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1. 发明授权

US06737145B1 Organic-inorganic composite graded material, method for preparation thereof and use thereof 失效
标题翻译：有机 - 无机复合分级材料，其制备方法和用途
公开(公告)号：US06737145B1
公开(公告)日：2004-05-18
申请号：US09807904
申请日：2001-06-08
申请人： Toshiya Watanabe , Kazuhito Hashimoto , Akira Fujishima , Kazuyuki Takami , Norihiro Nakayama , Taro Suzuki , Naoki Tanaka , Eisuke Tachibana , Tatsuhiko Adachi
发明人： Toshiya Watanabe , Kazuhito Hashimoto , Akira Fujishima , Kazuyuki Takami , Norihiro Nakayama , Taro Suzuki , Naoki Tanaka , Eisuke Tachibana , Tatsuhiko Adachi
IPC分类号： B32B514
CPC分类号： C08F8/42 , Y10T428/31504 , Y10T428/31855 , Y10T428/31935
摘要： The present invention is concerned with an organic-inorganic composite graded material containing a composite material formed by chemically bonding an organic polymer compound and a metallic compound and having a component graded structure in which the content of the metallic compound continuously changes in the depth direction from the material surface, a process for the production of the above organic-inorganic composite graded material by forming a coating layer composed of a specific coating solution for forming the organic-inorganic composite film on an organic substrate and drying the coating layer under heat, a coating agent composed of the above organic-inorganic composite graded material for forming a coating film, and an article coated with the above coating agent.
摘要翻译：本发明涉及含有通过化学键合有机高分子化合物和金属化合物形成的复合材料的有机 - 无机复合分级材料，并且具有其中金属化合物的含量在深度方向上连续变化的组分渐变结构材料表面，通过在有机基材上形成有机无机复合膜的特定涂布溶液形成涂层并在加热下干燥涂层来生产上述有机 - 无机复合分级材料的方法，由上述用于形成涂膜的有机 - 无机复合分级材料组成的涂布剂和涂覆有上述涂布剂的制品。

2. 发明申请

US20090297799A1 ANTIFOULING PRINTING SHEET 审中-公开
标题翻译：防伪印刷
公开(公告)号：US20090297799A1
公开(公告)日：2009-12-03
申请号：US11917648
申请日：2006-06-21
申请人： Takayoshi Nakasone , Norihiro Nakayama , Shinji Tanaka , Naoki Tanaka , Kazuyuki Takami
发明人： Takayoshi Nakasone , Norihiro Nakayama , Shinji Tanaka , Naoki Tanaka , Kazuyuki Takami
IPC分类号： B32B5/00 , B32B9/00
CPC分类号： B41M5/504 , B41M5/502 , B41M5/506 , Y10T428/24802 , Y10T428/24851 , Y10T428/266 , Y10T428/31504 , Y10T428/31786
摘要： The present invention provides an anti-fouling printing sheet, characterized by including a transparent support sheet, a hydrophilic anti-fouling layer provided on one side of the support sheet, and a printing surface provided on the opposite side of the support sheet; and an anti-fouling printed product and printed object having an image printed thereon. The anti-fouling printing sheet, printed product, and printed object exhibit a self-cleaning property based on a photocatalytic action for a long period of time.
摘要翻译：本发明提供一种防污印刷用纸，其特征在于，包括透明支撑片，设置在所述支持片的一侧的亲水性防污层和设置在所述支撑片的相反侧的印刷面; 以及具有打印在其上的图像的防污印刷产品和印刷对象。防污印刷用纸，印刷品和印刷品长时间地表现出基于光催化作用的自清洁性。

3. 发明授权

US5750258A Crosslinked resin-coated silica fine particles and process for the production thereof 失效
标题翻译：交联树脂涂覆二氧化硅微粒及其制备方法
公开(公告)号：US5750258A
公开(公告)日：1998-05-12
申请号：US553442
申请日：1995-11-21
申请人： Kazuhiko Sakai , Tatsuhiko Adachi , Norihiro Nakayama , Kenichi Fujino
发明人： Kazuhiko Sakai , Tatsuhiko Adachi , Norihiro Nakayama , Kenichi Fujino
IPC分类号： C08F292/00 , C08K9/06 , C08K9/08 , C09C1/30 , G02F1/1339 , B32B5/16 , B05D7/00
CPC分类号： C08K9/08 , C08F292/00 , C08K9/06 , C09C1/3081 , C09C1/309 , C01P2004/32 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2004/86 , C01P2006/90 , G02F1/1339 , Y10T428/2995 , Y10T428/2998
摘要： The present invention relates to crosslinked resin-coated silica fine particles each of which has a crosslinked resin coating formed of a structure of a single layer or a plurality of layers formed on the surface of each calcined silica fine particle through a vinyl-containing silane coupling agent, and the crosslinked resin-coated silica fine particles of the present invention have characteristic features in that the peeling of the resin coatings substantially do not occur when they are dispersed in a dispersing medium with ultrasonic vibration, and that they substantially do not move after the formation of a liquid crystal cell and substantially do not affect a liquid crystal itself and its orientation when used as a spacer for a liquid crystal display device.
摘要翻译： PCT No.PCT / JP95 / 00685 Sec。 371日期：1995年11月21日 102（e）1995年11月21日PCT PCT 1995年4月7日提交PCT公布。出版物WO95 / 27680 日期：1995年10月19日本发明涉及交联树脂被覆二氧化硅微粒，其中，所述交联树脂被覆二氧化硅微粒具有通过以下方式形成的交联树脂涂层：由煅烧二氧化硅微粒表面形成的单层或多层结构，含乙烯基的硅烷偶联剂和本发明的交联树脂包覆的二氧化硅微粒具有特征，其特征在于当它们以超声波振动分散在分散介质中时基本上不会发生树脂涂层的剥离，并且它们在用作液晶显示装置的间隔物之后基本上不会移动液晶单元，并且基本上不影响液晶本身及其取向。

4. 发明授权

US06194069B1 Process for the production of coated particles 失效
标题翻译：生产涂层颗粒的方法
公开(公告)号：US06194069B1
公开(公告)日：2001-02-27
申请号：US09363398
申请日：1999-07-29
申请人： Tatsuhiko Adachi , Kazuhiko Sakai , Norihiro Nakayama , Kenichi Fujino , Hidekazu Takagi
发明人： Tatsuhiko Adachi , Kazuhiko Sakai , Norihiro Nakayama , Kenichi Fujino , Hidekazu Takagi
IPC分类号： B32B516
CPC分类号： B01J2/003 , G02F1/1339 , Y10T428/2991 , Y10T428/2993
摘要： A process for the production of insulator-coated black particles, which comprises the steps of (1-a) dispersing particles of silica or a metal oxide in an alcohol-based solvent consisting mainly of an intermediate alcohol to obtain a dispersion of the above particles, (1-c) forming a titanium oxide coating of TiO2 on the surface of each of the particles whose surfaces have been activated in the above step, to obtain titanium oxide-coated particles, (1-d) calcining the titanium oxide-coated particles obtained in the above step in a reducing and/or nitriding atmosphere and thereby blackening the above titanium oxide coatings to obtain black particles, and (1-e) forming an electrical insulator coating on a surface of each of the black particles obtained in the above step, to obtain insulator-coated black particles; characerized in that the process includes a step of (1-b) adding an alkaline aqueous solution to the dispersion obtained instep (1-a) to activate a surface of each of the particles of a metal oxide.
摘要翻译：一种制备绝缘体涂覆的黑色颗粒的方法，其包括以下步骤：（1-a）将二氧化硅或金属氧化物的颗粒分散在主要由中间体醇组成的醇基溶剂中以获得上述颗粒的分散体，（1-c）在上述步骤中已经活化表面的每个颗粒的表面上形成TiO 2的氧化钛涂层，以获得氧化钛涂覆的颗粒（1-d），煅烧氧化钛涂覆在上述步骤中获得的颗粒在还原和/或氮化气氛中，从而使上述氧化钛涂层变黑以获得黑色颗粒，和（1-e）在每个黑色颗粒的表面上形成电绝缘体涂层上述步骤，获得绝缘体涂覆的黑色颗粒; 其特征在于，该方法包括（a-b）将碱性水溶液加入到所得到的分散体（1-a）中以活化金属氧化物的每个颗粒的表面的步骤。

5. 发明授权

US6013369A Process for the production of titanium oxide coated particles 失效
标题翻译：生产氧化钛涂层颗粒的方法
公开(公告)号：US6013369A
公开(公告)日：2000-01-11
申请号：US684745
申请日：1996-07-22
申请人： Tatsuhiko Adachi , Kazuhiko Sakai , Norihiro Nakayama , Kenichi Fujino , Hidekazu Takagi , Takako Sakai , Mitsumasa Kimata
发明人： Tatsuhiko Adachi , Kazuhiko Sakai , Norihiro Nakayama , Kenichi Fujino , Hidekazu Takagi , Takako Sakai , Mitsumasa Kimata
IPC分类号： B01J2/00 , G02F1/1339 , B32B5/16 , B01J13/04 , B05D3/02
CPC分类号： B01J2/003 , G02F1/1339 , Y10T428/2991 , Y10T428/2993
摘要： A process for the production of insulator-coated black particles, which comprises the steps of(1-a) dispersing particles of silica or a metal oxide in an alcohol-based solvent consisting mainly of an intermediate alcohol to obtain a dispersion of the above particles,(1-c) forming a titanium oxide coating of TiO.sub.2 on the surface of each of the particles whose surfaces have been activated in the above step, to obtain titanium oxide-coated particles,(1-d) calcining the titanium oxide-coated particles obtained in the above step in a reducing and/or nitriding atmosphere and thereby blackening the above titanium oxide coatings to obtain black particles, and(1-e) forming an electrical insulator coating on a surface of each of the black particles obtained in the above step, to obtain insulator-coated black particles; characterized in that the process includes a step of(1-b) adding an alkaline aqueous solution to the dispersion obtained in step (1-a) to activate a surface of each of the particles of a metal oxide.
摘要翻译：一种制备绝缘体涂覆的黑色颗粒的方法，其包括以下步骤：（1-a）将二氧化硅或金属氧化物的颗粒分散在主要由中间体醇组成的醇基溶剂中以获得上述颗粒的分散体，（1-c）在上述步骤中已经活化表面的每个颗粒的表面上形成TiO 2的氧化钛涂层，以获得氧化钛涂覆的颗粒（1-d），煅烧氧化钛涂覆在上述步骤中获得的颗粒在还原和/或氮化气氛中，从而使上述氧化钛涂层变黑以获得黑色颗粒，和（1-e）在每个黑色颗粒的表面上形成电绝缘体涂层上述步骤，获得绝缘体涂覆的黑色颗粒; 其特征在于，所述方法包括（a-b）向在步骤（1-a）中得到的分散体中加入碱性水溶液以活化金属氧化物颗粒的表面的步骤。

6. 发明授权

US07488524B2 High-durability photocatalyst film and structure having photocatalytic functions on surface 失效
标题翻译：高耐久性光催化膜及其表面具有光催化功能的结构
公开(公告)号：US07488524B2
公开(公告)日：2009-02-10
申请号：US10522915
申请日：2003-07-30
申请人： Ryouzo Nishikawa , Naoki Tanaka , Norihiro Nakayama
发明人： Ryouzo Nishikawa , Naoki Tanaka , Norihiro Nakayama
IPC分类号： B32B9/00 , B32B33/00
CPC分类号： B32B27/36 , B01J21/063 , B01J35/004 , B01J37/0217 , B01J37/0219 , B32B7/06 , B32B27/08 , B32B27/18 , B32B27/308 , B32B37/26 , B32B2037/268 , B32B2038/0076 , B32B2255/10 , B32B2255/28 , B32B2307/412 , B32B2307/712 , B32B2307/7145 , B32B2551/08 , B32B2590/00 , B32B2605/006 , Y10S428/913 , Y10T428/14 , Y10T428/1462 , Y10T428/1471 , Y10T428/1476 , Y10T428/149 , Y10T428/266
摘要： A high-durability photocatalyst film that is a laminated film comprising a substrate film and a photocatalytically active material layer formed thereon via a protective layer, wherein the substrate film is a film having specific performances in a weather resistance test with a sunshine weatherometer, the protective layer is an organic-inorganic composite graded film and the above laminated film exhibits specific performances in an accelerated weather resistance test with a sunshine weatherometer, and a structure having photocatalytic functions on a surface formed of the above photocatalyst film.
摘要翻译：一种高耐久性光催化剂膜，其是通过保护层在其上形成的基板膜和光催化活性物质层的层压膜，其中，基板膜是在耐候性试验中具有特定性能的膜，其具有阳光耐候性，保护性层是有机 - 无机复合分级膜，上述层压膜在日照老化试验机的加速耐候性试验中具有特定的性能，在由上述光催化剂膜形成的表面上具有光催化功能的结构。

7. 发明申请

US20050249943A1 High durabel photocatalyst film and structure having surface exhibiting photocatalytic function 失效
标题翻译：具有表现出光催化功能的高Durabel光催化膜和结构
公开(公告)号：US20050249943A1
公开(公告)日：2005-11-10
申请号：US10522915
申请日：2003-07-30
申请人： Ryouzo Nishikawa , Naoki Tanaka , Norihiro Nakayama
发明人： Ryouzo Nishikawa , Naoki Tanaka , Norihiro Nakayama
IPC分类号： B32B1/00 , B32B7/02 , B32B27/36
CPC分类号： B32B27/36 , B01J21/063 , B01J35/004 , B01J37/0217 , B01J37/0219 , B32B7/06 , B32B27/08 , B32B27/18 , B32B27/308 , B32B37/26 , B32B2037/268 , B32B2038/0076 , B32B2255/10 , B32B2255/28 , B32B2307/412 , B32B2307/712 , B32B2307/7145 , B32B2551/08 , B32B2590/00 , B32B2605/006 , Y10S428/913 , Y10T428/14 , Y10T428/1462 , Y10T428/1471 , Y10T428/1476 , Y10T428/149 , Y10T428/266
摘要： A high-durability photocatalyst film that is a laminated film comprising a substrate film and a photocatalytically active material layer formed thereon via a protective layer, wherein the substrate film is a film having specific performances in a weather resistance test with a sunshine weatherometer, the protective layer is an organic-inorganic composite graded film and the above laminated film exhibits specific performances in an accelerated weather resistance test with a sunshine weatherometer, and a structure having photocatalytic functions on a surface formed of the above photocatalyst film.
摘要翻译：一种高耐久性光催化剂膜，其是通过保护层在其上形成的基板膜和光催化活性物质层的层压膜，其中，基板膜是在耐候性试验中具有特定性能的膜，其具有阳光耐候性，保护性层是有机 - 无机复合分级膜，上述层压膜在日照老化试验机的加速耐候性试验中具有特定的性能，在由上述光催化剂膜形成的表面上具有光催化功能的结构。

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