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1. 发明授权

US5518583A Zero discharge mill distillation, salt recovery, and water management 失效
标题翻译：零排料机蒸馏，盐回收和水管理
公开(公告)号：US5518583A
公开(公告)日：1996-05-21
申请号：US138968
申请日：1993-10-21
申请人： Tuomo S. Nykanen , Brian F. Greenwood , Johan Gullichsen , Erkki Kiiskila , Esko Mattelmaki , Joseph R. Phillips , Jan T. Richardsen , Rolf Ryham , Jarmo Soderman , Karl G. Wiklund
发明人： Tuomo S. Nykanen , Brian F. Greenwood , Johan Gullichsen , Erkki Kiiskila , Esko Mattelmaki , Joseph R. Phillips , Jan T. Richardsen , Rolf Ryham , Jarmo Soderman , Karl G. Wiklund
IPC分类号： C01B7/01 , C01D1/04 , C01D3/04 , C01D5/00 , C01D7/00 , D21C11/00 , D21C11/06 , D21C11/10 , D21C11/12
CPC分类号： D21C11/0021 , C01B7/01 , C01D1/04 , C01D3/04 , C01D5/00 , C01D7/00 , D21C11/00 , D21C11/0007 , D21C11/0028 , D21C11/066 , D21C11/10 , D21C11/12 , Y10S162/08
摘要： In minimizing effluents from a cellulose pulp mill, liquid effluents from a bleach plant are concentrated, and then incinerated to produce a residue including sodium, sulfate, and sodium chloride. This residue is distilled with sulfuric acid to produce gaseous hydrogen chloride and remaining residue, the HCl being used in chloride dioxide production for the bleach plant, while the remaining residue is passed to the recovery loop (e.g. recovery boiler). Sulfur containing gases from the non-condensible gas system may be combusted to produce gaseous sulfur dioxide, which is then converted to sulfuric acid, to distill the residue. Where a non-chlorine bleach plant is provided, the liquid effluents may be concentrated in evaporators and then passed directly to the recovery boiler. The liquid streams in the mill are managed by a cascade principle to reserve the cleanest water for only those processes where it is needed while minimizing its use where it is not necessary.
摘要翻译：在使来自纤维素纸浆厂的流出物最小化的同时，将来自漂白设备的液体流出物浓缩，然后焚化以产生包括钠，硫酸盐和氯化钠的残余物。该残余物用硫酸蒸馏以产生气态氯化氢和剩余残余物，HCl用于漂白设备的二氧化氯生产中，而剩余的残余物通过回收回路（例如回收锅炉）。来自不可冷凝气体系统的含硫气体可以燃烧以产生气态二氧化硫，然后将其转化为硫酸以蒸馏残余物。当提供非氯漂白设备时，液体流出物可以浓缩在蒸发器中，然后直接通入回收锅炉。磨机中的液体流是通过级联原理进行管理的，以便在需要的地方只为那些需要处理的过程保留最干净的水，同时尽可能减少不必要的使用。

2. 发明授权

US5549788A Minimal effluents discharge pulp mill with chemical recovery 失效
标题翻译：排放最小的废纸浆厂具有化学回收率
公开(公告)号：US5549788A
公开(公告)日：1996-08-27
申请号：US113642
申请日：1993-08-31
申请人： Tuomo S. Nykanen , Brian F. Greenwood , Johan Gullichsen , Erkki Kiiskila , Esko Mattelmaki , Joseph R. Phillips , Jan T. Richardsen , Rolf Ryham , Jarmo Soderman , Karl G. Wiklund
发明人： Tuomo S. Nykanen , Brian F. Greenwood , Johan Gullichsen , Erkki Kiiskila , Esko Mattelmaki , Joseph R. Phillips , Jan T. Richardsen , Rolf Ryham , Jarmo Soderman , Karl G. Wiklund
IPC分类号： C01B7/01 , C01D1/04 , C01D3/04 , C01D5/00 , C01D7/00 , D21C11/00 , D21C11/06 , D21C11/10 , D21C11/12
CPC分类号： C01B7/01 , C01D1/04 , C01D3/04 , C01D5/00 , C01D7/00 , D21C11/0007 , D21C11/0021 , D21C11/0028 , D21C11/066 , D21C11/10 , D21C11/12 , Y10S162/08
摘要： Effluents are minimized from a cellulose pulp mill having a recovery boiler by concentrating liquid effluents from the bleach plant and/or liquid spills from process streams, incinerating the concentrated effluents in the recovery boiler, removing particles present in the flue gases from the recovery boiler to produce an ash including salts containing potassium and chloride, and sulfur compounds, and removing the potassium and chloride from the ash while returning the sulfur containing compounds to the recovery loop, so as to balance the sulfur, chloride and potassium levels in the mill. The sulfur is typically returned directly to a stream of black liquor just before entry into the recovery boiler. Green liquor is produced from the melt, which preferably is treated to remove metals from it prior to caustization (e.g. by sedimentation and/or filtration), and prior to green liquor crystallization to produce sodium hydroxide.
摘要翻译：通过从漂白设备中浓缩液体流出物和/或来自工艺物流的液体溢出，焚化回收锅炉中的浓缩废水，将来自回收锅炉的烟道气中存在的颗粒除去，从具有回收锅炉的纤维素纸浆厂中将废水最小化产生包含含有氯化钾和氯化物的盐的灰分和硫化合物，并将灰分中的钾和氯从灰分中除去，同时将含硫化合物返回到回收回路中，以平衡磨机中的硫，氯和钾的含量。在进入回收锅炉之前，硫通常直接返回到黑液流中。从熔体中生产绿液，其优选在去除（例如通过沉淀和/或过滤）之前以及在绿液结晶以产生氢氧化钠之前经处理以从其中除去金属。

3. 发明授权

US5380402A Reducing pulp mill liquid discharge 失效
标题翻译：减少纸浆厂液体排放
公开(公告)号：US5380402A
公开(公告)日：1995-01-10
申请号：US959905
申请日：1992-10-13
申请人： Rolf Ryham , Tuomo S. Nykanen , Brian F. Greenwood , Johan Gullichsen , Erkki Kiiskila , Esko Mattelmaki , Joseph R. Phillips , Jan Richardsen , Jarmo Soderman , Karl G. Wiklund
发明人： Rolf Ryham , Tuomo S. Nykanen , Brian F. Greenwood , Johan Gullichsen , Erkki Kiiskila , Esko Mattelmaki , Joseph R. Phillips , Jan Richardsen , Jarmo Soderman , Karl G. Wiklund
IPC分类号： D21C9/10 , D21C11/00 , D21C11/12
CPC分类号： D21C11/0021 , Y10S159/08 , Y10S162/08
摘要： A pulp mill has zero or minimum liquid discharges. The large amounts of liquid that must be processed to achieve this result are handled utilizing a multiple effect evaporator provided with heat from a steam exhaust of a condensing type steam turbine. Super heated steam from the recovery and bark boilers is fed to the turbine to generate electricity for the production of bleaching chemical and other uses in the mill. Three or four steam exhausts having different composite temperature and pressure values are taken from the turbine and used where most suitable in the pulp mill. For evaporation of bleach plant effluent the steam taken from the turbine preferably has a pressure of about 1-3 psia and a temperature of about 120.degree.-140 .degree. F, and has no significant adverse affect on power generation.
摘要翻译：纸浆厂具有零或最小液体排放。为了实现该结果而必须处理的大量液体利用从冷凝式蒸汽轮机的蒸汽排气口提供热量的多效蒸发器来处理。来自回收和树皮锅炉的超级加热蒸汽被供给到涡轮机以产生用于在磨机中生产漂白化学品和其它用途的电力。从涡轮机取出具有不同复合温度和压力值的三个或四个蒸汽排气口，并在纸浆厂最适合的地方使用。为了蒸发漂白设备的流出物，从涡轮机获取的蒸汽优选具有约1-3psia的压力和约120-140°F的温度，并且对发电没有显着的不利影响。

4. 发明授权

US5374333A Method for minimizing pulp mill effluents 失效
标题翻译：减少纸浆厂废水的方法
公开(公告)号：US5374333A
公开(公告)日：1994-12-20
申请号：US922334
申请日：1992-07-30
申请人： Tuomo S. Nykanen , Brian F. Greenwood , Johan Gullichsen , Erkki Kiiskila , Esko Mattelmaki , Joseph R. Phillips , Jan Richardsen , Rolf Ryham , Jarmo Soderman , Karl G. Wiklund
发明人： Tuomo S. Nykanen , Brian F. Greenwood , Johan Gullichsen , Erkki Kiiskila , Esko Mattelmaki , Joseph R. Phillips , Jan Richardsen , Rolf Ryham , Jarmo Soderman , Karl G. Wiklund
IPC分类号： D21C9/10 , D21C11/00 , D21C11/12
CPC分类号： D21C11/0021 , Y10S162/08
摘要： Apparatus for a pulp and paper mill, and methods of acting on liquid effluents produced in the mill, which minimizes the discharge of polluting gaseous and liquid effluents to the environment. Liquid effluents from the bleach plant are concentrated (e.g. evaporated), incinerated (e.g. gasified), leached, crystallized (e.g. freeze crystallized) then washed, and then fed to the plant chemical recovery loop. White liquor produced from the recovery boiler melt is fully oxidized and used in place of caustic in the bleach plant. Essentially all sulfuric acid, sulfur dioxide, caustic, and chlorine dioxide necessary for the pulp mill is produced from mill liquid effluents and gas waste streams, on site at the pulp mill. Typical bleaching sequences that can be used are DE.sub.op D.sub.n D, or AZE.sub.o PZP.
摘要翻译：用于纸浆和造纸厂的设备，以及作用于在磨机中产生的液体流出物上的方法，其最大限度地减少污染的气态和液体流出物排放到环境中。来自漂白设备的液体流出物被浓缩（例如蒸发），焚化（例如气化），沥滤，结晶（例如冷冻结晶），然后洗涤，然后进料至植物化学回收循环。从回收锅炉熔体产生的白液被完全氧化并用于漂白设备中的苛性碱。纸浆厂所必需的硫酸，二氧化硫，苛性碱和二氧化氯基本上都是从磨浆液流出物和废气流中产生的。可以使用的典型漂白序列是DEopDnD或AZEoPZP。

5. 发明授权

US5547543A Apparatus for minimizing effluent discharges and recovering chemicals in a pulp mill 失效
标题翻译：用于最大程度减少废纸浆排放和在纸浆厂回收化学品的设备
公开(公告)号：US5547543A
公开(公告)日：1996-08-20
申请号：US274091
申请日：1994-07-12
申请人： Tuomo S. Nykanen , Brian F. Greenwood , Johan Gullichsen , Erkki Kiiskila , Esko Mattelmaki , Joseph R. Phillips , Jan Richardsen , Rolf Ryham , Jarmo Soderman , Karl Wiklund
发明人： Tuomo S. Nykanen , Brian F. Greenwood , Johan Gullichsen , Erkki Kiiskila , Esko Mattelmaki , Joseph R. Phillips , Jan Richardsen , Rolf Ryham , Jarmo Soderman , Karl Wiklund
IPC分类号： D21C9/10 , D21C11/00 , D21C11/12
CPC分类号： D21C11/0021 , Y10S162/08
摘要： Apparatus for a pulp and paper mill, and methods of acting on liquid effluents produced in the mill, which minimizes the discharge of polluting gaseous and liquid effluents to the environment. Liquid effluents from the bleach plant are concentrated (e.g. evaporated), incinerated (e.g. gasified), leached, crystallized (e.g. freeze crystallized) then washed, and then fed to the plant chemical recovery loop. White liquor produced from the recovery boiler melt is fully oxidized and used in place of caustic in the bleach plant. Essentially all sulfuric acid, sulfur dioxide, caustic, and chlorine dioxide necessary for the pulp mill is produced from mill liquid effluents and gas waste streams, on site at the pulp mill. Typical bleaching sequences that can be used are DE.sub.op D.sub.n D, or AZE.sub.o PZP.
摘要翻译：用于纸浆和造纸厂的设备，以及作用于在磨机中产生的液体流出物上的方法，其最大限度地减少污染的气态和液体流出物排放到环境中。来自漂白设备的液体流出物被浓缩（例如蒸发），焚化（例如气化），沥滤，结晶（例如冷冻结晶），然后洗涤，然后进料至植物化学回收循环。从回收锅炉熔体产生的白液被完全氧化并用于漂白设备中的苛性碱。纸浆厂所必需的硫酸，二氧化硫，苛性碱和二氧化氯基本上都是从磨浆液流出物和废气流中产生的。可以使用的典型漂白序列是DEopDnD或AZEo PZP。

6. 发明授权

US5149448A Method and apparatus for thickening lime sludge 失效
标题翻译：用于增稠泥浆的方法和装置
公开(公告)号：US5149448A
公开(公告)日：1992-09-22
申请号：US688086
申请日：1991-04-22
申请人： Esko Mattelmaki
发明人： Esko Mattelmaki
IPC分类号： B01D33/06 , B01D24/46 , B01D33/073 , B01D33/44 , B01D33/58 , B01D37/02 , C04B2/02
CPC分类号： B01D37/02 , B01D33/073 , B01D2201/282
摘要： A drum filter for thickening lime sludge in which the lime sludge is thickened on a filter layer (precoat) formed by the lime sludge on the filter periphery. The filter is provided with high pressure liquid nozzles continuously reciprocating in the longitudinal direction of the drum in such a way that, during each rotation of the drum, part of the filtering layer is continuously detached and drops into a vat containing the lime sludge.

7. 发明授权

US07207280B2 Combustion air system for recovery boilers, burning spent liquors from pulping processes 有权
标题翻译：用于回收锅炉的燃烧空气系统，从制浆过程燃烧废液
公开(公告)号：US07207280B2
公开(公告)日：2007-04-24
申请号：US10747293
申请日：2003-12-30
申请人： Kari Saviharju , Jorma Simonen , Liisa Simonen , Esa Vakkilainen , Esko Mattelmaki
发明人： Kari Saviharju , Jorma Simonen , Liisa Simonen , Esa Vakkilainen , Esko Mattelmaki
IPC分类号： F23G7/04
CPC分类号： D21C11/12 , F23G7/04 , F23L9/02 , Y02P70/24
摘要： An arrangement is disclosed for supplying an air jet form to the furnace of a recovery boiler, where the furnace has a front wall, a rear wall and side walls. Black liquor spraying devices are disposed on the furnace walls at one or several levels of the furnace. A plurality of air ports are located at several horizontal levels for introducing air into the furnace from an air supply. In the arrangement for the secondary air flows, two horizontal air levels at different elevations are arranged above the lower primary levels and below the black liquor sprayer. Secondary air is supplied from two opposite walls and the air ports from each of the two levels are located so that the air jets are introduced in an interlaced pattern having an even number of jets on one opposite wall and an uneven number of jets on the other opposite wall. The air jets of said at least two air levels are located substantially one above each other in substantially vertical rows.
摘要翻译：公开了一种用于将空气喷射形式提供给回收锅炉的炉的装置，其中炉具有前壁，后壁和侧壁。将黑液喷涂装置设置在炉壁上的一个或多个炉膛上。多个空气端口位于几个水平位置，用于从空气源将空气引入炉中。在二次空气流动的布置中，不同高度处的两个水平空气水平布置在下一级和下方的黑液喷雾器之下。从两个相对的壁供应二次空气，并且从两个水平面中的每一个的空气端口被定位成使得空气射流以一个相对的壁上具有偶数喷射的交错图案被引入，并且在另一个相对的壁上引入不均匀的喷射数对面墙所述至少两个空气水平的空气射流基本上彼此大致垂直地排列。

8. 发明授权

US5366716A Method for recovering sulphur dioxide from the chemical circulation of a sulphate pulp mill 失效
标题翻译：从硫酸盐纸浆厂的化学循环中回收二氧化硫的方法
公开(公告)号：US5366716A
公开(公告)日：1994-11-22
申请号：US983160
申请日：1992-11-30
申请人： Esko Mattelmaki
发明人： Esko Mattelmaki
IPC分类号： B01D1/00 , B01D53/14 , B01D53/34 , B01D53/50 , B01D53/77 , C01B11/02 , C01B17/60 , D21C11/00 , D21C11/04 , D21C11/06 , C01B17/48
CPC分类号： C01B17/60 , B01D53/501 , C01B11/023 , D21C11/0007 , D21C11/06 , Y10S159/08
摘要： Sulphur dioxide is separated from the flue gases of a cellulose pulp mill by absorbing it into a sodium sulphite solution. Sulphur dioxide is regenerated from the sodium bisulphite solution produced by an evaporation-crystallization method utilizing thermo-compressor evaporation technique. A lamella evaporator is utilized as the evaporator-crystallizer, the evaporator being divided into separate compartments for ease of cleaning the lamella surfaces. The recovered concentrated sulphur dioxide can be used wherever desired, for example for the production of chlorine dioxide.
摘要翻译：通过将二氧化硫吸收到亚硫酸钠溶液中，将二氧化硫与纤维素纸浆厂的烟道气分离。二氧化硫由使用热压缩机蒸发技术的蒸发结晶法生产的亚硫酸氢钠溶液再生。利用薄片蒸发器作为蒸发器结晶器，蒸发器被分成独立的隔室，以便于清洁薄片表面。回收的浓二氧化硫可以在需要的地方使用，例如用于生产二氧化氯。

9. 发明授权

US5455328A Method for acidification of soap with sodium bisulphite solution 失效
标题翻译：用亚硫酸氢钠溶液酸化皂的方法
公开(公告)号：US5455328A
公开(公告)日：1995-10-03
申请号：US145507
申请日：1993-11-04
申请人： Olavi Vuorikari , Teemu Tanner , Jukka Koistinen , Kari Sarkkinen , Esko Mattelmaki
发明人： Olavi Vuorikari , Teemu Tanner , Jukka Koistinen , Kari Sarkkinen , Esko Mattelmaki
IPC分类号： C11B13/02 , D21C11/00 , D21C11/06 , B01D17/02
CPC分类号： D21C11/0007 , C11B13/02 , D21C11/06 , Y02W30/74
摘要： The invention relates to acidification of soap, wherein the acidification is performed with a sodium bisulphite solution produced by absorbing the SO.sub.2 entrained in the flue gases obtained from the combustion of odor gases derived from a chemical pulp mill into an alkaline sodium solution which is NaOH or oxidized white liquor, or with a sodium bisulphite solution which is NaHSO.sub.3 -containing mother liquid obtained from SO.sub.2 or NaHSO.sub.3 acidification of soap. The acidification can be conducted in one or more steps and by the cross-current and/or counter-current method by recycling the Na.sub.2 SO.sub.3 mother liquid obtained from the acidification.
摘要翻译：本发明涉及皂的酸化，其中酸化是用亚硫酸氢钠溶液进行的，所述亚硫酸氢钠溶液通过吸收由从化学纸浆磨机衍生的气味气体的燃烧中获得的烟道气中所携带的SO 2而制成的碱式钠溶液是NaOH或氧化白液，或与由SO 2或NaHSO 3酸化肥皂得到的含NaHSO 3的母液的亚硫酸氢钠溶液。酸化可以通过循环从酸化获得的Na 2 SO 3母液，以一个或多个步骤和交叉流和/或逆流方法进行。

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