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1. 发明授权

US06214954B1 Olefin polymerization catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US06214954B1
公开(公告)日：2001-04-10
申请号：US08849835
申请日：1997-06-12
申请人： Yu Nitto , Tokitaka Kaneshima , Toshiya Aoki
发明人： Yu Nitto , Tokitaka Kaneshima , Toshiya Aoki
IPC分类号： C08F442
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , Y10S526/943
摘要： Disclosed is an olefin polymerization catalyst comprising: a transition metal compound comprising one transition metal selected from the group consisting of Ti, Zr and Hf, and at least two ligands, wherein one ligand is a group having a cyclopentadienyl skeleton, and the remaining at least one ligand is a monovalent, bidentate, anionic chelating ligand having two coordinating atoms each coordinated to the transition metal, one of which atoms is selected from the group consisting of O, S, Se and Te, and the other of which atoms is selected from the group consisting of N, S, Se and Te, and wherein one of the remaining at least one ligand is optionally bonded to the group having a cyclopentadienyl skeleton through a bridging group. Also disclosed is a method for efficiently producing an olefin homopolymer or olefin copolymer by using this catalyst. By polymerizing an olefin using the olefin polymerization catalyst of the present invention, there can be advantageously produced an olefin homopolymer having a narrow molecular weight distribution or an olefin copolymer having not only a narrow molecular weight distribution but also a uniform copolymerization distribution. The produced polymer has high impact strength, high resistance to stress cracking, high transparency, excellent heat sealing properties at low temperatures, high blocking resistance, low tackiness, low extractability and the like.
摘要翻译：公开了一种烯烃聚合催化剂，其包括：包含一种选自Ti，Zr和Hf的过渡金属的过渡金属化合物和至少两个配体，其中一个配体是具有环戊二烯基骨架的基团，其余至少一个配位体是具有两个与过渡金属配位的两个配位原子的单价二齿阴离子螯合配体，其中一个原子选自O，S，Se和Te，其中原子选自由N，S，Se和Te组成的组，并且其中剩余的至少一种配体之一任选地通过桥连基团与具有环戊二烯基骨架的基团键合。还公开了通过使用该催化剂有效地制备烯烃均聚物或烯烃共聚物的方法。通过使用本发明的烯烃聚合催化剂聚合烯烃，可以有利地制备具有窄分子量分布的烯烃均聚物或不仅具有窄分子量分布而且具有均匀共聚分布的烯烃共聚物。所生产的聚合物具有高冲击强度，高抗应力开裂性，高透明性，低温下的热封性优异性，耐粘连性，低粘性，低萃取性等优异性。

2. 发明授权

US5817724A Olefin polymerization method using a highly active catalyst having a multidentate ligand 失效
标题翻译：使用具有多齿配体的高活性催化剂的烯烃聚合方法
公开(公告)号：US5817724A
公开(公告)日：1998-10-06
申请号：US786657
申请日：1997-01-21
申请人： Toshiya Aoki , Tokitaka Kaneshima
发明人： Toshiya Aoki , Tokitaka Kaneshima
IPC分类号： C08F4/42 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/00 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F2420/02 , C08F2420/05 , C08F4/6192 , C08F4/659 , C08F4/65912 , C08F4/6592
摘要： Disclosed is an olefin polymerization method using a highly active catalyst comprising a transition metal selected from metals of Groups IIIA including the lanthanide series, IVA, VA, VIA, VIIA and VIII of the Periodic Table of the Elements, and ligands L.sup.1 and L.sup.2 bonded thereto, wherein a combination of L.sup.1 and L.sup.2 is (1) a combination of ligand L.sup.1 which is a group containing at least one phosphorus-containing group and ligand L.sup.2 which is a ligand having a .sigma.-bond, or a ligand having a .sigma.-bond and a bond selected from at least one .pi.-bond and at least one lone electron pair donative bond; (2) a combination of ligand L.sup.1 which is a 5-membered heterocyclic pentadentate ligand having one or more heteroatoms and ligand L.sup.2 which is a ligand having a .sigma.-bond, or a ligand having a .sigma.-bond and a bond selected from at least one .pi.-bond and at least one lone electron pair donative bond, provided that when the pentadentate ligand contains only one heteroatom, L.sup.2 is a ligand having a .sigma.-bond, or a ligand having a .sigma.-bond and at least one lone electron pair donative bond; and (3) a combination of ligand L.sup.1 which is a trispyrazolyl tridentate ligand and ligand L.sup.2 which is an alkapolyenyl ligand, and wherein each L.sup.1 contains an element of Group VB or Group VIB. By the method of the present invention, a desired olefin polymer can be produced efficiently with a high productivity per unit by weight of the catalyst.
摘要翻译：公开了一种使用高活性催化剂的烯烃聚合方法，该催化剂包含选自元素周期表中的镧系，IVA，VA，VIA，VIIA和VIII族的IIIA族金属的过渡金属，以及与其结合的配位体L1和L2 其中L1和L2的组合是（1）配体L1，其是含有至少一个含磷基团的基团和具有σ键的配体的配体L2或具有σ型配体的配体和选自至少一个π键和至少一个单电子对捐赠键的键; （2）配体L1，其是具有一个或多个杂原子的5元杂环五齿配体和具有σ键的配体的配体L2或具有σ-键的配体和至少选自至少一个π键和至少一个单独的电子对供体键，条件是当五齿配体仅含有一个杂原子时，L2是具有σ-键的配体或具有σ-键和至少一个单电子对的配体捐赠债券和（3）作为三吡唑基三齿配体的配体L1和作为多聚烯基配体的配体L2的组合，并且其中每个L1包含VB族或VIB族元素。通过本发明的方法，可以以每单位重量的催化剂高生产率有效地制备所需的烯烃聚合物。

3. 发明授权

US4863887A Additive for the hydroconversion of a heavy hydrocarbon oil 失效
标题翻译：加氢转化重质烃油的添加剂
公开(公告)号：US4863887A
公开(公告)日：1989-09-05
申请号：US131437
申请日：1987-12-11
申请人： Nobumitsu Ohtake , Tokitaka Kaneshima
发明人： Nobumitsu Ohtake , Tokitaka Kaneshima
IPC分类号： B01J23/28 , C10G47/04 , C10G47/26 , C10G49/00
CPC分类号： C10G47/26 , C10G49/00
摘要： There is provided an additive for the hydroconversion of a heavy hydrocarbon oil, which is obtained by suspending a fine powder of a carbonaceous substance and a solution of a heteropolymolybdic acid and/or transition metal salts thereof in a hydrocarbon oil. By the use of the additive of the present invention, the hydroconversion of a heavy hydrocarbon oil can be effectively performed at high conversion without occurrence of coking.
摘要翻译：提供了通过将碳质物质的细粉末和杂多钼酸和/或其过渡金属盐的溶液悬浮在烃油中而获得的重质烃油的加氢转化的添加剂。通过使用本发明的添加剂，可以以高转化率有效地进行重质烃油的加氢转化而不发生焦化。

4. 发明授权

US5968342A Zeolite catalyst and method of converting hydrocarbons using the same 失效
标题翻译：沸石催化剂和使用其的碳氢化合物的转化方法
公开(公告)号：US5968342A
公开(公告)日：1999-10-19
申请号：US809830
申请日：1997-03-21
申请人： Takashi Tsunoda , Mitsuhiro Sekiguchi , Tokitaka Kaneshima
发明人： Takashi Tsunoda , Mitsuhiro Sekiguchi , Tokitaka Kaneshima
IPC分类号： B01J29/064 , B01J29/068 , B01J29/44 , B01J29/46 , C07B61/00 , C07C4/06 , C07C5/393 , C07C5/41 , C07C11/02 , C07C15/02 , C10G11/02 , C10G11/05 , C10G35/095 , C10G47/20 , B01J29/40
CPC分类号： B01J29/44 , B01J29/068 , C07C4/06 , C07C5/415 , C10G11/05 , C10G11/18 , C07C2529/40 , C10G2400/20 , C10G2400/30
摘要： The present invention provides a catalyst to convert hydrocarbons, which comprises a zeolite containing substantially no proton and having an intermediate pore diameter, a molar ratio of SiO.sub.2 to Al.sub.2 O.sub.3 of at least 20 and one or more metals belonging to Group Ib of the Periodic Table. Further, the present invention provides a method to catalytically convert hydrocarbons by using the above catalyst. By means of the present invention, there can be provided a stable catalyst for conversion of hydrocarbons, which is capable of obtaining olefins containing ethylene as a main component and monocyclic aromatic hydrocarbons with good balance and a high yield, and which is hardly deteriorated by steam having a high temperature.
摘要翻译： PCT No.PCT / JP95 / 02040 Sec。 371日期1997年3月21日 102（e）1997年3月21日PCT PCT 1995年10月5日PCT公布。 WO96 / 13331 PCT出版物日期：1996年5月9日本发明提供了一种转化烃的催化剂，其包含基本上不含质子且具有中等孔径，SiO 2与Al 2 O 3的摩尔比为至少20的沸石和属于Ib族的Ib族的一种或多种金属周期表。此外，本发明提供了通过使用上述催化剂催化转化烃的方法。通过本发明，可以提供一种用于转化烃的稳定催化剂，其能够获得含有乙烯作为主要成分的烯烃和具有良好平衡和高产率的单环芳烃，并且几乎不被蒸汽劣化具有高温。

5. 发明授权

US5319119A Oleophilic molybdenum compound for use in hydroconversion of a hydrocarbon and a method for producing the same 失效
标题翻译：用于加氢转化烃的亲油性钼化合物及其制备方法
公开(公告)号：US5319119A
公开(公告)日：1994-06-07
申请号：US849683
申请日：1992-03-11
申请人： Tokitaka Kaneshima , Takashi Takahashi , Kazuhiro Matsubara
发明人： Tokitaka Kaneshima , Takashi Takahashi , Kazuhiro Matsubara
IPC分类号： C07F11/00 , B01J31/02 , B01J31/16 , B01J31/18 , B01J31/34 , C10G47/26 , C07F9/00 , C07F9/06
CPC分类号： C10G47/26 , B01J31/0239 , B01J31/34
摘要： An oleophilic molybdenum compound comprising an aliphatic amine group and a heteropolyanion group containing at least one molybdenum atom as a polyatom is disclosed. The oleophilic molybdenum compound is a catalyst precursor capable of being changed, in the hydroconversion reaction system, to a catalyst having excellent catalytic activity in hydroconversion of a hydrocarbon feedstock to a hydrocarbon product having a decreased molecular weight. The oleophilic molybdenum compound is efficiently produced from an aliphatic amine and a heteropolyacid.
摘要翻译：公开了包含脂族胺基和含有至少一个钼原子作为多原子的杂多阴离子基团的亲油钼化合物。亲油钼化合物是能够在加氢转化反应体系中改变为在将烃原料加氢转化成具有降低的分子量的烃产物的催化活性的催化剂前体。亲油钼化合物由脂族胺和杂多酸有效生产。

6. 发明授权

US06552235B2 Process for the preparation of cyclohexanol 有权
标题翻译：环己醇的制备方法
公开(公告)号：US06552235B2
公开(公告)日：2003-04-22
申请号：US10169153
申请日：2002-06-28
申请人： Yoshikazu Takamatsu , Tokitaka Kaneshima
发明人： Yoshikazu Takamatsu , Tokitaka Kaneshima
IPC分类号： C07C2920
CPC分类号： C07C29/04 , C07C2601/14 , C07C35/08
摘要： A method for producing cyclohexanol by subjecting cyclohexene to a hydration reaction in the presence of water using a solid acid as a catalyst in which as a reaction solvent, there is used an organic solvent having a solubility in water at 25° C. of not higher than 5% by weight, a boiling point which is at least 20° C. higher than that of the cyclohexanol produced, a conversion rate of not more than 3% under the hydration reaction conditions, and a solvent effect index of not less than 1.5 which indicates the effect of making the distribution of cyclohexene into the aqueous phase predominate.
摘要翻译：在使用固体酸作为催化剂的情况下，使环己烯在水存在下进行水合反应来制造环己醇的方法，其中作为反应溶剂，使用在25℃下在水中的溶解度不高的有机溶剂 5重量％以下的沸点比生成的环己醇的沸点高20℃以上，在水合反应条件下的转化率不大于3％，溶剂效果指数不低于1.5 这表明使环己烯分布到水相中的作用占主导地位。

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