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    • 7. 发明授权
    • Propylene composition with high stiffness and impact strength
    • 丙烯组合物具有高刚度和冲击强度
    • US08759452B2
    • 2014-06-24
    • US13129511
    • 2010-02-04
    • Markus GahleitnerBo MalmKlaus BernreitnerJuliane Braun
    • Markus GahleitnerBo MalmKlaus BernreitnerJuliane Braun
    • C08J3/22C08F290/14C08L23/00C08F110/02
    • C08F10/00C08F10/06C08F110/06C08F4/6543C08F4/6492C08F4/651C08F210/16C08F2500/04C08F2500/19C08F2500/12C08F2500/11C08F2500/20C08F2500/24
    • The present invention is directed to a polypropylene composition comprising a propylene homo- or copolymer (A) with a polydispersity index (PI), determined according ISO 6721-1, of at least 5.8 Pa−1; and an inorganic filler (B) in an amount from 2.0 to 20 parts per weight based on 100 parts per weight of (A)+(B); The present invention is furthermore directed to a polypropylene composition comprising a propylene homo- or copolymer (A); and an inorganic filler (B); whereby the following relation is fulfilled (80F+1700)MPa≦T wherein F are the parts per weight of component (B) based on 100 parts per weight of the total amount of (A)+(B). T is the tensile modulus in MPa, determined according to ISO 527-2, of the polypropylene composition measured on a test specimen prepared by injection molding according to ISO 1873-2. The present invention is also directed to a process for the production of the polypropylene compositions according to the invention and to an article made of the polypropylene compositions according to the invention.The present invention is furthermore directed to the use of the polypropylene compositions according to the invention for the production of pipes, car components, appliance housings, transport containers.
    • 本发明涉及一种聚丙烯组合物,其包含根据ISO 6721-1测定的至少5.8Pa-1的具有多分散指数(PI)的丙烯均聚物或共聚物(A) 和每100重量份(A)+(B))为2.0〜20重量份的无机填料(B)。 本发明还涉及包含丙烯均聚物或共聚物(A)的聚丙烯组合物; 和无机填料(B); 由此满足以下关系(80F + 1700)MPa< NlE; T其中F是基于(A)+(B)的总量的每100重量份的组分(B)的重量份数。 T是根据ISO 527-2测定的根据ISO 1873-2通过注射成型制备的试样上测量的聚丙烯组合物的拉伸弹性模量(MPa)。 本发明还涉及一种生产根据本发明的聚丙烯组合物和由本发明的聚丙烯组合物制成的制品的方法。 本发明还涉及根据本发明的聚丙烯组合物用于生产管道,汽车部件,电器外壳,运输容器的用途。
    • 8. 发明授权
    • Pressureless polymer pipe, a compositon therefore, and a process for preparing it
    • 因此,无压聚合物管,组合物及其制备方法
    • US08563109B2
    • 2013-10-22
    • US11661574
    • 2005-08-30
    • Carl-Gustaf EkBo MalmOlli Tuominen
    • Carl-Gustaf EkBo MalmOlli Tuominen
    • B32B1/08C08L23/14C08L23/16C08L23/20
    • F16L9/147C08F210/06C08F210/16C08L23/12C08L23/14Y10T428/139C08F2/001C08L2666/06C08F2500/17C08F2500/12C08F2500/13
    • A pressureless polymer pipe, a composition therefore, and a process of preparing the composition are described. The pipe is characterized in that the polymer comprises a propylene polymer composition where the propylene base polymer is a heterophasic propylene copolymer having a matrix of a propylene homopolymer and a dispersed phase of an elastomeric copolymer of propylene and at least one olefin comonomer; has a comonomer content of 2-7% by weight, based on the weight of the heterophasic propylene copolymer; has a melt flow rate MFR (2/230), determined according to ISO 1133 C4, of 0.1-2.0 g/10 min; has a broad molecular weight distribution as defined by its rheology shear thinning index, SHI0/50, measured at 200° C. of 9-30; has a tensile modulus, determined according to ISO 527-2/1B at 1 mm/min and 23° C. of at least 1800 MPa; has an impact strength, determined according to ISO 179/1 eA of at least 6 kJ/m2 at 0° C. and at least 2 kJ/m2 at −20° C. The composition is a polymer composition as defined above. The process is characterized by polymerizing in the presence of a stereospecific Ziegler-Natta catalyst including an electron donor:(i) a propylene homopolymer matrix in at least one loop reactor at a temperature of at least 80° C. and a pressure of 4600-10000 kPa; and (ii) an elastomeric copolymer of propylene and at least one olefin comonomer in at least one gas-phase reactor at a lower temperature than in stage (i); to obtain a base polymer of heterophasic propylene copolymer as defined above.
    • 描述了无压聚合物管,组合物和制备该组合物的方法。 管的特征在于聚合物包括丙烯聚合物组合物,其中丙烯基聚合物是具有丙烯均聚物基质和丙烯与至少一种烯烃共聚单体的弹性体共聚物的分散相的多相丙烯共聚物; 基于多相丙烯共聚物的重量,共聚单体含量为2-7重量%; 具有根据ISO 1133 C4测定的熔体流动速率MFR(2/230)为0.1-2.0g / 10min; 具有由流变剪切稀化指数SHI0 / 50定义的宽分子量分布,其在200℃下测量为9-30; 具有根据ISO 527-2 / 1B在1mm / min和23℃下测定的至少1800MPa的拉伸模量; 具有根据ISO 179/1eA在0℃下测定为至少6kJ / m 2和-20℃下至少2kJ / m 2的冲击强度。组合物是如上所定义的聚合物组合物。 该方法的特征在于在包含电子给体的立体特异性齐格勒 - 纳塔催化剂存在下聚合:(i)至少一个环管反应器中的丙烯均聚物基质,温度至少为80℃,压力为4600- 10000 kPa; 和(ii)在低于阶段(i)的温度下,在至少一个气相反应器中的丙烯和至少一种烯烃共聚单体的弹性体共聚物; 以获得如上所定义的异相丙烯共聚物的基础聚合物。