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    • 2. 发明授权
    • Copolyamide production method
    • 共聚酰胺生产方法
    • US5587447A
    • 1996-12-24
    • US417118
    • 1995-04-05
    • Masahiro HaradaYasuo Inaba
    • Masahiro HaradaYasuo Inaba
    • C08G69/26C08G69/28
    • C08G69/265C08G69/28
    • A method for producing a copolyamide, which comprises (1) heating either one dicarboxylic acid selected from the group consisting of adipic acid and a mixture containing 40 mol % or more of adipic acid to a temperature higher than the melting point of adipic acid but lower than a temperature lower by 30.degree. C. than the melting point of the resulting copolyamide, (2) dropping a diamine comprising paraxylylene diamine and metaxylylene diamine into the heated dicarboxylic acid before a conversion of the dicarboxylic acid reaches 90 mol %, (3) stopping dropping of the diamine before the conversion of the dicarboxylic acid reaches 90 mol %, and dropping metaxylylene diamine or a diamine mixture of metaxylylene diamine and paraxylylene diamine in place of the diamine until a molar ratio of the total of the diamines to the total of the dicarboxylic acids becomes 0.97 to 1.03, and (4) heating a reaction system to a temperature higher than a temperature lower by 30.degree. C. than the melting point of the finally formed copolyamide before the conversion of the dicarboxylic acid reaches 95 mol %, and elevating the temperature of the reaction system to a temperature higher than the melting point of the finally formed copolyamide upon termination of dropping the diamine.
    • 一种制备共聚酰胺的方法,其包括(1)将选自己二酸和含40mol%或更多己二酸的混合物中的一种二羧酸加热至高于己二酸熔点但较低的温度 比所得共聚酰胺的熔点低30℃的温度,(2)在二羧酸的转化率达到90摩尔%之前,将包含对二甲苯二胺和间苯二胺的二胺滴加到加热的二羧酸中,(3) 在二羧酸转化率达到90mol%之前停止二胺的滴加,并滴加二亚甲基二胺或二亚胺二甲苯与二亚胺二胺混合物代替二胺,直到二胺的总量与总二胺的摩尔比 二羧酸变为0.97〜1.03,(4)将反应体系加热到比熔点低30℃的温度 的最终形成的共聚酰胺在二羧酸转化率达到95mol%之前,并且当终止滴加二胺时,将反应体系的温度升高到高于最终形成的共聚酰胺的熔点的温度。