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    • 5. 发明授权
    • Dielectric ceramic materials with insulated boundaries between crystal
grains, and process for preparation
    • 介电陶瓷材料与晶粒之间具有绝缘边界,以及制备工艺
    • US4405478A
    • 1983-09-20
    • US443781
    • 1982-11-22
    • Kiyoshi MuraseNobutatsu YamaokaMasayuki Fujimoto
    • Kiyoshi MuraseNobutatsu YamaokaMasayuki Fujimoto
    • C04B35/47H01G4/12C04B35/46H01B3/12
    • H01G4/1281C04B35/47
    • A dielectric ceramic material composed of primary and secondary ingredients forming in combination a polycrystalline ceramic proper, and of insulating substances diffused throughout the intergranular boundaries of the ceramic proper for an increase in apparent relative dielectric constant. The primary ingredients comprise, in relative proportions, 90.68-99.88 wt. % SrTiO.sub.3, 0.07-5.32 wt. % Nb.sub.2 O.sub.5, and 0.05-4.00 wt. % GeO.sub.2. The secondary ingredients comprise 0.02-0.10 wt. part SiO.sub.2 and 0.01-0.03 wt. part Al.sub.2 O.sub.3 with respect to 100 wt. parts of the primary ingredients, with the weight ratio of SiO.sub.2 to Al.sub.2 O.sub.3 being from 1.5 to 5.0. The insulating substances comprise 0.03-2.90 wt. % PbO, 0.11-4.34 wt. % Bi.sub.2 O.sub.3, and 0.001-0.18 wt. % B.sub.2 O.sub.3 with respect to the total weight of the primary and the secondary ingredients. In the fabrication of bodies of the ceramic the mixture of the insulating substances is coated or otherwise layered on polycrystalline ceramic bodies prepared from the primary and secondary ingredients. The coated ceramic bodies are then heated to cause diffusion of the insulating substances throughout their intergranular boundaries.
    • 由主要和次要成分组成的介电陶瓷材料,其组合形成多晶陶瓷本身,并且绝缘物质在陶瓷本身的整个晶界处扩散,以增加表观相对介电常数。 主要成分以相对比例包含90.68-99.88wt。 %SrTiO 3,0.07-5.32wt。 %Nb2O5和0.05-4.00wt。 %GeO2。 次要成分包含0.02-0.10wt。 部分SiO2和0.01-0.03wt。 部分Al2O3相对于100wt。 主要成分的一部分,SiO 2与Al 2 O 3的重量比为1.5-5.0。 绝缘物质包含0.03-2.90重量% %PbO,0.11-4.34wt。 %Bi 2 O 3和0.001-0.18wt。 %B2O3相对于初级和次级成分的总重量。 在陶瓷体的制造中,绝缘物质的混合物被涂覆或以其它方式分层在由初级和次级成分制备的多晶陶瓷体上。 然后将涂覆的陶瓷体加热,使绝缘物质扩散到其晶间界面。
    • 6. 发明授权
    • Dielectric ceramic materials with insulated boundaries between crystal
grains, and process for preparation
    • 介电陶瓷材料与晶粒之间具有绝缘边界,以及制备工艺
    • US4405474A
    • 1983-09-20
    • US443775
    • 1982-11-22
    • Kiyoshi MuraseNobutatsu YamaokaMasayuki Fujimoto
    • Kiyoshi MuraseNobutatsu YamaokaMasayuki Fujimoto
    • H01B3/12C04B35/47H01G4/12C04B35/46
    • H01G4/1281C04B35/47
    • A dielectric ceramic material composed of primary and secondary ingredients forming in combination a polycrystalline ceramic proper, and of insulating substances diffused throughout the intergranular boundaries of the ceramic proper for an increase in apparent relative dielectric constant. The primary ingredients comprise in relative proportions, 96.70-99.83 wt. % SrTiO.sub.3, 0.15-2.30 wt. % WO.sub.3, and 0.02-1.00 wt. % CuO. The secondary ingredients comprise 0.02-0.10 wt %. part SiO.sub.2 and 0.01-0.03 wt. part Al.sub.2 O.sub.3 with respect to 100 wt. parts of the primary ingredients, with the weight ratio of SiO.sub.2 to Al.sub.2 O.sub.3 being from 1.5 to 5.0. The insulating substances comprise 0.003-2.83 wt. % PbO, 0.10-4.30 wt. % Bi.sub.2 O.sub.3, and 0.001-0.18 wt. % B.sub.2 O.sub.3 with respect to the total weight of the primary and the secondary ingredients. In the fabrication of bodies of the ceramic the mixture of the insulating substances is coated or otherwise layered on polycrystalline ceramic bodies prepared from the primary and secondary ingredients. The coated ceramic bodies are then heated to cause diffusion of the insulating substances throughout their intergranular boundaries.
    • 由主要和次要成分组成的介电陶瓷材料,其组合形成多晶陶瓷本身,并且绝缘物质在陶瓷本身的整个晶界处扩散,以增加表观相对介电常数。 主要成分包括相对比例为96.70-99.83wt。 %SrTiO 3,0.15-2.30重量% %WO3和0.02-1.00wt。 %CuO。 次要成分占0.02-0.10重量%。 部分SiO2和0.01-0.03wt。 部分Al2O3相对于100wt。 主要成分的一部分,SiO 2与Al 2 O 3的重量比为1.5-5.0。 绝缘物质包含0.003-2.83wt。 %PbO,0.10-4.30wt。 %Bi 2 O 3和0.001-0.18wt。 %B2O3相对于初级和次级成分的总重量。 在陶瓷体的制造中,绝缘物质的混合物被涂覆或以其它方式分层在由初级和次级成分制备的多晶陶瓷体上。 然后将涂覆的陶瓷体加热,使绝缘物质扩散到其晶间界面。
    • 7. 发明授权
    • Dielectric ceramic materials with insulated boundaries between crystal
grains, and process for preparation
    • 介电陶瓷材料与晶粒之间具有绝缘边界,以及制备工艺
    • US4405472A
    • 1983-09-20
    • US443773
    • 1982-11-22
    • Kiyoshi MuraseNobutatsu YamaokaMasayuki Fujimoto
    • Kiyoshi MuraseNobutatsu YamaokaMasayuki Fujimoto
    • H01B3/12C04B35/47H01G4/12C04B35/46
    • C04B35/47H01G4/1281
    • A dielectric ceramic material composed of primary and secondary ingredients forming in combination a polycrystalline ceramic proper, and of insulating substances diffused throughout the intergranular boundaries of the ceramic proper for an increase in apparent relative dielectric constant. The primary ingredients comprise, in relative proportions, 95.18-99.65 wt. % SrTiO.sub.3, 0.33-3.32 wt. % Ta.sub.2 O.sub.5, and 0.02-1.50 wt. % CuO. The secondary ingredients comprise 0.02-0.10 wt. % part SiO.sub.2 and 0.01-0.03 wt. part Al.sub.2 O.sub.3 with respect to 100 wt. parts of the primary ingredients, with the weight ratio of SiO.sub.2 to Al.sub.2 O.sub.3 being from 1.50 to 5.0. The insulating substances comprise 0.03-2.75 wt. % PbO, 0.11-4.22 wt. % Bi.sub.2 O.sub.3, and 0.001-0.18 wt. % B.sub.2 O.sub.3 with respect to the total weight of the primary and the secondary ingredients. In the fabrication of bodies of the ceramic the mixture of the insulating substances is coated or otherwise layered on polycrystalline ceramic bodies prepared from the primary and secondary ingredients. The coated ceramic bodies are then heated to cause diffusion of the insulating substances throughout their intergranular boundaries.
    • 由主要和次要成分组成的介电陶瓷材料,其组合形成多晶陶瓷本身,并且绝缘物质在陶瓷本身的整个晶界处扩散,以增加表观相对介电常数。 主要成分以相对比例包含95.18-99.65wt。 %SrTiO3,0.33-3.32wt。 %Ta2O5和0.02-1.50wt。 %CuO。 次要成分包含0.02-0.10wt。 %部分SiO 2和0.01-0.03重量% 部分Al2O3相对于100wt。 主要成分的一部分,SiO 2与Al 2 O 3的重量比为1.50〜5.0。 绝缘物质包含0.03-2.75重量% %PbO,0.11-4.22wt。 %Bi 2 O 3和0.001-0.18wt。 %B2O3相对于初级和次级成分的总重量。 在陶瓷体的制造中,绝缘物质的混合物被涂覆或以其它方式分层在由初级和次级成分制备的多晶陶瓷体上。 然后将涂覆的陶瓷体加热,使绝缘物质扩散到其晶间界面。
    • 10. 发明授权
    • Dielectric ceramic materials with insulated boundaries between crystal
grains, and process for preparation
    • 介电陶瓷材料与晶粒之间具有绝缘边界,以及制备工艺
    • US4405479A
    • 1983-09-20
    • US443782
    • 1982-11-22
    • Kiyoshi MuraseNobutatsu YamaokaMasayuki Fujimoto
    • Kiyoshi MuraseNobutatsu YamaokaMasayuki Fujimoto
    • C04B35/46C04B35/47H01B3/12H01G4/12
    • H01G4/1281C04B35/47
    • A dielectric ceramic material composed of primary and secondary ingredients forming in combination a polycrystalline ceramic proper, and of insulating substances diffused throughout the intergranular boundaries of the ceramic proper for an increase in apparent relative dielectric constant. The primary ingredients comprise, in relative proportions, 95.20-99.80 wt. % SrTiO.sub.3, 0.15-2.30 wt. % WO.sub.3, and 0.05-2.50 wt. % ZnO. The seconary ingredients comprise 0.02-0.10 wt. part SiO.sub.2 and 0.01-0.03 wt. part Al.sub.2 O.sub.3 with respect to 100 wt. parts of the primary ingredients, with the weight ratio of SiO.sub.2 to Al.sub.2 O.sub.3 being from 1.5 to 5.0. The insulating substances comprise 0.03-2.75 wt. % PbO, 0.11-4.23 wt. % Bi.sub.2 O.sub.3, and 0.001-0.18 wt. % B.sub.2 O.sub.3 with respect to the total weight of the primary and the secondary ingredients. In the fabrication of bodies of the ceramic the mixture of the insulating substances is coated or otherwise layered on polycrystalline ceramic bodies prepared from the primary and secondary ingredients. The coated ceramic bodies are then heated to cause diffusion of the insulating substances throughout their intergranular boundaries.
    • 由主要和次要成分组成的介电陶瓷材料,其组合形成多晶陶瓷本身,并且绝缘物质在陶瓷本身的整个晶界处扩散,以增加表观相对介电常数。 主要成分以相对比例包含95.20-99.80wt。 %SrTiO 3,0.15-2.30重量% %WO3和0.05-2.50wt。 %ZnO。 所述第二成分包含0.02-0.10wt。 部分SiO2和0.01-0.03wt。 部分Al2O3相对于100wt。 主要成分的一部分,SiO 2与Al 2 O 3的重量比为1.5-5.0。 绝缘物质包含0.03-2.75重量% %PbO,0.11-4.23wt。 %Bi 2 O 3和0.001-0.18wt。 %B2O3相对于初级和次级成分的总重量。 在陶瓷体的制造中,绝缘物质的混合物被涂覆或以其它方式分层在由初级和次级成分制备的多晶陶瓷体上。 然后将涂覆的陶瓷体加热,使绝缘物质扩散到其晶间界面。