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    • 1. 发明授权
    • Ink jet printing process
    • 喷墨打印过程
    • US06871945B2
    • 2005-03-29
    • US10354258
    • 2003-01-29
    • Thomas W. SmithKathleen M. McGraneDavid J. LucaWilliam W. Limburg
    • Thomas W. SmithKathleen M. McGraneDavid J. LucaWilliam W. Limburg
    • B41J2/01B41J2/14B41J2/155B41J2/175B41J2/21B41M5/00C09D11/00B41J2/17
    • B41M7/0018B41J2/14008B41J2/155B41J2/17523B41J2/2114B41J2202/20B41M5/0023
    • A process comprising incorporating into an ink jet printing apparatus a developing composition; an oxidizing composition a coloring composition; and a fixing composition; ejecting droplets of the developing composition onto the substrate; ejecting droplets of the oxidizing composition onto the substrate; ejecting droplets of the coloring composition onto the substrate; and ejecting droplets of the fixing composition onto the substrate; wherein the process results in at least some portions of the substrate bearing images comprising all four compositions, the portions forming a printed image. Specific embodiments are directed to the realization of continuous tone and gray scale in image by control of the time at which color forming reactions are quenched by controlling the lime period between deposition of the color forming liquids and deposition of the fixing liquid; or control of the extent of color forming reactions by limitation of the quantity of one of the color forming liquids.
    • 一种方法,包括将喷墨打印设备结合到显影组合物中; 氧化组合物,着色组合物; 和定影组合物; 将显影组合物的液滴喷射到基底上; 将氧化组合物的液滴喷射到基底上; 将着色组合物的液滴喷射到基底上; 并将定影组合物的液滴喷射到基底上; 其中所述工艺导致所述基材的至少一些部分承载包含所有四种组合物的图像,所述部分形成印刷图像。 具体实施方案涉及通过控制成色反应淬灭的时间,通过控制成色液体的沉积和沉积定影液之间的石灰周期来实现图像中的连续色调和灰度级; 或通过限制一种成色液体的量来控制着色反应的程度。
    • 2. 发明授权
    • Ink jet printing process
    • 喷墨打印过程
    • US06547380B2
    • 2003-04-15
    • US09911111
    • 2001-07-23
    • Thomas W. SmithKathleen M. McGraneDavid J. LucaWilliam W. Limburg
    • Thomas W. SmithKathleen M. McGraneDavid J. LucaWilliam W. Limburg
    • B41J217
    • B41M7/0018B41J2/14008B41J2/155B41J2/17523B41J2/2114B41J2202/20B41M5/0023
    • A process comprising (a) incorporating into an ink jet printing apparatus (1) a developing composition comprising a liquid vehicle and a color developer; (2) an oxidizing composition comprising a liquid vehicle and an oxidizing agent; (3) a coloring composition comprising a liquid vehicle and a dye coupler; and (4) a fixing composition comprising a liquid vehicle and a fixative; (b) causing droplets of the developing composition to be ejected in an imagewise pattern onto the substrate; (c) causing droplets of the oxidizing composition to be ejected in an imagewise pattern onto the substrate; (d) causing droplets of the coloring composition to be ejected in an imagewise pattern onto the substrate; and (e) causing droplets of the fixing composition to be ejected in an imagewise pattern onto the substrate; wherein the process results in at least some portions of the substrate bearing images comprising all four of the developing composition, the oxidizing composition, the coloring composition, and the fixing composition, said portions forming a printed image. Specific embodiments of the present invention are directed to the realization of continuous tone and gray scale in images by (1) control of the time at which color forming reactions are quenched by controlling the time period between deposition of the color forming liquids and deposition of the fixing liquid; (2) control of the extent of color forming reactions by limitation of the quantity of one of the color forming liquids; or (3) control of pixel size by drop placement control over the overlap areas of drops of color forming liquids.
    • 一种方法,包括(a)将包含液体载体和彩色显影剂的显影组合物结合到喷墨打印设备(1)中; (2)包含液体载体和氧化剂的氧化组合物; (3)包含液体载体和染料偶合剂的着色组合物; 和(4)包含液体载体和固定剂的定影组合物; (b)使显影组合物的液滴以成像图案喷射到基材上; (c)使氧化组合物的液滴以成像图案喷射到基材上; (d)使着色组合物的液滴以成像图案喷射到基材上; 和(e)使定影组合物的液滴以成像图案喷射到基底上; 其中所述工艺导致所述基材的至少部分部分具有包含显影组合物全部四种,氧化组合物,着色组合物和定影组合物的图像,所述部分形成印刷图像。 本发明的具体实施方案涉及通过以下方式实现图像中的连续色调和灰度级:(1)通过控制成色液体的沉积和沉积成色液体之间的时间来控制成色反应淬火的时间 固定液体 (2)通过限制一种成色液体的量来控制成色反应的程度; 或(3)通过在成色液滴的重叠区域上的放置位置控制来控制像素尺寸。
    • 3. 发明授权
    • Ink jet printing process
    • 喷墨打印过程
    • US06312121B1
    • 2001-11-06
    • US09152100
    • 1998-09-11
    • Thomas W. SmithKathleen M. McGraneDavid J. LucaWilliam W. Limburg
    • Thomas W. SmithKathleen M. McGraneDavid J. LucaWilliam W. Limburg
    • B41J217
    • B41M7/0018B41J2/14008B41J2/155B41J2/17523B41J2/2114B41J2202/20B41M5/0023
    • A process comprising (a) incorporating into an ink jet printing apparatus (1) a developing composition comprising a liquid vehicle and a color developer; (2) an oxidizing composition comprising a liquid vehicle and an oxidizing agent; (3) a coloring composition comprising a liquid vehicle and a dye coupler; and (4) a fixing composition comprising a liquid vehicle and a fixative; (b) causing droplets of the developing composition to be ejected in an imagewise pattern onto the substrate; (c) causing droplets of the oxidizing composition to be ejected in an imagewise pattern onto the substrate; (d) causing droplets of the coloring composition to be ejected in an imagewise pattern onto the substrate; and (e) causing droplets of the fixing composition to be ejected in an imagewise pattern onto the substrate; wherein the process results in at least some portions of the substrate bearing images comprising all four of the developing composition, the oxidizing composition, the coloring composition, and the fixing composition, said portions forming a printed image. Specific embodiments of the present invention are directed to the realization of continuous tone and gray scale in images by (1) control of the time at which color forming reactions are quenched by controlling the time period between deposition of the color forming liquids and deposition of the fixing liquid; (2) control of the extent of color forming reactions by limitation of the quantity of one of the color forming liquids; or (3) control of pixel size by drop placement control over the overlap areas of drops of color forming liquids.
    • 一种方法,包括(a)将包含液体载体和彩色显影剂的显影组合物结合到喷墨打印设备(1)中; (2)包含液体载体和氧化剂的氧化组合物; (3)包含液体载体和染料偶合剂的着色组合物; 和(4)包含液体载体和固定剂的定影组合物; (b)使显影组合物的液滴以成像图案喷射到基材上; (c)使氧化组合物的液滴以成像图案喷射到基材上; (d)使着色组合物的液滴以成像图案喷射到基材上; 和(e)使定影组合物的液滴以成像图案喷射到基底上; 其中所述工艺导致所述基材的至少部分部分具有包含显影组合物全部四种,氧化组合物,着色组合物和定影组合物的图像,所述部分形成印刷图像。 本发明的具体实施方案涉及通过以下方式实现图像中的连续色调和灰度级:(1)通过控制成色液体的沉积和沉积成色液体之间的时间来控制成色反应淬火的时间 固定液体 (2)通过限制一种成色液体的量来控制成色反应的程度; 或(3)通过在成色液滴的重叠区域上的放置位置控制来控制像素尺寸。
    • 6. 发明授权
    • Ink jet printing process with improved image fixation
    • 喷墨印刷工艺具有改进的图像固定
    • US06270214B1
    • 2001-08-07
    • US09069111
    • 1998-04-29
    • Thomas W. SmithSamuel KaplanKathleen M. McGraneDavid J. Luca
    • Thomas W. SmithSamuel KaplanKathleen M. McGraneDavid J. Luca
    • B41J201
    • B41M5/529B41M5/0017B41M5/508B41M7/0018
    • Disclosed is a process which comprises (a) applying to a substrate a fixing fluid which comprises a material selected from the group consisting of (1) block or graft copolymers of dialkylsiloxanes and polar, hydrophilic monomers capable of interacting with an ink colorant to cause the colorant to become complexed, laked, or mordanted, (2) organopolysiloxane copolymers having functional side groups capable of interacting with an ink colorant to cause the colorant to become complexed, laked, or mordanted, (3) perfluorinated polyalkoxy polymers, (4) perfluoroalkyl surfactants having thereon at least one group capable of interacting with an ink colorant to cause the colorant to become complexed, laked, or mordanted, and (5) mixtures thereof; (b) incorporating into an ink jet printing apparatus an ink composition which comprises water and a colorant which becomes complexed, laked, or mordanted upon contacting the fixing fluid; and (c) causing droplets of the ink composition to be ejected in an imagewise pattern onto the substrate.
    • 公开了一种方法,其包括(a)向基材施加固定流体,所述固定流体包括选自(1)二烷基硅氧烷的嵌段或接枝共聚物和能够与油墨着色剂相互作用的极性亲水单体的材料, (3)全氟化聚烷氧基聚合物,(4)全氟烷基,(3)全氟烷基氧基聚合物,(4)全氟烷基 表面活性剂上具有至少一个能够与油墨着色剂相互作用的基团,使得着色剂变得复合,沉淀或发生混合,和(5)它们的混合物; (b)在喷墨打印设备中引入包含水和着色剂的油墨组合物,所述着色剂在接触固定液体时变得复合,沾污或发生流动; 和(c)使油墨组合物的液滴以成像图案喷射到基材上。