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1. 发明授权

US4988608A Method for forming fine pattern of conjugated polymer film 失效
标题翻译：用于形成共轭聚合物薄膜精细图案的方法
公开(公告)号：US4988608A
公开(公告)日：1991-01-29
申请号：US431178
申请日：1989-11-03
申请人： Toshihiko Tanaka , Shuji Doi
发明人： Toshihiko Tanaka , Shuji Doi
IPC分类号： G03F7/038 , H01L21/027
CPC分类号： G03F7/038 , Y10S430/115
摘要： Disclosed is a method for forming a fine pattern of a conjugated polymer according to which the fine pattern can be formed even by using a high pressure mercury lamp as a light source for irradiation. This method comprises irradiating a coat containing a precursor for conjugated polymers which has a recurring unit represented by the formula (1): ##STR1## wherein R.sub.1 represents ##STR2## ps in which R.sub.3 and R.sub.4 each represents a hydrogen atom or an alkyl or alkoxy group of 1-5 carbon atoms, R.sub.5 represents a hydrocarbon group of 1-5 carbon atoms and m is 1 or 2; and R.sub.2 represents a hydrogen atom or a hydrocarbon group of 1-10 carbon atoms with a light of 200-500 nm in wavelength in pattern form and then dissolving and removing the polymer of unirradiated portion. It is preferred to heat treat the resulting fine pattern. Furthermore, the resulting pattern can have electrical conductivity by doping it with an electron donating or accepting dopant.
摘要翻译：公开了一种用于形成共轭聚合物的精细图案的方法，通过使用高压汞灯作为照射光源，可以形成精细图案。该方法包括：照射含有共轭聚合物前体的涂层，该共聚物具有式（1）表示的重复单元：其中R 1表示其中R 3和R 4各自表示氢原子或 1-5个碳原子的烷基或烷氧基，R5代表1-5个碳原子的烃基，m是1或2; R2表示氢原子或1-10个碳原子的烃基，其波长为200-500nm的图案形式，然后溶解并除去未照射部分的聚合物。优选热处理所得到的精细图案。此外，所得到的图案可以通过用给电子或接受掺杂剂掺杂而具有导电性。

2. 发明授权

US07662478B2 Polymer and polymer light-emitting device using the same 失效
标题翻译：聚合物和聚合物发光装置使用它
公开(公告)号：US07662478B2
公开(公告)日：2010-02-16
申请号：US10954223
申请日：2004-10-01
申请人： Satoshi Kobayashi , Takanobu Noguchi , Yoshiaki Tsubata , Makoto Kitano , Shuji Doi , Takahiro Ueoka , Akiko Nakazono
发明人： Satoshi Kobayashi , Takanobu Noguchi , Yoshiaki Tsubata , Makoto Kitano , Shuji Doi , Takahiro Ueoka , Akiko Nakazono
IPC分类号： B32B25/20
CPC分类号： C07F9/65683 , C07D333/76 , C07D339/08 , C07F7/081 , C08G61/122 , C08G2261/1424 , C08G2261/3162 , C08G2261/3243 , C08G2261/3244 , C08G2261/5222 , C09K11/06 , C09K2211/1416 , Y10T428/31663
摘要： Provided is a polymer comprising a repeating unit represented by formula (1), wherein, A1 represents a divalent group in which the bond distance ratio (bond distance of C(α)-A1/bond distance of C(α)-C(β)) is 1.10 or more; R1, R2, R3, R4, R5, and R6, each independently represent a hydrogen atom, alkyl group, alkyloxy group, aryloxy group, arylalkyloxy group, etc. The polymer is useful as a light-emitting material, a charge transporting material, etc.
摘要翻译：本发明提供包含由式（1）表示的重复单元的聚合物，其中，A1表示二价基团，其中键距距离（C（α）-A1的键距离/ C（α）-C（β ））为1.10以上; R1，R2，R3，R4，R5和R6各自独立地表示氢原子，烷基，烷氧基，芳氧基，芳基烷氧基等。该聚合物可用作发光材料，电荷输送材料，等等

3. 发明申请

US20080138651A1 Polymer Compound And Polymer Light-Emitting Device Using The Same 有权
公开(公告)号：US20080138651A1
公开(公告)日：2008-06-12
申请号：US10532937
申请日：2003-10-03
申请人： Shuji Doi , Satoshi Kobayashi , Takanobu Noguchi
发明人： Shuji Doi , Satoshi Kobayashi , Takanobu Noguchi
IPC分类号： B32B33/00 , C08F12/08 , C07D311/80 , B32B27/00 , C07D221/12
CPC分类号： C08G61/122 , C08G61/02 , C09K11/06 , C09K2211/14 , C09K2211/1416 , C09K2211/1425 , C09K2211/1433 , Y10S428/917 , Y10T428/31504
摘要： High-molecular compounds comprising repeating units represented by the general formula (1) or (2) and having number-average molecular weights of 103 to 108 in terms of polystyrene: (1) [wherein Ar1 and Ar2 are each independently a trivalent aromatic hydrocarbon group or a trivalent heterocyclic group; and X1 and X2 are each independently O, S, C(═O), S(═O), SO2, C(R1)(R2), Si(R3)(R4), N(R5), B(R6), P(R7), or P(═O)(R8), with the provisos that X1 and X2 must not be the same and that X1 and Ar2 are bonded respectively to the adjacent carbon atoms constituting the aromatic ring of Ar1, and X2 and Ar1 are bonded respectively to the adjacent carbon atoms constituting the aromatic ring of Ar2] (2) [wherein Ar3 and Ar4 are each independently a trivalent aromatic hydrocarbon group or a trivalent heterocyclic group; and X3 and X4 are each independently N, B, P, C(R9), or Si(R10), with the provisos that X3 and X4 must not be the same and that X3 and Ar4 are bonded respectively to the adjacent carbon atoms constituting the aromatic ring of Ar3, and X4 and Ar3 are bonded respectively to the adjacent carbon atoms constituting the aromatic ring of Ar4].

4. 发明授权

US06926973B2 Copolymer, polymer composition and polymer light-emitting device 有权
标题翻译：共聚物，聚合物组合物和聚合物发光装置
公开(公告)号：US06926973B2
公开(公告)日：2005-08-09
申请号：US10322046
申请日：2002-12-18
申请人： Tomoyuki Suzuki , Shuji Doi , Takanobu Noguchi , Akihiko Okada
发明人： Tomoyuki Suzuki , Shuji Doi , Takanobu Noguchi , Akihiko Okada
IPC分类号： C08G61/00 , C08G61/02 , H05B33/14 , C09K11/06
CPC分类号： H01L51/0043 , C08G61/02 , C08L65/00 , C09K11/06 , C09K2211/1416 , C09K2211/1433 , H01L51/0035 , H01L51/0037 , H01L51/0039 , H01L51/5012 , H05B33/14 , Y10S428/917
摘要： A copolymer has a polystyrene reduced number average molecular weight of 103-108, and includes repeating units represented by formulas (1), (2), and (3), —Ar1— (3) The copolymer has an excellent solubility in an organic solvent, and a high glass transition temperature in good valance. Further, a polymer LED has high performance, such as low-voltage driving and high luminance.
摘要翻译：共聚物的聚苯乙烯换算数均分子量为10 -3 -10 8，并且包括由式（1），（2）和（3）表示的重复单元， -Ar 1 - （3）共聚物在有机溶剂中的溶解性优异，玻璃化转变温度高。此外，聚合物LED具有高性能，例如低电压驱动和高亮度。

5. 发明申请

US20050042195A1 New polymer and polymer light-emitting device using the same 失效
标题翻译：新型聚合物和聚合物发光装置使用它
公开(公告)号：US20050042195A1
公开(公告)日：2005-02-24
申请号：US10954223
申请日：2004-10-01
申请人： Satoshi Kobayashi , Takanobu Noguchi , Yoshiaki Tsubata , Makoto Kitano , Shuji Doi , Takahiro Ueoka , Akiko Nakazono
发明人： Satoshi Kobayashi , Takanobu Noguchi , Yoshiaki Tsubata , Makoto Kitano , Shuji Doi , Takahiro Ueoka , Akiko Nakazono
IPC分类号： C07D339/08 , C07F7/08 , C07F9/6568 , C08G61/12 , C08G77/00 , C09K11/06 , A61K31/765 , A61K31/785 , C08L25/02
CPC分类号： C07F9/65683 , C07D333/76 , C07D339/08 , C07F7/081 , C08G61/122 , C08G2261/1424 , C08G2261/3162 , C08G2261/3243 , C08G2261/3244 , C08G2261/5222 , C09K11/06 , C09K2211/1416 , Y10T428/31663
摘要： Provided is a polymer comprising a repeating unit represented by formula (1), wherein, A1 represents a divalent group in which the bond distance ratio (bond distance of C(α)-A1/bond distance of C(α)-C(β)) is 1.10 or more; R1, R2, R3, R4, R5, and R6, each independently represent a hydrogen atom, alkyl group, alkyloxy group, aryloxy group, arylalkyloxy group, etc. The polymer is useful as a light-emitting material, a charge transporting material, etc.
摘要翻译：本发明提供包含由式（1）表示的重复单元的聚合物，其中A 1表示键合距离比（C（α）-A 1的键距离/ C（键距离） α）-C（β））为1.10以上; R 1，R 2，R 3，R 4，R 5和R 6各自独立地表示氢原子，烷基，烷氧基，芳氧基，芳基烷氧基，聚合物可用作发光材料，电荷输送材料等。

6. 发明授权

US06521359B1 Polymeric fluorescent substance and polymer light emitting device 有权
标题翻译：聚合物荧光物质和聚合物发光装置
公开(公告)号：US06521359B1
公开(公告)日：2003-02-18
申请号：US09540901
申请日：2000-03-31
申请人： Takanobu Noguchi , Shuji Doi , Makoto Kitano , Fumi Yamaguchi
发明人： Takanobu Noguchi , Shuji Doi , Makoto Kitano , Fumi Yamaguchi
IPC分类号： H05B3314
CPC分类号： C09K11/06 , H01L51/0038 , H01L51/5012 , Y10S428/917
摘要： Provided is a polymeric fluorescent substance which emits a fluorescence in a solid state, which comprises the following repeating unit in an amount of 20 mol % or more based on the total amount of all repeating units, in the formula, X1 represents a group selected from the group consisting of —CR3═CR4—, —C≡C—, —SiR5R6—, —NR7—, —CO—, —CO—O—, —O—CO—, —SO2—, a carbon-carbon single bond, —O— and —S—. The polymeric fluorescent substance has strong fluorescence, and can be suitably used as a polymer LED and a dye for laser.
摘要翻译：本发明提供一种以固体状态发出荧光的聚合物荧光物质，其以所有重复单元的总量计为20摩尔％以上的重复单元，式中，X1表示选自由-CR3 = CR4-，-C = C-，-SiR5R6-，-NR7-，-CO-，-CO-O-，-O-CO-，-SO2-，碳 - 碳单键组成的组，-O-和-S-。聚合物荧光物质具有强荧光，可适用于聚合物LED和激光用染料。

7. 发明授权

US08003226B2 Metal complex and organic electroluminescent device 有权
标题翻译：金属络合物和有机电致发光器件
公开(公告)号：US08003226B2
公开(公告)日：2011-08-23
申请号：US10508861
申请日：2003-03-24
申请人： Satoshi Kobayashi , Shuji Doi , Satoshi Mikami
发明人： Satoshi Kobayashi , Shuji Doi , Satoshi Mikami
IPC分类号： H01L51/54 , C09K11/06
CPC分类号： H05B33/14 , C07F9/5045 , C07F15/004 , C08G61/12 , C08G61/124 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1092 , C09K2211/182 , C09K2211/185 , H01L51/0084 , H01L51/0085 , H01L51/0089 , H01L51/5016 , Y10S428/917
摘要： A metal complex which has a metal complex structure showing light emission from triplet excited state, and has a monovalent group derived from carbazole, and a light-emitting device using said metal complex.
摘要翻译：具有显示来自三重激发态的发光的金属络合物结构的金属络合物，并且具有衍生自咔唑的一价基团，以及使用所述金属络合物的发光器件。

8. 发明授权

US07701129B2 Polymeric fluorescent substance and polymer light-emitting device using the same 有权
标题翻译：聚合物荧光物质和使用其的聚合物发光装置
公开(公告)号：US07701129B2
公开(公告)日：2010-04-20
申请号：US09995814
申请日：2001-11-29
申请人： Shuji Doi , Yoshiaki Tsubata , Takahiro Ueoka , Shigeru Sasaki , Takanobu Noguchi
发明人： Shuji Doi , Yoshiaki Tsubata , Takahiro Ueoka , Shigeru Sasaki , Takanobu Noguchi
IPC分类号： H01L51/54 , C09K11/06 , C08G61/00
CPC分类号： C09K11/06 , C09K2211/1014 , C09K2211/1408 , C09K2211/1416 , C09K2211/1425 , C09K2211/145 , C09K2211/1466 , H01L51/0035 , H01L51/0038 , H01L51/0039 , H01L51/0043 , H01L51/0059 , H01L51/0085 , H01L51/5012 , Y10S428/917 , Y10T428/10
摘要： A polymeric fluorescent substance exhibiting fluorescence in the solid state, having a polystyrene reduced number-average molecular weight of 1×103 to 1×108, and comprising one or more repeating units of formula (1) and one or more repeating units of formula (8), —Ar1—(CR1═CR2)n— (1) —Ar2—(CR36═CR37)n— (8) wherein Ar1 represents a specific arylene or a divalent heterocyclic compound group, and Ar2 represent an arylene or a divalent heterocyclic compound group other than Ar1. By using the polymeric fluorescent substance, a high performance polymer LED can easily be obtained.
摘要翻译：表现出固态荧光的聚合物荧光物质，其聚苯乙烯换算的数均分子量为1×10 3〜1×10 8，含有一种以上式（1）的重复单元和一种以上式（1）的重复单元， 8），-Ar1-（CR 1 = CR 2）n - （1）-Ar 2 - （CR 36 = CR 37）n - （8）其中Ar 1表示特定亚芳基或二价杂环化合物基团，Ar 2表示亚芳基或二价 Ar1以外的杂环化合物。通过使用聚合物荧光物质，可以容易地获得高性能聚合物LED。

9. 发明授权

US06403236B1 Polymer light emitting device 失效
标题翻译：聚合物发光装置
公开(公告)号：US06403236B1
公开(公告)日：2002-06-11
申请号：US09145338
申请日：1998-09-01
申请人： Toshihiro Ohnishi , Takanobu Noguchi , Shuji Doi
发明人： Toshihiro Ohnishi , Takanobu Noguchi , Shuji Doi
IPC分类号： H05B3300
CPC分类号： H01L51/5012 , H01L51/0035 , H01L51/0038 , Y10S428/917 , Y10T428/24942
摘要： A polymer light emitting device at least having a light emitting layer containing a polymeric fluorescent substance and a charge transporting layer, wherein said polymeric fluorescent substance contains one or more kind of repeating units represented by the following formula (1), —Ar1—CR1═CR2— (1) and said charge transporting layer contains an organic compound satisfying the following conditions 1 and 2 in an amount of from 1 to 70% by weight EOX2−0.15≦EOX1≦EOX2+0.10 (condition 1) &lgr;edge2−30≦&lgr;edge1≦&lgr;edge2+20 (condition 2) (wherein EOX1 and &lgr;edge1 respectively represent an electrochemically determined oxidation potential and an absorption edge wavelength of an absorption spectrum of said organic compound; EOX2 and &lgr;edge2 respectively represent an electrochemically determined oxidation potential and an absorption edge wavelength of an absorption spectrum of said polymeric fluorescent substance used in said light emitting layer; and the unit in the condition 1 is V and the unit in the condition 2 is nm). The polymer light emitting device has a long and excellent stability on driving.
摘要翻译：至少具有含有聚合物荧光物质和电荷输送层的发光层的聚合物发光元件，其中所述聚合物荧光物质含有一种以上由下式（1）表示的重复单元，所述电荷输送层含有满足以下条件1和2的有机化合物的量为1至70重量％（其中EOX1和lambdedge1分别表示所述有机化合物的吸收光谱的电化学测定的氧化电位和吸收边缘波长; EOX2和 lambdedge2分别表示在所述发光层中使用的所述聚合物荧光物质的电化学测定的氧化电位和吸收光谱的吸收边缘波长;条件1中的单位为V，条件2中的单位为nm）。聚合物发光装置在驱动时具有长且极好的稳定性。

10. 发明授权

US5424150A Polymeric solid electrolyte 失效
标题翻译：聚合物固体电解质
公开(公告)号：US5424150A
公开(公告)日：1995-06-13
申请号：US202675
申请日：1994-02-25
申请人： Toshihiro Ohnishi , Shuji Doi , Sumio Hara
发明人： Toshihiro Ohnishi , Shuji Doi , Sumio Hara
IPC分类号： C08G65/26 , H01M10/052 , H01M10/0565 , H01M6/18
CPC分类号： H01M10/052 , C08G65/2609 , C08L71/02 , H01M10/0565 , C08G2650/24 , C08L2205/05
摘要： A polymeric solid electrolyte comprising a high molecular compound and a salt wherein the high molecular compound is a product formed by graft-polymerizing an alkylene oxide to the saponification product of a copolymer of ethylene with a vinyl ester of an aliphatic carboxylic acid. The polymeric solid electrolyte has a high ionic conductivity of 10.sup.-5 S/cm or more even at a temperature of 30.degree. C., shows a low temperature dependency of ionic conductivity and thus can be used as the solid electrolyte of various electrochemical devices such as batteries.
摘要翻译：包含高分子化合物和盐的聚合物固体电解质，其中高分子化合物是通过将烯化氧与乙烯与脂肪族羧酸的乙烯酯的共聚物的皂化产物接枝聚合形成的产物。聚合物固体电解质即使在30℃的温度下也具有10-5S / cm以上的高离子电导率，表现出离子导电性的低温依赖性，因此可用作各种电化学装置的固体电解质，例如作为电池。

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