycloalkylene, C.sub.6 -C.sub.18 arylene, or C.sub.7 -C.sub.30 alkylarylene;R.sup.3 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.4 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;M' represents alkali metal;M" represents alkaline-earth metal.Also disclosed are polymerization and alkylation processes utilizing the immobilized Lewis Acid catalysts. Another aspect of the present invention is a method of manufacturing immobilized Lewis Acid catalysts.
    • 固定化路易斯酸催化剂,其包含具有固定在其结构内的至少一种路易斯酸的聚合物,所述聚合物具有由以下结构式表示的单体单元: - [A] a- [B] b- [C] c - 其中a表示约1 至约99摩尔%b表示约0至约50摩尔%c表示约1至约99摩尔%a + b + c优选约100%; 其中D是OH,卤化物,OR4,NH2,NHR3,OM'或其组合的组合。 OM“ E是至少一种路易斯酸与单体单元B的D取代基反应的残基; R1表示质子,C1-C24烷基或C3-C24环烷基; R2表示C1-C24亚烷基,C3-C24亚环烷基,C6-C18亚芳基或C7-C30烷基亚芳基; R3表示C1-C24烷基,C3-C24环烷基,C1-C24芳基或C7-C30烷基芳基; R4表示C1-C24烷基,C3-C24环烷基,C1-C24芳基或C7-C30烷基芳基; M'表示碱金属; M“表示碱土金属。 还公开了使用固定化的路易斯酸催化剂的聚合和烷基化方法。 本发明的另一方面是制备固定化的路易斯酸催化剂的方法。
    • 3. 发明授权
    • Immobilized Lewis acid catalysts
    • 固定化路易斯酸催化剂
    • US5288677A
    • 1994-02-22
    • US723130
    • 1991-06-28
    • Tze-Chiang ChungFrank J. ChenJon E. StanatAlok Kumar
    • Tze-Chiang ChungFrank J. ChenJon E. StanatAlok Kumar
    • C08F4/02C08F4/00C08F4/06C08F4/14C08F8/00C08F10/00B01J31/00
    • C08F10/00
    • Immobilized Lewis Acid catalyst comprising polymer having at least one Lewis Acid immobilized within the structure therein, said polymer having monomer units represented by the structural formula: ##STR1## wherein a represents about 1 to about 99 mole % b represents about 0 to about 50 mole %c represents about 1 to about 99 mole %a+b+c is preferably about 100%; ##STR2## C is selected from the group consisting of: ##STR3## D is OH, halide, OR.sup.4, NH.sub.2, NHR.sup.3, OM', or OM"; E is the residue of the reaction of at least one Lewis Acid with the D substituent of monomer unit B;R.sup.1 represents proton, C.sub.1 -C.sub.24 alkyl group, or C.sub.3 -C.sub.24 cycloalkyl;R.sup.2 represents C.sub.1 -C.sub.24 alkyl group, C.sub.3 -C.sub.24 cycloalkyl, C.sub.6 -C.sub.18 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.3 represents C.sub.6 -C.sub.18 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.6 -C.sub.18 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.4 represents C.sub.6 -C.sub.18 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.6 -C.sub.18 aryl, or C.sub.7 -C.sub.30 alkylaryl;M' represents alkali metal;M" represents alkaline-earth metal.Also disclosed are polymerization and alkylation processes utilizing the immobilized Lewis Acid catalysts. Another aspect of the present invention is a method of manufacturing immobilized Lewis Acid catalysts.
    • 固定化路易斯酸催化剂,其包含具有固定在其结构内的至少一种路易斯酸的聚合物,所述聚合物具有由以下结构式表示的单体单元:(*化学结构*)其中a表示约1至约99摩尔%b表示约0至 约50摩尔%c表示约1至约99摩尔%a + b + c优选约100%; (*化学结构*)(*化学结构*)C选自:(*化学结构*)(I)(*化学结构*)(II)的组合。(III)D是OH,卤化物 ,OR4,NH2,NHR3,OM'或OM“; E是至少一种路易斯酸与单体单元B的D取代基反应的残基; R 1表示质子,C 1 -C 24烷基或C 3 -C 24 环烷基; R2表示C1-C24烷基,C3-C24环烷基,C6-C18芳基或C7-C30烷基芳基; R3表示C6-C18烷基,C3-C24环烷基,C6-C18芳基或C7-C30烷基芳基; R4 代表C 6 -C 18烷基,C 3 -C 24环烷基,C 6 -C 18芳基或C 7 -C 30烷基芳基; M'表示碱金属; M“表示碱土金属。 还公开了利用固定化的路易斯酸催化剂的聚合和烷基化方法。 本发明的另一方面是制备固定化的路易斯酸催化剂的方法。
    • 4. 发明授权
    • Immobilized Lewis Acid catalysts
    • 固定化路易斯酸催化剂
    • US5481054A
    • 1996-01-02
    • US398637
    • 1995-03-03
    • Tze-Chiang ChungFrank J. ChenJon E. StanatAlok Kumar
    • Tze-Chiang ChungFrank J. ChenJon E. StanatAlok Kumar
    • C08F4/02C08F4/00C08F4/06C08F4/14C08F8/00C08F10/00C07C2/70C07C2/58
    • C08F10/00
    • Immobilized Lewis Acid catalyst comprising polymer having at least one Lewis Acid immobilized within the structure therein, said polymer having monomer units represented by the structural formula:--[A].sub.a --[B].sub.b --[C].sub.c --whereina represents about 1 to about 99 mole %b represents about 0 to about 50 mole %c represents about 1 to about 99 mole %a+b+c is preferably about 100%; ##STR1## C is selected from the group consisting of: ##STR2## (III) combinations thereof, wherein D is OH, halide, OR.sup.4, NH.sub.2, NHR.sup.3, OM', or OM";E is the residue of the reaction of at least one Lewis Acid with the D substituent of monomer unit B;R.sup.1 represents proton, C.sub.1 -C.sub.24 alkyl group, or C.sub.3 -C.sub.24 cycloalkyl;R.sup.2 represents C.sub.1 -C.sub.24 alkylene group, C.sub.3 -C.sub.24 cycloalkylene, C.sub.6 -C.sub.18 arylene, or C.sub.7 -C.sub.30 alkylarylene;R.sup.3 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.4 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;M' represents alkali metal;M" represents alkaline-earth metal.Also disclosed are polymerization and alkylation processes utilizing the immobilized Lewis Acid catalysts. Another aspect of the present invention is a method of manufacturing immobilized Lewis Acid catalysts.
    • 固定化路易斯酸催化剂,其包含具有固定在其结构内的至少一种路易斯酸的聚合物,所述聚合物具有由以下结构式表示的单体单元: - [A] a- [B] b- [C] c-,其中a表示约1 至约99摩尔%b表示约0至约50摩尔%c表示约1至约99摩尔%a + b + c优选约100%; 其中D是OH,卤化物,OR4,NH2,NHR3,OM'或其组合的组合。 OM“ E是至少一种路易斯酸与单体单元B的D取代基反应的残基; R1表示质子,C1-C24烷基或C3-C24环烷基; R2表示C1-C24亚烷基,C3-C24亚环烷基,C6-C18亚芳基或C7-C30烷基亚芳基; R3表示C1-C24烷基,C3-C24环烷基,C1-C24芳基或C7-C30烷基芳基; R4表示C1-C24烷基,C3-C24环烷基,C1-C24芳基或C7-C30烷基芳基; M'表示碱金属; M“表示碱土金属。 还公开了利用固定化的路易斯酸催化剂的聚合和烷基化方法。 本发明的另一方面是制备固定化的路易斯酸催化剂的方法。
    • 5. 发明授权
    • Immobilized Lewis Acid catalysts
    • 固定化路易斯酸催化剂
    • US5600055A
    • 1997-02-04
    • US436508
    • 1995-05-08
    • Tze-Chiang ChungFrank J.-Y. ChenJon E. StanatAlok Kumar
    • Tze-Chiang ChungFrank J.-Y. ChenJon E. StanatAlok Kumar
    • C08F4/02C08F4/00C08F4/06C08F4/14C08F8/00C08F10/00C07C2/62
    • C08F10/00
    • Immobilized Lewis Acid catalyst comprising polymer having at least one Lewis Acid immobilized within the structure therein, said polymer having monomer units represented by the structural formula: ##STR1## wherein a represents about 1 to about 99 mole %b represents about 0 to about 50 mole %c represents about 1 to about 99 mole %a+b+c is preferably about 100%; ##STR2## C is selected from the group consisting of: ##STR3## (III) combinations thereof. D is OH, halide, OR.sup.4, NH.sub.2, NHR.sup.3, OM', or OM";E is the residue of the reaction of at least one Lewis Acid with the D substituent of monomer unit B;R.sup.1 represents proton, C.sub.1 -C.sub.24 alkyl group, or C.sub.3 -C.sub.24 cycloalkyl;R.sup.2 represents C.sub.1 -C.sub.24 alkyl group, C.sub.3 -C.sub.24 cycloalkyl, C.sub.6 -C.sub.18 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.3 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.4 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;M' represents alkali metal;M" represents alkaline-earth metal.Also disclosed are polymerization and alkylation processes utilizing the immobilized Lewis Acid catalysts. Another aspect of the present invention is a method of manufacturing immobilized Lewis Acid catalysts.
    • 固定化路易斯酸催化剂,其包含具有固定在其结构内的至少一种路易斯酸的聚合物,所述聚合物具有由结构式表示的单体单元:其中a表示约1至约99摩尔%b表示约0至约50摩尔 %c表示约1至约99摩尔%a + b + c优选为约100%; C选自:(I)(II)(III)组合。 D是OH,卤化物,OR4,NH2,NHR3,OM'或OM“; E是至少一种路易斯酸与单体单元B的D取代基反应的残基; R1表示质子,C1-C24烷基或C3-C24环烷基; R2表示C1-C24烷基,C3-C24环烷基,C6-C18芳基或C7-C30烷基芳基; R3表示C1-C24烷基,C3-C24环烷基,C1-C24芳基或C7-C30烷基芳基; R4表示C1-C24烷基,C3-C24环烷基,C1-C24芳基或C7-C30烷基芳基; M'表示碱金属; M“表示碱土金属。 还公开了利用固定化的路易斯酸催化剂的聚合和烷基化方法。 本发明的另一方面是制备固定化的路易斯酸催化剂的方法。
    • 6. 发明授权
    • Immobilized lewis acid catalysts
    • 固定的路易斯酸催化剂
    • US5571885A
    • 1996-11-05
    • US398635
    • 1995-03-03
    • Tze-Chiang ChungFrank J.-Y. ChenJon E. StanatAlok Kumar
    • Tze-Chiang ChungFrank J.-Y. ChenJon E. StanatAlok Kumar
    • C08F4/02C08F4/00C08F4/06C08F4/14C08F8/00C08F10/00C08F10/08C08F36/02C08F36/06
    • C08F10/00
    • Immobilized Lewis Acid catalyst comprising polymer having at least one Lewis Acid immobilized within the structure therein, said polymer having monomer units represented by the structural formula:--[A].sub.a --[B].sub.b --[C].sub.c --whereina represents about 1 to about 99 mole %b represents about 0 to about 50 mole %c represents about 1 to about 99 mole %a+b+c is preferably about 100%; ##STR1## C is selected from the group consisting of: ##STR2## (III) combinations thereof, wherein D is OH, halide, OR.sup.4, NH.sub.2, NHR.sup.3, OM', or OM";E is the residue of the reaction of at least one Lewis Acid with the D substituent of monomer unit B;R.sup.1 represents proton, C.sub.1 -C.sub.24 alkyl group, or C.sub.3 -C.sub.24 cycloalkyl;R.sup.2 represents C.sub.1 -C.sub.24 alkylene group, C.sub.3 -C.sub.24 cycloalkylene, C.sub.6 -C.sub.18 arylene, or C.sub.7 -C.sub.30 alkylarylene;R.sup.3 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;R.sup.4 represents C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 cycloalkyl, C.sub.1 -C.sub.24 aryl, or C.sub.7 -C.sub.30 alkylaryl;M' represents alkali metal;M" represents alkaline-earth metal.Also disclosed are polymerization and alkylation processes utilizing the immobilized Lewis Acid catalysts. Another aspect of the present invention is a method of manufacturing immobilized Lewis Acid catalysts.
    • 固定化路易斯酸催化剂,其包含具有固定在其结构内的至少一种路易斯酸的聚合物,所述聚合物具有由以下结构式表示的单体单元: - [A] a- [B] b- [C] c - 其中a表示约1 至约99摩尔%b表示约0至约50摩尔%c表示约1至约99摩尔%a + b + c优选约100%; 其中D为OH,卤化物,OR4,NH2,NHR3,OM'或OM“;其中D为OH,卤素,OR4,NH2,NHR3,OM'或OM”。 E是至少一种路易斯酸与单体单元B的D取代基反应的残基; R1表示质子,C1-C24烷基或C3-C24环烷基; R2表示C1-C24亚烷基,C3-C24亚环烷基,C6-C18亚芳基或C7-C30烷基亚芳基; R3表示C1-C24烷基,C3-C24环烷基,C1-C24芳基或C7-C30烷基芳基; R4表示C1-C24烷基,C3-C24环烷基,C1-C24芳基或C7-C30烷基芳基; M'表示碱金属; M“表示碱土金属。 还公开了利用固定化的路易斯酸催化剂的聚合和烷基化方法。 本发明的另一方面是制备固定化的路易斯酸催化剂的方法。