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1. 发明授权

US5466778A Process for polymerization of tetrahydrofuran using acidic zeolite catalysts 失效
标题翻译：使用酸性沸石催化剂聚合四氢呋喃的方法
公开(公告)号：US5466778A
公开(公告)日：1995-11-14
申请号：US138026
申请日：1993-10-19
申请人： Timothy L. Lambert , John F. Knifton
发明人： Timothy L. Lambert , John F. Knifton
IPC分类号： C08G63/672 , C08G65/20 , C08G65/26 , C08G63/66
CPC分类号： C08G65/20 , C08G63/672 , C08G65/2657
摘要： Disclosed is an improved process for polymerization of tetrahydrofuran to prepare poly(tetrahydrofuran) products with a MW range of 200 to 5000 and a dispersity of
摘要翻译：公开了一种改进的四氢呋喃聚合方法，以制备MW范围为200至5000且分散度<2的聚（四氢呋喃）产物，其包括预混合羧酸酐，例如乙酸酐和脱铝Y- 沸石，随后在低于100℃的温度下加入四氢呋喃，其中加入反应物的顺序是关键的，通过预混合乙酸酐和沸石，然后加入四氢呋喃来提高产率。

2. 发明授权

US08692013B2 Preparation of antiplasticizers for thermoplastic polyesters 有权
标题翻译：制备热塑性聚酯的抗增塑剂
公开(公告)号：US08692013B2
公开(公告)日：2014-04-08
申请号：US13684541
申请日：2012-11-25
申请人： Rick Tabor , Brian K. Mirous , Timothy L. Lambert , Michael E. O'Brien , Matthew I. Levinson , Daniel J. Dershowitz
发明人： Rick Tabor , Brian K. Mirous , Timothy L. Lambert , Michael E. O'Brien , Matthew I. Levinson , Daniel J. Dershowitz
IPC分类号： C07C69/76
CPC分类号： C08K5/1345 , C07C67/03 , C07C67/29 , C07C69/82 , C08K5/12 , Y02P20/582
摘要： A process for making bis(aryloxyalkyl)terephthalates useful as antiplasticizers for thermoplastic polyesters is disclosed. Dimethyl terephthalate is reacted with an excess of an aryloxyalkanol in the presence of a condensation catalyst to produce an intermediate mixture comprising a bis(aryloxyalkyl)terephthalate, a mono(aryloxyalkyl)terephthalate, and unreacted aryloxyalkanol. This mixture continues to react at reduced pressure while unreacted aryloxyalkanol is removed and the mono-ester content is reduced to less than 1 mole % based on the combined amounts of mono- and bis-esters. Both steps are performed substantially in the absence of oxygen. Additional unreacted aryloxyalkanol is then removed to provide a purified bis(aryloxyalkyl)terephthalate having an overall purity of at least 98 mole % and a yellowness index less than 10. Careful control over catalysis, exposure to air, and other process conditions enables the preparation of high yields of bis(aryloxyalkyl)terephthalates that have low color and other valuable attributes. A method of producing bis(aryloxyalkyl)terephthalate articles having improved compressive strength is also disclosed.
摘要翻译：公开了一种制备用作热塑性聚酯的抗增塑剂的双（芳氧基烷基）对苯二甲酸酯的方法。在缩合催化剂的存在下，对苯二甲酸二甲酯与过量的芳氧基烷醇反应，以产生包含双（芳氧基烷基）对苯二甲酸酯，单（芳氧基烷基）对苯二甲酸酯和未反应的芳氧基烷醇的中间体混合物。该混合物在减压下继续反应，同时除去未反应的芳氧基烷醇，并且基于单酯和双酯的组合量，单酯含量降低至小于1摩尔％。两个步骤基本上在不存在氧的情况下进行。然后除去另外的未反应的芳氧基烷醇，以提供纯度为至少98摩尔％，黄度指数小于10的纯化双（芳氧基烷基）对苯二甲酸酯。小心控制催化，暴露于空气和其它工艺条件使得能够制备具有低颜色和其他有价值属性的双（芳氧基烷基）对苯二甲酸酯的高收率。还公开了一种制备具有改善的抗压强度的双（芳氧基烷基）对苯二甲酸酯制品的方法。

3. 发明申请

US20130085216A1 PREPARATION OF ANTIPLASTICIZERS FOR THERMOPLASTIC POLYESTERS 有权
标题翻译：热塑性聚酯抗菌剂的制备
公开(公告)号：US20130085216A1
公开(公告)日：2013-04-04
申请号：US13684541
申请日：2012-11-25
申请人： Rick Tabor , Brian K. Mirous , Timothy L. Lambert , Michael E. O'Brien , Matthew I. Levinson , Daniel J. Dershowitz
发明人： Rick Tabor , Brian K. Mirous , Timothy L. Lambert , Michael E. O'Brien , Matthew I. Levinson , Daniel J. Dershowitz
IPC分类号： C07C67/29
CPC分类号： C08K5/1345 , C07C67/03 , C07C67/29 , C07C69/82 , C08K5/12 , Y02P20/582
摘要： A process for making bis(aryloxyalkyl)terephthalates useful as antiplasticizers for thermoplastic polyesters is disclosed. Dimethyl terephthalate is reacted with an excess of an aryloxyalkanol in the presence of a condensation catalyst to produce an intermediate mixture comprising a bis(aryloxyalkyl)terephthalate, a mono(aryloxyalkyl)terephthalate, and unreacted aryloxyalkanol. This mixture continues to react at reduced pressure while unreacted aryloxyalkanol is removed and the mono-ester content is reduced to less than 1 mole % based on the combined amounts of mono- and bis-esters. Both steps are performed substantially in the absence of oxygen. Additional unreacted aryloxyalkanol is then removed to provide a purified bis(aryloxyalkyl)terephthalate having an overall purity of at least 98 mole % and a yellowness index less than 10. Careful control over catalysis, exposure to air, and other process conditions enables the preparation of high yields of bis(aryloxyalkyl)terephthalates that have low color and other valuable attributes. A method of producing bis(aryloxyalkyl)terephthalate articles having improved compressive strength is also disclosed.
摘要翻译：公开了一种制备用作热塑性聚酯的抗增塑剂的双（芳氧基烷基）对苯二甲酸酯的方法。在缩合催化剂的存在下，对苯二甲酸二甲酯与过量的芳氧基烷醇反应，以产生包含双（芳氧基烷基）对苯二甲酸酯，单（芳氧基烷基）对苯二甲酸酯和未反应的芳氧基烷醇的中间体混合物。该混合物在减压下继续反应，同时除去未反应的芳氧基烷醇，并且基于单酯和双酯的组合量，单酯含量降低至小于1摩尔％。两个步骤基本上在不存在氧的情况下进行。然后除去另外的未反应的芳氧基烷醇，以提供纯度为至少98摩尔％，黄度指数小于10的纯化双（芳氧基烷基）对苯二甲酸酯。仔细控制催化，暴露于空气和其它工艺条件使得能够制备具有低颜色和其他有价值属性的双（芳氧基烷基）对苯二甲酸酯的高收率。还公开了一种制备具有改善的抗压强度的双（芳氧基烷基）对苯二甲酸酯制品的方法。

4. 发明授权

US5962748A Process for preparing low unsaturation polyether polyols 失效
标题翻译：制备低不饱和聚醚多元醇的方法
公开(公告)号：US5962748A
公开(公告)日：1999-10-05
申请号：US956960
申请日：1997-10-23
申请人： Timothy L. Lambert
发明人： Timothy L. Lambert
IPC分类号： C08G18/48 , C08G65/26 , C08G65/30 , C08G65/324 , C07C41/44
CPC分类号： C08G18/4866 , C08G65/2642 , C08G65/30 , C08G65/324
摘要： Polyether polyols having reduced terminal unsaturation are prepared in a process comprising a first step comprising reacting propylene oxide with an initiator having at least two hydroxyl groups in the presence of a basic catalyst, a second step of contacting the polyether product of the first step having allyl terminal unsaturation with an isomerization catalyst whereby the allyl terminal unsaturation of the polyether is reduced by at least 90% conversion to propenyl terminal unsaturation in one step and, in a final step, the resulting polyether product of the first step is contacted with an acid catalyst whereby a substantial amount of the propenyl terminal unsaturation of the polyether is removed and the corresponding polyether having an additional hydroxyl group is obtained.
摘要翻译：具有降低的末端不饱和度的聚醚多元醇在包括第一步骤的方法中制备，所述第一步骤包括在碱性催化剂存在下使环氧丙烷与具有至少两个羟基的引发剂反应，第二步是使第一步的聚醚产物与具有异构化催化剂的末端不饱和键，其中聚醚的烯丙基末端不饱和键在一个步骤中降低至少90％转化为丙烯基末端不饱和度，并且在最后步骤中，将所得第一步的聚醚产物与酸催化剂由此除去大量的聚醚的丙烯基末端不饱和度，并获得具有另外的羟基的相应的聚醚。

5. 发明申请

US20120245268A1 PREPARATION OF ANTIPLASTICIZERS FOR THERMOPLASTIC POLYESTERS 有权
标题翻译：热塑性聚酯抗菌剂的制备
公开(公告)号：US20120245268A1
公开(公告)日：2012-09-27
申请号：US13071952
申请日：2011-03-25
申请人： Rick Tabor , Brian K. Mirous , Timothy L. Lambert , Michael E. O'Brien , Matthew I. Levinson , Daniel J. Dershowitz
发明人： Rick Tabor , Brian K. Mirous , Timothy L. Lambert , Michael E. O'Brien , Matthew I. Levinson , Daniel J. Dershowitz
IPC分类号： C08K5/12 , C07C69/82 , C08L67/02
CPC分类号： C08K5/1345 , C07C67/03 , C07C67/29 , C07C69/82 , C08K5/12 , Y02P20/582
摘要： A process for making bis(aryloxyalkyl)terephthalates useful as antiplasticizers for thermoplastic polyesters is disclosed. Dimethyl terephthalate is reacted with an excess of an aryloxyalkanol in the presence of a condensation catalyst to produce an intermediate mixture comprising a bis(aryloxyalkyl)terephthalate, a mono(aryloxyalkyl)terephthalate, and unreacted aryloxyalkanol. This mixture continues to react at reduced pressure while unreacted aryloxyalkanol is removed and the mono-ester content is reduced to less than 1 mole % based on the combined amounts of mono- and bis-esters. Both steps are performed substantially in the absence of oxygen. Additional unreacted aryloxyalkanol is then removed to provide a purified bis(aryloxyalkyl)terephthalate having an overall purity of at least 98 mole % and a yellowness index less than 10. Careful control over catalysis, exposure to air, and other process conditions enables the preparation of high yields of bis(aryloxyalkyl)terephthalates that have low color and other valuable attributes. A method of producing bis(aryloxyalkyl)terephthalate articles having improved compressive strength is also disclosed.
摘要翻译：公开了一种制备用作热塑性聚酯的抗增塑剂的双（芳氧基烷基）对苯二甲酸酯的方法。在缩合催化剂的存在下，对苯二甲酸二甲酯与过量的芳氧基烷醇反应，以产生包含双（芳氧基烷基）对苯二甲酸酯，单（芳氧基烷基）对苯二甲酸酯和未反应的芳氧基烷醇的中间体混合物。该混合物在减压下继续反应，同时除去未反应的芳氧基烷醇，并且基于单酯和双酯的组合量，单酯含量降低至小于1摩尔％。两个步骤基本上在不存在氧的情况下进行。然后除去另外的未反应的芳氧基烷醇，以提供纯度为至少98摩尔％，黄度指数小于10的纯化双（芳氧基烷基）对苯二甲酸酯。小心控制催化，暴露于空气和其它工艺条件使得能够制备具有低颜色和其他有价值属性的双（芳氧基烷基）对苯二甲酸酯的高收率。还公开了一种制备具有改善的抗压强度的双（芳氧基烷基）对苯二甲酸酯制品的方法。

6. 发明授权

US07189875B2 Diphenylamine alkylated with olefin mixtures containing fractions with varying degrees of activity 有权
$Diphenylamine alkylated with olefin mixtures containing fractions with varying degrees of activity$
标题翻译：用含有不同程度活性的级分的烯烃混合物烷基化的二苯胺
公开(公告)号：US07189875B2
公开(公告)日：2007-03-13
申请号：US10815578
申请日：2004-03-31
申请人： Karl J. Duyck , Timothy L. Lambert
发明人： Karl J. Duyck , Timothy L. Lambert
IPC分类号： C07C211/00 , C07C211/43
CPC分类号： C08K5/18 , C07C211/55 , C10L1/223 , C10L1/2383 , C10M133/14 , C10M133/54 , C10M2203/1006 , C10M2205/02 , C10M2207/16 , C10M2215/064 , C10M2215/26 , C10M2215/28 , C10M2219/044 , C10M2219/046 , C10M2223/045 , C10N2230/10 , C10N2240/10 , C08L21/00 , C10N2210/08 , C10N2210/02
摘要： Disclosed herein is a process for the preparation of alkylated diarylamines comprising adding to said diarylamine an olefin mixture containing highly reactive fractions, as well as fractions exhibiting a relatively lower chemical reactivity, in the presence of an acidic clay catalyst at a temperature low enough to prevent substantial deactivation of the catalyst until the addition is complete and then increasing the temperature to increase the alkylation rate of the less reactive fractions.
摘要翻译：本文公开了一种制备烷基化二芳基胺的方法，包括在酸性粘土催化剂存在下，在足够低的温度下加入到所述二芳基胺中含有高反应性级分的烯烃混合物以及表现出相对较低化学反应性的馏分催化剂显着失活直到添加完成，然后升高温度以增加反应活性较低的部分的烷基化速率。

7. 发明授权

US6037516A Method for removal of oxygenate impurities from organic chemical streams 失效
标题翻译：从有机化学物流中去除含氧化合物杂质的方法
公开(公告)号：US6037516A
公开(公告)日：2000-03-14
申请号：US975523
申请日：1997-11-20
申请人： Peter S. Morford , Timothy L. Lambert , William K. Culbreth, III
发明人： Peter S. Morford , Timothy L. Lambert , William K. Culbreth, III
IPC分类号： C07C7/148 , C07D301/32 , C07C7/10
CPC分类号： C07D301/32 , C07C7/148 , C07C7/1485
摘要： Oxygenate impurities are removed from an organic chemical feed or stream by treatment with an aqueous reducing agent and aqueous base, accompanied by separation. An aqueous solution of reducing agent and an aqueous solution of base are typically introduced sequentially into the organic chemical stream, where they may react with any oxygenate impurities present. The reaction products of the oxygenate impurities and aqueous reducing agent and aqueous base are water soluble, and are typically removed in sequential fashion via any suitable separation means. For example, oxygenate impurities such as formaldehyde, acetaldehyde, propionaldehyde, and methyl formate may be removed from a propylene stream by treating the stream sequentially with aqueous sodium bisulfite and aqueous sodium hydroxide, accompanied by separation of the oxygenate impurity reaction products in coalescers.
摘要翻译：通过用水性还原剂和碱水溶液处理，伴随着分离，从有机化学原料或料流中除去氧化物杂质。还原剂的水溶液和碱的水溶液通常依次引入有机化学物流中，在那里它们可以与存在的任何含氧化合物杂质反应。含氧化合物杂质和水性还原剂和水性碱的反应产物是水溶性的，并且通常通过任何合适的分离方法以顺序的方式除去。例如，可以通过用亚硫酸氢钠水溶液和氢氧化钠水溶液依次处理流，同时伴随着聚结器中的含氧化合物杂质反应产物的分离，从丙烯流中除去含氧化合物杂质如甲醛，乙醛，丙醛和甲酸甲酯。

8. 发明授权

US07312346B2 Method of purifying hydroxyalkyl amide 失效
标题翻译：羟烷基酰胺的纯化方法
公开(公告)号：US07312346B2
公开(公告)日：2007-12-25
申请号：US10712830
申请日：2003-11-12
申请人： Timothy L. Lambert , E. Brian Fox
发明人： Timothy L. Lambert , E. Brian Fox
IPC分类号： C11C3/00
CPC分类号： C10L10/08 , C07C231/24 , C10L1/224 , C07C233/18 , C07C233/20
摘要： A method for purifying hydroxyalkyl amide of residual alkanolamine by using nonpolar solvent, an acidic pH, salt solutions and an elevated temperature.
摘要翻译：通过使用非极性溶剂，酸性pH，盐溶液和升高的温度来纯化残余链烷醇胺的羟烷基酰胺的方法。

9. 发明授权

US07244857B2 Method of making hydroxyalkyl amide containing reduced level of unreacted alkanolamine 有权
标题翻译：制备含有降低水平的未反应的链烷醇胺的羟烷基酰胺的方法
公开(公告)号：US07244857B2
公开(公告)日：2007-07-17
申请号：US10713805
申请日：2003-11-14
申请人： E. Brian Fox , Timothy L. Lambert
发明人： E. Brian Fox , Timothy L. Lambert
IPC分类号： C07C231/00
CPC分类号： C07B43/06 , C07C231/02 , C10L1/221 , C10L1/224 , C10L10/08 , C07C233/18
摘要： A method for reacting alkanolamine with ester in the presence of a metal silicate compound and, optionally, a catalyst, to produce a hydroxyalkyl amide composition with a decreased level of alkanolamine and residual catalyst.
摘要翻译：在金属硅酸盐化合物和任选的催化剂的存在下使链烷醇胺与酯反应的方法，以产生具有降低的链烷醇胺和残余催化剂水平的羟烷基酰胺组合物。

10. 发明授权

US5698746A Process for preparing low unsaturation polyether polyols 失效
标题翻译：制备低不饱和聚醚多元醇的方法
公开(公告)号：US5698746A
公开(公告)日：1997-12-16
申请号：US743366
申请日：1996-11-04
申请人： Timothy L. Lambert
发明人： Timothy L. Lambert
IPC分类号： C08G18/48 , C08G65/26 , C08G65/30 , C08G65/324 , C07C41/44
CPC分类号： C08G18/4866 , C08G65/2642 , C08G65/30 , C08G65/324
摘要： Polyether polyols having reduced terminal unsaturation are prepared in a process comprising a first step of contacting a polyether having allyl terminal unsaturation with an isomerization catalyst whereby the allyl terminal unsaturation of the polyether is reduced by at least 90% conversion to propenyl terminal unsaturation in one step and, in a final step, the resulting polyether product of the first step is contacted with an acid catalyst whereby a substantial amount of the propenyl terminal unsaturation of the polyether is removed and the corresponding polyether having an additional hydroxyl group is obtained.
摘要翻译：具有降低的末端不饱和度的聚醚多元醇在包括使具有烯丙基末端不饱和键的聚醚与异构化催化剂接触的第一步骤的方法中制备，由此聚醚的烯丙基末端不饱和键在一个步骤中降低至至少90％转化为丙烯基末端不饱和度并且在最终步骤中，使所得第一步的聚醚产物与酸催化剂接触，由此除去大量的聚醚的丙烯基末端不饱和度，并获得具有另外的羟基的相应的聚醚。

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