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1. 发明申请

US20120277331A1 Vessel For Containing Catalyst In A Tubular Reactor 有权
标题翻译：在管式反应器中含有催化剂的容器
公开(公告)号：US20120277331A1
公开(公告)日：2012-11-01
申请号：US13501794
申请日：2010-10-19
申请人： Timothy Douglas Gamlin , Brendon Bruce Miller
发明人： Timothy Douglas Gamlin , Brendon Bruce Miller
IPC分类号： B65D6/00 , C01C1/02 , C07C29/00 , C07D307/60 , C07D303/04 , B01J19/00 , C07C27/00
CPC分类号： B01J8/06 , B01J8/0015 , B01J8/0214 , B01J8/0415 , B01J8/067 , B01J2208/00814
摘要： A catalyst carrier for insertion in a radial tube reactor, said catalyst carrier comprising: an annular container for holding catalyst in use, said container having a perforated inner wall defining a tube, a perforated outer wall, a top surface closing the annular container and a bottom surface closing the annular container; a surface closing the bottom of said tube formed by the inner wall of the annular container; a skirt extending upwardly from the perforated outer wall of the annular container from a position at or near the bottom surface of said container to a position below the location of a seal; and a seal located at or near the top surface and extending from the container by a distance which extends beyond an outer surface of the skirt.
摘要翻译：一种用于插入径向管式反应器的催化剂载体，所述催化剂载体包括：用于在使用中保持催化剂的环形容器，所述容器具有限定管的穿孔内壁，穿孔外壁，封闭环形容器的顶表面和底面关闭环形容器; 封闭由所述环形容器的内壁形成的所述管的底部的表面; 从所述环形容器的穿孔外壁向上延伸的裙部，从所述容器的底表面处或附近的位置向下延伸到密封位置下方的位置; 以及密封件，其位于或靠近顶部表面并且从容器延伸超过裙部外表面的距离。

2. 发明授权

US08722747B2 Vessel for containing catalyst in a tubular reactor 有权
标题翻译：在管式反应器中容纳催化剂的容器
公开(公告)号：US08722747B2
公开(公告)日：2014-05-13
申请号：US13501794
申请日：2010-10-19
申请人： Timothy Douglas Gamlin , Brendon Bruce Miller
发明人： Timothy Douglas Gamlin , Brendon Bruce Miller
IPC分类号： C07C27/00 , B01J21/00 , B01J8/00
CPC分类号： B01J8/06 , B01J8/0015 , B01J8/0214 , B01J8/0415 , B01J8/067 , B01J2208/00814
摘要： In a catalyst carrier for insertion in a tube of a reactor, an annular container holds the catalyst in use and has a perforated inner wall defining a tube, a perforated outer wall, a top surface closing the annular container and a bottom surface closing the annular container. A surface closes the bottom of the tube formed by the inner wall of the annular container. A skirt extends upwardly from the perforated outer wall of the annular container from a position at or near the bottom surface to a position below the location of a seal located at or near the top surface and extending from the container by a distance which extends beyond an outer surface of the skirt.
摘要翻译：在用于插入反应器的管中的催化剂载体中，环形容器将催化剂保持在使用中，并且具有限定管的穿孔内壁，穿孔的外壁，封闭环形容器的顶表面和封闭环形容器的底表面容器。表面封闭由环形容器的内壁形成的管的底部。裙部从环形容器的穿孔外壁向上延伸，从底表面处或附近的位置向下延伸到位于顶表面处或附近的密封件位置的位置，并从容器延伸一段距离裙子的外表面。

3. 发明授权

US08906970B2 Fischer-tropsch process in a radial reactor 有权
标题翻译：径向反应器中的费 - 托法
公开(公告)号：US08906970B2
公开(公告)日：2014-12-09
申请号：US13579973
申请日：2012-02-06
申请人： Timothy Douglas Gamlin
发明人： Timothy Douglas Gamlin
IPC分类号： C07C1/04 , B65D6/00 , B01J8/02 , B01J8/06 , B01J8/04 , B01J19/24 , C10G2/00
CPC分类号： C07C1/041 , B01J8/0214 , B01J8/0285 , B01J8/0415 , B01J8/067 , B01J19/2485 , B01J2208/00814 , B01J2219/00038 , B01J2219/0004 , C10G2/341
摘要： In a process for converting synthesis gas to higher hydrocarbons in a tubular reactor, reactants are introduced through an inlet of the reactor. The reactants are passed downwardly through at least one tube to an upper surface of a catalyst carrier where they pass into a passage defined by an inner perforated wall of a catalyst container before passing radially through the catalyst bed towards the perforated outer wall. Reaction occurs as the synthesis gas contacts the catalyst. Unreacted reactant and product is passed out of the container through a perforated outer wall thereof and then upwardly between a skirt and an outer wall of the container, followed by being directed over the end of the skirt and downwardly between the skirt and the reactor tube where heat transfer takes place. These steps are repeated for any subsequent catalyst carrier, then product is removed from an outlet of the reactor.
摘要翻译：在管式反应器中将合成气转化为高级烃的方法中，通过反应器的入口引入反应物。反应物通过至少一个管子向下通过催化剂载体的上表面，在催化剂载体的上表面通过催化剂容器的内部穿孔壁限定的通道中，然后通过催化剂床朝向穿孔的外壁。当合成气与催化剂接触时，会发生反应。未反应的反应物和产物通过穿孔的外壁从容器中穿过，然后在容器的裙部和外壁之间向上延伸，随后被引导到裙部的端部上并在裙部和反应器管之间向下传热发生。对于任何后续的催化剂载体重复这些步骤，然后从反应器的出口除去产物。

4. 发明授权

US07071238B2 Fischer-tropsch process in the presence of a coolant introduced into the reactor system 有权
标题翻译：在引入反应器系统的冷却剂存在下的费 - 托法
公开(公告)号：US07071238B2
公开(公告)日：2006-07-04
申请号：US10476798
申请日：2002-05-17
申请人： Timothy Douglas Gamlin , Lawrence Trevor Hardy , David Newton
发明人： Timothy Douglas Gamlin , Lawrence Trevor Hardy , David Newton
IPC分类号： C07C27/00
CPC分类号： C10G2/342 , C10G2300/44
摘要： Process for the conversion of synthesis gas to hydrocarbons, at least a portion of which are liquid at ambient temperature and pressure, by contacting the synthesis gas at an elevated temperature and pressure with a suspension comprising a particulate Fischer-Tropsch catalyst suspended in a liquid medium, in a reactor system comprising at least one high shear mixing zone and a reactor vessel. The process comprises passing the suspension and synthesis gas through the high shear mixing zone(s) where the synthesis gas is broken down into gas bubbles and/or irregularly shaped gas voids; discharging suspension having gas bubbles and/or irregularly shaped gas voids dispersed therein from the high shear mixing zone(s) into the reactor vessel; and introducing a liquid coolant into the reactor system.
摘要翻译：通过使合成气在升高的温度和压力下与包含悬浮在液体介质中的颗粒状费 - 托催化剂的悬浮液接触将合成气转化为烃的方法，其中至少一部分在环境温度和压力下为液体在包括至少一个高剪切混合区和反应器容器的反应器系统中。该方法包括使悬浮液和合成气通过高剪切混合区，其中合成气被分解成气泡和/或不规则形状的气体空隙; 从高剪切混合区排出具有气泡和/或分散在其中的不规则形状的气体空隙的悬浮液进入反应器容器; 并将液体冷却剂引入反应器系统中。

5. 发明授权

US08785506B2 Process for the synthesis of methanol 有权
标题翻译：合成甲醇的方法
公开(公告)号：US08785506B2
公开(公告)日：2014-07-22
申请号：US13581709
申请日：2012-02-14
申请人： Timothy Douglas Gamlin
发明人： Timothy Douglas Gamlin
IPC分类号： C07C27/00 , B01J35/04 , B01J8/04 , C07C29/152 , B01J19/24 , B01J8/06
CPC分类号： C07C29/152 , B01J8/0415 , B01J8/0496 , B01J8/067 , B01J19/2485 , B01J35/04 , B01J2208/00814 , B01J2219/00038 , B01J2219/0004 , Y02P20/52 , C07C31/04
摘要： In a process for converting synthesis gas to methanol, gas is introduced through an inlet of a tubular reactor. Reactants pass downwardly through at least one reactor tube to an upper surface of a catalyst carrier and into a passage defined by an inner perforated wall of a carrier container before passing radially through the catalyst bed towards a perforated outer container wall. Reaction occurs as synthesis gas contacts the catalyst. Unreacted reactant and product pass out of the container through the outer container wall and then upwardly between the inner surface of a container skirt and an outer annular container wall, and then over the end of the skirt and downwardly between the outer surface of the skirt and the inner surface of the reactor tube where heat transfer takes place. The steps are repeated at any subsequent catalyst carrier and then product is removed from the reactor outlet.
摘要翻译：在将合成气转化为甲醇的方法中，通过管式反应器的入口引入气体。反应物通过至少一个反应器管到催化剂载体的上表面并进入由载体容器的内部穿孔壁限定的通道中，然后在径向通过催化剂床之前穿过穿孔的外部容器壁。当合成气与催化剂接触时，会发生反应。未反应的反应物和产物通过外部容器壁从容器中流出，然后在容器裙部的内表面和外部环形容器壁之间向上，然后在裙部的端部之上，并且在裙部的外表面和反应器管的内表面发生热传递。在任何随后的催化剂载体上重复这些步骤，然后从反应器出口除去产物。

6. 发明申请

US20140018451A1 Monolithic Reactor 有权
标题翻译：单片反应堆
公开(公告)号：US20140018451A1
公开(公告)日：2014-01-16
申请号：US13580920
申请日：2012-02-06
申请人： Timothy Douglas Gamlin , Richard Spratt
发明人： Timothy Douglas Gamlin , Richard Spratt
IPC分类号： B01J15/00
CPC分类号： B01J15/005 , B01J8/06 , B01J19/2485 , B01J35/04 , B01J2219/2424 , B01J2219/2443 , Y10S502/52711 , Y10S502/52724
摘要： A monolith catalyst carrier for insertion in a tube of a tubular reactor has a container for holding a monolith catalyst in use. The container has a bottom surface closing the container and a skirt extending upwardly from the bottom surface of the container to a position below the location of a seal and spaced therefrom. The skirt is positioned such that there is a space between an outer surface of the monolith catalyst and the skirt. A seal is located at or near a top surface of the monolith catalyst and extends from the monolith catalyst by a distance which extends beyond an outer surface of the skirt.
摘要翻译：用于插入管状反应器的管中的整体式催化剂载体具有用于保持使用中的整料催化剂的容器。容器具有封闭容器的底表面和从容器的底表面向上延伸到密封件位置下方并与其间隔开的位置的裙部。裙部被定位成使得在整体式催化剂的外表面和裙部之间存在空间。密封件位于整料催化剂的顶表面上或附近，并从整体催化剂延伸超过裙部的外表面的距离。

7. 发明授权

US06191174B1 Process and plant for the production of methanol 有权
标题翻译：生产甲醇的工艺和设备
公开(公告)号：US06191174B1
公开(公告)日：2001-02-20
申请号：US09117861
申请日：1998-08-07
申请人： Simon Robert Early , Timothy Douglas Gamlin , Mark Andrew Linthwaite
发明人： Simon Robert Early , Timothy Douglas Gamlin , Mark Andrew Linthwaite
IPC分类号： C07C2700
CPC分类号： C07C29/1518 , Y02P20/132 , C07C31/04
摘要： The present invention relates to a process for the production of methanol from a hydrocarbon feedstock comprising: contacting a vaporous mixture comprising the feedstock and steam in a steam reforming zone with a catalyst effective for catalysis of at least one reforming reaction; recovering from the reforming zone a synthesis gas mixture comprising carbon oxides, hydrogen and methane; supplying material of the synthesis gas mixture to a methanol synthesis zone charged with a methanol synthesis catalyst and maintained under methanol synthesis conditions; recovering from the methanol synthesis zone a product gas mixture comprising methanol and unreacted material of the synthesis gas mixture; supplying material of the product gas mixture to a methanol recovery zone maintained under methanol recovery conditions; recovering from the methanol recovery zone a crude methanol product stream and a vaporous steam comprising unreacted material of the synthesis gas mixture; separating material of the synthesis gas mixture into a first hydrogen-rich stream and a second hydrogen-depleted stream comprising carbon oxides and methane; supplying at least part of the first hydrogen-rich stream to the steam reforming zone as fuel; and recycling at least part of the second hydrogen-depleted stream to the steam reforming zone to form part of the mixture of the vaporous mixture comprising the feedstock and steam and to a plant constructed and arranged so as to be operable in accordance with the process.
摘要翻译：本发明涉及一种从烃原料生产甲醇的方法，包括：使蒸汽重整区中含有原料和蒸汽的蒸气混合物与有效催化至少一种重整反应的催化剂接触; 从重整区回收包含碳氧化物，氢气和甲烷的合成气混合物; 将合成气混合物的材料供应到装有甲醇合成催化剂并在甲醇合成条件下保持的甲醇合成区; 从甲醇合成区回收包含甲醇和合成气混合物的未反应物质的产物气体混合物; 将产物气体混合物的材料供应到在甲醇回收条件下保持的甲醇回收区; 从甲醇回收区回收粗甲醇产物流和包含合成气混合物的未反应物质的蒸汽蒸汽; 将所述合成气混合物的材料分离成第一富氢流和包含碳氧化物和甲烷的第二贫氢流; 将第一富氢流的至少一部分作为燃料供应到蒸汽重整区; 以及将至少部分所述第二贫氢物流再循环到所述蒸汽重整区，以形成包含所述原料和蒸汽的所述蒸气混合物的混合物的一部分，以及构造和布置为可根据所述方法操作的设备。

8. 发明授权

US09012358B2 Monolithic reactor 有权
标题翻译：整体反应堆
公开(公告)号：US09012358B2
公开(公告)日：2015-04-21
申请号：US13580920
申请日：2012-02-06
申请人： Timothy Douglas Gamlin , Richard Spratt
发明人： Timothy Douglas Gamlin , Richard Spratt
IPC分类号： B01J19/24 , B01J15/00 , B01J8/06 , B01J35/04
CPC分类号： B01J15/005 , B01J8/06 , B01J19/2485 , B01J35/04 , B01J2219/2424 , B01J2219/2443 , Y10S502/52711 , Y10S502/52724
摘要： A monolith catalyst carrier for insertion in a tube of a tubular reactor has a container for holding a monolith catalyst in use. The container has a bottom surface closing the container and a skirt extending upwardly from the bottom surface of the container to a position below the location of a seal and spaced therefrom. The skirt is positioned such that there is a space between an outer surface of the monolith catalyst and the skirt. A seal is located at or near a top surface of the monolith catalyst and extends from the monolith catalyst by a distance which extends beyond an outer surface of the skirt.
摘要翻译：用于插入管状反应器的管中的整体式催化剂载体具有用于保持使用中的整料催化剂的容器。容器具有封闭容器的底表面和从容器的底表面向上延伸到密封件位置下方并与其间隔开的位置的裙部。裙部被定位成使得在整体式催化剂的外表面和裙部之间存在空间。密封件位于整料催化剂的顶表面上或附近，并从整体催化剂延伸超过裙部的外表面的距离。

9. 发明申请

US20140187653A1 Fischer-Tropsch Process In A Radial Reactor 有权
标题翻译：径向反应器中的费 - 托工艺
公开(公告)号：US20140187653A1
公开(公告)日：2014-07-03
申请号：US13579973
申请日：2012-02-06
申请人： Timothy Douglas Gamlin
发明人： Timothy Douglas Gamlin
IPC分类号： C07C1/04
CPC分类号： C07C1/041 , B01J8/0214 , B01J8/0285 , B01J8/0415 , B01J8/067 , B01J19/2485 , B01J2208/00814 , B01J2219/00038 , B01J2219/0004 , C10G2/341
摘要： In a process for converting synthesis gas to higher hydrocarbons in a tubular reactor, reactants are introduced through an inlet of the reactor. The reactants are passed downwardly through at least one tube to an upper surface of a catalyst carrier where they pass into a passage defined by an inner perforated wall of a catalyst container before passing radially through the catalyst bed towards the perforated outer wall. Reaction occurs as the synthesis gas contacts the catalyst. Unreacted reactant and product is passed out of the container through a perforated outer wall thereof and then upwardly between a skirt and an outer wall of the container, followed by being directed over the end of the skirt and downwardly between the skirt and the reactor tube where heat transfer takes place. These steps are repeated for any subsequent catalyst carrier, then product is removed from an outlet of the reactor.
摘要翻译：在管式反应器中将合成气转化为高级烃的方法中，通过反应器的入口引入反应物。反应物通过至少一个管子向下通过催化剂载体的上表面，在催化剂载体的上表面通过催化剂容器的内部穿孔壁限定的通道中，然后通过催化剂床朝向穿孔的外壁。当合成气与催化剂接触时，会发生反应。未反应的反应物和产物通过其穿孔的外壁从容器中穿过，然后在容器的裙部和外壁之间向上延伸，随后被引导到裙部的端部上并在裙部和反应器管之间向下传热发生。对于任何后续的催化剂载体重复这些步骤，然后从反应器的出口除去产物。

10. 发明申请

US20140107235A1 Process For The Synthesis Of Methanol 有权
标题翻译：甲醇合成方法
公开(公告)号：US20140107235A1
公开(公告)日：2014-04-17
申请号：US13581709
申请日：2012-02-14
申请人： Timothy Douglas Gamlin
发明人： Timothy Douglas Gamlin
IPC分类号： C07C29/152
CPC分类号： C07C29/152 , B01J8/0415 , B01J8/0496 , B01J8/067 , B01J19/2485 , B01J35/04 , B01J2208/00814 , B01J2219/00038 , B01J2219/0004 , Y02P20/52 , C07C31/04
摘要： In a process for converting synthesis gas to methanol, gas is introduced through an inlet of a tubular reactor. Reactants pass downwardly through at least one reactor tube to an upper surface of a catalyst carrier and into a passage defined by an inner perforated wall of a carrier container before passing radially through the catalyst bed towards a perforated outer container wall. Reaction occurs as synthesis gas contacts the catalyst. Unreacted reactant and product pass out of the container through the outer container wall and then upwardly between the inner surface of a container skirt and an outer annular container wall, and then over the end of the skirt and downwardly between the outer surface of the skirt and the inner surface of the reactor tube where heat transfer takes place. The steps are repeated at any subsequent catalyst carrier and then product is removed from the reactor outlet.
摘要翻译：在将合成气转化为甲醇的方法中，通过管式反应器的入口引入气体。反应物通过至少一个反应器管到催化剂载体的上表面并进入由载体容器的内部穿孔壁限定的通道中，然后在径向通过催化剂床之前穿过穿孔的外部容器壁。当合成气与催化剂接触时，会发生反应。未反应的反应物和产物通过外部容器壁从容器中流出，然后在容器裙部的内表面和外部环形容器壁之间向上，然后在裙部的端部之上，并且在裙部的外表面和反应器管的内表面发生热传递。在任何随后的催化剂载体上重复这些步骤，然后从反应器出口除去产物。

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