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    • 9. 发明申请
    • POSITIVE ELECTRODE FOR LITHIUM SECONDARY BATTERIES AND LITHIUM SECONDARY BATTERY
    • 锂二次电池和锂二次电池的正极
    • US20100297503A1
    • 2010-11-25
    • US12783746
    • 2010-05-20
    • Kan KitagawaAtsushi UedaToyotaka YuasaTatsuya Toyama
    • Kan KitagawaAtsushi UedaToyotaka YuasaTatsuya Toyama
    • H01M4/58
    • H01M4/5825H01M4/136H01M4/621H01M10/0525
    • A positive electrode for lithium secondary batteries and a lithium secondary battery are provided in which, by using an olivine Mn based positive-electrode active material and an optimal binder for the olivine Mn based positive-electrode active material, peel-off of the electrode and gelatinization of the slurry can be prevented, with large energy density, excellent in rate characteristic and cycle life. The positive electrode includes a positive-electrode composite including at least a positive-electrode active material and a binder; and a positive-electrode current collector. The positive-electrode active material includes a lithium composite oxide having an olivine-type structure, which is represented by the formula LiMnxM1−xPO4 (where 0.3≦x≦1 and M is one or more elements selected from the group consisting of Li, Fe, Ni, Co, Ti, Cu, Zn, Mg, and Zr) . The binder includes an acrylonitrile-based copolymer.
    • 提供了一种锂二次电池用正极和锂二次电池,其中,通过使用橄榄石Mn系正极活性物质和橄榄石Mn系正极活性物质的最佳粘合剂,电极剥离和 可以防止浆料糊化,能量密度大,速率特性和循环寿命优异。 正极包括至少包含正极活性物质和粘合剂的正极复合体; 和正极集电体。 正极活性物质包括具有橄榄石型结构的锂复合氧化物,其由式LiMn x M 1-x PO 4表示(其中,0.3< 1lE; x≦̸ 1和M是选自Li, Fe,Ni,Co,Ti,Cu,Zn,Mg和Zr)。 粘合剂包括丙烯腈基共聚物。