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1. 发明申请

US20100286000A1 Nano-Sized Particle-Coated Proppants for Formation Fines Fixation in Proppant Packs 有权
标题翻译：纳米尺寸颗粒涂层支撑剂，用于支撑剂填充物中的细粉固定
公开(公告)号：US20100286000A1
公开(公告)日：2010-11-11
申请号：US12776990
申请日：2010-05-10
申请人： Tianping Huang , James B. Crews , John R. Willingham , James R. Pace , Christopher K. Belcher
发明人： Tianping Huang , James B. Crews , John R. Willingham , James R. Pace , Christopher K. Belcher
IPC分类号： C09K8/82
CPC分类号： C09K8/575 , C09K8/516 , C09K8/565 , C09K8/572 , C09K8/665 , C09K8/68 , C09K8/805 , C09K2208/10 , E21B43/267
摘要： A fracturing fluid, gravel pack fluid and/or frac pack fluid containing particles such as proppants, gravel and/.or sand, may contain an effective amount of a nano-sized particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The nano-sized particulate additive is optionally bound to the particles with a coating agent such as an oil, alcohol, glycol, glycol ethers, ketones, terpenes, etc. The particle size of the magnesium oxide or other agent may be nanometer scale but may be a larger scale than nanometer but still relatively small, which scale may provide unique particle charges that help fixate the formation fines. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based.
摘要翻译：包含颗粒如支撑剂，砾石和/或砂的压裂液，砾石充填液和/或压裂填料流体可能含有有效量的纳米级颗粒添加剂来固定或减少细粉迁移，其中颗粒添加剂是碱土金属氧化物，碱土金属氢氧化物，碱金属氧化物，碱金属氢氧化物过渡金属氧化物，过渡金属氢氧化物，后过渡金属氧化物，后过渡金属氢氧化物压电晶体和热电晶体。纳米级颗粒添加剂任选地与涂覆剂如油，醇，乙二醇，二醇醚，酮，萜烯等结合到颗粒上。氧化镁或其它试剂的粒度可以是纳米级，但是比纳米尺寸更大，但仍然相对较小，这种规模可以提供独特的颗粒电荷，有助于确定成矿细粉。在处理流体中使用的载体流体可以是水性，盐水，醇或烃类。

2. 发明申请

US20130157906A1 Nano-Sized Particle-Coated Proppants for Formation Fines Fixation in Proppant Packs 有权
标题翻译：纳米尺寸颗粒涂层支撑剂，用于支撑剂填充物中的细粉固定
公开(公告)号：US20130157906A1
公开(公告)日：2013-06-20
申请号：US13771634
申请日：2013-02-20
申请人： Tianping Huang , James B. Crews , John R. Willingham , James R. Pace , Christopher K. Belcher
发明人： Tianping Huang , James B. Crews , John R. Willingham , James R. Pace , Christopher K. Belcher
IPC分类号： C09K8/575 , C09K8/57 , C09K8/565
CPC分类号： C09K8/575 , C09K8/516 , C09K8/565 , C09K8/572 , C09K8/665 , C09K8/68 , C09K8/805 , C09K2208/10 , E21B43/267
摘要： A fracturing fluid, gravel pack fluid and/or frac pack fluid containing particles such as proppants, gravel and/.or sand, may contain an effective amount of a nano-sized particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The nano-sized particulate additive is optionally bound to the particles with a coating agent such as an oil, alcohol, glycol, glycol ethers, ketones, terpenes, etc. The particle size of the magnesium oxide or other agent may be nanometer scale but may be a larger scale than nanometer but still relatively small, which scale may provide unique particle charges that help fixate the formation fines. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based.
摘要翻译：包含颗粒如支撑剂，砾石和/或砂的压裂液，砾石充填液和/或压裂填料流体可能含有有效量的纳米级颗粒添加剂来固定或减少细粉迁移，其中颗粒添加剂为碱土金属氧化物，碱土金属氢氧化物，碱金属氧化物，碱金属氢氧化物过渡金属氧化物，过渡金属氢氧化物，后过渡金属氧化物，后过渡金属氢氧化物压电晶体和热电晶体。纳米级颗粒添加剂任选地与涂覆剂如油，醇，乙二醇，二醇醚，酮，萜烯等结合到颗粒上。氧化镁或其它试剂的粒度可以是纳米级，但是比纳米尺寸更大，但仍然相对较小，这种规模可以提供独特的颗粒电荷，有助于确定成矿细粉。在处理流体中使用的载体流体可以是水性，盐水，醇或烃类。

3. 发明授权

US08397812B2 Nano-sized particle-coated proppants for formation fines fixation in proppant packs 有权
标题翻译：纳米尺寸颗粒涂层的支撑剂，用于在支撑剂包中形成细粉固定
公开(公告)号：US08397812B2
公开(公告)日：2013-03-19
申请号：US12776990
申请日：2010-05-10
申请人： Tianping Huang , James B. Crews , John R. Willingham , James R. Pace , Christopher K. Belcher
发明人： Tianping Huang , James B. Crews , John R. Willingham , James R. Pace , Christopher K. Belcher
IPC分类号： E21B43/04 , E21B43/267
CPC分类号： C09K8/575 , C09K8/516 , C09K8/565 , C09K8/572 , C09K8/665 , C09K8/68 , C09K8/805 , C09K2208/10 , E21B43/267
摘要： A fracturing fluid, gravel pack fluid and/or frac pack fluid containing particles such as proppants, gravel and/.or sand, may contain an effective amount of a nano-sized particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The nano-sized particulate additive is optionally bound to the particles with a coating agent such as an oil, alcohol, glycol, glycol ethers, ketones, terpenes, etc. The particle size of the magnesium oxide or other agent may be nanometer scale but may be a larger scale than nanometer but still relatively small, which scale may provide unique particle charges that help fixate the formation fines. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based.
摘要翻译：包含颗粒如支撑剂，砾石和/或砂的压裂液，砾石充填液和/或压裂填料流体可能含有有效量的纳米级颗粒添加剂来固定或减少细粉迁移，其中颗粒添加剂为碱土金属氧化物，碱土金属氢氧化物，碱金属氧化物，碱金属氢氧化物过渡金属氧化物，过渡金属氢氧化物，后过渡金属氧化物，后过渡金属氢氧化物压电晶体和热电晶体。纳米级颗粒添加剂任选地与涂覆剂如油，醇，乙二醇，二醇醚，酮，萜烯等结合到颗粒上。氧化镁或其它试剂的粒度可以是纳米级，但是比纳米尺寸更大，但仍然相对较小，这种规模可以提供独特的颗粒电荷，有助于确定成矿细粉。在处理流体中使用的载体流体可以是水性，盐水，醇或烃类。

4. 发明申请

US20120267102A1 Nano-Sized Particles for Formation Fines Fixation 审中-公开
标题翻译：纳米粒子用于形成细粉固定
公开(公告)号：US20120267102A1
公开(公告)日：2012-10-25
申请号：US13415505
申请日：2012-03-08
申请人： Tianping Huang , James B. Crews , John R. Willingham , Christopher K. Belcher
发明人： Tianping Huang , James B. Crews , John R. Willingham , Christopher K. Belcher
IPC分类号： C09K8/62 , E21B43/00 , C09K8/72 , C09K8/60 , B82Y30/00
CPC分类号： C09K8/516 , C09K8/032 , C09K8/665 , C09K8/68 , C09K8/74 , C09K2208/10
摘要： A treating fluid may contain an effective amount of a particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The particle size of the magnesium oxide or other agent may be nanometer scale, which scale may provide unique particle charges that help fixate the formation fines. These treating fluids may be used as treatment fluids for subterranean hydrocarbon formations, such as in hydraulic fracturing, completion fluids, gravel packing fluids and fluid loss pills. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based.
摘要翻译：处理流体可以含有有效量的微粒添加剂以固定或减少细粉迁移，其中颗粒添加剂是碱土金属氧化物碱土金属氢氧化物，碱金属氧化物，碱金属氢氧化物过渡金属氧化物，过渡金属氢氧化物，柱过渡金属氧化物，过渡金属氢氧化物压电晶体和热电晶体。氧化镁或其他试剂的粒度可以是纳米级，其规模可以提供有助于固定细粉的独特的颗粒电荷。这些处理流体可以用作地下烃地层的处理流体，例如在水力压裂，完井液，砾石填充液和流体损失丸中。在处理流体中使用的载体流体可以是水性，盐水，醇或烃类。

5. 发明申请

US20090312201A1 Nano-Sized Particles for Formation Fines Fixation 审中-公开
标题翻译：纳米粒子用于形成细粉固定
公开(公告)号：US20090312201A1
公开(公告)日：2009-12-17
申请号：US11931706
申请日：2007-10-31
申请人： Tianping Huang , James B. Crews , John R. Willingham , Christopher K. Belcher
发明人： Tianping Huang , James B. Crews , John R. Willingham , Christopher K. Belcher
IPC分类号： C09K8/92 , C09K8/64 , C09K8/62 , C09K8/80 , C09K8/72
CPC分类号： C09K8/516 , C09K8/665 , C09K8/68 , C09K8/80 , C09K2208/10
摘要： A treating fluid may contain an effective amount of a particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The particle size of the magnesium oxide or other agent may be nanometer scale, which scale may provide unique particle charges that help fixate the formation fines. These treating fluids may be used as treatment fluids for subterranean hydrocarbon formations, such as in hydraulic fracturing, completion fluids, gravel packing fluids and fluid loss pills. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based.
摘要翻译：处理流体可以含有有效量的微粒添加剂以固定或减少细粉迁移，其中颗粒添加剂是碱土金属氧化物碱土金属氢氧化物，碱金属氧化物，碱金属氢氧化物过渡金属氧化物，过渡金属氢氧化物，柱过渡金属氧化物，过渡金属氢氧化物压电晶体和热电晶体。氧化镁或其他试剂的粒度可以是纳米级，其规模可以提供有助于固定细粉的独特的颗粒电荷。这些处理流体可以用作地下烃地层的处理流体，例如在水力压裂，完井液，砾石填充液和流体损失丸中。在处理流体中使用的载体流体可以是水性，盐水，醇或烃类。

6. 发明申请

US20090107673A1 Nano-Sized Particle-Coated Proppants for Formation Fines Fixation in Proppant Packs 有权
标题翻译：纳米尺寸颗粒涂层支撑剂，用于支撑剂填充物中的细粉固定
公开(公告)号：US20090107673A1
公开(公告)日：2009-04-30
申请号：US11931501
申请日：2007-10-31
申请人： Tianping Huang , James B. Crews , John R. Willingham , James R. Pace , Christopher K. Belcher
发明人： Tianping Huang , James B. Crews , John R. Willingham , James R. Pace , Christopher K. Belcher
IPC分类号： E21B43/267
CPC分类号： C09K8/516 , C09K8/665 , C09K8/68 , C09K8/805 , E21B43/267
摘要： A fracturing fluid, gravel pack fluid and/or frac pack fluid containing particles such as proppants, gravel and/or sand, may contain an effective amount of a nano-sized particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides, transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The nano-sized particulate additive is bound to the particles with a coating agent such as an oil. The particle size of the magnesium oxide or other agent may be nanometer scale, which scale may provide unique particle charges that help fixate the formation fines. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based.
摘要翻译：包含颗粒如支撑剂，砾石和/或砂的压裂液，砾石充填液和/或压裂填料液可能含有有效量的纳米级颗粒添加剂来固定或减少细粉迁移，其中颗粒添加剂为碱土金属氧化物，碱土金属氢氧化物，碱金属氧化物，碱金属氢氧化物，过渡金属氧化物，过渡金属氢氧化物，后过渡金属氧化物，过渡金属氢氧化物压电晶体和热电晶体。纳米尺寸的颗粒添加剂与涂覆剂例如油结合到颗粒上。氧化镁或其他试剂的粒度可以是纳米级，其规模可以提供有助于固定细粉的独特的颗粒电荷。在处理流体中使用的载体流体可以是水性，盐水，醇或烃类。

7. 发明授权

US07721803B2 Nano-sized particle-coated proppants for formation fines fixation in proppant packs 有权
标题翻译：纳米尺寸颗粒涂层的支撑剂，用于在支撑剂包中形成细粉固定
公开(公告)号：US07721803B2
公开(公告)日：2010-05-25
申请号：US11931501
申请日：2007-10-31
申请人： Tianping Huang , James B. Crews , John R. Willingham , James R. Pace , Christopher K. Belcher
发明人： Tianping Huang , James B. Crews , John R. Willingham , James R. Pace , Christopher K. Belcher
IPC分类号： E21B43/04 , E21B43/267
CPC分类号： C09K8/516 , C09K8/665 , C09K8/68 , C09K8/805 , E21B43/267
摘要： A fracturing fluid, gravel pack fluid and/or frac pack fluid containing particles such as proppants, gravel and/or sand, may contain an effective amount of a nano-sized particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides, transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The nano-sized particulate additive is bound to the particles with a coating agent such as an oil. The particle size of the magnesium oxide or other agent may be nanometer scale, which scale may provide unique particle charges that help fixate the formation fines. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based.
摘要翻译：包含颗粒如支撑剂，砾石和/或砂的压裂液，砾石充填液和/或压裂填料液可能含有有效量的纳米级颗粒添加剂来固定或减少细粉迁移，其中颗粒添加剂为碱土金属氧化物，碱土金属氢氧化物，碱金属氧化物，碱金属氢氧化物，过渡金属氧化物，过渡金属氢氧化物，后过渡金属氧化物，过渡金属氢氧化物压电晶体和热电晶体。纳米尺寸的颗粒添加剂与涂覆剂例如油结合到颗粒上。氧化镁或其他试剂的粒度可以是纳米级，其规模可以提供有助于固定细粉的独特的颗粒电荷。在处理流体中使用的载体流体可以是水性，盐水，醇或烃类。

8. 发明申请

US20120322700A1 Nano-Sized Particles for Stabilizing Viscoelastic Surfactant Fluids 审中-公开
标题翻译：用于稳定粘弹性表面活性剂流体的纳米尺寸颗粒
公开(公告)号：US20120322700A1
公开(公告)日：2012-12-20
申请号：US13597554
申请日：2012-08-29
申请人： James B. Crews , Tianping Huang , James H. Treadway, JR. , John R. Willingham
发明人： James B. Crews , Tianping Huang , James H. Treadway, JR. , John R. Willingham
IPC分类号： C09K8/62
CPC分类号： C09K8/602 , C09K8/665 , C09K8/68 , C09K8/74 , C09K8/845 , C09K8/86 , C09K2208/10 , C09K2208/30
摘要： An aqueous, viscoelastic fluid gelled with a viscoelastic surfactant (VES) is stabilized and improved with an effective amount of an alkaline earth metal oxide alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, and post-transition metal hydroxides. These fluids are more stable and have a reduced or no tendency to precipitate, particularly at elevated temperatures. The additives may reduce the amount of VES required to maintain a given viscosity. These stabilized, enhanced, aqueous viscoelastic fluids may be used as treatment fluids for subterranean hydrocarbon formations, such as in hydraulic fracturing. The particle size of the magnesium oxide or other agent may be nanometer scale, which scale may provide unique particle charges that use chemisorption, crosslinking and/or other chemistries to associate and stabilize the VES fluids.
摘要翻译：用粘弹性表面活性剂（VES）凝胶化的水性粘弹性流体通过有效量的碱土金属氧化物碱土金属氢氧化物，碱金属氧化物，碱金属氢氧化物过渡金属氧化物，过渡金属氢氧化物，转变后稳定和改善金属氧化物和过渡后金属氢氧化物。这些流体更稳定，并且具有降低或没有沉淀的倾向，特别是在升高的温度下。添加剂可以减少维持给定粘度所需的VES的量。这些稳定的，增强的水性粘弹性流体可以用作地下烃地层的处理流体，例如在水力压裂中。氧化镁或其它试剂的粒径可以是纳米级，其规模可以提供使用化学吸附，交联和/或其它化学物质来缔合和稳定VES流体的独特的颗粒电荷。

9. 发明授权

US08403051B2 Stabilizing emulsified acids for carbonate acidizing 有权
标题翻译：稳定乳化酸用于碳酸盐酸化
公开(公告)号：US08403051B2
公开(公告)日：2013-03-26
申请号：US12903802
申请日：2010-10-13
申请人： Tianping Huang , James B. Crews , John R. Willingham , Richard A. Mitchell , Kushal Seth
发明人： Tianping Huang , James B. Crews , John R. Willingham , Richard A. Mitchell , Kushal Seth
IPC分类号： E21B43/16
CPC分类号： C09K8/72 , C09K8/74 , C09K2208/10
摘要： Emulsified acids have been used to increase production rates of oil and gas in carbonate reservoirs through acid fracturing and matrix acidizing operations. An emulsifier is used to emulsify the aqueous acid with an oil, usually diesel. Very small particles, such as colloidal clay particles and/or nanoparticles increase the stability of the emulsified acids over an elevated temperature range.
摘要翻译：已经使用乳化酸通过酸压裂和基体酸化操作来提高碳酸盐岩储层中的油气产量。乳化剂用于通过油（通常为柴油）乳化含水酸。非常小的颗粒，例如胶态粘土颗粒和/或纳米颗粒增加乳化酸在升高的温度范围内的稳定性。

10. 发明申请

US20120090845A1 Stabilizing Emulsified Acids for Carbonate Acidizing 有权
标题翻译：稳定化酸化乳化酸
公开(公告)号：US20120090845A1
公开(公告)日：2012-04-19
申请号：US12903802
申请日：2010-10-13
申请人： Tianping Huang , James B. Crews , John R. Willingham , Richard A. Mitchell , Kushal Seth
发明人： Tianping Huang , James B. Crews , John R. Willingham , Richard A. Mitchell , Kushal Seth
IPC分类号： E21B43/27 , E21B43/22 , C09K8/58
CPC分类号： C09K8/72 , C09K8/74 , C09K2208/10
摘要： Emulsified acids have been used to increase production rates of oil and gas in carbonate reservoirs through acid fracturing and matrix acidizing operations. An emulsifier is used to emulsify the aqueous acid with an oil, usually diesel. Very small particles, such as colloidal clay particles and/or nanoparticles increase the stability of the emulsified acids over an elevated temperature range.
摘要翻译：已经使用乳化酸通过酸压裂和基体酸化操作来提高碳酸盐岩储层中的油气产量。乳化剂用于通过油（通常为柴油）乳化含水酸。非常小的颗粒，例如胶态粘土颗粒和/或纳米颗粒增加乳化酸在升高的温度范围内的稳定性。

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