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    • 4. 发明授权
    • Method for bonding glass and metal
    • 玻璃和金属接合方法
    • US5336287A
    • 1994-08-09
    • US77371
    • 1993-06-17
    • Toshio AkimotoKazuo Shibaoka
    • Toshio AkimotoKazuo Shibaoka
    • C03C8/14C03C8/24C03C27/04H01J9/236
    • C03C27/044C03C8/24
    • A method of bonding a glass and a metal with a low-melting glass frit, in which the low-melting glass frit contains from 1 to 10% by weight of an aluminum borate whisker, and the difference in linear expansion coefficient between the low-melting glass frit and the glass is 10.times.10.sup.-7 /.degree.C. or less; and a method for producing a cathode ray tube comprising the step of bonding a glass back plate and a metal stud pin with a low-melting glass frit, the low-melting glass frit containing from 1 to 10% by weight of an aluminum borate whisker, and the difference in linear expansion coefficient between the low-melting glass frit and the glass back plate being 10.times.10.sup.-7 /.degree.C. or less.
    • 一种玻璃和金属与低熔点玻璃料接合的方法,其中低熔点玻璃料含有1-10重量%的硼酸铝晶须,以及低熔点玻璃料之间的线性膨胀系数的差异, 熔融玻璃料,玻璃为10×10 -7 /℃以下; 以及一种制造阴极射线管的方法,包括将玻璃背板和金属柱销与低熔点玻璃料接合的步骤,所述低熔点玻璃料含有1至10重量%的硼酸铝晶须 低熔点玻璃料和玻璃后板之间的线膨胀系数差为10×10 -7 /℃以下。
    • 9. 发明授权
    • Glass panel resistant to coloring when irradiated with electron rays
    • 玻璃面板在电子射线照射时耐着色
    • US5296294A
    • 1994-03-22
    • US989826
    • 1992-12-14
    • Kouichi SuzukiKazuo Shibaoka
    • Kouichi SuzukiKazuo Shibaoka
    • C03C3/087C03C3/095C03C21/00H01J29/86B32B17/06
    • C03C3/095C03C21/002C03C3/087H01J29/863H01J2329/00Y10T428/31Y10T428/315
    • A glass panel resistant to coloring when irradiated with electron rays, which has the following glass composition:______________________________________ SiO.sub.2 64-75% by weight Al.sub.2 O.sub.3 1.5-2.0% by weight CaO 6.5-9.0% by weight MgO 0-5.0% by weight Li.sub.2 O 0.5-2.5% by weight Na.sub.2 O 7.0-12% by weight K.sub.2 O 2.1-5.0% by weight SrO + BaO + ZrO.sub.2 0-10% by weight CeO.sub.2 0-0.5% by weight, ______________________________________ wherein part of the Na ion, in at least the surface layer of the panel region to be irradiated with electron rays, is substituted with K ion by an ion exchange treatment in a K-containing molten salt so that the molar ratio of Na ion and K ion expressed by Na.sub.2 O/(Na.sub.2 O+K.sub.2 O) in at least the glass layer ranging from 0.5 .mu.m to 6.5 .mu.m in depth from the panel surface, of said panel region to be irradiated with electron rays, is 0.3-0.75.
    • 具有以下玻璃组成的耐电子着色的玻璃面板:-SiO264-75重量%-Al2O31.5-2.0重量%-CaO6.5-9.0重量%MgO0-5.0% 重量Li 2 O 0.5-2.5%(重量)Na 2 O 7.0-12%(重量)K 2 O 2 -2-5.0%(重量)-SoO + BaO + ZrO 2 O-10%(重量)CeO 20 -0.5%(重量) 的Na离子在至少要用电子射线照射的面板区域的表面层中,用K离子通过在含K熔融盐中的离子交换处理被K离子取代,使得Na离子和K离子的摩尔比 在要被照射电子射线的所述面板区域的至少距离面板表面的0.5(my)m至6.5(my)m的玻璃层中的Na 2 O /(Na 2 O + K 2 O)表示为0.3-0.75 。