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1. 发明申请

US20080124552A1 Particle With Rough Surface For Plating Or Vapor Deposition 审中-公开
标题翻译：具有粗糙表面的颗粒用于电镀或气相沉积
公开(公告)号：US20080124552A1
公开(公告)日：2008-05-29
申请号：US11569462
申请日：2005-05-24
申请人： Toshifumi Hashiba , Nami Tsukamoto , Kazutoshi Hayakawa , Satomi Kudo
发明人： Toshifumi Hashiba , Nami Tsukamoto , Kazutoshi Hayakawa , Satomi Kudo
IPC分类号： B32B5/16
CPC分类号： C23C18/1641 , C23C18/1635 , Y10T428/2998
摘要： A particle with a rough surface for plating or vapor deposition which has been formed from a base (A) having first functional groups on the surface thereof and particles (B) having on the surface thereof second functional groups reactive with the first functional groups and having an average particle diameter which is smaller than the diameter of the base (A) and not smaller than 0.1 μm, by uniting the base (A) with the particles (B) through chemical bonds between the first functional groups and the second functional groups, wherein the base (A) has at least two projecting parts on the surface thereof. In this particle, the base has been tenaciously bonded to the protruding particles. Because of this, even when the protruding particles used have a size not smaller than the given size, the particle with a rough surface can secure a surface area while maintaining a thickness of a conductive coating film. As a result, the particle can have high conductivity.
摘要翻译：由表面具有第一官能团的基体（A）形成的具有用于电镀或气相沉积的粗糙表面的颗粒和在其表面上具有与第一官能团反应的第二官能团的颗粒（B），并且具有通过第一官能团和第二官能团之间的化学键将基体（A）与颗粒（B）结合在一起的平均粒径小于基体（A）的直径并且不小于0.1μm，其中所述基座（A）在其表面上具有至少两个突出部分。在该颗粒中，基底已经牢固地结合到突出的颗粒上。因此，即使使用的突出粒子的尺寸不小于给定的尺寸，具有粗糙表面的粒子也可以确保表面积同时保持导电性涂膜的厚度。结果，颗粒可以具有高导电性。

2. 发明申请

US20080020207A1 Particle With Rough Surface And Process For Producing The Same 审中-公开
标题翻译：具有粗糙表面的颗粒和用于生产的颗粒
公开(公告)号：US20080020207A1
公开(公告)日：2008-01-24
申请号：US11569458
申请日：2005-05-24
申请人： Toshifumi Hashiba , Nami Tsukamoto , Kazutoshi Hayakawa , Satomi Kudo
发明人： Toshifumi Hashiba , Nami Tsukamoto , Kazutoshi Hayakawa , Satomi Kudo
IPC分类号： C08J7/12 , C08J5/00
CPC分类号： C01B33/18 , C01P2002/82 , C01P2004/03 , C08F257/02 , C08F265/04 , C08F291/00 , C08F292/00 , C08F293/005 , C08J3/126 , C08J7/12 , C08J2333/00 , C08L51/003 , C08L51/10 , C09C1/3072 , C09C1/3081 , C09C1/309 , C09C1/407 , C09C3/10 , Y10T428/2982 , C08L2666/02
摘要： A particle having a rough surface and obtained from a particle (A) having grafted on the surface thereof a polymer having first functional groups and particles (B) having grafted on the surface thereof a polymer having second functional groups reactive with the first functional groups, by uniting the particle (A) with the particles (B) through chemical bonds between the first functional groups and the second functional groups. In this particle with a rough surface, the core particle has been tenaciously bonded to the protruding particles. Because of this, even when the protruding particles have an increased particle diameter, the protruding particles can be prevented from readily shedding from the core particle.
摘要翻译：具有粗糙表面并由其表面上接枝有第一官能团的聚合物的颗粒（A）获得的颗粒（B）在其表面上接枝具有与第一官能团反应的第二官能团的聚合物，通过使第一官能团和第二官能团之间的化学键将颗粒（A）与颗粒（B）结合在一起。在具有粗糙表面的该颗粒中，核心颗粒已经坚固地结合到突出的颗粒。因此，即使突出粒子具有增加的粒径，也能够防止突起粒子容易从核心粒子脱落。

3. 发明申请

US20070244241A1 Resin Composition 审中-公开
标题翻译：树脂组合物
公开(公告)号：US20070244241A1
公开(公告)日：2007-10-18
申请号：US11578179
申请日：2005-04-11
申请人： Gen Masuda , Toshifumi Hashiba , Kazutoshi Hayakawa , Nami Tsukamoto
发明人： Gen Masuda , Toshifumi Hashiba , Kazutoshi Hayakawa , Nami Tsukamoto
IPC分类号： C08K9/04 , C08L101/00
CPC分类号： C08K9/04
摘要： Disclosed is a resin composition wherein dispersibility of a modifying agent such as an inorganic substance is improved. The acid resistance of this resin composition is not deteriorated even when a modifying agent is blended therein. Specifically, the resin composition includes a base material having a cyano group-containing organic layer and an organic resin. This resin composition is extremely excellent in acid resistance when compared with organic resins which use a base material having an organic layer not containing a cyano group.
摘要翻译：公开了改善了无机物质等改性剂的分散性的树脂组合物。即使在其中混合改性剂，该树脂组合物的耐酸性也不会降低。具体地，树脂组合物包括具有含氰基的有机层和有机树脂的基材。与使用不含氰基的有机层的基材的有机树脂相比，该树脂组合物的耐酸性极好。

4. 发明申请

US20070185240A1 Inorganic-organic composite flame retardant composition 审中-公开
标题翻译：无机 - 有机复合阻燃剂组合物
公开(公告)号：US20070185240A1
公开(公告)日：2007-08-09
申请号：US10583410
申请日：2004-12-17
申请人： Gen Masuda , Toshifumi Hashiba , Kazutoshi Hayakawa , Nami Tsukamoto
发明人： Gen Masuda , Toshifumi Hashiba , Kazutoshi Hayakawa , Nami Tsukamoto
IPC分类号： C08K9/00 , C09K21/00
CPC分类号： C08K9/04
摘要： Disclosed is an inorganic-organic composite flame retardant composition which contains an inorganic hydroxide having a polymer layer and an organic resin. The polymer layer is formed through graft polymerization and has an average thickness of not less than 3 nm. When a shaped article is formed by using such a composition, the shaped article can have a sufficient flame retardance while being prevented from decrease in acid resistance, increase in dielectric constant or the like.
摘要翻译：公开了含有具有聚合物层和有机树脂的无机氢氧化物的无机 - 有机复合阻燃剂组合物。聚合物层通过接枝聚合形成，平均厚度不小于3nm。当通过使用这种组合物形成成形制品时，成形制品可以具有足够的阻燃性，同时防止耐酸性降低，介电常数增加等。

5. 发明授权

US09093196B2 Conductive particles and method of preparing the same 有权
标题翻译：导电颗粒及其制备方法
公开(公告)号：US09093196B2
公开(公告)日：2015-07-28
申请号：US11863379
申请日：2007-09-28
申请人： Toshifumi Hashiba , Kazutoshi Hayakawa , Satomi Kudo , Kohei Moriyama , Tsuyoshi Fujii
发明人： Toshifumi Hashiba , Kazutoshi Hayakawa , Satomi Kudo , Kohei Moriyama , Tsuyoshi Fujii
IPC分类号： H01B1/00 , H01B1/20 , C08J3/12 , H01B1/12 , H05K3/32
CPC分类号： H01B1/20 , C08J3/12 , C08J3/126 , C08J2333/20 , H01B1/128 , H05K3/321 , H05K3/323 , H05K2201/0221 , H05K2201/0233 , Y10T428/2998
摘要： Conductive particles each includes a polymer base particle and a conductive layer coating the polymer base particle. Let the compressive elastic deformation characteristic KX of one conductive particle when the displacement of particle diameter of the conductive particles is X % be defined by the following formula: KX=(3/√2)·(SX−3/2)·(R−1/2)·FX. FX is the load (N) necessary for X % displacement of the conductive particles. SX is the compressive deformation amount (mm) upon X % displacement of the conductive particles. R is the particle radius (mm) of the conductive particles. The compressive elastic deformation characteristic K50 when the displacement of particle diameter of the conductive particles is 50% is 100 to 50000 N/mm2 at 20° C., and the recovery factor of particle diameter of the conductive particles when the displacement of particle diameter of the conductive particles is 50% is not less than 30% at 20° C.
摘要翻译：导电粒子各自包含聚合物基体颗粒和涂覆聚合物基础颗粒的导电层。使导电粒子的粒径的位移为X％时的一个导电性粒子的压缩弹性变形特性KX由下式定义：KX =（3 /√2）·（SX-3/2）·（R -1/2）·FX。 FX是导电颗粒的X％位移所需的载荷（N）。 SX是导电颗粒的X％位移时的压缩变形量（mm）。 R是导电粒子的粒子半径（mm）。导电粒子的粒径为50％时的压缩弹性变形特性K50在20℃为100〜50000N / mm 2，当导电粒子的粒径移动时的导电粒子的粒径的回收率导电颗粒在20℃下为50％不小于30％

6. 发明授权

US07258921B2 Composite particle with a carbodiimide resin layer and a process for producing the same 失效
标题翻译：具有碳二亚胺树脂层的复合颗粒及其制造方法
公开(公告)号：US07258921B2
公开(公告)日：2007-08-21
申请号：US10523816
申请日：2003-08-07
申请人： Toshifumi Hashiba , Kazutoshi Hayakawa , Satomi Kudo , Kaori Satoh , Takaya Sato , Hiroshi Yoshida
发明人： Toshifumi Hashiba , Kazutoshi Hayakawa , Satomi Kudo , Kaori Satoh , Takaya Sato , Hiroshi Yoshida
IPC分类号： B32B5/66
CPC分类号： C08G73/00 , C08J3/005 , C08J3/12 , C08J2379/00 , C08L79/00 , Y10T428/2982 , Y10T428/2991 , Y10T428/2998
摘要： A composite particle that can be easily converted to cured particle or half cured particle by the use of carbodiimide resin without changing of the configuration of matrix particle of, for example a thermoplastic resin, excelling in mechanical and functional characteristics by virtue of the reaction capability inherently possessed by a carbodiimide group. In particular, a composite particle comprising matrix particle (A) having a functional group capable of reacting with a carbodiimide group and carbodiimide resin (B), characterized in that the functional group of the matrix particle (A) couples with the carbodiimide group of the carbodiimide resin (B) and that the composite particle is provided with an outer shell layer of carbodiimide resin (B) having an average thickness diameter (L), defined by the following formula [1], ranging from 0.01 to 20 μm: L=(L2−L1)/2 [1] wherein L1 represents the average diameter of matrix particle, and L2 represents the average diameter of composite particle.
摘要翻译：通过使用碳二亚胺树脂可以容易地转化为固化颗粒或半固化颗粒的复合颗粒，而不改变例如热塑性树脂的基质颗粒的构型，其本身具有优异的机械和功能特性拥有碳化二亚胺组。特别是，具有能够与碳二亚胺基反应的官能团的基质粒子（A）和碳二亚胺树脂（B）的复合粒子，其特征在于，所述基质粒子（A）的官能团与所述碳二亚胺基团碳化二亚胺树脂（B），并且复合颗粒具有由下式[1]定义的平均厚度直径（L）的碳二亚胺树脂（B）的外壳层，其范围为0.01至20μm：L = （L 2 -L 1 -L 1）/ 2 [1]其中L1表示基质颗粒的平均直径，L2表示复合颗粒的平均直径。

7. 发明申请

US20050271875A1 Composite particle with a carbodimide resin layer and process for producing the same 失效
标题翻译：具有碳二酰亚胺树脂层的复合颗粒及其制造方法
公开(公告)号：US20050271875A1
公开(公告)日：2005-12-08
申请号：US10523816
申请日：2003-08-07
申请人： Toshifumi Hashiba , Kazutoshi Hayakawa , Satomi Kudo , Kaori Satoh , Takaya Sato , Hiroshi Yoshida
发明人： Toshifumi Hashiba , Kazutoshi Hayakawa , Satomi Kudo , Kaori Satoh , Takaya Sato , Hiroshi Yoshida
IPC分类号： C08G73/00 , C08J3/00 , C08J3/12 , C08L79/00 , B32B5/16
CPC分类号： C08G73/00 , C08J3/005 , C08J3/12 , C08J2379/00 , C08L79/00 , Y10T428/2982 , Y10T428/2991 , Y10T428/2998
摘要： A composite particle that can be easily converted to cured particle or half cured particle by the use of carbodiimide resin without changing of the configuration of matrix particle of, for example. a thermoplastic resin, excelling in mechanical and functional characteristics by virtue of the reaction capability inherently possessed by a carbodiimide group. In particular, a composite particle comprising matrix particle (A) having a functional group capable of reacting with a carbodiimide group and carbodiimide resin (B), characterized in that the functional group of the matrix particle (A) couples with the carbodiimide group of the carbodiimide resin (B) and that the composite particle is provided with an outer shell layer of carbodiimide resin (B) having an average thickness diameter (L), defined by the following formula [1], ranging from 0.01 to 20 μm: L=(L2−L1)/2 [1] wherein L1 represents the average diameter of matrix particle, and L2 represents the average diameter of composite particle.
摘要翻译：例如可以通过使用碳二亚胺树脂容易地转化为固化颗粒或半固化颗粒的复合颗粒，而不改变例如基质颗粒的构型。一种热塑性树脂，由于碳化二亚胺基固有的反应能力而具有优异的机械性能和功能特性。特别是，具有能够与碳二亚胺基反应的官能团的基质粒子（A）和碳二亚胺树脂（B）的复合粒子，其特征在于，所述基质粒子（A）的官能团与所述碳二亚胺基团碳化二亚胺树脂（B），并且复合颗粒具有由下式[1]定义的平均厚度直径（L）的碳二亚胺树脂（B）的外壳层，其范围为0.01至20μm：L = （L 2 -L 1 -L 1）/ 2 [1]其中L1表示基质颗粒的平均直径，L2表示复合颗粒的平均直径。

8. 发明申请

US20100222477A1 FILLER FOR SUBSTRATE AND COMPOSITION FOR USE AS MATERIAL FOR INORGANIC/ORGANIC COMPOSITE SUBSTRATE FORMATION 审中-公开
标题翻译：用于无机/有机复合材料形成材料的基材和组合物填料
公开(公告)号：US20100222477A1
公开(公告)日：2010-09-02
申请号：US11993350
申请日：2006-06-21
申请人： Nami Tsukamoto , Toshifumi Hashiba , Mayumi Mizushiri
发明人： Nami Tsukamoto , Toshifumi Hashiba , Mayumi Mizushiri
IPC分类号： C08K5/29 , C07C267/00
CPC分类号： C08K9/04 , H05K1/0373 , H05K2201/0209 , H05K2201/0224
摘要： A filler for substrates which comprises an inorganic substance and a carbodiimide-group-containing organic layer chemically bonded to the surface of the inorganic substance. Examples of the carbodiimide-group-containing organic layer include a layer comprising a carbodiimide-group-containing compound represented by either of the following formulae. Due to the constitution, the filler for substrates can be highly dispersed in a resin for substrates even when added in a high proportion and can give a substrate inhibited from deteriorating in electrical properties, mechanical properties, etc. (X1)m—Z-[A-(R1—N═C═N)n—R1—NCO]1 (1) (X1)m—Z-[A-(R1—N═C═N)n—R1-A-Z—(X2)3]1 (2) [R1 represents a residue of an isocyanate compound; X′ and X2 each independently represents hydrogen, halogeno, etc.; Z′s each independently represents silicon or titanium; A represents an organic group having a valence of 2 or higher containing a bond derived from an isocyanate group; m and 1 each is an integer of 1-3, provided that m+1=4; and n is an integer of 1-100.]
摘要翻译：一种用于基材的填料，其包含无机物质和与无机物质的表面化学键合的含碳二亚胺基的有机层。含有碳二亚胺基的有机层的实例包括由下式表示的含碳二亚胺基化合物的层。由于该结构，即使以高比例添加，基板用填料也可以高分散在基板用树脂中，能够抑制电性，机械性能等劣化的基板（X1）m-Z- [ A-（R1-N = C = N）n-R1-NCO] 1（1）（X1）m-Z- [A-（R1-N = C = N）n-R1-AZ-（X2）3 ] 1（2）[R1表示异氰酸酯化合物的残基] X'和X2各自独立地表示氢，卤素等; Z各自独立地表示硅或钛; A表示含有来自异氰酸酯基的键的化合价为2以上的有机基团; m和1各自为1-3的整数，条件是m + 1 = 4; n为1-100的整数。]

9. 发明申请

US20100160512A1 FLAME RETARDANT AND INORGANIC/ORGANIC COMPOSITE FLAME-RETARDANT COMPOSITION 审中-公开
标题翻译：阻燃剂和无机/有机复合阻燃剂组合物
公开(公告)号：US20100160512A1
公开(公告)日：2010-06-24
申请号：US11993333
申请日：2006-06-21
申请人： Nami Tsukamoto , Toshifumi Hashiba , Mayumi Mizushiri
发明人： Nami Tsukamoto , Toshifumi Hashiba , Mayumi Mizushiri
IPC分类号： C08K5/29 , C07C267/00 , C09K21/10 , C07F7/28 , C07F7/02 , B32B5/00
CPC分类号： H05K1/0373 , C08K9/04 , H05K2201/012 , H05K2201/0209 , H05K2201/0224 , Y10T428/2982
摘要： A flame retardant which comprises an inorganic hydroxide and a carbodiimide-group-containing organic layer chemically bonded to the surface of the inorganic hydroxide. Examples of the carbodiimide-group-containing organic layer include a layer comprising a carbodiimide-group-containing compound represented by either of the following formulae. Due to the constitution, the flame retardant can be highly dispersed in a resin even when added in a high proportion and can give a molding inhibited from deteriorating in electrical properties, mechanical properties, etc. (X1)m-Z-[A-(R1—N═C═N)n—R1—NCO]1 (1) (X1)m-Z-[A-(R1—N═C═N)n—R1-A-Z-(X2)3])3 (2) [R1 represents a residue of an isocyanate compound; X1 and X2 each independently represents hydrogen, halogeno, etc.; Z's each independently represents silicon or titanium; A represents an organic group having a valence of 2 or higher containing a bond derived from an isocyanate group; m and l each is an integer of 1-3, provided that m+1=4; and n is an integer of 1-100.]
摘要翻译：一种阻燃剂，其包含无机氢氧化物和与无机氢氧化物的表面化学键合的含碳二亚胺基的有机层。含有碳二亚胺基的有机层的实例包括由下式表示的含碳二亚胺基化合物的层。由于该结构，即使以高比例添加，阻燃剂也可以高度分散在树脂中，并且可以使模制品不受电性能，机械性能等的恶化。（X1）mZ- [A-（R1- N = C-N）n-R1-NCO] 1（1）（X1）mZ- [A-（R1-N = C = N）n-R1-AZ-（X2）3]）3（2）[ R1表示异氰酸酯化合物的残基; X1和X2各自独立地表示氢，卤素等; Z各自独立地表示硅或钛; A表示含有来自异氰酸酯基的键的化合价为2以上的有机基团; m和l各自为1-3的整数，条件是m + 1 = 4; n为1-100的整数。]

10. 发明申请

US20070142595A1 Oval-spherical organic polymer particle and process for producing the same 审中-公开
标题翻译：椭圆球形有机聚合物颗粒及其制备方法
公开(公告)号：US20070142595A1
公开(公告)日：2007-06-21
申请号：US10591404
申请日：2005-03-02
申请人： Toshifumi Hashiba , Kazutoshi Hayakawa , Chihiro Fujii
发明人： Toshifumi Hashiba , Kazutoshi Hayakawa , Chihiro Fujii
IPC分类号： C08F210/00
CPC分类号： C08F212/08 , C08F212/14 , C08F2/08
摘要： Oval-spherical organic polymer panicles having ionic functional groups, which have each one continuous curved surface whose aspect ratio calculated by the formula: aspect ratio (P1)=major axis (L1)/minor axis (D1), wherein the major axis (L1) and minor axis (D1) are those of a projection two-dimensional drawing obtained by light irradiation in the direction orthogonal to the direction of major axis of the panicle, satisfies the relationship (P1)≧1.8. The obtained particles excel in optical properties, such as light scattering and light focusing, and frictional properties, such as sliding characteristic.
摘要翻译：具有离子官能团的椭圆球形有机聚合物圆锥花序，其具有通过下式计算的每个连续曲面的纵横比：纵横比（P <1> 1）=长轴（L 1> 其中长轴（L 1> 1）和短轴（D 1 N 1）是短轴（L 1 SUB）和短轴（D 1 N）通过在与圆锥花序的长轴方向正交的方向上的光照射获得的投影二维图形满足关系式（P1-1）= 1.8。所得到的颗粒在光散射和光聚焦等光学特性以及滑动特性等摩擦性方面优异。

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