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    • 1. 发明申请
    • Thermoplastic polymer powder
    • 热塑性聚合物粉末
    • US20060036030A1
    • 2006-02-16
    • US10533808
    • 2003-10-30
    • Toyoaki KuriharaKenichi Hamda
    • Toyoaki KuriharaKenichi Hamda
    • C08L51/08C08F297/02C08G63/91
    • C08F297/026B29C41/003B29C41/18C08L53/00
    • A thermoplastic polymer powder which (i) consists mainly of an acrylic block copolymer comprising one or more acrylic ester polymer blocks (A) and bonded thereto at least one polymer block selected among methacrylic ester polymer blocks (B) and acrylic ester polymer blocks (C) differing in structure from the blocks (A); (ii) has a complex dynamic viscosity η*(5) of 5.0×103 Pa.s or lower as measured under the conditions of a temperature of 250° C. and an oscillation frequency of 5 rad/sec; (iii) has a Newtonian viscosity index n represented by the equation n=log η*(5)-log η*(50) [wherein η*(5) and η*(50) indicate the complex dynamic viscosities (unit, Pa.s) as measured under the conditions of a temperature of 250° C. and oscillation frequencies of 5 and 50 rad/sec, respectively] of 0.50 or smaller; and (iv) has an average particle diameter of 1 mm or smaller. The thermoplastic polymer powder is suitable for use in molding techniques employing a powder, such as slush molding and in powder coating. A molding, skin material, and the like which are excellent in weatherability, flexibility, mechanical strength, low-temperature properties, adhesion to polar resins, rubber elasticity, safety, etc. can be smoothly produced from the powder.
    • 一种热塑性聚合物粉末,其主要由包含一种或多种丙烯酸酯聚合物嵌段(A)的丙烯酸嵌段共聚物组成并与至少一种选自甲基丙烯酸酯聚合物嵌段(B)和丙烯酸酯聚合物嵌段(C) )结构与块(A)不同; (ii)在250℃的温度和5rad / min的温度条件下测定的复数动态粘度η(5)为5.0×10 3 Pa以下, 秒 (iii)具有由等式n = log eta *(5)-log eta *(50)表示的牛顿粘度指数n [其中eta *(5)和eta *(50)表示复数动态粘度(单位Pa .s)在温度250℃,振荡频率分别为5和50弧度/秒的条件下测定]为0.50以下; 和(iv)的平均粒径为1mm以下。 热塑性聚合物粉末适用于使用粉末的成型技术,例如搪塑和粉末涂料。 可以从粉末中平滑地制造耐候性,柔软性,机械强度,低温性,与极性树脂的粘合性,橡胶弹性,安全性等优异的成型品,表皮材料等。
    • 2. 发明申请
    • THERMOPLASTIC POLYMER POWDER
    • 热塑性聚合物粉末
    • US20090152383A1
    • 2009-06-18
    • US12370875
    • 2009-02-13
    • Toyoaki KURIHARAKenichi Hamda
    • Toyoaki KURIHARAKenichi Hamda
    • B02C23/18
    • C08F297/026B29C41/003B29C41/18C08L53/00
    • A thermoplastic polymer powder which (i) consists mainly of an acrylic block copolymer comprising one or more acrylic ester polymer blocks (A) and bonded thereto at least one polymer block selected among methacrylic ester polymer blocks (B) and acrylic ester polymer blocks (C) differing in structure from the blocks (A); (ii) has a complex dynamic viscosity η*(5) of 5.0×103 Pa·s or lower as measured under the conditions of a temperature of 250° C. and an oscillation frequency of 5 rad/sec; (iii) has a Newtonian viscosity index n represented by the equation n=log η*(5)−log η*(50) [wherein η*(5) and η*(50) indicate the complex dynamic viscosities (unit, Pa·s) as measured under the conditions of a temperature of 250° C. and oscillation frequencies of 5 and 50 rad/sec, respectively] of 0.50 or smaller; and (iv) has an average particle diameter of 1 mm or smaller. The thermoplastic polymer powder is suitable for use in molding techniques employing a powder, such as slush molding and in powder coating. A molding, skin material, and the like which are excellent in weatherability, flexibility, mechanical strength, low-temperature properties, adhesion to polar resins, rubber elasticity, safety, etc. can be smoothly produced from the powder.
    • 一种热塑性聚合物粉末,其主要由包含一种或多种丙烯酸酯聚合物嵌段(A)的丙烯酸嵌段共聚物组成并与至少一种选自甲基丙烯酸酯聚合物嵌段(B)和丙烯酸酯聚合物嵌段(C) )结构与块(A)不同; (ii)在250℃的温度和5rad / sec的振荡频率的条件下测定的复数动态粘度η(5)为5.0×10 3 Pa·s以下; (iii)具有由等式n = log eta *(5)-log eta *(50)表示的牛顿粘度指数n [其中eta *(5)和eta *(50)表示复数动态粘度(单位Pa .s)在温度250℃,振荡频率分别为5和50弧度/秒的条件下测定]为0.50以下; 和(iv)的平均粒径为1mm以下。 热塑性聚合物粉末适用于使用粉末的成型技术,例如搪塑和粉末涂料。 可以从粉末中平滑地制造耐候性,柔软性,机械强度,低温性,与极性树脂的粘合性,橡胶弹性,安全性等优异的成型品,表皮材料等。