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1. 发明授权

US6033809A Lithium secondary battery and electrolyte thereof 有权
标题翻译：锂二次电池及其电解质
公开(公告)号：US6033809A
公开(公告)日：2000-03-07
申请号：US137600
申请日：1998-08-21
申请人： Toshikazu Hamamoto , Atsuo Hitaka , Yukio Nakada , Koji Abe
发明人： Toshikazu Hamamoto , Atsuo Hitaka , Yukio Nakada , Koji Abe
IPC分类号： H01M4/58 , H01M10/40
CPC分类号： H01M10/0569 , H01M10/0525 , H01M4/587
摘要： A non-aqueous electrolyte lithium secondary battery comprising a cathode, an anode and a non-aqueous electrolyte comprising an electrolyte dissolved in a non-aqueous solvent, wherein the cathode is composed of a material containing a lithium complex oxide, the anode is composed of a material containing graphite and the non-aqueous solvent contains, as main components, a cyclic carbonate and a linear carbonate and 0.1 to 4% by weight, based upon the total weight of the non-aqueous solvent, of a sultone derivative having the general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently represent an alkyl group having 1 to 12 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms or a hydrogen atom and n is an integer of 0 to 2.
摘要翻译：一种非水电解质锂二次电池，其包含阴极，阳极和非水电解质，其包含溶解在非水溶剂中的电解质，其中所述阴极由含有锂复合氧化物的材料构成，所述阳极由含有石墨和非水溶剂的材料以环状碳酸酯和直链碳酸酯为主成分，以非水溶剂的总重量计含有0.1〜4重量％的具有一般的磺酸内酯衍生物式（I）：其中R 1，R 2，R 3，R 4，R 5和R 6独立地表示碳原子数1〜12的烷基，碳原子数3〜6的环烷基，碳原子数6〜12的芳基或氢原子，n为0〜2的整数。

2. 发明授权

US6139991A Electrolyte solution for lithium secondary battery and lithium secondary battery using the same 有权
标题翻译：锂二次电池和锂二次电池使用电解液
公开(公告)号：US6139991A
公开(公告)日：2000-10-31
申请号：US137599
申请日：1998-08-21
申请人： Toshikazu Hamamoto , Atsuo Hitaka , Yukio Nakada , Koji Abe , Tsutomu Takai
发明人： Toshikazu Hamamoto , Atsuo Hitaka , Yukio Nakada , Koji Abe , Tsutomu Takai
IPC分类号： H01M10/05 , H01M10/052 , H01M10/0567 , H01M6/18
CPC分类号： H01M10/0569
摘要： An electrolyte solution for a lithium secondary battery comprising a non-aqueous solvent, and an electrolyte and a carbonic ester derivative both dissolved therein, said carbonic ester derivative having the formula (I): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 independently represent an alkyl group having 1 to 12 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms, provided that R.sup.2 may be a hydrogen atom and provided that R.sup.1 and R.sup.2 may be connected through a methylene group to form a cycloalkyl group having 3 to 6 carbon atoms.
摘要翻译：一种锂二次电池的电解质溶液，其包含非水溶剂，和溶解于其中的电解质和碳酸酯衍生物，所述具有式（I）的碳酸酯衍生物：其中R1，R2和R3独立地表示具有式 1至12个碳原子，具有3至6个碳原子的环烷基或具有6至12个碳原子的芳基，条件是R 2可以是氢原子，并且R 1和R 2可以通过亚甲基连接形成具有3至6个碳原子的环烷基。

3. 发明授权

US06045945A Electrolyte solution for lithium secondary battery 失效
标题翻译：锂二次电池电解液
公开(公告)号：US06045945A
公开(公告)日：2000-04-04
申请号：US46964
申请日：1998-03-24
申请人： Toshikazu Hamamoto , Atsuo Hitaka , Koji Abe , Yohsuke Ueno , Noriyuki Ohira , Masahiko Watanabe
发明人： Toshikazu Hamamoto , Atsuo Hitaka , Koji Abe , Yohsuke Ueno , Noriyuki Ohira , Masahiko Watanabe
IPC分类号： H01M10/0567 , H01M10/40 , H01M6/04
CPC分类号： H01M10/0567
摘要： An electrolyte solution for a lithium secondary battery comprises a nonaqueous solvent and a fluorine-containing electrolyte capable of dissociating into lithium ions, wherein the content of HF in the electrolyte solution is less than 30 ppm.
摘要翻译：锂二次电池用电解液包括非水溶剂和能够离解成锂离子的含氟电解质，其中电解液中的HF含量小于30ppm。

4. 发明授权

US07968220B2 Non-aqueous electrolytic solution and lithium secondary battery 有权
标题翻译：非水电解液和锂二次电池
公开(公告)号：US07968220B2
公开(公告)日：2011-06-28
申请号：US12605490
申请日：2009-10-26
申请人： Toshikazu Hamamoto , Koji Abe , Akira Ueki
发明人： Toshikazu Hamamoto , Koji Abe , Akira Ueki
IPC分类号： H01M10/056
CPC分类号： H01M10/0525 , H01M10/0567 , H01M2300/0037
摘要： A non-aqueous electrolytic solution favorably employable for a lithium secondary battery employs a non-aqueous electrolytic solution which comprises a non-aqueous solvent and an electrolyte which further contains 0.001 to 0.8 weight % of a biphenyl derivative having the formula: in which each of Y1 and Y2 represents hydroxyl, alkoxy, hydrocarbyl, hydrogen, acyloxy, alkoxycarbonyloxy, alkylsulfonyloxy, or halogen, and each of p and q is an integer of 1 to 3.
摘要翻译：适用于锂二次电池的非水电解液使用非水电解液，其包含非水溶剂和电解质，该电解质还含有0.001至0.8重量％的具有下式的联苯衍生物：其中， Y 1和Y 2表示羟基，烷氧基，烃基，氢，酰氧基，烷氧基羰基氧基，烷基磺酰氧基或卤素，p和q各自为1〜3的整数。

5. 发明授权

US07867657B2 Electrolyte for non-aqueous cell and non-aqueous secondary cell 有权
标题翻译：非水电解槽和非水电解槽电解液
公开(公告)号：US07867657B2
公开(公告)日：2011-01-11
申请号：US12846732
申请日：2010-07-29
申请人： Shoichiro Watanabe , Shusaku Goto , Masaru Takagi , Sumihito Ishida , Toshikazu Hamamoto , Akira Ueki , Koji Abe
发明人： Shoichiro Watanabe , Shusaku Goto , Masaru Takagi , Sumihito Ishida , Toshikazu Hamamoto , Akira Ueki , Koji Abe
IPC分类号： H01M6/16 , H01M4/583 , H01M4/40 , H01M10/0561
CPC分类号： H01M10/0567 , H01M4/131 , H01M4/133 , H01M6/168 , H01M10/052 , H01M10/4235 , H01M2300/0037 , Y02T10/7011
摘要： In a rechargeable non-aqueous electrolyte secondary battery using positive electrodes, negative electrodes and a non-aqueous electrolytic solution, additives to the electrolytic solution are used in combination, preferably in combination of at least two compounds selected from o-terphenyl, triphenylene, cyclohexylbenzene and biphenyl, and thus there are provided batteries excellent in safety and storage characteristics.
摘要翻译：在使用正电极，负电极和非水电解液的可再充电非水电解质二次电池中，电解溶液的添加剂组合使用，优选组合至少两种选自邻三苯基，三苯基苯，环己基苯和联苯，因此提供了安全性和储存特性优异的电池。

6. 发明申请

US20070207389A1 Non-aqueous electrolyte and lithium secondary battery using the same 有权
标题翻译：非水电解质和锂二次电池使用相同
公开(公告)号：US20070207389A1
公开(公告)日：2007-09-06
申请号：US11699327
申请日：2007-01-30
申请人： Toshikazu Hamamoto , Koji Abe , Tsutomu Takai , Yasuo Matsumori
发明人： Toshikazu Hamamoto , Koji Abe , Tsutomu Takai , Yasuo Matsumori
IPC分类号： H01M10/40
CPC分类号： H01M10/0567 , H01M4/137 , H01M4/405 , H01M4/485 , H01M4/587 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M2004/021 , H01M2004/027 , H01M2300/0037
摘要： A non-aqueous electrolyte comprising (i) a non-aqueous solvent, especially mainly composed of a cyclic carbonate and a cyclic ester and optionally a linear carbonate, and (ii) an electrolyte salt, especially LiBF4, dissolved therein and (iii) a vinyl sulfone derivative having the formula (I): wherein R indicates a C1 to C12 alkyl group, C2 to C12 alkenyl group, or C3 to C6 cycloalkyl, and also a lithium secondary battery using the same are disclosed.
摘要翻译：一种非水电解质，其包含（i）非水溶剂，特别是主要由环状碳酸酯和环状酯和任选的直链碳酸酯组成的非水溶剂，和（ii）电解质盐，特别是LiBF 4 ，和（iii）具有式（I）的乙烯基砜衍生物：其中R表示C 1至C 12烷基的C 1〜C 12， / C 1〜C 12链烯基或C 3〜C 6环烷基，并且还公开了使用其的锂二次电池。

7. 发明授权

US06866966B2 Non-aqueous secondary battery having enhanced discharge capacity retention 有权
标题翻译：具有增强放电容量保持性的非水二次电池
公开(公告)号：US06866966B2
公开(公告)日：2005-03-15
申请号：US10021130
申请日：2001-10-22
申请人： Toshikazu Hamamoto , Koji Abe , Tsutomu Takai , Yasuo Matsumori , Akira Ueki
发明人： Toshikazu Hamamoto , Koji Abe , Tsutomu Takai , Yasuo Matsumori , Akira Ueki
IPC分类号： H01M4/587 , H01M10/052 , H01M10/0567 , H01M10/08
CPC分类号： H01M10/052 , H01M4/587 , H01M10/0567 , H01M2300/0025
摘要： A discharge capacity retention of a non-aqueous secondary battery is enhanced by incorporating into its non-aqueous electrolytic solution a small amount of a substituted diphenyldisulfide derivative in which each of the diphenyl groups has a substituent such as alkoxy, alkenyloxy, alkynyloxy, cycloalkyloxy, aryloxy, acyloxy, alkanesulfonyloxy, arylsulfonyloxy, alkoxycarbonyloxy, aryloxycarbonyloxy, halogen, CF3, CCl3, or CBr3. Preferably, a small amount of methyl 2-propylcarbonate, 2-propynyl methanesulfonate, 1,3-propanesultone, divinylsulfone, 1,4-butanediol dimethanesulfonate or cyclohexylbenzene is further incorporated.
摘要翻译：通过在其非水电解液中加入少量二苯基中具有取代基的取代二苯基二硫化物衍生物，例如烷氧基，烯氧基，炔氧基，环烷氧基，芳氧基，酰氧基，烷磺酰氧基，芳基磺酰氧基，烷氧基羰基氧基，芳氧基羰基氧基，卤素，CF 3，CCl 3或CBr 3。优选少量的碳酸2-丙酯，2-丙炔基甲磺酸酯，1,3-丙磺酸内酯，二乙烯基砜，1,4-丁二醇二甲磺酸酯或环己基苯。

8. 发明授权

US06699998B2 Non-aqueous electrolyte and lithium secondary battery using the same 有权
标题翻译：非水电解质和锂二次电池使用相同
公开(公告)号：US06699998B2
公开(公告)日：2004-03-02
申请号：US10109943
申请日：2002-03-29
申请人： Toshikazu Hamamoto , Koji Abe , Tsutomu Takai , Yasuo Matsumori
发明人： Toshikazu Hamamoto , Koji Abe , Tsutomu Takai , Yasuo Matsumori
IPC分类号： C07D31712
CPC分类号： H01M10/052 , H01M4/587 , H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M2300/0025 , H01M2300/0037
摘要： A non-aqueous electrolyte comprising a non-aqueous solvent and a lithium salt dissolved therein, and a cyclic carbonate, linear carbonate, and vinylene carbonate having a chlorine content of 100 ppm or less, and a lithium secondary battery using the same.
摘要翻译：包含溶解在其中的非水溶剂和锂盐的非水电解质和氯含量为100ppm以下的环状碳酸酯，直链碳酸酯和碳酸亚乙烯酯，以及使用该非水电解质的锂二次电池。

9. 发明授权

US06413677B1 Lithium secondary battery electrolyte and lithium secondary battery using the same 失效
标题翻译：锂二次电池电解液和锂二次电池使用相同
公开(公告)号：US06413677B1
公开(公告)日：2002-07-02
申请号：US09466332
申请日：1999-12-17
申请人： Toshikazu Hamamoto , Koji Abe , Tsutomu Takai , Yasuo Matsumori , Kazuhiro Miyoshi , Akira Ueki
发明人： Toshikazu Hamamoto , Koji Abe , Tsutomu Takai , Yasuo Matsumori , Kazuhiro Miyoshi , Akira Ueki
IPC分类号： H01M1040
CPC分类号： H01M10/052 , H01M10/0567
摘要： A lithium secondary battery electrolyte comprising a non-aqueous solvent and a lithium salt dissolved therein, said electrolyte containing at least one compound having the formula (I) or (II): wherein, R1 and R2 independently indicate, a C1 to C12 alkyl group, a C3 to C6 cycloalkyl group, or an aryl group, x indicates an oxygen atom or a sulfur atom, and n indicates an integer of 1 or 2; R3—S—M (II) wherein, R3 indicates a C1 to C15 alkyl group or a C3 to C12 cycloalkyl group which may be substituted with at least one C1 to C4 alkyl group, a C7 to C15 benzyl group which may be substituted with at least one C1 to C4 alkyl group, or a C6 to C15 aryl group, which may be substituted with at least one C1 to C4 alkyl group, M indicates an alkali metal, and R3 may be substituted with at least one halogen atom; and a lithium secondary battery using the same.
摘要翻译：包含溶解在其中的非水溶剂和锂盐的锂二次电池电解质，所述电解质含有至少一种具有式（I）或（II）的化合物：其中，R 1和R 2独立地表示C1-C12烷基，C3〜C6环烷基或芳基，x表示氧原子或硫原子，n表示1或2的整数;其中，R3表示C1〜C15烷基或C3〜C12环烷基其可以被至少一个C 1至C 4烷基，可被至少一个C 1至C 4烷基取代的C 7至C 15苄基或C 6至C 15芳基取代，其可被至少一个 C1至C4烷基，M表示碱金属，R3可以被至少一个卤素原子取代; 和使用该二次电池的锂二次电池。

10. 发明授权

US07824809B2 Electrolyte for non-aqueous cell and non-aqueous secondary cell 有权
标题翻译：非水电解槽和非水电解槽电解液
公开(公告)号：US07824809B2
公开(公告)日：2010-11-02
申请号：US12630685
申请日：2009-12-03
申请人： Shoichiro Watanabe , Shusaku Goto , Masaru Takagi , Sumihito Ishida , Toshikazu Hamamoto , Akira Ueki , Koji Abe
发明人： Shoichiro Watanabe , Shusaku Goto , Masaru Takagi , Sumihito Ishida , Toshikazu Hamamoto , Akira Ueki , Koji Abe
IPC分类号： H01M6/16 , H01M4/583 , H01M4/40 , H01M10/0561
CPC分类号： H01M10/0567 , H01M4/131 , H01M4/133 , H01M6/168 , H01M10/052 , H01M10/4235 , H01M2300/0037 , Y02T10/7011
摘要： In a rechargeable non-aqueous electrolyte secondary battery using positive electrodes, negative electrodes and a non-aqueous electrolytic solution, additives to the electrolytic solution are used in combination, preferably in combination of at least two compounds selected from o-terphenyl, triphenylene, cyclohexylbenzene and biphenyl, and thus there are provided batteries excellent in safety and storage characteristics.
摘要翻译：在使用正电极，负电极和非水电解液的可再充电非水电解质二次电池中，电解溶液的添加剂组合使用，优选组合至少两种选自邻三苯基，三苯基苯，环己基苯和联苯，因此提供了安全性和储存特性优异的电池。

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