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1. 发明授权

US4381221A Process for recovering a reaction product while preventing decomposition of the catalyst 失效
标题翻译：回收反应产物同时防止催化剂分解的方法
公开(公告)号：US4381221A
公开(公告)日：1983-04-26
申请号：US292924
申请日：1981-08-14
申请人： Tomiya Isshiki , Hisashi Yoshino , Kaoru Tsuyuki
发明人： Tomiya Isshiki , Hisashi Yoshino , Kaoru Tsuyuki
IPC分类号： C07C53/00 , B01J23/86 , B01J23/94 , B01J23/96 , B01J27/32 , B01J31/40 , B01J38/00 , C07C51/00 , C07C51/12 , C07C51/44 , C07C67/00 , C07C67/36 , B01D3/34
CPC分类号： C07C51/44
摘要： In a process for recovering an aliphatic carboxylic acid and/or an ester thereof by distilling a liquid mixture containing the aliphatic carboxylic acid and/or the ester thereof and a catalyst of a metal of Group VIII of the periodic table of elements, the improvement wherein the distillation is carried out in the presence of carbon monoxide at a partial pressure of at least 0.01 kg/cm.sup.2 (absolute) in the distillation system to prevent the decomposition of said catalyst.
摘要翻译：在通过蒸馏含有脂族羧酸和/或其酯的液体混合物和元素周期表第Ⅷ族金属催化剂的方法中回收脂肪族羧酸和/或其酯的方法，其改进在于蒸馏在一氧化碳存在下，在蒸馏系统中以至少0.01kg / cm 2（绝对）的分压进行，以防止所述催化剂分解。

2. 发明授权

US4239741A Process for producing hydrazine sulfate 失效
标题翻译：硫酸肼生产方法
公开(公告)号：US4239741A
公开(公告)日：1980-12-16
申请号：US955166
申请日：1978-10-27
申请人： Tomiya Isshiki , Tetsuo Tomita , Toshiaki Kozaki , Osamu Aoki , Mitsuo Abe , Norio Takeda , Mitsuo Miura , Yoshiyuki Aoki , Takao Kondo , Kaoru Tsuyuki
发明人： Tomiya Isshiki , Tetsuo Tomita , Toshiaki Kozaki , Osamu Aoki , Mitsuo Abe , Norio Takeda , Mitsuo Miura , Yoshiyuki Aoki , Takao Kondo , Kaoru Tsuyuki
IPC分类号： C01B21/16 , C01B21/54
CPC分类号： C01B21/16
摘要： Hydrazine sulfate having a relatively large particle diameter and a high purity is produced by hydrolysis of benzophenoneazines by sulfuric acid having a concentration of 75% by weight or less in an amount of 1.1 times by mole or more the stoichiometric amount in a very high conversion and a high yield with less operational loss.
摘要翻译：通过以非常高的转化率使化学计量量为1.1倍摩尔以上的浓度为75重量％以下的硫酸水解二苯甲酮酮而产生具有较大粒径且高纯度的硫酸肼，产量高，运营损失少。

3. 发明授权

US5344972A Process for producing acetic acid 失效
标题翻译：生产乙酸的方法
公开(公告)号：US5344972A
公开(公告)日：1994-09-06
申请号：US400106
申请日：1982-07-20
申请人： Tomiya Isshiki , Yasuhiko Kijima , Takayuki Watanabe
发明人： Tomiya Isshiki , Yasuhiko Kijima , Takayuki Watanabe
IPC分类号： B01J27/00 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/12 , C07C51/353 , C07C53/08 , C07C67/00
CPC分类号： C07C51/353
摘要： There is disclosed a process for producing acetic acid in which methyl formate is isomerized into acetic acid with a catalyst containing at least one of Pd, Ru and Ir, at least one compound of said metals or a mixture thereof, and a promoter of a halide compound in the presence of carbon monoxide. This process can be carried out under mild reaction conditions and acetic acid is obtained in high yield.
摘要翻译：公开了一种生产乙酸的方法，其中甲酸甲酯与含有Pd，Ru和Ir中至少一种的催化剂异构化成乙酸，至少一种所述金属或其混合物的化合物和卤化物的助催化剂化合物在一氧化碳存在下。该方法可以在温和的反应条件下进行，并以高产率获得乙酸。

4. 发明授权

US4517377A Process for producing vinyl acetate 失效
标题翻译：乙酸乙烯酯的制造方法
公开(公告)号：US4517377A
公开(公告)日：1985-05-14
申请号：US390074
申请日：1982-06-18
申请人： Tomiya Isshiki , Takanari Nawata , Yasuhiko Kijima , Akira Ito , Takayuki Watanabe
发明人： Tomiya Isshiki , Takanari Nawata , Yasuhiko Kijima , Akira Ito , Takayuki Watanabe
IPC分类号： B01J27/00 , B01J27/06 , B01J31/00 , B01J31/02 , C07B61/00 , C07C67/297 , C07C69/15
CPC分类号： C07C67/297
摘要： A process for producing vinyl acetate which comprises decomposing ethylidene diacetate in the presence of at least one compound selected from fluorides, bromides, chlorides, iodides, halogens and mixtures thereof is disclosed. According to this invention decomposition rate of ethylidene diacetate is high and selectivity to vinyl acetate is also high.
摘要翻译：公开了一种制备乙酸乙烯酯的方法，其包括在至少一种选自氟化物，溴化物，氯化物，碘化物，卤素及其混合物的化合物存在下分解亚乙基二乙酸酯。根据本发明，亚乙基二乙酸酯的分解速率高，对乙酸乙烯酯的选择性也高。

5. 发明授权

US4659865A Process for producing ethylidenediacetate 失效
标题翻译：乙二乙酸乙酯的制备方法
公开(公告)号：US4659865A
公开(公告)日：1987-04-21
申请号：US636067
申请日：1984-07-30
申请人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi , Takayuki Yasunaga
发明人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi , Takayuki Yasunaga
IPC分类号： C07C67/37 , B01J27/00 , C07B61/00 , C07C27/00 , C07C67/00 , C07C67/36 , C07C69/16 , C07C67/38
CPC分类号： C07C67/36 , C07C67/37
摘要： A process for producing ethylidenediacetate which comprises reacting methyl acetate or dimethyl ether, carbon monoxide and hydrogen in the presence of catalyst comprising as a secondary-component at least one material selected from the group consisting of, iodides and bromides and as a main component combination of (1) at least one material selected from the group consisting of nickel and nickel compounds, at least one material selected from the group consisting of cobalt and cobalt compounds under substantially anhydrous conditions is disclosed. According to the present invention synthesis of ethylidenediacetate is achieved by using a cheaper catalyst than the prior catalyst.
摘要翻译：制备亚乙基二乙酸酯的方法，其包括在催化剂存在下使乙酸甲酯或二甲醚，一氧化碳和氢气反应，所述催化剂包含作为次要组分的至少一种选自碘化物和溴化物的材料，并且作为主要组分（1）公开了在基本无水条件下选自镍和镍化合物，至少一种选自钴和钴化合物的材料中的至少一种材料。根据本发明，通过使用比现有催化剂更便宜的催化剂来实现亚乙基二乙酸酯的合成。

6. 发明授权

US4556519A Process for producing acetic anhydride 失效
标题翻译：生产乙酸酐的方法
公开(公告)号：US4556519A
公开(公告)日：1985-12-03
申请号：US568526
申请日：1984-01-06
申请人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi , Takao Kondo
发明人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi , Takao Kondo
IPC分类号： C07C51/54 , C07C51/56
CPC分类号： C07C51/54 , C07C51/56
摘要： A process for producing acetic anhydride which comprises reacting methyl acetate or dimethyl ether with carbon monoxide in the presence of a catalyst comprising (a) nickel or a nickel compound and (b) at least one halide selected from the group consisting of bromides, iodides and mixtures thereof, and together with a specific co-catalyst which is disclosed. According to this invention acetic anhydride is produced by using highly active non-expensive catalyst and co-catalyst.
摘要翻译：一种生产乙酸酐的方法，其包括使乙酸甲酯或二甲醚与一氧化碳在催化剂存在下反应，所述催化剂包含（a）镍或镍化合物和（b）至少一种选自溴化物，碘化物和并且与所公开的特定助催化剂一起。根据本发明，通过使用高活性非昂贵的催化剂和助催化剂制备乙酸酐。

7. 发明授权

US4239698A Process for preparing carboxylic acid anhydrides 失效
标题翻译：制备羧酸酐的方法
公开(公告)号：US4239698A
公开(公告)日：1980-12-16
申请号：US949853
申请日：1978-10-10
申请人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi
发明人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi
IPC分类号： C07C53/00 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/10 , C07C51/56 , C07C67/00 , C07C51/54
CPC分类号： C07C51/10
摘要： A process for preparing a carboxylic acid anhydride by reacting an aliphatic carboxylic acid ester or an ether with carbon monoxide in the presence of elemental nickel or a nickel compound, iodine or an iodine compound and an organic compound of a trivalent nitrogen-group element; wherein said iodine or iodine compound is selected from the following formulae (I) to (IV),RX.sub.n (I)wherein R represents a hydrogen atom or an alkyl or alkylene group, X represents an iodine or bromine atom, n represents an integer of 1 to 3, and at least one of n X's is an iodine atom,I.sub.2 or I.sub.3.sup.- (II)RCOI (III)wherein R represents an alkyl group, andMI.sub.2 (IV)wherein M represents an alkaline earth metal, and is used in an amount such that the free iodine or iodine compound not chemically combined with said nickel or nickel compound or with said organic compound of a nitrogen-group element is present in an amount of at least 0.2 mole, as elemental iodine, per mole of each of said nitrogen-group element compound and said nickel or nickel compound, and wherein the reaction is carried out in the presence of an aliphatic carboxylic acid solvent.
摘要翻译：在元素镍或镍化合物，碘或碘化合物和三价氮基元素的有机化合物存在下，使脂族羧酸酯或醚与一氧化碳反应制备羧酸酐的方法; 其中所述碘或碘化合物选自下式（I）至（IV），RXn（I）其中R表示氢原子或烷基或亚烷基，X表示碘或溴原子，n表示整数 1至3，并且n X中的至少一个为碘原子，I 2或I 3 - （II）R COI（III）其中R表示烷基，MI 2（IV）其中M表示碱土金属，并且使用其量使得不与所述镍或镍化合物或所述有机化合物与氮基元素化学结合的游离碘或碘化合物以每摩尔每摩尔至少0.2摩尔的元素碘的量存在，作为元素碘的所述氮族元素化合物和所述镍或镍化合物，并且其中所述反应在脂族羧酸溶剂的存在下进行。

8. 发明授权

US4828762A Process for the production of 2,3,5-trimethylbenzoquinone 失效
标题翻译：生产2,3,5-三甲基苯醌的方法
公开(公告)号：US4828762A
公开(公告)日：1989-05-09
申请号：US947503
申请日：1986-12-29
申请人： Tomiya Isshiki , Tomoyuki Yui , Mitsuo Abe , Masahiro Jono , Hideo Uno
发明人： Tomiya Isshiki , Tomoyuki Yui , Mitsuo Abe , Masahiro Jono , Hideo Uno
IPC分类号： B01J27/08 , B01J27/122 , C07C46/08
CPC分类号： B01J27/122 , B01J27/08 , C07C46/08
摘要： A process for the production of 2,3,5-trimethylbenzoquinone (TMBQ) from 2,3,6-trimethylphenol (TMP) is described, comprising contacting TMP with oxygen or an oxygen containing gas in a medium of water and an aliphatic alcohol having from 5 to 10 carbon atoms in the presence of catalyst of a copper halogen complex represented by the formula as shown below or a mixture of the copper halogen complex and an alkali metal halide or a mixture of the copper halogen complex, an alkali metal halide and cupric hydroxide and/or cuprous chlorideM.sub.l [Cu(II).sub.m X.sub.n ].sub.pwherein M is an alkali metal or ammonium, Cu(II) is a divalent copper, X is a halogen atom, l is an integer of 1 to 3, m is 1 or 2, n is an integer or 3 to 8, p is 1 or 2, and l+2mp=np. The process is carried out in a batch system, a semi-batch system or in a continuous flow system. The third mentioned catalyst system is most effectively utilized in the semi-batch system. The present process yields various advantages; for example, TMBQ can be produced with high selectivity, and since the reaction is performed in a specific medium (the medium is heterogeneous because the alcohols are immiscible or only slightly miscible with water) and TMBQ is soluble in the alcohol layer, while the catalyst is soluble in the water layer, the TMBQ can be easily separated and reuse of the catalyst can be accomplished by a simplified procedure. TMBQ is a useful compound as an intermediate for use in the preparation of Vitamin E.
摘要翻译：描述了从2,3,6-三甲基苯酚（TMP）生产2,3,5-三甲基苯醌（TMBQ）的方法，包括将TMP与氧或含氧气体在水和脂族醇的介质中接触，在由下式表示的铜卤素络合物的催化剂存在下的5至10个碳原子或铜卤素络合物和碱金属卤化物的混合物或铜卤素络合物，碱金属卤化物和碱金属卤化物的混合物氢氧化铜和/或氯化亚铜M1 [Cu（II）mXn] p其中M为碱金属或铵，Cu（II）为二价铜，X为卤素原子，l为1〜3的整数，m 为1或2，n为整数或3至8，p为1或2，l + 2mp = np。该方法在分批系统，半分批系统或连续流系统中进行。第三种催化剂体系在半分批系统中最有效地利用。本方法产生各种优点; 例如，可以高选择性地制备TMBQ，并且由于反应在特定介质中进行（介质是异质的，因为醇是不混溶的或仅与水轻微混溶），并且TMBQ可溶于醇层，而催化剂可溶于水层，TMBQ可以容易地分离，催化剂的再利用可以通过简化的程序完成。 TMBQ是一种有用的化合物，作为用于制备维生素E的中间体。

9. 发明授权

US4336399A Process for producing carboxylic acids and/or esters thereof 失效
标题翻译：制备羧酸和/或其酯的方法
公开(公告)号：US4336399A
公开(公告)日：1982-06-22
申请号：US205591
申请日：1980-11-10
申请人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi
发明人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi
IPC分类号： C07C67/37 , B01J23/00 , B01J27/00 , B01J31/00 , C07B61/00 , C07C27/00 , C07C51/00 , C07C51/12 , C07C51/56 , C07C53/00 , C07C67/00 , C07C69/00 , C07C67/36 , C07C69/76
CPC分类号： C07C51/12 , C07C51/56 , C07C67/36 , C07C67/37
摘要： A process for producing a carboxylic acid and/or its ester, which comprises reacting an alcohol or ether with carbon monoxide in the presence of elemental nickel or a nickel compound, iodine or an iodine compound and an organic compound of a trivalent nitrogen-group element; wherein the iodine or iodine compound is selected from the following formulae (I) to (IV),RX.sub.n (I)wherein R represents a hydrogen atom or an alkyl or alkylene group, X represents an iodine or bromine atom, and n is an integer of 1 to 3, at least one of n.multidot.X's being an iodine atom,I.sub.2 or I.sub.3 - (II)RCOI (III)wherein R represents an alkyl group,MI.sub.2 (IV)wherein M represents an alkaline earth metal, and the amount of the iodine or iodine compound is such that the amount of the free iodine or iodine compound not chemically bonded to the nickel or nickel compound or the organic compound of a nitrogen-group element is at least 0.2 mole as elemental iodine per mole of each of the nitrogen-group element compound and the nickel or nickel compound.
摘要翻译：一种制备羧酸和/或其酯的方法，其包括在元素镍或镍化合物，碘或碘化合物和三价氮基元素的有机化合物存在下使醇或醚与一氧化碳反应 ; 其中所述碘或碘化合物选自下式（I）至（IV），其中R表示氢原子或烷基或亚烷基的RXn（I），X表示碘或溴原子，n为整数为1〜3，nxX为碘原子中的至少1种，I 2 - 或I 3 - （II）RCOI（III），其中R为烷基，MI2（Ⅳ）其中M为碱土金属，碘或碘化合物使得未化学键合到镍或镍化合物或氮基元素的有机化合物的游离碘或碘化合物的量为每摩尔氮中的元素碘至少0.2摩尔 - 元素化合物和镍或镍化合物。

10. 发明授权

US4212989A Process for producing carboxylic acids or esters thereof 失效
标题翻译：制备羧酸或其酯的方法
公开(公告)号：US4212989A
公开(公告)日：1980-07-15
申请号：US955411
申请日：1978-10-26
申请人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi
发明人： Tomiya Isshiki , Yasuhiko Kijima , Yuh Miyauchi
IPC分类号： C07C67/37 , C07C51/00 , C07C51/12 , C07C67/00 , C07C67/36 , C07C69/157
CPC分类号： C07C51/12
摘要： In a process for producing a carboxylic acid or its ester by reacting an alcohol or an ether with carbon monoxide, the improvement wherein the reaction is performed in the presence of, as a solvent, an aryl ester of an aliphatic carboxylic acid represented by the formula ##STR1## wherein n is an integer of 1 to 5, R.sub.1 represents hydrogen or C.sub.1 -C.sub.4 alkyl or alkenyl, and R.sub.2 represents hydrogen, alkyl, aryl, alkenyl, hydroxymethyl, acyl, acyloxy, formyl, carboxy, hydroxy, halogen, sulfo, nitro, nitroso, amino, acid amide or cyano, and two or more R.sub.2 groups may be the same or different, and the substituents R.sub.2 may be bonded to each other to form a penta- or hexa-carbocyclic or heterocyclic ring.
摘要翻译：在通过醇或醚与一氧化碳反应制备羧酸或其酯的方法中，其中反应在作为溶剂存在下由式（I）表示的脂族羧酸的芳基酯进行，其中n为1〜5的整数，R1表示氢或C1-C4烷基或烯基，R2表示氢，烷基，芳基，烯基，羟甲基，酰基，酰氧基，甲酰基，羧基，羟基，卤素，磺基，硝基，亚硝基，氨基，酰胺或氰基，两个或更多个R 2基可以相同或不同，并且取代基R 2可以彼此键合形成五 - 或六碳环或杂环。

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