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1. 发明授权

US4414276A Novel assembly of composite fibers 失效
标题翻译：复合纤维的新型装配
公开(公告)号：US4414276A
公开(公告)日：1983-11-08
申请号：US288202
申请日：1981-07-29
申请人： Tsutomu Kiriyama , Susumu Norota , Yasuhiko Segawa , Shingo Emi , Tadasi Imoto , Toshinori Azumi
发明人： Tsutomu Kiriyama , Susumu Norota , Yasuhiko Segawa , Shingo Emi , Tadasi Imoto , Toshinori Azumi
IPC分类号： B01F5/06 , D01D5/30 , D01D3/00 , D01D5/10 , D01D5/20 , D01D5/28 , D02G3/04
CPC分类号： D01D5/253 , B01F5/0604 , D01D5/30 , Y10S264/75 , Y10T428/2931 , Y10T428/2973 , Y10T428/2976 , Y10T428/2978 , Y10T428/298
摘要： An assembly of fibers composed of at least two dissimilar fiber-forming polymers, characterized by the fact that(1) it consists of numerous fibers,(2) at least 90% of said fibers have a non-circular cross-sectional shape,(3) the cross sections of at least 50% of said fibers differ from each other in at least one of shape and size, and(4) at least 50% of said fibers each have in their cross section taken at right angles to the fiber axis at least two side-by-side coalesced blocks of at least two dissimilar fiber-forming polymer phases with at least a part thereof being exposed to the peripheral surface of the fiber, at least one of the number, shape and size of the blocks varying from fiber to fiber. The assembly of fibers can be produced by extruding a molten macroblend composed of many molten phases of at least two dissimilar fiber-forming polymers through a mesh spinneret having many small openings; and taking up the extrudates from the small openings while cooling them by supplying a cooling fluid to the extrusion surface of said spinneret or to its neighborhood, whereby said extrudates are converted into numerous separated fine fibrous streams and solidified; characterized in that said macroblend is prepared by coalescing many distinct molten phases of at least two dissimilar polymers in such a manner that in a phantom cross section of the molten macroblend taken parallel to the spinneret, there exist many effective continuous boundary lines between the molten phases of dissimilar polymers each of which lines has a length larger than one-fourth of the length of a partitioning member which defines one small opening in the spinneret, whereby said many boundary lines are cut with the partitioning members in the spinneret.
摘要翻译：由至少两种异纤维形成聚合物组成的纤维组合物，其特征在于：（1）它由许多纤维组成，（2）至少90％的所述纤维具有非圆形横截面形状， 3）所述纤维的至少50％的横截面在至少一种形状和尺寸上彼此不同，和（4）至少50％的所述纤维各自具有与纤维成直角的横截面轴至少两个并排聚结的至少两个不同纤维形成聚合物相的块，其至少一部分暴露于纤维的周边表面，块的数量，形状和尺寸中的至少一个从纤维变为纤维。纤维的组装可以通过将具有许多小孔的网眼喷丝头挤出由至少两种不同纤维形成聚合物的许多熔融相组成的熔融大孔混合物来制造; 并通过将冷却流体供应到所述喷丝头的挤出表面或其附近来从小开口处取出挤出物，由此将所述挤出物转化成许多分离的细纤维流并固化; 其特征在于，所述大型共混物通过以至少两种不同的聚合物的许多不同的熔融相聚结来制备，使得在平行于喷丝头的熔融大混合物的幻影横截面中，在熔融相之间存在许多有效的连续边界线不同的聚合物，其中每条线的长度大于在喷丝板中限定一个小开口的分隔件的长度的四分之一，由此在喷丝头中用分隔件切割所述许多边界线。

2. 发明授权

US4568506A Process for producing an assembly of many fibers 失效
标题翻译：用于生产许多纤维的组件的方法
公开(公告)号：US4568506A
公开(公告)日：1986-02-04
申请号：US500229
申请日：1983-06-01
申请人： Tsutomu Kiriyama , Susumu Norota , Yasuhiko Segawa , Shingo Emi , Tadasi Imoto , Toshinori Azumi
发明人： Tsutomu Kiriyama , Susumu Norota , Yasuhiko Segawa , Shingo Emi , Tadasi Imoto , Toshinori Azumi
IPC分类号： B01F5/06 , D01D5/30 , D01D5/32 , B29C47/30 , D01D4/02 , D01D5/40
CPC分类号： D01D5/253 , B01F5/0604 , D01D5/30 , Y10S264/75 , Y10T428/2931 , Y10T428/2973 , Y10T428/2976 , Y10T428/2978 , Y10T428/298
摘要： An assembly of fibers composed of at least two dissimilar fiber-forming polymers, characterized by the fact that(1) it consists of numerous fibers,(2) at least 90% of said fibers have a non-circular cross-sectional shape,(3) the cross-sections of at least 50% of said fibers differ from each other in at least one of shape and size, and(4) at least 50% of said fibers each have in their cross-section taken at right angles to the fiber axis at least two side-by-side coalesced blocks of at least two dissimilar fiber-forming polymer phases with at least a part thereof being exposed to the peripheral surface of the fiber, at least one of the number, shape and size of the blocks varying from fiber to fiber. The assembly of fibers can be produced by extruding a molten macroblend composed of many molten phases of at least two dissimilar fiber-forming polymers through a mesh spinneret having many small openings; and taking up the extrudates from the small openings while cooling them by supplying a cooling fluid to the extrusion surface of said spinneret or to its neighborhood, whereby said extrudates are converted into numerous separated fine fibrous streams and solidified.

3. 发明授权

US4526735A Process for producing fibrous assembly 失效
标题翻译：纤维集合体的制造方法
公开(公告)号：US4526735A
公开(公告)日：1985-07-02
申请号：US465339
申请日：1983-02-09
申请人： Susumu Norota , Yasuhiko Segawa , Tsutomu Kiriyama , Shingo Emi , Tadasi Imoto , Tetsuo Yamauchi
发明人： Susumu Norota , Yasuhiko Segawa , Tsutomu Kiriyama , Shingo Emi , Tadasi Imoto , Tetsuo Yamauchi
IPC分类号： B29C47/12 , B29C47/86 , D01D4/02 , D01D5/08 , D01D13/00 , D01F1/02 , D01F6/60 , B29F3/08
CPC分类号： B29C47/86 , B29C47/0014 , B29C47/12 , B29C47/862 , B29C47/90 , B29C47/908 , D01D13/00 , D01D4/02 , D01D5/08 , D01F1/02 , D01F6/605 , B29C47/0016 , Y10S264/46
摘要： A process and apparatus for producing a fibrous assembly. At least one fiber-forming polymer is extruded through a spinneret having numerous small openings. The process uses a die equipped with a spinneret having numerous closely spaced small openings and an opening ratio (.alpha.) of at least 30%. At least one fiber-forming polymer in the form of a shaped mass having a specified compression resistance is continuously stuffed into said die. Said shaped mass has a shape such that it measures more in one direction than in another. There is passed through the spinneret an electric current sufficient to give said fiber-forming polymer Joule heat required for cutting said polymer by partitioning members defining the numerous small openings of the spinneret. The cut fiber-forming polymer is taken up as fine streams.The present invention provides ultrathick aromatic polyamide fibers having an average cross-sectional area of about 0.01 mm.sup.2 to about 5 mm.sup.2 and comprising at least one fiber-forming aromatic polyamide and an inorganic or metallic fine powder or a fibrous material.
摘要翻译：用于生产纤维集合体的方法和设备。至少一种纤维形成聚合物通过具有许多小孔的喷丝头挤出。该方法使用装备有具有多个紧密间隔的小开口的喷丝头的模具和至少30％的开口率（α）。将具有特定抗压性的成形块形式的至少一种纤维形成聚合物连续地填充到所述模具中。所述成形块具有使得其在一个方向上比另一个方向更多的形状。通过喷丝头使电流足以使所述纤维形成聚合物焦耳热通过限定喷丝头的许多小开口的分隔构件切割所述聚合物所需的热量。切割的纤维形成聚合物被吸收为细小的流。本发明提供平均横截面积为约0.01mm 2至约5mm 2的超薄芳族聚酰胺纤维，并且包含至少一种成纤芳香族聚酰胺和无机或金属细粉或纤维材料。

4. 发明授权

US4399084A Process for producing a fibrous assembly 失效
标题翻译：纤维集合体的制造方法
公开(公告)号：US4399084A
公开(公告)日：1983-08-16
申请号：US293269
申请日：1981-08-17
申请人： Yasuhiko Sagawa , Susumu Norota , Tsutomu Kiriyama , Shingo Emi , Tadasi Imoto , Tetsuo Yamauchi
发明人： Yasuhiko Sagawa , Susumu Norota , Tsutomu Kiriyama , Shingo Emi , Tadasi Imoto , Tetsuo Yamauchi
IPC分类号： D01D4/02 , D01D5/088 , D01D5/20 , D01F6/60 , H05B1/00
CPC分类号： D01D5/20 , D01D4/02 , D01D5/088 , D01F6/605
摘要： The present invention provides a process for producing a fibrous assembly, which comprises extruding a melt of a fiber-forming polymer through a mesh spinneret, said spinneret including many closely arranged small openings and having an opening ratio (.alpha.), represented by the following formula, of at least about 10% ##EQU1## V.sub.a is the total apparent volume of the spinneret which is taken within a unit area of its mesh portion, and V.sub.f is the total volume of partitioning members defining the small openings which is taken within a unit area of the mesh portion of the spinneret; said extrusion being carried out while generating Joule heat in the partitioning members of the spinneret and cooling the vicinity of the extrusion surface of the spinneret by supplying a cooling fluid, whereby the melt is stably converted into fine streams by the partitioning members; and taking up and solidifying the fine streams; and also provides the process wherein the extrusion surface of the spinneret is turned upward so that the normal vector of the extruding surface is reverse to the direction of gravity, and the fine streams extruded from the extrusion surface are taken up against gravity.The present invention provides a molding apparatus for production of a fibrous assembly having a mesh spinneret which has many closely arranged small openings having an opening ratio .alpha. defined by the above formula of at least 10% and the extrusion surface of the spinneret being turned upwardly such that the normal vector of the extrusion surface is reverse to the direction of gravity.
摘要翻译：本发明提供一种纤维集合体的制造方法，该方法包括通过网眼喷丝头挤出成纤聚合物的熔体，所述喷丝头包括许多紧密排列的小孔，并具有开口率（α），由下式，至少约10％，是在其网眼部分的单位面积内拍摄的喷丝头的总表观体积，Vf是限定在单位内的小开口的分隔构件的总体积喷丝板网部分的面积; 所述挤出是在喷丝板的分隔件中产生焦耳热并且通过供应冷却流体冷却喷丝板的挤压表面附近而进行的，从而通过分隔件稳定地将熔体转化成细流; 捡起和凝固细流; 并且还提供了其中喷丝板的挤出表面向上转动使得挤出表面的法向矢量与重力方向相反的过程，并且从挤压表面挤出的细流被克服重力。本发明提供了一种用于生产具有网眼喷丝头的纤维组件的模制设备，其具有许多紧密排列的小开口，其具有由上述公式定义的至少10％的开口比α，并且喷丝头的挤出表面向上转动，挤压表面的法向量与重力方向相反。

5. 发明授权

US4288484A Novel fibrous assembly and process for production thereof 失效
标题翻译：新型纤维集合体及其制造方法
公开(公告)号：US4288484A
公开(公告)日：1981-09-08
申请号：US46753
申请日：1979-06-08
申请人： Susumu Norota , Tsutomu Kiriyama , Tadasi Imoto
发明人： Susumu Norota , Tsutomu Kiriyama , Tadasi Imoto
IPC分类号： B01D39/08 , D04H13/00 , B32B5/12
CPC分类号： B01D39/1623 , B01D39/08 , D04H13/00 , B01D2239/04 , B01D2239/0457 , B01D2239/0464 , B01D2239/0636 , B01D2239/065 , B01D2239/0654 , B01D2239/0668 , B01D2239/0681 , B01D2239/1233 , Y10S264/08 , Y10T428/24124 , Y10T428/24479 , Y10T428/24612 , Y10T428/24802 , Y10T428/2922 , Y10T428/2929 , Y10T428/2973
摘要： A fibrous assembly of many fibers, the individual constituent fibers being interconnected at random in a spaced-apart relationship so that when spread in a direction at right angles to the longitudinal axes of the fibers, said assembly can form a continuous integral reticulated structure; said individual fibers having asymmetrical irregularly-shaped cross sections of substantially different profiles and sizes from one another when said assembly is cut at right angles to the longitudinal axes of the fibers at an arbitrary point therealong; at least 40% of the entire cross-sectional area of each fiber consisting of at least two different polymer phases which are coalesced side-by-side as at least two irregular blocks; and each of the individual fibers of said assembly having a non-uniform cross-sectional shape along its longitudinal axis; fibrous structures prepared from a plurality of such fibrous assemblies; and a process for producing such fibrous assembly.
摘要翻译：许多纤维的纤维集合体，各个构成纤维以间隔的关系随机地相互连接，使得当沿与纤维的纵向轴线成直角的方向扩展时，所述组件可以形成连续的整体网状结构; 所述单根纤维具有不对称的不规则形状的横截面，当所述组件在与所述纤维的纵向轴线成直角的任意点被切割时，彼此具有基本不同的轮廓和尺寸; 由至少两个不同的聚合物相组成的每个纤维的整个横截面积的至少40％，其至少两个不规则块并排聚结; 并且所述组件的各个纤维沿其纵向轴线具有不均匀的横截面形状; 由多个这样的纤维集合体制备的纤维结构; 以及这种纤维集合体的制造方法。

6. 发明授权

US4429006A Filament-like fibers and bundles thereof, and novel process and apparatus for production thereof 失效
标题翻译：丝状纤维及其束，以及其生产方法和设备
公开(公告)号：US4429006A
公开(公告)日：1984-01-31
申请号：US394892
申请日：1982-07-02
申请人： Susumu Norota , Tsutomu Kiriyama , Tadashi Imoto , Toshinori Azumi
发明人： Susumu Norota , Tsutomu Kiriyama , Tadashi Imoto , Toshinori Azumi
IPC分类号： D01D5/20 , D01D5/253 , D02G3/00
CPC分类号： D01D5/30 , D01D5/20 , D01D5/253 , Y10T428/2913 , Y10T428/2922 , Y10T428/2929 , Y10T428/2973 , Y10T428/2976 , Y10T428/2978
摘要： A novel filament composed of at least one thermoplastic synthetic polymer, said filament being characterized by having (1) an irregular variation in the size of its cross section along its longitudinal direction, and (2) a coefficient of intrafilament cross-sectional area variation [CV(F)] of 0.05 to 1.0; and a novel bundle of said filament. The bundle of filament-like fibers can be produced by extruding a melt of a thermoplastic synthetic polymer through a spinneret having numerous small openings, which comprises extruding said melt from said spinneret, said spinneret having such a structure that discontinuous elevations are provided between adjacent small openings on the extruding side of the spinneret, and the melt extruded from one opening can move to and from the melt extruded from another opening adjacent thereto or vice versa through a depression existing between said elevation; and taking up the extrudates from the small openings while cooling them by supplying a cooling fluid to the extrusion surface of said spinneret or its neighborhood, whereby said extrudates are converted into numerous separated fine fibrous streams and solidified.

7. 发明授权

US4355075A Novel filament-like fibers and bundles thereof, and novel process and apparatus for production thereof 失效
标题翻译：新颖的丝状纤维及其束，以及用于生产它的新颖工艺和装置
公开(公告)号：US4355075A
公开(公告)日：1982-10-19
申请号：US133288
申请日：1980-03-24
申请人： Susumu Norota , Tsutomu Kiriyama , Tadashi Imoto , Toshinori Azumi
发明人： Susumu Norota , Tsutomu Kiriyama , Tadashi Imoto , Toshinori Azumi
IPC分类号： D01D5/20 , D01D5/253 , D02G3/00
CPC分类号： D01D5/30 , D01D5/20 , D01D5/253 , Y10T428/2913 , Y10T428/2922 , Y10T428/2929 , Y10T428/2973 , Y10T428/2976 , Y10T428/2978
摘要： A novel filament composed of at least one thermoplastic synthetic polymer, said filament being characterized by having (1) an irregular variation in the size of its cross section along its longitudinal direction, and (2) a coefficient of intrafilament cross-sectional area variation [CV(F)] of 0.05 to 1.0; and a novel bundle of said filament. The bundle of filament-like fibers can be produced by extruding a melt of a thermoplastic synthetic polymer through a spinneret having numerous small openings, which comprises extruding said melt from said spinneret, said spinneret having such a structure that discontinuous elevations are provided between adjacent small openings on the extruding side of the spinneret, and the melt extruded from one opening can move to and from the melt extruded from another opening adjacent thereto or vice versa through a depression existing between said elevation; and taking up the extrudates from the small openings while cooling them by supplying a cooling fluid to the extrusion surface of said spinneret or its neighborhood, whereby said extrudates are converted into numerous separated fine fibrous streams and solidified.
摘要翻译：一种由至少一种热塑性合成聚合物组成的新型细丝，所述长丝的特征在于具有（1）沿着其纵向方向的横截面尺寸的不规则变化，和（2）内部纱线横截面积变化系数[ CV（F）]为0.05〜1.0; 和所述细丝的新颖的束。长丝状纤维束可以通过将热塑性合成聚合物的熔体挤出通过具有许多小孔的喷丝板来制造，该喷丝头包括从所述喷丝头挤出所述熔体，所述喷丝头具有这样的结构，即在相邻的小孔之间设置不连续的高度在喷丝头的挤出侧上的开口，从一个开口挤出的熔体可以移动到从与其相邻的另一开口挤出的熔体或反之亦然，通过存在于所述高度之间的凹陷; 并且通过向所述喷丝头或其附近的挤出表面供应冷却流体来冷却它们从小开口处取出挤出物，由此将所述挤出物转化成许多分离的细纤维流并固化。

8. 发明授权

US4521364A Filament-like fibers and bundles thereof, and novel process and apparatus for production thereof 失效
标题翻译：丝状纤维及其束，以及其生产方法和设备
公开(公告)号：US4521364A
公开(公告)日：1985-06-04
申请号：US394891
申请日：1982-07-02
申请人： Susumi Norota , Tsutomu Kiriyama , Tadashi Imoto , Toshinori Azumi
发明人： Susumi Norota , Tsutomu Kiriyama , Tadashi Imoto , Toshinori Azumi
IPC分类号： D01D5/20 , D01D5/253 , D01D5/088
CPC分类号： D01D5/30 , D01D5/20 , D01D5/253 , Y10T428/2913 , Y10T428/2922 , Y10T428/2929 , Y10T428/2973 , Y10T428/2976 , Y10T428/2978
摘要： A novel filament composed of at least one thermoplastic synthetic polymer, said filament being characterized by having (1) an irregular variation in the size of its cross section along its longitudinal direction, and (2) a coefficient of intrafilament cross-sectional area variation [CV(F)] of 0.05 to 1.0; and a novel bundle of said filament. The bundle of filament-like fibers can be produced by extruding a melt of a thermoplastic synthetic polymer through a spinneret having numerous small openings, which comprises extruding said melt from said spinneret, said spinneret having such a structure that discontinuous elevations are provided between adjacent small openings on the extruding side of the spinneret, and the melt extruded from one opening can move to and from the melt extruded from another opening adjacent thereto or vice versa through a depression existing between said elevation; and taking up the extrudates from the small openings while cooling them by supplying a cooling fluid to the extrusion surface of said spinneret or its neighborhood, whereby said extrudates are converted into numerous separated fine fibrous streams and solidified.

9. 发明授权

US5312851A Wholly aromatic polyamide resin composition having enhanced light resistance 失效
标题翻译：具有增强的耐光性的全芳族聚酰胺树脂组合物
公开(公告)号：US5312851A
公开(公告)日：1994-05-17
申请号：US998010
申请日：1992-12-29
申请人： Toshitsugu Matsuki , Tsutomu Kiriyama , Toshihiro Santa
发明人： Toshitsugu Matsuki , Tsutomu Kiriyama , Toshihiro Santa
IPC分类号： C08K5/16 , C08K5/20 , C08K5/3417 , C08L77/00 , C08L77/10
CPC分类号： C08K5/20 , C08K5/3417
摘要： A light-resistant wholly aromatic polyamide resin composition comprises a light-resisting agent blended to a wholly aromatic polyamide resin and comprising at least one naphthalene ring structure-containing compound of the formula (I): ##STR1## wherein Ar.sub.1, Ar.sub.2, Ar.sub.3 =a divalent organic group, X=an amide bond group (--CONH), Y=an amide bond group or an imide bond group ##STR2## A and B=a monovalent organic group when Y=an amide bond group, or =a divalent organic group when Y=an imide bond group, n=1 to 10, and at least one of Ar.sub.1, Ar.sub.2, Ar.sub.3, A and B has a naphthalene ring structure.
摘要翻译：耐光全芳族聚酰胺树脂组合物包含与全芳香族聚酰胺树脂混合并包含至少一种含萘环结构的式（I）化合物的耐光剂：其中Ar 1，Ar 2 ，Ar 3 =二价有机基团，X =酰胺键基（-CONH），Y =酰胺键基或酰亚胺键基团A和B =当Y =酰胺键基团时的单价有机基团，或 = Y =酰亚胺键合基团时的二价有机基团，n = 1〜10，Ar 1，Ar 2，Ar 3，A和B中的至少1个具有萘环结构。

10. 发明授权

US4539389A Biaxially oriented polyester film 失效
标题翻译：双轴取向聚酯薄膜
公开(公告)号：US4539389A
公开(公告)日：1985-09-03
申请号：US593237
申请日：1984-03-26
申请人： Tsutomu Kiriyama , Shigeru Horie , Tetsuo Ichihashi , Masahiro Oshida
发明人： Tsutomu Kiriyama , Shigeru Horie , Tetsuo Ichihashi , Masahiro Oshida
IPC分类号： C08J5/18 , G11B5/73 , C08G63/02
CPC分类号： C08J5/18 , G11B5/7305 , C08J2367/02 , Y10S428/90 , Y10T428/31786
摘要： A biaxially oriented film of a film-forming aromatic polyester derived from an aromatic dicarboxylic acid as a main acid component and an aliphatic glycol as a main glycol component, said film having surface properties such that(1) it has a surface flatness, R.sub.CLA, of from 0.001 to 0.016 micron,(2) it has a coefficient of travelling friction, .mu.k, of from 0.01 to 0.20, and(3) the following relation is established between R.sub.CLA and .mu.k,0.10.ltoreq.10.times.R.sub.CLA +.mu.k.ltoreq.0.31.Preferably, said film has many minute protrusions on its surface which are attributed to fine particles of titanium dioxide or of both titanium dioxide and calcium carbonate, and has such further surface property that(4) a distribution curve showing the relation between the heights of said many protrusions on the film surface and the numbers of the protrusions having the respective heights does not cross a straight line represented by the following equation (1)log.sub.10 y=-8.0.times.+4.34 (1)where x and y are as defined above, within the range of log.sub.10 >1.
摘要翻译：由作为主要成分的芳香族二羧酸和作为主要二醇成分的脂肪族二醇衍生的成膜性芳香族聚酯的双轴取向膜，具有表面特性使得（1）具有表面平坦性，RCLA，为0.001〜0.016微米，（2）其行摩擦系数μk为0.01〜0.20，（3）RCLA与μk之间的关系如下：0.10 1的范围。

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