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    • 1. 发明授权
    • Anthrapyridone compounds, their production process and their use
    • 蒽吡啶酮化合物,其生产工艺及其用途
    • US5367075A
    • 1994-11-22
    • US167443
    • 1993-12-14
    • Toshio NakamatsuYoshitugu EgashiraYasuyuki Suzuki
    • Toshio NakamatsuYoshitugu EgashiraYasuyuki Suzuki
    • C08K5/3437C09B5/14
    • C08K5/3437C09B5/14
    • An anthrapyridone compound of the following formula (I) and which is useful for coloring resins: ##STR1## wherein X.sup.1 is hydrogen, --NHCOR.sup.1, --CONR.sup.2 R.sup.3, --COR.sup.4, --SO.sub.2 R.sup.5 or --SO.sub.2 NR.sup.6 R.sup.7, in which R.sup.1 and R.sup.4 are each C.sub.1-4 alkyl, R.sup.2 and R.sup.3 are each hydrogen or C.sub.1-4 alkyl, R.sup.5 is C.sub.1-4 alkyl or hydroxyethyl, R.sup.6 and R.sup.7 are each hydrogen or C.sub.1-4 alkyl, X.sup.2 is hydrogen or imidomethyl of the formula (II): ##STR2## wherein n is a number of 1 to 2, X.sup.4 is hydrogen or carboxylic acid C.sub.1-4 alkyl-ester, X.sup.3 is hydrogen, halogen, hydroxyl, C.sub.1-4 alkyl or C.sub.1-4 alkoxyl, with the proviso that X.sup.1 is --NHCOR.sup.1, --CONR.sup.2 R.sup.3, --COR.sup.4, --SO.sub.2 R.sup.5 or --SO.sub.2 NR.sup.6 R.sup.7 when X.sup.2 is hydrogen, X.sup.2 is the imidomethyl of the formula (II) when X.sup.1 is the hydrogen, is provided, which is prepared by allowing an .alpha.-haloanthraquinone compound with an acylated primary aromatic amine compound in a nonaqueous medium in the presence of metallic copper or a copper compound.
    • 用于着色树脂的下式(I)的蒽并吡啶酮化合物:其中X 1是氢,-NHCOR 1,-CONR 2 R 3,-COR 4,-SO 2 R 5或-SO 2 NR 6 R 7,其中R 1和R 4是 每个C 1-4烷基,R 2和R 3各自为氢或C 1-4烷基,R 5为C 1-4烷基或羟乙基,R 6和R 7各自为氢或C 1-4烷基,X 2为氢或式(II)的亚氨基甲基) :其中n为1至2的数,X 4为氢或羧酸C 1-4烷基酯,X 3为氢,卤素,羟基,C 1-4烷基或C 1-4烷氧基,其中 条件是当X 2为氢时,X 1为-NHCOR 1,-CONR 2 R 3,-COR 4,-SO 2 R 5或-SO 2 NR 6 R 7,X 1为氢时,X 2为式(II)的亚氨基甲基,其通过使α - 卤代蒽醌化合物与非水介质中的酰化伯芳族胺化合物在金属铜或铜化合物的存在下反应。
    • 2. 发明授权
    • Anthrapyridone compounds
    • 蒽吡啶酮化合物
    • US4902798A
    • 1990-02-20
    • US126596
    • 1987-11-30
    • Toshio NakamatsuYoshitugu EgashiraYasuyuki Suzuki
    • Toshio NakamatsuYoshitugu EgashiraYasuyuki Suzuki
    • C08K5/3437C09B5/14
    • C08K5/3437C09B5/14
    • An anthrapyridone compound of the following formula (I) and which is useful for coloring resins: ##STR1## wherein X.sup.1 is hydrogen, --NHCOR.sup.1, --CONR.sup.2 R.sup.3, --COR.sup.4, --SO.sub.2 R.sup.5 or --SO.sub.2 NR.sup.6 R.sup.7, in which R.sup.1 and R.sup.4 are each C.sub.1-4 alkyl, R.sup.2 and R.sup.3 are each hydrogen or C.sub.1-4 alkyl, R.sup.5 is C.sub.1-4 alkyl or hydroxyethyl, R.sup.6 and R.sup.7 are each hydrogen or C.sub.1-4 alkyl, X.sup.2 is hydrogen or imidomethyl of the formula (II): ##STR2## wherein n is a number of 1 to 2, X.sup.4 is hydrogen or carboxylic acid C.sub.1-4 alkyl-ester, X.sup.3 is hydrogen, halogen, hydroxyl, C.sub.1-4 alkyl or C.sub.1-4 alkoxyl, with the proviso that X.sup.1 is --NHCOR.sup.1, --CONR.sup.2 R.sup.3, --COR.sup.4, --SO.sub.2 R.sup.5 or --SO.sub.2 NR.sup.6 R.sup.7 when X.sup.2 is hydrogen, X.sup.2 is the imidomethyl of the formula (II) when X.sup.1 is the hydrogen, is provided, which is prepared by allowing the .alpha.-halonathraquinone compound with an acylated primary aromatic amine compound in a nonaqueous medium in the presence of metallic copper or a copper compound.
    • 用于着色树脂的下式(I)的蒽并吡啶酮化合物:其中X 1是氢,-NHCOR 1,-CONR 2 R 3,-COR 4,-SO 2 R 5或-SO 2 NR 6 R 7,其中R 1和R 4是 每个C 1-4烷基,R 2和R 3各自为氢或C 1-4烷基,R 5为C 1-4烷基或羟乙基,R 6和R 7各自为氢或C 1-4烷基,X 2为氢或式(II)的亚氨基甲基) :其中n为1至2的数,X 4为氢或羧酸C 1-4烷基酯,X 3为氢,卤素,羟基,C 1-4烷基或C 1-4烷氧基,其中 条件是当X 2是氢时,X 1是-NHCOR 1,-CONR 2 R 3,-COR 4,-SO 2 R 5或-SO 2 NR 6 R 7,X 2是当X1是氢时式(II)的亚氨基甲基,其通过使α - 在金属铜或铜化合物的存在下,在非水介质中使用具有酰化伯芳香胺化合物的卤代萘醌化合物。