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1. 发明授权

US08729106B2 Pesticidal compositions 有权
标题翻译：杀虫剂组合物
公开(公告)号：US08729106B2
公开(公告)日：2014-05-20
申请号：US12516649
申请日：2007-12-12
申请人： Toru Koyanagi , Masayuki Morita , Tetsuo Yoneda , Tsuyoshi Ueda , Kazuhisa Kiriyama , Taku Hamamoto
发明人： Toru Koyanagi , Masayuki Morita , Tetsuo Yoneda , Tsuyoshi Ueda , Kazuhisa Kiriyama , Taku Hamamoto
IPC分类号： A01N43/40 , A01N25/32
CPC分类号： A01N43/56 , A01N43/08 , A01N43/40 , A01N43/78 , A01N53/00 , A01N57/32 , A01N2300/00
摘要： A pesticidal composition comprising synergistically effective amounts of at least one anthranilamide compound represented by the formula (I) or its salt and other pesticide: wherein each of R1a and R1b which are independent of each other, is halogen; each of R2 and R3 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or cyano; A is alkyl substituted by Y; Y is C3-4 cycloalkyl which may be substituted by at least one substituent selected from the group consisting of halogen, alkyl and haloalkyl; n is 0 or 1; and q is an integer of from 0 to 4; provided that R1a and R1b are not simultaneously chlorine nor bromine.
摘要翻译：一种杀虫组合物，其包含协同有效量的由式（I）表示的至少一种邻氨基苯甲酰胺化合物或其盐和其它农药：其中彼此独立的R 1a和R 1b各自为卤素; R2和R3各自为卤素，烷基，卤代烷基，烷氧基，卤代烷氧基或氰基; A是被Y取代的烷基; Y是可被至少一个选自卤素，烷基和卤代烷基的取代基取代的C3-4环烷基; n为0或1; q为0〜4的整数，条件是R1a和R1b不同时为氯或溴。

2. 发明申请

US20100028304A1 PESTICIDAL COMPOSITIONS 有权
标题翻译：农药组合物
公开(公告)号：US20100028304A1
公开(公告)日：2010-02-04
申请号：US12516649
申请日：2007-12-12
申请人： Toru Koyanagi , Masayuki Morita , Tetsuo Yoneda , Tsuyoshi Ueda , Kazuhisa Kiriyama , Taku Hamamoto
发明人： Toru Koyanagi , Masayuki Morita , Tetsuo Yoneda , Tsuyoshi Ueda , Kazuhisa Kiriyama , Taku Hamamoto
IPC分类号： A01N43/40 , A01N63/02 , A01N63/04 , A01P7/04 , A01P3/00
CPC分类号： A01N43/56 , A01N43/08 , A01N43/40 , A01N43/78 , A01N53/00 , A01N57/32 , A01N2300/00
摘要： A pesticidal composition comprising synergistically effective amounts of at least one anthranilamide compound represented by the formula (I) or its salt and other pesticide: wherein each of R1a and R1b which are independent of each other, is halogen; each of R2 and R3 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or cyano; A is alkyl substituted by Y; Y is C3-4 cycloalkyl which may be substituted by at least one substituent selected from the group consisting of halogen, alkyl and haloalkyl; n is 0 or 1; and q is an integer of from 0 to 4; provided that R1a and R1b are not simultaneously chlorine nor bromine.
摘要翻译：一种杀虫组合物，其包含协同有效量的由式（I）表示的至少一种邻氨基苯甲酰胺化合物或其盐和其它农药：其中彼此独立的R 1a和R 1b各自为卤素; R2和R3各自为卤素，烷基，卤代烷基，烷氧基，卤代烷氧基或氰基; A是被Y取代的烷基; Y是可被至少一个选自卤素，烷基和卤代烷基的取代基取代的C3-4环烷基; n为0或1; q为0〜4的整数，条件是R1a和R1b不同时为氯或溴。

3. 发明授权

US5288727A Hydrazone compounds, processes for their production, intermediates useful for their production and pesticidal compositions containing them 失效
标题翻译：腙化合物，其制备方法，可用于其生产的中间体和含有它们的杀虫组合物
公开(公告)号：US5288727A
公开(公告)日：1994-02-22
申请号：US834835
申请日：1992-02-13
申请人： Tadaaki Toki , Toru Koyanagi , Kiyomitsu Yoshida , Hiroshi Sasaki , Masayuki Morita , Tetsuo Yoneda
发明人： Tadaaki Toki , Toru Koyanagi , Kiyomitsu Yoshida , Hiroshi Sasaki , Masayuki Morita , Tetsuo Yoneda
IPC分类号： H01L21/02 , A01N33/00 , A01N35/10 , A01N37/52 , A01N47/06 , A01N47/24 , A01N47/34 , A01N55/00 , C07C45/00 , C07C45/27 , C07C49/215 , C07C49/233 , C07C49/782 , C07C49/813 , C07C249/16 , C07C251/08 , C07C251/72 , C07C251/86 , C07C251/88 , C07C257/02 , C07C257/06 , C07C257/22 , C07C281/04 , C07C281/14 , C07C303/30 , C07C303/40 , C07C309/65 , C07C309/66 , C07C309/73 , C07C311/08 , C07C311/49 , C07C317/32 , C07C319/20 , C07C323/45 , C07C323/48 , C07C323/65 , C07F7/18 , C07F9/09 , H01L21/677 , H01L21/68 , C07C251/80 , A01N47/40
CPC分类号： C07C323/65 , A01N35/10 , A01N37/52 , A01N47/06 , A01N47/24 , A01N47/34 , A01N55/00 , C07C251/86 , C07C251/88 , C07C257/06 , C07C257/22 , C07C281/04 , C07C281/14 , C07C309/65 , C07C309/66 , C07C309/73 , C07C311/08 , C07C311/49 , C07C317/32 , C07C323/45 , C07C45/004 , C07C45/27 , C07C49/782 , C07C49/813
摘要： The present invention relates to a hydrazone compound of the formula (I) or its salt, a process for its preparation, an intermediate of the formula (II-5), a pesticidal composition containing said hydrazone compound or its salt as the active ingredient, and a pesticidal method of applying an effective amount thereof: ##STR1##
摘要翻译：本发明涉及式（I）的腙化合物或其盐，其制备方法，式（II-5）的中间体，含有所述腙化合物或其盐作为活性成分的杀虫组合物，（*化学结构*）（I）（*化学结构*）（II-5）的有效量的杀虫剂法

4. 发明授权

US5360806A Amide compounds and their salts and pesticidal compositions containing them 失效
标题翻译：酰胺化合物及其盐和含有它们的农药组合物
公开(公告)号：US5360806A
公开(公告)日：1994-11-01
申请号：US95192
申请日：1993-07-23
申请人： Tadaaki Toki , Toru Koyanagi , Masayuki Morita , Tetsuo Yoneda , Chiharu Kagimoto , Hiroshi Okada
发明人： Tadaaki Toki , Toru Koyanagi , Masayuki Morita , Tetsuo Yoneda , Chiharu Kagimoto , Hiroshi Okada
IPC分类号： A01N43/40 , C07D213/82 , C07D213/89 , C07D401/12 , C07D401/14 , C07D413/12
CPC分类号： C07D213/82 , A01N43/40 , C07D213/89
摘要： The present invention relates to an amide compound and its salt, process for its production and a pesticidal composition containing it.The amide compound of the formula (I) or its salt: ##STR1## wherein the radicals are defined in the claims.
摘要翻译：本发明涉及酰胺化合物及其盐，其生产方法和含有它的杀虫组合物。式（I）的酰胺化合物或其盐：其中基团在权利要求中定义。

5. 发明授权

US06624179B1 Geometrical isomers of acrylonitrile compounds, mixture thereof, and process for producing these 有权
标题翻译：丙烯腈化合物的几何异构体，其混合物，及其制备方法
公开(公告)号：US06624179B1
公开(公告)日：2003-09-23
申请号：US10030122
申请日：2002-01-24
申请人： Toru Koyanagi , Yuji Nakamura , Masayuki Morita , Tsuyoshi Ueda , Akihiro Hisamatsu , Mayumi Kanamori
发明人： Toru Koyanagi , Yuji Nakamura , Masayuki Morita , Tsuyoshi Ueda , Akihiro Hisamatsu , Mayumi Kanamori
IPC分类号： A61K3144
CPC分类号： C07C329/16 , C07B2200/09 , C07C255/34 , C07C255/38 , C07C329/04 , C07C329/06
摘要： A geometrical isomer of an acrylonitrile compound represented by the formula (I) or of its salt, or a mixture thereof: [wherein T is phenyl or pyridyl, which is substituted by R2, Q is phenyl, thienyl, pyridyl or benzyl, which may be substituted by R3, R1 is —C(═O)R4 or —C(═S)R4, R4 is alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, alkenylthio, alkynylthio, cycloalkyl, cycloalkyloxy, cycloalkylthio, —N(R5)R6, phenyl, phenoxy, phenylthio, benzyl, benzyloxy, benzylthio, —J, —O—J or —S—J], wherein the geometrical isomer has a longer retention time when analyzed by reversed phase liquid chromatography in which a packing comprising silica having chemically bonded thereto an alkyl group selected from trimethyl, octyl and octadecyl, is used as the stationary phase, and a polar solvent selected from water, methanol and acetonitrile, is used as the mobile phase, and the geometrical isomer mixture contains such geometrical isomer in a larger proportion.
摘要翻译：由式（I）表示的丙烯腈化合物或其盐的几何异构体或其混合物：[其中T是被R 2取代的苯基或吡啶基，Q是苯基，噻吩基，吡啶基或苄基，其可以被R 3取代，R 1是-C（= O）R 4或-C（= S）R 4，R 4是烷基，烯基，炔基，烷氧基，烯氧基，炔氧基，烷硫基，链烯硫基，炔硫基，环烷基，环烷氧基， N（R 5）R 6，苯基，苯氧基，苯硫基，苄基，苄氧基，苄硫基，-J，-OJ或-SJ]，其中几何异构体在通过反相液相色谱分析时具有更长的保留时间，化学键合有选自三甲基，辛基和十八烷基的烷基作为固定相，使用选自水，甲醇和乙腈的极性溶剂作为流动相，几何异构体混合物含有这种几何异构体比例较大。

6. 发明授权

US08115006B2 Process for producing anthranilamide compound 有权
标题翻译：邻氨基苯甲酰胺化合物的制备方法
公开(公告)号：US08115006B2
公开(公告)日：2012-02-14
申请号：US12519177
申请日：2007-12-14
申请人： Toru Koyanagi , Kazuhiro Yamamoto , Tetsuo Yoneda , Shigehisa Kanbayashi , Toyoshi Tanimura , Yohei Taguchi , Tatsunori Yoshida
发明人： Toru Koyanagi , Kazuhiro Yamamoto , Tetsuo Yoneda , Shigehisa Kanbayashi , Toyoshi Tanimura , Yohei Taguchi , Tatsunori Yoshida
IPC分类号： C07D401/04
CPC分类号： C07D401/04 , C07C237/30 , C07C237/42 , C07C2601/02 , C07C2601/04 , C07D231/08 , C07D267/06
摘要： To provide a process for producing a specific anthranilamide compound or its salt.To provide a process for producing an anthranilamide compound represented by the formula (I) or its salt: wherein each of R1a and R3 which are independent of each other, is halogen or haloalkyl; R2 is cyclopropyl alkyl or cyclobutyl alkyl; and Hal is a chlorine atom or a bromine atom, which comprises a step of selectively halogenating a compound represented by the formula (II): wherein R1a, R2 and R3 are as defined above.
摘要翻译：提供制备特定的邻氨基苯甲酰胺化合物或其盐的方法。提供一种制备由式（I）表示的邻氨基苯甲酰胺化合物或其盐：其中彼此独立的R 1a和R 3各自为卤素或卤代烷基; R2是环丙基烷基或环丁基烷基; 和Hal是氯原子或溴原子，其包括选择性卤化由式（II）表示的化合物的步骤：其中R 1a，R 2和R 3如上所定义。

7. 发明申请

US20100063293A1 PROCESS FOR PRODUCING ANTHRANILAMIDE COMPOUND 有权
标题翻译：生产苯磺酰胺化合物的方法
公开(公告)号：US20100063293A1
公开(公告)日：2010-03-11
申请号：US12519177
申请日：2007-12-14
申请人： Toru Koyanagi , Kazuhiro Yamamoto , Tetsuo Yoneda , Shigehisa Kanbayashi , Toyoshi Tanimura , Yohei Taguchi , Tatsunori Yoshida
发明人： Toru Koyanagi , Kazuhiro Yamamoto , Tetsuo Yoneda , Shigehisa Kanbayashi , Toyoshi Tanimura , Yohei Taguchi , Tatsunori Yoshida
IPC分类号： C07D401/04 , C07C233/00 , C07D231/00
CPC分类号： C07D401/04 , C07C237/30 , C07C237/42 , C07C2601/02 , C07C2601/04 , C07D231/08 , C07D267/06
摘要： To provide a process for producing a specific anthranilamide compound or its salt.To provide a process for producing an anthranilamide compound represented by the formula (I) or its salt: wherein each of R1a and R3 which are independent of each other, is halogen or haloalkyl; R2 is cyclopropyl alkyl or cyclobutyl alkyl; and Hal is a chlorine atom or a bromine atom, which comprises a step of selectively halogenating a compound represented by the formula (II): wherein R1a, R2 and R3 are as defined above.
摘要翻译：提供制备特定的邻氨基苯甲酰胺化合物或其盐的方法。提供一种制备由式（I）表示的邻氨基苯甲酰胺化合物或其盐：其中彼此独立的R 1a和R 3各自为卤素或卤代烷基; R2是环丙基烷基或环丁基烷基; 和Hal是氯原子或溴原子，其包括选择性卤化由式（II）表示的化合物的步骤：其中R 1a，R 2和R 3如上所定义。

8. 发明授权

US5708175A Process for producing 4-trifluoromethylnicotinic acid 失效
标题翻译：生产4-三氟甲基烟酸的方法
公开(公告)号：US5708175A
公开(公告)日：1998-01-13
申请号：US648761
申请日：1996-05-16
申请人： Toru Koyanagi , Tetsuo Yoneda , Fumio Kanamori , Shigehisa Kanbayashi , Toyoshi Tanimura , Noriyuki Horiuchi
发明人： Toru Koyanagi , Tetsuo Yoneda , Fumio Kanamori , Shigehisa Kanbayashi , Toyoshi Tanimura , Noriyuki Horiuchi
IPC分类号： C07C45/45 , C07C49/255 , C07C221/00 , C07C225/14 , C07C229/22 , C07C229/30 , C07C251/08 , C07D213/80 , C07D213/12 , C07D213/08
CPC分类号： C07D213/80 , C07C221/00 , C07C229/22 , C07C229/30 , C07C251/08 , C07C45/455 , C07C49/255
摘要： A process for producing 4-trifluoromethylnicotinic acid of the formula (VIII) or its salt: ##STR1## which comprises (i) a first step of reacting a halide of the formula (I): CF.sub.3 COHal (I) wherein Hal is a halogen atom, with a compound of the formula (II): CH.sub.2 .dbd.CHOR.sup.1 (II) wherein R.sup.1 is an alkyl group, in the presence of a base to obtain a 4-alkoxy-1,1,1-trifluoro-3-buten-2-one of the formula (III): CF.sub.3 CO--CH.dbd.CH--OR.sup.1 (III) wherein R.sup.1 is as defined above, and reacting this compound with ammonia to obtain 4-amino-1,1,1-trifluoro-3-buten-2-one of the formula (IV): ##STR2## and (ii) a second step of subjecting the 4-amino-1,1,1-trifluoro-3-buten-2-one obtained in the first step and a compound of the formula (V): ACO.sub.2 R.sup.2 (V) wherein R.sup.2 is an ester-forming residue, and A is (R.sup.3 O)CH.dbd.CH-- or (R.sup.3 O).sub.2 CHCH.sub.2 --, wherein R.sup.3 is an alkyl group, to a condensation reaction to obtain a compound of the formula (VI) (inclusive of its salt): ##STR3## wherein R.sup.2 is as defined above, and/or a compound of the formula (VII) (inclusive of its salt): ##STR4## wherein R.sup.2 and R.sup.3 are as defined above, as the reaction product, and then subjecting the reaction product to ring closure and hydrolysis.
摘要翻译：（VIII）的4-三氟甲基烟酸或其盐：（Ⅷ）的方法，其包括（ⅰ）使式（I）的卤化物：CF 3 COHal（I）（其中Hal为卤素原子与式（II）的化合物：CH 2 = CHOR 1（II）其中R 1是烷基，在碱的存在下，得到4-烷氧基-1,1,1-三氟-3- （III）的丁烯-2-酮：CF 3 CO-CH = CH-OR 1（III）其中R 1如上定义，并使该化合物与氨反应，得到4-氨基-1,1,1-三氟-3 （IV）的2-丁烯-2-酮：（IV）和（ii）第二步，将得到的4-氨基-1,1,1-三氟-3-丁烯-2-酮第一步和式（V）化合物：其中R 2为酯形成残基，A为（R 3 O）CH = CH-或（R 3 O）2 CHCH 2 - ，其中R 3为烷基，进行缩合反应，得到式（VI）化合物（包括其盐）：其中R 2如上所定义，和/或式（VII）（包括其盐）：其中R2和R3如上定义，作为反应产物，然后使反应产物闭环并水解。

9. 发明授权

US08470856B2 Anthranilamide compounds, process for their production and pesticides containing them 有权
标题翻译：邻氨基苯甲酰胺化合物，其生产过程和含有它们的农药
公开(公告)号：US08470856B2
公开(公告)日：2013-06-25
申请号：US13172358
申请日：2011-06-29
申请人： Toru Koyanagi , Masayuki Morita , Kenichi Nakamoto , Akihiro Hisamatsu
发明人： Toru Koyanagi , Masayuki Morita , Kenichi Nakamoto , Akihiro Hisamatsu
IPC分类号： A01N43/56 , A01N43/40 , C07D401/12
CPC分类号： C07D401/04 , A01N43/56
摘要： Anthranilamide compounds, a process for their production, and pesticides containing these compounds as active ingredients. This Abstract is not intended to define the invention disclosed in the specification, nor intended to limit the scope of the invention in any way.
摘要翻译：邻氨基苯甲酰胺化合物，其生产方法和含有这些化合物作为活性成分的农药。本摘要不旨在限定说明书中公开的发明，也不旨在以任何方式限制本发明的范围。

10. 发明申请

US20070129407A1 Anthranilamides, process for the production thereof, and pest controllers containing the same 有权
标题翻译：邻氨基苯甲酰胺，其制备方法和含有它们的害虫控制剂
公开(公告)号：US20070129407A1
公开(公告)日：2007-06-07
申请号：US10589782
申请日：2005-02-16
申请人： Toru Koyanagi , Masayuki Morita , Kenichi Nakamoto , Akihiro Hisamatsu
发明人： Toru Koyanagi , Masayuki Morita , Kenichi Nakamoto , Akihiro Hisamatsu
IPC分类号： A61K31/4439 , C07D403/02
CPC分类号： C07D401/04 , A01N43/56
摘要： To provide a novel anthranilamide compound or its salt which is useful as a pesticide; a process for its production; and a pesticide containing such a compound as an active ingredient. An anthranilamide compound represented by the formula (I) or its salt. In the formula, R1 is halogen, alkyl, haloalkyl, etc.; each of R2 and R3 which are independent of each other, is halogen, alkyl, haloalkyl, etc.; A is alkyl substituted by Y; Y is C3-4 cycloalkyl which may be substituted by at least one substituent selected from the group consisting of halogen, alkyl and haloalkyl; m is from 0 to 4; n is 0 or 1; and q is from 0 to 4.
摘要翻译：提供可用作农药的新型邻氨基苯甲酰胺化合物或其盐; 一个生产过程; 和含有这种化合物作为活性成分的农药。由式（I）表示的邻氨基苯甲酰胺化合物或其盐。在该式中，R 1是卤素，烷基，卤代烷基等; R 2和R 3彼此独立的是卤素，烷基，卤代烷基等; A是被Y取代的烷基; Y是可被至少一个选自卤素，烷基和卤代烷基的取代基取代的C 3-4环烷基; m为0〜4; n为0或1; q为0〜4。

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